Abdar, M, Zomorodi-Moghadam, M, Zhou, X, Gururajan, R, Tao, X, Barua, PD & Gururajan, R 2020, 'A new nested ensemble technique for automated diagnosis of breast cancer', Pattern Recognition Letters, vol. 132, pp. 123-131.
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Abdollahi, A, Pradhan, B & Alamri, A 2020, 'VNet: An End-to-End Fully Convolutional Neural Network for Road Extraction From High-Resolution Remote Sensing Data', IEEE Access, vol. 8, pp. 179424-179436.
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Abdollahi, A, Pradhan, B, Gite, S & Alamri, A 2020, 'Building Footprint Extraction from High Resolution Aerial Images Using Generative Adversarial Network (GAN) Architecture', IEEE Access, vol. 8, pp. 209517-209527.
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Abdollahi, A, Pradhan, B, Shukla, N, Chakraborty, S & Alamri, A 2020, 'Deep Learning Approaches Applied to Remote Sensing Datasets for Road Extraction: A State-Of-The-Art Review', Remote Sensing, vol. 12, no. 9, pp. 1444-1444.
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One of the most challenging research subjects in remote sensing is feature extraction, such as road features, from remote sensing images. Such an extraction influences multiple scenes, including map updating, traffic management, emergency tasks, road monitoring, and others. Therefore, a systematic review of deep learning techniques applied to common remote sensing benchmarks for road extraction is conducted in this study. The research is conducted based on four main types of deep learning methods, namely, the GANs model, deconvolutional networks, FCNs, and patch-based CNNs models. We also compare these various deep learning models applied to remote sensing datasets to show which method performs well in extracting road parts from high-resolution remote sensing images. Moreover, we describe future research directions and research gaps. Results indicate that the largest reported performance record is related to the deconvolutional nets applied to remote sensing images, and the F1 score metric of the generative adversarial network model, DenseNet method, and FCN-32 applied to UAV and Google Earth images are high: 96.08%, 95.72%, and 94.59%, respectively.
Abdollahi, M, Ghobadian, B, Najafi, G, Hoseini, SS, Mofijur, M & Mazlan, M 2020, 'Impact of water – biodiesel – diesel nano-emulsion fuel on performance parameters and diesel engine emission', Fuel, vol. 280, pp. 118576-118576.
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© 2020 Elsevier Ltd The use of emulsion fuel in the engine has been reported as an effective solution to reduce the harmful emission. This experimental study examined the effects of nano-emulsion biodiesel fuel on engine efficiency, gas emission parameters and combustion parameters of a single-cylinder air-cooled diesel engine. Nano-emulsion fuel made of 5% waste cooking oil biodiesel and 5% distilled water were used to test the performance of the diesel engine. This fuel was produced using ultrasonic waves by stabilizing 5% by volume tween 80 and spans 80 surfactants in HLB8 (Hydrophilic-Lipophilic Balance). Performance parameters and pollutants emission of a diesel engine using nano-emulsion fuel were compared with emulsion fuel. This test was performed on four different engine loads (25%, 50%, 75%, and 100%) at different speeds of 1700, 2000, 2300, and 2600 rpm. Power, torque, cylinder pressure levels, and emissions including soot opacity, carbon monoxide (CO), unburned hydrocarbon (UHC), carbon dioxide (CO2), and nitrogen oxides (NOX) were measured. The test results show that diesel engine power and torque using nano-emulsion fuel improved by about 4.84% and 4.65% compared to emulsion fuel, respectively. The use of nano-emulsion fuel significantly decreased CO (~11%), UHCs (~6%), NOx (~9%) and soot opacity (~10%) emission. However, a small rise in CO2 (~7%) emission was observed. The combustion result shows that nano-emulsion fuel creates more cylinder pressure (CP) than emulsion fuel during combustion. The highest CP was recorded at 10° crank angle after the top dead centre with diesel fuel. Finally, nano-emulsion fuel can be a satisfactory alternative to diesel fuel in a diesel engine without having to change the engine.
Abraham, MT, Satyam, N, Bulzinetti, MA, Pradhan, B, Pham, BT & Segoni, S 2020, 'Using Field-Based Monitoring to Enhance the Performance of Rainfall Thresholds for Landslide Warning', Water, vol. 12, no. 12, pp. 3453-3453.
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Landslides are natural disasters which can create major setbacks to the socioeconomic of a region. Destructive landslides may happen in a quick time, resulting in severe loss of lives and properties. Landslide Early Warning Systems (LEWS) can reduce the risk associated with landslides by providing enough time for the authorities and the public to take necessary decisions and actions. LEWS are usually based on statistical rainfall thresholds, but this approach is often associated to high false alarms rates. This manuscript discusses the development of an integrated approach, considering both rainfall thresholds and field monitoring data. The method was implemented in Kalimpong, a town in the Darjeeling Himalayas, India. In this work, a decisional algorithm is proposed using rainfall and real-time field monitoring data as inputs. The tilting angles measured using MicroElectroMechanical Systems (MEMS) tilt sensors were used to reduce the false alarms issued by the empirical rainfall thresholds. When critical conditions are exceeded for both components of the systems (rainfall thresholds and tiltmeters), authorities can issue an alert to the public regarding a possible slope failure. This approach was found effective in improving the performance of the conventional rainfall thresholds. We improved the efficiency of the model from 84% (model based solely on rainfall thresholds) to 92% (model with the integration of field monitoring data). This conceptual improvement in the rainfall thresholds enhances the performance of the system significantly and makes it a potential tool that can be used in LEWS for the study area.
Abraham, MT, Satyam, N, Kushal, S, Rosi, A, Pradhan, B & Segoni, S 2020, 'Rainfall Threshold Estimation and Landslide Forecasting for Kalimpong, India Using SIGMA Model', Water, vol. 12, no. 4, pp. 1195-1195.
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Rainfall-induced landslides are among the most devastating natural disasters in hilly terrains and the reduction of the related risk has become paramount for public authorities. Between the several possible approaches, one of the most used is the development of early warning systems, so as the population can be rapidly warned, and the loss related to landslide can be reduced. Early warning systems which can forecast such disasters must hence be developed for zones which are susceptible to landslides, and have to be based on reliable scientific bases such as the SIGMA (sistema integrato gestione monitoraggio allerta—integrated system for management, monitoring and alerting) model, which is used in the regional landslide warning system developed for Emilia Romagna in Italy. The model uses statistical distribution of cumulative rainfall values as input and rainfall thresholds are defined as multiples of standard deviation. In this paper, the SIGMA model has been applied to the Kalimpong town in the Darjeeling Himalayas, which is among the regions most affected by landslides. The objectives of the study is twofold: (i) the definition of local rainfall thresholds for landslide occurrences in the Kalimpong region; (ii) testing the applicability of the SIGMA model in a physical setting completely different from one of the areas where it was first conceived and developed. To achieve these purposes, a calibration dataset of daily rainfall and landslides from 2010 to 2015 has been used; the results have then been validated using 2016 and 2017 data, which represent an independent dataset from the calibration one. The validation showed that the model correctly predicted all the reported landslide events in the region. Statistically, the SIGMA model for Kalimpong town is found to have 92% efficiency with a likelihood ratio of 11.28. This performance was deemed satisfactory, thus SIGMA can be integrated with rainfall forecasting and can be used to develop a l...
Abraham, MT, Satyam, N, Pradhan, B & Alamri, AM 2020, 'Forecasting of Landslides Using Rainfall Severity and Soil Wetness: A Probabilistic Approach for Darjeeling Himalayas', Water, vol. 12, no. 3, pp. 804-804.
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Rainfall induced landslides are creating havoc in hilly areas and have become an important concern for the stakeholders and public. Many approaches have been proposed to derive rainfall thresholds to identify the critical conditions that can initiate landslides. Most of the empirical methods are defined in such a way that it does not depend upon any of the in situ conditions. Soil moisture plays a key role in the initiation of landslides as the pore pressure increase and loss in shear strength of soil result in sliding of soil mass, which in turn are termed as landslides. Hence this study focuses on a Bayesian analysis, to calculate the probability of occurrence of landslides, based on different combinations of severity of rainfall and antecedent soil moisture content. A hydrological model, called Système Hydrologique Européen Transport (SHETRAN) is used for the simulation of soil moisture during the study period and event rainfall-duration (ED) thresholds of various exceedance probabilities were used to characterize the severity of a rainfall event. The approach was used to define two-dimensional Bayesian probabilities for occurrence of landslides in Kalimpong (India), which is a highly landslide susceptible zone in the Darjeeling Himalayas. The study proves the applicability of SHETRAN model for simulating moisture conditions for the study area and delivers an effective approach to enhance the prediction capability of empirical thresholds defined for the region.
Abraham, MT, Satyam, N, Pradhan, B & Alamri, AM 2020, 'IoT-Based Geotechnical Monitoring of Unstable Slopes for Landslide Early Warning in the Darjeeling Himalayas', Sensors, vol. 20, no. 9, pp. 2611-2611.
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In hilly areas across the world, landslides have been an increasing menace, causing loss of lives and properties. The damages instigated by landslides in the recent past call for attention from authorities for disaster risk reduction measures. Development of an effective landslide early warning system (LEWS) is an important risk reduction approach by which the authorities and public in general can be presaged about future landslide events. The Indian Himalayas are among the most landslide-prone areas in the world, and attempts have been made to determine the rainfall thresholds for possible occurrence of landslides in the region. The established thresholds proved to be effective in predicting most of the landslide events and the major drawback observed is the increased number of false alarms. For an LEWS to be successfully operational, it is obligatory to reduce the number of false alarms using physical monitoring. Therefore, to improve the efficiency of the LEWS and to make the thresholds serviceable, the slopes are monitored using a sensor network. In this study, micro-electro-mechanical systems (MEMS)-based tilt sensors and volumetric water content sensors were used to monitor the active slopes in Chibo, in the Darjeeling Himalayas. The Internet of Things (IoT)-based network uses wireless modules for communication between individual sensors to the data logger and from the data logger to an internet database. The slopes are on the banks of mountain rivulets (jhoras) known as the sinking zones of Kalimpong. The locality is highly affected by surface displacements in the monsoon season due to incessant rains and improper drainage. Real-time field monitoring for the study area is being conducted for the first time to evaluate the applicability of tilt sensors in the region. The sensors are embedded within the soil to measure the tilting angles and moisture content at shallow depths. The slopes were monitored continuously during three monsoon seas...
Abraham, MT, Satyam, N, Rosi, A, Pradhan, B & Segoni, S 2020, 'The Selection of Rain Gauges and Rainfall Parameters in Estimating Intensity-Duration Thresholds for Landslide Occurrence: Case Study from Wayanad (India)', Water, vol. 12, no. 4, pp. 1000-1000.
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Recurring landslides in the Western Ghats have become an important concern for authorities, considering the recent disasters that occurred during the 2018 and 2019 monsoons. Wayanad is one of the highly affected districts in Kerala State (India), where landslides have become a threat to lives and properties. Rainfall is the major factor which triggers landslides in this region, and hence, an early warning system could be developed based on empirical rainfall thresholds considering the relationship between rainfall events and their potential to initiate landslides. As an initial step in achieving this goal, a detailed study was conducted to develop a regional scale rainfall threshold for the area using intensity and duration conditions, using the landslides that occurred during the years from 2010 to 2018. Detailed analyses were conducted in order to select the most effective method for choosing a reference rain gauge and rainfall event associated with the occurrence of landslides. The study ponders the effect of the selection of rainfall parameters for this data-sparse region by considering four different approaches. First, a regional scale threshold was defined using the nearest rain gauge. The second approach was achieved by selecting the most extreme rainfall event recorded in the area, irrespective of the location of landslide and rain gauge. Third, the classical definition of intensity was modified from average intensity to peak daily intensity measured by the nearest rain gauge. In the last approach, four different local scale thresholds were defined, exploring the possibility of developing a threshold for a uniform meteo-hydro-geological condition instead of merging the data and developing a regional scale threshold. All developed thresholds were then validated and empirically compared to find the best suited approach for the study area. From the analysis, it was observed that the approach selecting the rain gauge based on the most extrem...
Abu Bakar, MS, Ahmed, A, Jeffery, DM, Hidayat, S, Sukri, RS, Mahlia, TMI, Jamil, F, Khurrum, MS, Inayat, A, Moogi, S & Park, Y-K 2020, 'Pyrolysis of solid waste residues from Lemon Myrtle essential oils extraction for bio-oil production', Bioresource Technology, vol. 318, pp. 123913-123913.
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Solid waste residues from the extraction of essential oils are projected to increase and need to be treated appropriately. Valorization of waste via pyrolysis can generate value-added products, such as chemicals and energy. The characterization of lemon myrtle residues (LMR) highlights their suitability for pyrolysis, with high volatile matter and low ash content. Thermogravimetric analysis/derivative thermogravimetric revealed the maximum pyrolytic degradation of LMR at 335 °C. The pyrolysis of LMR for bio-oil production was conducted in a fixed-bed reactor within a temperature range of 350-550 °C. Gas chromatography-mass spectrometry showed that the bio-oil contained abundant amounts of acetic acid, phenol, 3-methyl-1,2-cyclopentanedione, 1,2-benzenediol, guaiacol, 2-furanmethanol, and methyl dodecanoate. An increase in pyrolysis temperature led to a decrease in organic acid and ketones from 18.09% to 8.95% and 11.99% to 8.75%, respectively. In contrast, guaiacols and anhydrosugars increased from 24.23% to 30.05% and from 3.57% to 7.98%, respectively.
Adanta, D, Fattah, IMR & Muhammad, NM 2020, 'COMPARISON OF STANDARD k-epsilon AND SST k-omega TURBULENCE MODEL FOR BREASTSHOT WATERWHEEL SIMULATION', Journal of Mechanical Science and Engineering, vol. 7, no. 2, pp. 039-044.
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Currently, Computational Fluid Dynamics (CFD) was utilized to predict the performance, geometry optimization or physical phenomena of a breastshot waterwheel. The CFD method requires the turbulent model to predict the turbulent flow. However, until now there is special attention on the effective turbulent model used in the analysis of breastshot waterwheel. This study is to identify the suitable turbulence model for a breatshot waterwheel. The two turbulence models investigated are: standard k-epsilon model and shear stress transport (SST) k-omega. Pressure based and one degrees of freedom (one-DoF) feature was used in this case with 75 Nm, 150 Nm, 225 Nm and 300 Nm as preloads. Based on the results, the standard k-epsilon model gave similar result with the SST k-omega model. Therefore, the simulation for breastshot waterwheel will be efficient if using the standard k-epsilon model because it requires lower computational power than the SST k-omega model. However, to study about physical phenomenon, the SST k-omega model is recommend.
Afshar, A, Jahandari, S, Rasekh, H, Shariati, M, Afshar, A & Shokrgozar, A 2020, 'Corrosion resistance evaluation of rebars with various primers and coatings in concrete modified with different additives', Construction and Building Materials, vol. 262, pp. 120034-120034.
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Corrosion of steel rebars in concrete can reduce the durability of concrete structures in coastal environments. The corrosion rate of these concrete structures can be reduced by using suitable concrete additives and coating on rebars. This paper investigates the corrosion resistance of steel rebars by the addition of pozzolanic materials including fly ash, silica fume, polypropylene fibers, and industrial 2-dimethylaminoethanol (FerroGard 901) inhibitors to the concrete mixture. Three different types of rebars including mild steel rebar st37, and two stainless steel reinforcements, AISI 304 and AISI 316, were used. Various types of primer and coating including alkyd based primer, hot-dip galvanized coatings, alkyd top coating, zinc-rich epoxy primer, polyamide epoxy primer, polyamide epoxy top coating, polyurethane coatings, double layer of epoxy primer and alkyd top coating, and double layer of alkyd primer and alkyd top coating were applied on steel rebars to investigate the effect of coating type on the corrosion resistance of steel rebars in concrete. Polarization tests, electrochemical impedance spectroscopy, compressive strength and color adhesion tests were conducted. The best reinforced concrete mix design for corrosion resistance was the one including the rebar with zinc-rich epoxy primer and 25% fly ash, 10% silica fume, and 3% FerroGard 901 inhibitors by cementitious material weight. Polyurethane was the best coating due to the highest strength and the lowest corrosion rate. Alkyd primer was the weakest coating, although it was the most economical coating system.
Aghayarzadeh, M, Khabbaz, H, Fatahi, B & Terzaghi, S 2020, 'Interpretation of Dynamic Pile Load Testing for Open-Ended Tubular Piles Using Finite-Element Method', International Journal of Geomechanics, vol. 20, no. 2, pp. 04019169-04019169.
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© 2019 American Society of Civil Engineers. For a foundation to perform safely, the ultimate strength of each pile must satisfy the structural and geotechnical requirements. Pile load testing is considered to be a direct method for determining the ultimate geotechnical capacity of piles. In this paper the dynamic and static response of a driven steel pipe pile monitored as part of a highway bridge construction project in New South Wales, Australia, has been simulated and then numerically analyzed using the finite-element method. A continuum numerical model has been established to simulate the dynamic load testing of steel pipe piles with unplugged behavior in which adopting measured soil properties resulted in a reasonable match between the measured and predicted results and without needing random signal matching in an iterative process. Settlement at the head and toe of the pile was then calculated when a static load represented by a dead load plus a heavy platform load of a bridge was applied over the pile head. During the dynamic and static load testing simulation, a hardening soil model with small strain stiffness was used to obtain the best correlation between the large and small strains, which occurred while the pile was under static load and being driven. The numerical predictions obtained using continuum finite-element simulations were then compared with the corresponding predictions obtained from the Case Western Reserve University (CASE) method and CASE Pile Wave Analysis Program (CAPWAP) to evaluate the predictions. The results show that the hardening soil model with small strain stiffness exhibits a reasonable correlation with the field measurements during static and dynamic loading. Moreover, parametric studies have been carried out in the established continuum numerical model to evaluate how the interface properties between the pile and soil and the reference shear strain define the backbone on the velocity at the head of the pile and trac...
Ahmad, HA, Ni, S-Q, Ahmad, S, Zhang, J, Ali, M, Ngo, HH, Guo, W, Tan, Z & Wang, Q 2020, 'Gel immobilization: A strategy to improve the performance of anaerobic ammonium oxidation (anammox) bacteria for nitrogen-rich wastewater treatment', Bioresource Technology, vol. 313, pp. 123642-123642.
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Anaerobic ammonium oxidation (anammox) process appears a suitable substitute to nitrification-denitrification at a lower C/N ratios. Anammox is a chemolithoautotrophic process, belong to phylum Planctomycetes, and they are slow growing bacteria. Different strategies, e.g., biofilm formation, granulation and gel immobilization, have been applied to maintain a critical mass of bacterial cells in the system by avoiding washout from the bioreactor. Gel immobilization of anammox appears the best alternative to the natural process of biofilm formation and granulation. Polyvinyl alcohol-sodium alginate, polyethylene glycol, and waterborne polyurethane are the most reported materials used for the entrapment of anammox bacteria. However, dissolution of the gel beads refrains its application for long term bioprocess. Magnetic powder could coat on the surface of the beads which may increase the mechanical strength and durability of pellets. Application and problem of immobilization technology for the commercialization of this technology also addressed.
Ahmed, JB, Salisu, A, Pradhan, B & Alamri, AM 2020, 'Do Termitaria Indicate the Presence of Groundwater? A Case Study of Hydrogeophysical Investigation on a Land Parcel with Termite Activity', Insects, vol. 11, no. 11, pp. 728-728.
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Termite nests have long been suggested to be good indicators of groundwater but only a few studies are available to demonstrate the relationship between the two. This study therefore aims at investigating the most favourable spots for locating groundwater structures on a small parcel of land with conspicuous termite activity. To achieve this, geophysical soundings using the renowned vertical electrical sounding (VES) technique was carried out on the gridded study area. A total of nine VESs with one at the foot of a termitarium were conducted. The VES results were interpreted and assessed via two different techniques: (1) physical evaluation as performed by drillers in the field and (2) integration of primary and secondary geoelectrical parameters in a geographic information system (GIS). The result of the physical evaluation indicated a clear case of subjectivity in the interpretation but was consistent with the choice of VES points 1 and 6 (termitarium location) as being the most prospective points to be considered for drilling. Similarly, the integration of the geoelectrical parameters led to the mapping of the most prospective groundwater portion of the study area with the termitarium chiefly in the center of the most suitable region. This shows that termitaria are valuable landscape features that can be employed as biomarkers in the search of groundwater.
Ahmed, MB, Alam, MM, Zhou, JL, Xu, B, Johir, MAH, Karmakar, AK, Rahman, MS, Hossen, J, Hasan, ATMK & Moni, MA 2020, 'Advanced treatment technologies efficacies and mechanism of per- and poly-fluoroalkyl substances removal from water', Process Safety and Environmental Protection, vol. 136, pp. 1-14.
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© 2020 Institution of Chemical Engineers The increasing occurrence of chemically resistant per- and poly-fluoroalkyl substances (PFASs) in the natural environment, animal tissues and even the human body poses a significant health risk. Temporal trend studies on water, sediments, bird, fish, marine mammal and the human show that the exposure of PFAS has significantly increased over the last 20–30 years. Different physical, biological and chemical treatment processes have been investigated for PFAS removal from water. However, there is a lack of detailed understating of the mechanism of removal by different methods, especially by different advanced chemical treatment processes. This article reviews PFASs removal efficacy and mechanism by the advanced chemical treatment methods from aqueous solution. Review shows that several advanced oxidation processes (e.g., electrochemical oxidation, activated persulfate oxidation, photocatalysis, UV-induced oxidation) are successful in degrading PFASs. Moreover, defluorination treatment, some thermal and non-thermal degradation processes are also found to be prominent for the degradation of PFASs with some limitations including process costs over physical treatment (e.g., sorption), production of toxic by-products and greenhouse gases. Finally, knowledge gaps concerning the advanced chemical treatment of PFASs are discussed.
Ahmed, MB, Johir, MAH, McLaughlan, R, Nguyen, LN, Xu, B & Nghiem, LD 2020, 'Per- and polyfluoroalkyl substances in soil and sediments: Occurrence, fate, remediation and future outlook', Science of The Total Environment, vol. 748, pp. 141251-141251.
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Akther, N, Ali, SM, Phuntsho, S & Shon, H 2020, 'Surface modification of thin-film composite forward osmosis membranes with polyvinyl alcohol–graphene oxide composite hydrogels for antifouling properties', Desalination, vol. 491, pp. 114591-114591.
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© 2020 Elsevier B.V. In this study, the polyamide (PA) layers of commercial thin-film composite (TFC) forward osmosis (FO) membranes were coated with glutaraldehyde cross-linked polyvinyl alcohol (PVA) hydrogel comprising of graphene oxide (GO) at various loadings to enhance their fouling resistance. The optimal GO concentration of 0.02 wt% in hydrogel solution was confirmed from the FO membrane performance, and its influence on membrane antifouling properties was studied. The properties of the modified membranes, such as surface morphology, surface charge and wettability, were also investigated. PVA/GO coating was observed to increase the smoothness and hydrophilicity of the membrane surface. The foulant resistances of the pristine, PVA-coated and PVA/GO-coated membranes were also reported. PVA hydrogel-coated TFC membrane with a GO loading of 0.02 wt% showed a 55% reduction in specific reverse solute flux, only a marginal reduction in the water flux, and the best antifouling property with a 58% higher flux recovery than the pristine TFC membrane. The significant improvement in the selectivity of the modified membranes meant that the hydrogel coating could be used to seal PA defects. The biocidal GO flakes in PVA hydrogel coating also improved the biofouling resistance of the modified membranes, which could be attributed to their morphologies and superior surface properties.
Akther, N, Yuan, Z, Chen, Y, Lim, S, Phuntsho, S, Ghaffour, N, Matsuyama, H & Shon, H 2020, 'Influence of graphene oxide lateral size on the properties and performances of forward osmosis membrane', Desalination, vol. 484, pp. 114421-114421.
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Al-Abadi, AM & Pradhan, B 2020, 'In flood susceptibility assessment, is it scientifically correct to represent flood events as a point vector format and create flood inventory map?', Journal of Hydrology, vol. 590, pp. 125475-125475.
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© 2020 Elsevier B.V. In this discussion article, we try to highlight and discuss the wrong way for representing an areal phenomenon “flood” as a point vector format in GIS-based flood susceptibility studies and creating what is called “flood inventory map”. Two examples from the literature were taken to show that a flood event cannot be represented by point except with very small map scales (1: 10000000) and this flood event should be with other flood events to form the “flood inventory map”. With the help of the other two examples from the previous studies, this article showed the wrong used way for representing flood worldwide and suggested an appropriate method for mapping flood susceptibility.
Alam, MM, Hossain, MA, Hossain, MD, Johir, MAH, Hossen, J, Rahman, MS, Zhou, JL, Hasan, ATMK, Karmakar, AK & Ahmed, MB 2020, 'The Potentiality of Rice Husk-Derived Activated Carbon: From Synthesis to Application', Processes, vol. 8, no. 2, pp. 203-203.
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Activated carbon (AC) has been extensively utilized as an adsorbent over the past few decades. AC has widespread applications, including the removal of different contaminants from water and wastewater, and it is also being used in capacitors, battery electrodes, catalytic supports, and gas storage materials because of its specific characteristics e.g., high surface area with electrical properties. The production of AC from naturally occurring precursors (e.g., coal, biomass, coconut shell, sugarcane bagasse, and so on) is highly interesting in terms of the material applications in chemistry; however, recently much focus has been placed on the use of agricultural wastes (e.g., rice husk) to produce AC. Rice husk (RH) is an abundant as well as cheap material which can be converted into AC for various applications. Various pollutants such as textile dyes, organic contaminants, inorganic anions, pesticides, and heavy metals can be effectively removed by RH-derived AC. In addition, RH-derived AC has been applied in supercapacitors, electrodes for Li-ion batteries, catalytic support, and energy storage, among other uses. Cost-effective synthesis of AC can be an alternative for AC production. Therefore, this review mainly covers different synthetic routes and applications of AC produced from RH precursors. Different environmental, catalytic, and energy applications have been pinpointed. Furthermore, AC regeneration, desorption, and relevant environmental concerns have also been covered. Future scopes for further research and development activities are also discussed. Overall, it was found that RH-derived AC has great potential for different applications which can be further explored at real scales, i.e., for industrial applications in the future.
Alhathal Alanezi, A, Alqahs Alanezi, Y, Alazmi, R, Altaee, A, Alsalhy, QF & Sharif, AO 2020, 'Enhancing performance of the membrane distillation process using air injection zigzag system for water desalination', DESALINATION AND WATER TREATMENT, vol. 207, pp. 43-50.
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A novel design of an air injection zigzag system was developed to enhance the tubular membrane distillation module’s performance for desalination of water, unlike the basic design that works without an air injection system. Designed in a zigzag mode, the membrane distillation module is set to yield a high turbulence flow. Operating parameter effects, e.g. the feed temperature (40, 50, 60, and 70°C), feed concentration (1, 3, and 5 g/L), and airflow rate (30 - 90 L/h), on process performance were investigated. The system proved its capability to enhance the heat and mass transfer coefficients. The basic and developed modules’ performances were compared in terms of permeate flux (Jm) and thermal efficiency (η). The Reynolds Number increased threefold, which consequently, increased the mass transfer coefficient by 25% and the heat transfer coefficient twofold compared to the basic module at air flow rate of 90 (L/h). Moreover, the thermal efficiency and permeate flux were higher than the basic module’s by roughly 1.4 and 1.5-fold, respectively, for a 5 g/L feed concentration.
Alhathal Alanezi, A, Altaee, A & Sharif, AO 2020, 'The effect of energy recovery device and feed flow rate on the energy efficiency of reverse osmosis process', Chemical Engineering Research and Design, vol. 158, pp. 12-23.
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© 2020 Institution of Chemical Engineers The energy requirements for reverse osmosis (RO) seawater desalination continue to be a major matter of debate. Previous studies have shown the dependence of optimum RO desalination energy on the RO recovery rate. However, they overlooked including the effect of Energy Recovery Device (ERD) and pretreatment on the power consumption. In this work, a computer model was used to analyze the energy requirements for RO desalination, taking into account the effect of ERD efficiencies and pretreatment. The specific power consumption (SPC) of the RO was found to increase with the increase of RO recovery rate when the ERD system was included. The optimum SPC became more dependent on the RO recovery rate when the pretreatment energy was added. The recovery for optimum desalination energy was 46%, 44%, and 40% for the RO system coupled with an ERD of 65%, 80%, and 95% efficiency, respectively. The results showed that RO process could be operated at lower recovery rate and still meet the projected desalination capacity by increasing the feed flow rate and coupling with high-efficiency ERD. A trivial decrease of the total desalination energy was achieved when the feed flow rate increased from 7 m3/h to 8 m3/h and recovery rate decreased from 46% to 44% by coupling the RO with an ERD of 95% efficiency. This suggests that the RO–ERD system can be operated at a high feed flow rate and low recovery rate without affecting the plant capacity.
Ali, SM, Qamar, A, Phuntsho, S, Ghaffour, N, Vrouwenvelder, JS & Shon, HK 2020, 'Conceptual design of a dynamic turbospacer for efficient low pressure membrane filtration', Desalination, vol. 496, pp. 114712-114712.
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Al-Jubainawi, A, Ma, Z, Guo, Y & Nghiem, LD 2020, 'Effect of regulating main governing factors on the selectivity membranes of electrodialysis used for LiCl liquid desiccant regeneration', Journal of Building Engineering, vol. 28, pp. 101022-101022.
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Allioux, F-M, Merhebi, S, Ghasemian, MB, Tang, J, Merenda, A, Abbasi, R, Mayyas, M, Daeneke, T, O’Mullane, AP, Daiyan, R, Amal, R & Kalantar-Zadeh, K 2020, 'Bi–Sn Catalytic Foam Governed by Nanometallurgy of Liquid Metals', Nano Letters, vol. 20, no. 6, pp. 4403-4409.
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Metallic foams, with intrinsic catalytic properties, are critical for heterogeneous catalysis reactions and reactor designs. Market ready catalytic foams are costly and made of multimaterial coatings with large sub-millimeter open cells providing insufficient active surface area. Here we use the principle of nanometallurgy within liquid metals to prepare nanostructured catalytic metal foams using a low-cost alloy of bismuth and tin with sub-micrometer open cells. The eutectic bismuth and tin liquid metal alloy was processed into nanoparticles and blown into a tin and bismuth nanophase separated heterostructure in aqueous media at room temperature and using an indium brazing agent. The CO2 electroconversion efficiency of the catalytic foam is presented with an impressive 82% conversion efficiency toward formates at high current density of -25 mA cm-2 (-1.2 V vs RHE). Nanometallurgical process applied to liquid metals will lead to exciting possibilities for expanding industrial and research accessibility of catalytic foams.
Allison‐Logan, S, Fu, Q, Sun, Y, Liu, M, Xie, J, Tang, J & Qiao, GG 2020, 'From UV to NIR: A Full‐Spectrum Metal‐Free Photocatalyst for Efficient Polymer Synthesis in Aqueous Conditions', Angewandte Chemie, vol. 132, no. 48, pp. 21576-21580.
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AbstractPhoto‐mediation offers unparalleled spatiotemporal control over controlled radical polymerizations (CRP). Photo‐induced electron/energy transfer reversible addition–fragmentation chain transfer (PET‐RAFT) polymerization is particularly versatile owing to its oxygen tolerance and wide range of compatible photocatalysts. In recent years, broadband‐ and near‐infrared (NIR)‐mediated polymerizations have been of particular interest owing to their potential for solar‐driven chemistry and biomedical applications. In this work, we present the first example of a novel photocatalyst for both full broadband‐ and NIR‐mediated CRP in aqueous conditions. Well‐defined polymers were synthesized in water under blue, green, red, and NIR light irradiation. Exploiting the oxygen tolerant and aqueous nature of our system, we also report PET‐RAFT polymerization at the microliter scale in a mammalian cell culture medium.
Allison‐Logan, S, Fu, Q, Sun, Y, Liu, M, Xie, J, Tang, J & Qiao, GG 2020, 'From UV to NIR: A Full‐Spectrum Metal‐Free Photocatalyst for Efficient Polymer Synthesis in Aqueous Conditions', Angewandte Chemie International Edition, vol. 59, no. 48, pp. 21392-21396.
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AbstractPhoto‐mediation offers unparalleled spatiotemporal control over controlled radical polymerizations (CRP). Photo‐induced electron/energy transfer reversible addition–fragmentation chain transfer (PET‐RAFT) polymerization is particularly versatile owing to its oxygen tolerance and wide range of compatible photocatalysts. In recent years, broadband‐ and near‐infrared (NIR)‐mediated polymerizations have been of particular interest owing to their potential for solar‐driven chemistry and biomedical applications. In this work, we present the first example of a novel photocatalyst for both full broadband‐ and NIR‐mediated CRP in aqueous conditions. Well‐defined polymers were synthesized in water under blue, green, red, and NIR light irradiation. Exploiting the oxygen tolerant and aqueous nature of our system, we also report PET‐RAFT polymerization at the microliter scale in a mammalian cell culture medium.
Alshahrani, AA, Algamdi, MS, Alsohaimi, IH, Nghiem, LD, Tu, KL, Al-Rawajfeh, AE & in het Panhuis, M 2020, 'The rejection of mono- and di-valent ions from aquatic environment by MWNT/chitosan buckypaper composite membranes: Influences of chitosan concentrations', Separation and Purification Technology, vol. 234, pp. 116088-116088.
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© 2019 Elsevier B.V. Owing to the scarcity of proper drinking water is an urgent problem, MWNT/Chitosan membrane is greeting to reject mono- and di-valent ions from water. MWNT/Chitosan membrane was fabricated through the dispersion of Multi-walled carbon nanotubes (MWNTs) in an aqueous solution containing different concentrations of chitosan. The influence of solution concentration on membrane salt rejection properties, as well as contact angle, electrical conductivity, water permeability, mechanical properties, zeta potential, surface area and internal pores morphologies has been investigated. The resulting buckypaper demonstrate that the contact angle (91° ± 4° to 124° ± 3°), electrical conductivity (17 ± 1 to 83 ± 3 S/cm), water permeability (0.59 ± 0.04 to 5.73 ± 0.3 L/m2 h bar), surface area and internal pores morphologies of the buckypaper membranes were decreased by increasing the concentration of chitosan. While, the mechanical properties (tensile strengths varied between 35 ± 2 and 75 ± 3 MPa) and zeta potential of these buckypaper membranes were found to increase with increasing the amounts of chitosan. A buckypaper fabricated from MWNTs and a high concentration of chitosan (0.4% w/v) showed a higher rejection efficiency for these salts, possibly due to their smaller internal pore volumes and lower specific surface area.
Alshahrani, AA, Alsohaimi, IH, Alshehri, S, Alawady, AR, El-Aassar, MR, Nghiem, LD & Panhuis, MIH 2020, 'Nanofiltration membranes prepared from pristine and functionalised multiwall carbon nanotubes/biopolymer composites for water treatment applications', Journal of Materials Research and Technology, vol. 9, no. 4, pp. 9080-9092.
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Al-Shetwi, AQ, Hannan, MA, Jern, KP, Mansur, M & Mahlia, TMI 2020, 'Grid-connected renewable energy sources: Review of the recent integration requirements and control methods', Journal of Cleaner Production, vol. 253, pp. 119831-119831.
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© 2020 Elsevier Ltd The growing of renewable power generation and integration into the utility grid has started to touch on the security and stability of the power system operation. Hence, the grid integration requirements have become the major concern as renewable energy sources (RESs) such as wind and solar photovoltaic (PV) started to replace the conventional power plant slowly. In line with this, some of the new requirements and technical regulations have been established to ensure grid stability. This study aims to fill the gap and conduct an updating review of the recent integration requirements and compliance control methods regarding the penetration of renewable power plants to the power grid. The review is conducted by a comparing of the key requirements related to voltage stability, frequency stability, voltage ride-through (VRT), power quality, active and reactive power regulations towards grid stability. In order to fulfill these requirements, different control methods have been recently proposed. Accordingly, this paper compares and reviews the state-of-the-art solutions for compliance technology and control methods. Furthermore, a broad discussion on the global harmonization of the integration requirements, challenges, advantages and disadvantages is also highlighted. The rigorous review indicates that although the recent integration requirements can improve the grid operation, stability, security, and reliability, further improvements are still required with respect to protective regulations, global harmonization, and control optimization. Various recommendations for future research related to the integration and technical regulations of RESs are then presented. In sum, the insights provided by this review may aid the development of smooth and stable grid integration of RESs, help developers and researchers to develop the design and control strategies in the sense of current requirements. Additionally, assist power system operators in est...
Altaee, A & AlZainati, N 2020, 'Novel Thermal Desalination Brine Reject-Sewage Effluent Salinity Gradient for Power Generation and Dilution of Brine Reject', Energies, vol. 13, no. 7, pp. 1756-1756.
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Salinity gradient resource presents an essential role for power generated in the process of pressure-retarded osmosis (PRO). Researchers proposed several designs for coupling the PRO process with the desalination plants, particularly reverse osmosis technology for low-cost desalination but there is no study available yet on the utilization of the concentrated brine reject from a thermal desalination plant. This study evaluates the feasibility of power generation in the PRO process using thermal plant brine reject-tertiary sewage effluent (TSE) salinity gradient resource. Power generation in the PRO process was determined for several commercially available FO membranes. Water flux in Oasys Forward Osmosis membrane was more than 31 L/m2h while the average water flux in the Oasys module was 17 L/m2h. The specific power generation was higher in the thin film composite (TFC) membranes compared to the cellulose triacetate (CTA) membranes. The specific power generation for the Oasys membrane was 0.194 kWh/m3, which is 41% of the maximum Gibbs energy of the brine reject-TSE salinity gradient. However, the Hydration Technology Innovation CTA membrane extracted only 0.133 kWh/m3 or 28% of Gibbs free energy of mixing for brine reject-TSE salinity gradient. The study reveals the potential of the brine reject-TSE salinity gradient resource for power generation and the dilution of brine reject.
Altaee, A, Khlaifat, N & Zhou, JL 2020, 'Assessment of wind energy potential at Yanco, New South Wales, Australia', International Journal of Industrial Electronics and Electrical Engineering, vol. 8, no. 1, pp. 26-30.
Arabameri, A, Asadi Nalivan, O, Chandra Pal, S, Chakrabortty, R, Saha, A, Lee, S, Pradhan, B & Tien Bui, D 2020, 'Novel Machine Learning Approaches for Modelling the Gully Erosion Susceptibility', Remote Sensing, vol. 12, no. 17, pp. 2833-2833.
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The extreme form of land degradation caused by the formation of gullies is a major challenge for the sustainability of land resources. This problem is more vulnerable in the arid and semi-arid environment and associated damage to agriculture and allied economic activities. Appropriate modeling of such erosion is therefore needed with optimum accuracy for estimating vulnerable regions and taking appropriate initiatives. The Golestan Dam has faced an acute problem of gully erosion over the last decade and has adversely affected society. Here, the artificial neural network (ANN), general linear model (GLM), maximum entropy (MaxEnt), and support vector machine (SVM) machine learning algorithm with 90/10, 80/20, 70/30, 60/40, and 50/50 random partitioning of training and validation samples was selected purposively for estimating the gully erosion susceptibility. The main objective of this work was to predict the susceptible zone with the maximum possible accuracy. For this purpose, random partitioning approaches were implemented. For this purpose, 20 gully erosion conditioning factors were considered for predicting the susceptible areas by considering the multi-collinearity test. The variance inflation factor (VIF) and tolerance (TOL) limit were considered for multi-collinearity assessment for reducing the error of the models and increase the efficiency of the outcome. The ANN with 50/50 random partitioning of the sample is the most optimal model in this analysis. The area under curve (AUC) values of receiver operating characteristics (ROC) in ANN (50/50) for the training and validation data are 0.918 and 0.868, respectively. The importance of the causative factors was estimated with the help of the Jackknife test, which reveals that the most important factor is the topography position index (TPI). Apart from this, the prioritization of all predicted models was estimated taking into account the training and validation data set, which should help futu...
Arabameri, A, Asadi Nalivan, O, Saha, S, Roy, J, Pradhan, B, Tiefenbacher, JP & Thi Ngo, PT 2020, 'Novel Ensemble Approaches of Machine Learning Techniques in Modeling the Gully Erosion Susceptibility', Remote Sensing, vol. 12, no. 11, pp. 1890-1890.
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Gully erosion has become one of the major environmental issues, due to the severity of its impact in many parts of the world. Gully erosion directly and indirectly affects agriculture and infrastructural development. The Golestan Dam basin, where soil erosion and degradation are very severe problems, was selected as the study area. This research maps gully erosion susceptibility (GES) by integrating four models: maximum entropy (MaxEnt), artificial neural network (ANN), support vector machine (SVM), and general linear model (GLM). Of 1042 gully locations, 729 (70%) and 313 (30%) gully locations were used for modeling and validation purposes, respectively. Fourteen effective gully erosion conditioning factors (GECFs) were selected for spatial gully erosion modeling. Tolerance and variance inflation factors (VIFs) were used to examine the collinearity among the GECFs. The random forest (RF) model was used to assess factors’ effectiveness and significance in gully erosion modeling. An ensemble of techniques can provide more accurate results than can single, standalone models. Therefore, we compared two-, three-, and four-model ensembles (ANN-SVM, GLM-ANN, GLM-MaxEnt, GLM-SVM, MaxEnt-ANN, MaxEnt-SVM, ANN-SVM-GLM, GLM-MaxEnt-ANN, GLM-MaxEnt-SVM, MaxEnt-ANN-SVM and GLM-ANN-SVM-MaxEnt) for GES modeling. The susceptibility zones of the GESMs were classified as very-low, low, medium, high, and very-high using Jenks’ natural break classification method (NBM). Subsequently, the receiver operating characteristics (ROC) curve and the seed cell area index (SCAI) methods measured the reliability of the models. The success rate curve (SRC) and predication rate curve (PRC) and their area under the curve (AUC) values were obtained from the GES maps. The results show that the ANN model combined with two and three models are more accurate than the other combinations, but the ANN-SVM model had the highest accuracy. The rank of the others from best to worst accuracy ...
Arabameri, A, Blaschke, T, Pradhan, B, Pourghasemi, HR, Tiefenbacher, JP & Bui, DT 2020, 'Evaluation of Recent Advanced Soft Computing Techniques for Gully Erosion Susceptibility Mapping: A Comparative Study', Sensors, vol. 20, no. 2, pp. 335-335.
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Gully erosion is a problem; therefore, it must be predicted using highly accurate predictive models to avoid losses caused by gully development and to guarantee sustainable development. This research investigates the predictive performance of seven multiple-criteria decision-making (MCDM), statistical, and machine learning (ML)-based models and their ensembles for gully erosion susceptibility mapping (GESM). A case study of the Dasjard River watershed, Iran uses a database of 306 gully head cuts and 15 conditioning factors. The database was divided 70:30 to train and verify the models. Their performance was assessed with the area under prediction rate curve (AUPRC), the area under success rate curve (AUSRC), accuracy, and kappa. Results show that slope is key to gully formation. The maximum entropy (ME) ML model has the best performance (AUSRC = 0.947, AUPRC = 0.948, accuracy = 0.849 and kappa = 0.699). The second best is the random forest (RF) model (AUSRC = 0.965, AUPRC = 0.932, accuracy = 0.812 and kappa = 0.624). By contrast, the TOPSIS (Technique for Order Preference by Similarity to Ideal Solution) model was the least effective (AUSRC = 0.871, AUPRC = 0.867, accuracy = 0.758 and kappa = 0.516). RF increased the performance of statistical index (SI) and frequency ratio (FR) statistical models. Furthermore, the combination of a generalized linear model (GLM), and functional data analysis (FDA) improved their performances. The results demonstrate that a combination of geographic information systems (GIS) with remote sensing (RS)-based ML models can successfully map gully erosion susceptibility, particularly in low-income and developing regions. This method can aid the analyses and decisions of natural resources managers and local planners to reduce damages by focusing attention and resources on areas prone to the worst and most damaging gully erosion.
Arabameri, A, Cerda, A, Pradhan, B, Tiefenbacher, JP, Lombardo, L & Bui, DT 2020, 'A methodological comparison of head-cut based gully erosion susceptibility models: Combined use of statistical and artificial intelligence', Geomorphology, vol. 359, pp. 107136-107136.
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Arabameri, A, Chen, W, Loche, M, Zhao, X, Li, Y, Lombardo, L, Cerda, A, Pradhan, B & Bui, DT 2020, 'Comparison of machine learning models for gully erosion susceptibility mapping', Geoscience Frontiers, vol. 11, no. 5, pp. 1609-1620.
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© 2019 China University of Geosciences (Beijing) and Peking University Gully erosion is a disruptive phenomenon which extensively affects the Iranian territory, especially in the Northern provinces. A number of studies have been recently undertaken to study this process and to predict it over space and ultimately, in a broader national effort, to limit its negative effects on local communities. We focused on the Bastam watershed where 9.3% of its surface is currently affected by gullying. Machine learning algorithms are currently under the magnifying glass across the geomorphological community for their high predictive ability. However, unlike the bivariate statistical models, their structure does not provide intuitive and quantifiable measures of environmental preconditioning factors. To cope with such weakness, we interpret preconditioning causes on the basis of a bivariate approach namely, Index of Entropy. And, we performed the susceptibility mapping procedure by testing three extensions of a decision tree model namely, Alternating Decision Tree (ADTree), Naïve-Bayes tree (NBTree), and Logistic Model Tree (LMT). We dichotomized the gully information over space into gully presence/absence conditions, which we further explored in their calibration and validation stages. Being the presence/absence information and associated factors identical, the resulting differences are only due to the algorithmic structures of the three models we chose. Such differences are not significant in terms of performances; in fact, the three models produce outstanding predictive AUC measures (ADTree = 0.922; NBTree = 0.939; LMT = 0.944). However, the associated mapping results depict very different patterns where only the LMT is associated with reasonable susceptibility patterns. This is a strong indication of what model combines best performance and mapping for any natural hazard – oriented application.
Arabameri, A, Pradhan, B & Bui, DT 2020, 'Spatial modelling of gully erosion in the Ardib River Watershed using three statistical-based techniques', CATENA, vol. 190, pp. 104545-104545.
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© 2020 Elsevier B.V. Gully erosion threatens land sustainability. Gullies trigger considerable erosion, damaging agricultural land, infrastructure and urban areas; thus, predicting and modelling gully susceptibility is of utmost concern. In particular, such a model is urgently required in semiarid areas where soil loss from gullies is high. Three predictive models are evaluated to assess gully erosion susceptibility mapping (GESM) in Semnan Province, Iran. The index of entropy (IOE), frequency ratio (FR) and certainty factor (CF) models are combined with remote sensing and geographic information system techniques to predict gully erosion. The collation of data from geographic resources identified 287 gullies in the study area. These areas were then randomly divided into 2 groups for calibration (70% or 201 gullies) and validation (30% or 86 gullies). Pairwise linear dependency amongst geoenvironmental factors was also assessed. A total of 16 factors were screened for modelling. Four performance metrics, namely, true skill statistic (TSS), area under the receiver operating characteristic (AUROC) curve, seed cell area index (SCAI) and modified SCAI (mSCAI), were used to evaluate the prediction accuracy and robustness of each model using validation datasets. Bootstrapped replicates were considered in estimating the accuracy and robustness of each model by varying gully/no-gully samples. The IOE results indicated that elevation, lithology and slope angle promoted favourable conditions for gully erosion in the study area. The results showed that the IOE model performed better than the FR and CF models for all three validation datasets (AUROCmean = 0.874 and TSSmean = 0.855). This finding was also confirmed in terms of stability and robustness (RTSS = 0.024 and RAUROC = 0.023). The SCAI and mSCAI results showed that all the models exhibited acceptable accuracy, but IOE demonstrated superior performance. Accordingly, IOE was used as the reference model for the study are...
Arabameri, A, Pradhan, B, Rezaei, K, Lee, S & Sohrabi, M 2020, 'An ensemble model for landslide susceptibility mapping in a forested area', Geocarto International, vol. 35, no. 15, pp. 1680-1705.
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© 2019, © 2019 Informa UK Limited, trading as Taylor & Francis Group. This article proposes a new methodological approach using a combination of expert knowledge-based (analytic hierarchy process, AHP), bivariate (statistical index, SI) and multivariate (linear discriminant analysis, LDA) models for landslide susceptibility mapping (LSM) in Mazandran Province, Iran. Tolerance and variance inflation factor indicators were used for assessing multi-collinearity among parameters, and three (i.e. profile curvature, soil type and topography wetness index) of 18 factors were eliminated because of multi-collinearity issues. Fifteen geo-environmental conditioning factors including elevation, slope degree, slope aspect, plan curvature, slope length, convergence index, stream power index, distance from river, drainage density, distance from road, distance from fault, lithology, rainfall, land use/landcover and normalized difference vegetation index and 321 landslide locations (testing data set, 70% of total landslides) were used for modeling. The importance of factors showed that distance to road (AHP = 0.201, LDA = 0.301) was the most important factor in landslide occurrence. The validation results using validation data set (138 landslide locations, 30% of total landslides) and area under the receiver operating characteristic curve (AUROC) showed that the ensemble models AHP-LDR (83%), AHP-SI (95%) and SI-LDR (83%) had higher prediction accuracies than the individual AHP (82%), SI (82%) and LDA (79%) models and combination of AHP and SI models along with ALOS-PALSAR remote sensing data and geographic information system (GIS) technique provide powerful tool in LSM in the study area. The results of proposed novel methodological framework can be used by decision-makers and forest engineers for forest management spatially forest roads conservation that have key importance in sustainable development in local and regional scales.
Arabameri, A, Saha, S, Chen, W, Roy, J, Pradhan, B & Bui, DT 2020, 'Flash flood susceptibility modelling using functional tree and hybrid ensemble techniques', Journal of Hydrology, vol. 587, pp. 125007-125007.
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© 2020 Elsevier B.V. The present research aims to assess and judge the capability of flash flood susceptibility (FFS) models considering hybrid machine learning ensemble techniques for the FFS assessment in the Gorgan Basin in Iran. Three novel intelligence approaches, namely, bagging–functional tree (BFT), dagging–functional tree, and rotational forest–functional tree are used for modelling, with consideration to 15 flood conditioning factors (FCFs) as independent variables and 426 flood locations as dependent variables. Three threshold-dependent and -independent approaches are used to evaluate the goodness-of-fit and prediction capability of the ensemble models with a single functional tree (FT). These approaches include the area under the receiver operating characteristic curve of the success rate curve (SRC) and prediction rate curve (PRC), efficiency (E) and true skill statistics (TSS). The random forest model is used to determine the relative importance of FCFs. Elevation, stream distance and normalized difference vegetation index (NDVI) have crucial roles in the study area during flash flood occurrences. According to the results of all threshold-dependent and -independent approaches (AUC of SRC = 0.933, AUC of PRC = 0.959, E = 0.76 and TSS = 0.72), the BFT ensemble model has the greatest accuracy in terms of modelling FFS. Results also show that the performance of the FT model is enhanced by three meta-classifiers. The seed cell area index technique is also used to check model classification accuracy and reliability. Results of this technique show that all the models demonstrate good performance and reliability. However, the FFS maps prepared by machine learning ensemble techniques have excellent accuracy and reliability, as per the results of validation methods. Thus, these FFS maps can be used as a convenient tool to reduce the effect of flood in flash flood-prone areas.
Arabameri, A, Saha, S, Roy, J, Tiefenbacher, JP, Cerda, A, Biggs, T, Pradhan, B, Thi Ngo, PT & Collins, AL 2020, 'A novel ensemble computational intelligence approach for the spatial prediction of land subsidence susceptibility', Science of The Total Environment, vol. 726, pp. 138595-138595.
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Arabameri, A, Tiefenbacher, JP, Blaschke, T, Pradhan, B & Tien Bui, D 2020, 'Morphometric Analysis for Soil Erosion Susceptibility Mapping Using Novel GIS-Based Ensemble Model', Remote Sensing, vol. 12, no. 5, pp. 874-874.
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The morphometric characteristics of the Kalvārī basin were analyzed to prioritize sub-basins based on their susceptibility to erosion by water using a remote sensing-based data and a GIS. The morphometric parameters (MPs)—linear, relief, and shape—of the drainage network were calculated using data from the Advanced Land-observing Satellite (ALOS) phased-array L-type synthetic-aperture radar (PALSAR) digital elevation model (DEM) with a spatial resolution of 12.5 m. Interferometric synthetic aperture radar (InSAR) was used to generate the DEM. These parameters revealed the network’s texture, morpho-tectonics, geometry, and relief characteristics. A complex proportional assessment of alternatives (COPRAS)-analytical hierarchy process (AHP) novel-ensemble multiple-criteria decision-making (MCDM) model was used to rank sub-basins and to identify the major MPs that significantly influence erosion landforms of the Kalvārī drainage basin. The results show that in evolutionary terms this is a youthful landscape. Rejuvenation has influenced the erosional development of the basin, but lithology and relief, structure, and tectonics have determined the drainage patterns of the catchment. Results of the AHP model indicate that slope and drainage density influence erosion in the study area. The COPRAS-AHP ensemble model results reveal that sub-basin 1 is the most susceptible to soil erosion (SE) and that sub-basin 5 is least susceptible. The ensemble model was compared to the two individual models using the Spearman correlation coefficient test (SCCT) and the Kendall Tau correlation coefficient test (KTCCT). To evaluate the prediction accuracy of the ensemble model, its results were compared to results generated by the modified Pacific Southwest Inter-Agency Committee (MPSIAC) model in each sub-basin. Based on SCCT and KTCCT, the ensemble model was better at ranking sub-basins than the MPSIAC model, which indicated that sub-basins 1 and 4, with mean sediment ...
Ardalan, RB, Emamzadeh, ZN, Rasekh, H, Joshaghani, A & Samali, B 2020, 'Physical and mechanical properties of polymer modified self-compacting concrete (SCC) using natural and recycled aggregates', Journal of Sustainable Cement-Based Materials, vol. 9, no. 1, pp. 1-16.
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The study researched the effectiveness of four polymer admixtures (3%, 5%, 10%, and 15% of water weight) on the fresh and hardened properties of self-compacting concrete (SCC) cast using recycled and natural aggregates. Results show that polymer additives had positive effects on the fresh properties of SCC using recycled aggregates. Incorporating polymer additives increased the filling ability of concrete by more than four times. All polymer modified SCCs had a 100% passing ability compared to the 80% passing ability of the control samples. The compressive strength of materials at similar polymer ratios decreased by about 50% when natural aggregates were replaced with recycled aggregates. The flexural strength of SCC including recycled aggregates with 15% polymer was maintained compared to the control SCC including natural aggregates. The addition of 15% polymer to recycled aggregates concrete could improve workability and maintain flexural strength.
Arjmandi, A, Peyravi, M, Arjmandi, M & Altaee, A 2020, 'Exploring the use of cheap natural raw materials to reduce the internal concentration polarization in thin-film composite forward osmosis membranes', Chemical Engineering Journal, vol. 398, pp. 125483-125483.
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© 2020 Elsevier B.V. Internal concentration polarization (ICP) is a significant problem in Forward osmosis (FO) membranes, which reduces the water flux. In order to mitigate the ICP phenomenon, rice bran (RB) and wood sawdust (WSD) particles were selected as natural green pore formers and incorporated into the polyethersulfone (PES) matrix to fabricate mixed matrix membranes (MMMs). Fabricated MMMs were used as the porous support layer (SL) to make thin-film composite (TFC) FO membranes. Firstly, the water uptake experiment was performed to evaluate the water adsorption capacity of the RB and WSD particles. Furthermore, all samples were characterized by FTIR, FESEM, AFM, XPS, DLS, static contact angle (CA), and tensile strength. Also, performance tests in reverse osmosis (RO) and the FO units were performed to evaluate the fabricated membranes. The results showed that the use of RB and WSD particles dramatically reduced the structural parameter in all MMMs, resulting in lower ICP effects and high water flux. Due to the softer structure, smaller size, and more water uptake, the RB-based TFC membranes recorded better results. The TFC-RB-5 (with 5% of RB in the SL) was the best membrane with a water flux of about 65.71 L/m2.h for Caspian seawater desalination, while the FO water flux for DI water as the feed solution (FS) was 83.65 L/m2.h. The present study showed the membranes made in this study are competitive with the existing FO membranes and very cost-effective for broad applications.
Arjmandi, M, Altaee, A, Arjmandi, A, Pourafshari Chenar, M, Peyravi, M & Jahanshahi, M 2020, 'A facile and efficient approach to increase the magnetic property of MOF-5', Solid State Sciences, vol. 106, pp. 106292-106292.
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© 2020 Elsevier Masson SAS In this study, a facile and efficient approach to increase the magnetic property of metal-organic framework-5 (MOF-5) has been investigated. The basis of this approach is the encapsulation of cluster-oxygen composition (i.e. ZnO in MOF-5) during the synthesis process of MOF-5 to form ZnO@MOF-5 nanocrystals. Both MOF-5 and ZnO@MOF-5 were synthesized for comparison purposes, considering their magnetic property. The physicochemical properties of MOF-5 and ZnO@MOF-5 were characterized by XRD, FTIR, TGA, DLS, FESEM, and Magnetization measurements. The FTIR spectra confirmed the presence of additional ZnO molecules in the ZnO@MOF-5 structure. Results from the XRD showed that the presence of additional ZnO molecules in the ZnO@MOF-5 altered the structure of MOF-5. The TGA analysis also confirmed the presence of additional ZnO molecules in the ZnO@MOF-5 structure, indicating that the ZnO@MOF-5 contains 15.23 wt% ZnO more than MOF-5. The FESEM and DLS results showed that the average sizes of MOF-5 and ZnO@MOF-5 nanocrystals are below 100 nm, with no defined morphology. Finally, the magnetization measurements showed that the MOF-5 nanocrystals have diamagnetic properties. For ZnO@MOF-5 nanocrystals, a ferromagnetic-like character was observed in the scanned field range and the saturation value of about 2.59 × 10−3 emu/g was obtained. The success of this facile and hassle-free approach can be an important step towards enhancing the magnetic properties of MOFs.
Arjmandi, M, Peyravi, M, Altaee, A, Arjmandi, A, Pourafshari Chenar, M, Jahanshahi, M & Binaeian, E 2020, 'A state-of-the-art protocol to minimize the internal concentration polarization in forward osmosis membranes', Desalination, vol. 480, pp. 114355-114355.
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© 2020 Elsevier B.V. The main reason for the lower water flux, than expected, in the forward osmosis (FO) process, is the internal concentration polarization (DICP). Usually, the structural parameter (S) is used as an indicator of the intensity of DICP. Small S value is desirable for the FO membrane due to the low DICP. However, due to design and construction problems, structural parameter reduction has some drawbacks. In this work, DICP reduction in FO membranes will be investigated using an approach other than structural parameter reduction. Accordingly, during the FO process, the feed solution (FS) valve is opened and closed at a constant period of time (feed valve timing (FVT)). Four types of FO membranes with different S parameters were used. The effects of the implementation of the proposed protocol on the water flux (Jw), reverse salt flux (Js), specific reverse solute flux (Js/Jw) and effective driving force were investigated. The effects of the S parameter and draw solution (DS) concentration also investigated separately. The results showed that the proposed protocol significantly increased Jw. Also, the values of Js/Jw decreased with increasing the FVT values and reached the lowest level in the practical recovery time (PRT).
Arjmandi, M, Pourafshari Chenar, M, Altaee, A, Arjmandi, A, Peyravi, M, Jahanshahi, M & Binaeian, E 2020, 'Caspian seawater desalination and whey concentration through forward osmosis (FO)-reverse osmosis (RO) and FO-FO-RO hybrid systems: Experimental and theoretical study', Journal of Water Process Engineering, vol. 37, pp. 101492-101492.
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Ashok, B, Nanthagopal, K, Chyuan, OH, Le, PTK, khanolkar, K, Raje, N, Raj, A, Karthickeyan, V & Tamilvanan, A 2020, 'Multi-functional fuel additive as a combustion catalyst for diesel and biodiesel in CI engine characteristics', Fuel, vol. 278, pp. 118250-118250.
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© 2020 Elsevier Ltd The present research work aims at investigating the effect of newly developed multifunctional additive with diesel and Calophyllum Inophyllum biodiesel on compression ignition engine characteristics. A newly developed hydrocarbon based multifunctional fuel additive named as “Thermol-D” which comprises of various ingredients at suitable composition like surfactant, demulsifier, lubricity enhancer, dispersant, cetane improver, antioxidant and combustion catalyst. In this present study, the Thermol-D has been doped with conventional diesel and Calophyllum Inophyllum biodiesel at 0.5 ml, 1 ml and 2 ml concentrations. Moreover, the Thermol-D addition with diesel and biodiesel has shown remarkable stability at all concentrations without any phase separation issues. All the fuel comparative analysis is carried out using all the fuel samples at same operating conditions under load variation from No load to full load at constant engine speed. It has been noticed that the doping of Thermol-D with diesel and biodiesel has increased the brake thermal efficiency by 21% and 43% at 100% loading conditions due to the presence of combustion catalyst and cetane improver in the additive. The multifunctional additive presence in the fuel blends is reduced the carbon monoxide and unburnt hydrocarbon emissions by 32–36% and 20% respectively. Furthermore, the oxides of nitrogen emission has also reduced at significant rate in the range of 18–20.5% for 2% Thermol-D addition with diesel and biodiesel. The Thermol-D contains slight fraction of antioxidant and cetane improvers which has resulted in combustion temperature. All the combustion characteristics are improved by the addition of Thermol-D with diesel and biodiesel.
BAHARVAND, S, PARDHAN, B & SOORI, S 2020, 'Evaluation of active tectonics using geomorphic indices in a mountainous basin of Iran', Earth and Environmental Science Transactions of the Royal Society of Edinburgh, vol. 111, no. 2, pp. 109-117.
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ABSTRACTThis study aims to evaluate the tectonic activities of the Vark basin, located in the great basin of Dez River in northwestern Iran, using geomorphologic indices combined with the geographical information system technique. Some geomorphic indices were used to achieve this aim. In this regard, the indices of stream length (SL), drainage asymmetry (Af), hypsometric integral (Hi), valley floor ratio (Vf), basin shape (Bs), and mountain sinuosity (Smf) were estimated to reach an average index of relative tectonics (Iat), indicating the intensity classes of tectonic activity. The mean SL,Hi,Vf, andBsvalues were estimated as 2273, 0.55, 0.45, and 1.75, respectively, regarding the active class of tectonic activity. Therefore, considering theAfandSmfindices with values of 27 and 1.14, the basin was categorised as having semi-active conditions. The overallIat, with a value of 1.33, represented the very high class (1.0 <Iat< 1.5) of tectonic activity. Hence, by calculating the index of relative active tectonics, the study area is observed as the intensive class concerning tectonic movements. Overall, the mean values of theIatfor all sub-basins were calculated as 1.50, 1.17, and 1.83, revealing the very high and high classes of active tectonics in the basin. ...
Bai, X, Sun, B, Wang, X, Zhang, T, Hao, Q, Ni, B-J, Zong, R, Zhang, Z, Zhang, X & Li, H 2020, 'Defective crystal plane-oriented induced lattice polarization for the photocatalytic enhancement of ZnO', CrystEngComm, vol. 22, no. 16, pp. 2709-2717.
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The mechanism of the photocatalytic reaction of defective ZnO systems was determined.
Bai, X, Wang, X, Lu, X, Liang, Y, Li, J, Wu, L, Li, H, Hao, Q, Ni, B-J & Wang, C 2020, 'Surface defective g-C3N4−Cl with unique spongy structure by polarization effect for enhanced photocatalytic removal of organic pollutants', Journal of Hazardous Materials, vol. 398, pp. 122897-122897.
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Natural sponge is an ancient marine organism with a single lamellar structure, on which there are abundant porous channels to compose full-fledged spatial veins. Illumined by the natural spongy system, herein, the Cl doped surface defective graphite carbon nitride (g-C3N4-xClx) was constructed through microwave etching. In this process, microwave with HCl was employed to produce surface defects and peel bulk g-C3N4 to form natural spongy structured g-C3N4-xClx with three-dimensional networks. The spongy structure of the photocatalyst could provide abundant and unobstructed pathways for the transfer and separation of electron-hole pairs, and it was beneficial for photocatalytic reaction. The spongy defective g-C3N4-xClx achieved excellent degradation of diclofenac sodium (100%), bisphenol A (88.2%), phenol (85.7%) and methylene blue (97%) solution under simulated solar irradiation, respectively. The chlorine atoms were introduced into the g-C3N4 skeleton in microwave field with HCl, forming C-Cl bonds and surface polarization field, which could significantly accelerate the separation of photogenerated electrons and holes. As an efficient and universal approach, microwave etching can be generally used to create surface defects for most photocatalysts, which may have potential applications in environmental purification, energy conversion and photodynamic therapy.
Ball, J, Qiuhua, L, Jingming, H, Bingyao, L, Yu, T, Hui, L & Liping, M 2020, 'Cause Analysis for a New Type of Devastating Flash Flood', Hydrology Research: an international journal, vol. 51, no. 1, pp. 1-16.
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This work introduces an unprecedented flash flood that resulted in nine casualties in Shimen Valley, China, 2015. Through field survey and numerical simulation, the causes of the disaster are systematically analyzed, finding that the intense storm, terrain features, and the large woody debris(LWD) played important roles. The intense storm induced fast runoff and, in turn, high discharges as a result of the steep catchment surfaces and channels. The flood flushed LWD and boulders downstream until blockage occurred in a contraction section, forming a debris lake. When the debris dam broke, a dam break wave rapidly propagated to the valley mouth, washing people away. After considering the disaster-inducing factors, measures for preventing similar floods are proposed. The analysis presented herein should help others manage flash floods in mountain areas.
Ball, JE 2020, 'An Assessment of Continuous Modeling for Robust Design Flood Estimation in Urban Environments', Frontiers in Earth Science, vol. 8, p. 124.
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© Copyright © 2020 Ball. Catchment management is a complex task that, over the past decade, has become increasingly important to urban communities. While there are many water related management issues, estimation of the magnitude and likelihood of flood events is one that remains a concern to many mangers of urban drainage systems. Data is an essential component of any approach for estimation of the magnitude and likelihood of design flood characteristics. This data can be obtained from catchment monitoring or catchment modeling with these data sources being complementary rather than competitive. However, the absence of monitored data in urban environments has resulted in the data being obtained predominantly from the use of catchment modeling. Numerous alternative approaches for catchment modeling have been developed; these approaches can be categorized as either single event or continuous models. The philosophical basis behind the use of a continuous modeling approach is the concept that the model predictions will replicate the data that would have been recorded if catchment monitoring were to be undertaken at that location and for the modeled catchment conditions. When using this philosophy, a modeler must determine when the predicted data suitably replicates the true data. Presented herein is an analysis of continuous and event modeling undertaken for design flood estimation in an urban catchment located in Sydney, Australia where monitored data is available to assess the utility of the catchment model. It will be shown that frequency analysis of the predicted flows from the continuous model more closely resemble the frequency analysis of the recorded data.
Balogun, A-L, Yekeen, ST, Pradhan, B & Althuwaynee, OF 2020, 'Spatio-Temporal Analysis of Oil Spill Impact and Recovery Pattern of Coastal Vegetation and Wetland Using Multispectral Satellite Landsat 8-OLI Imagery and Machine Learning Models', Remote Sensing, vol. 12, no. 7, pp. 1225-1225.
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Oil spills are a global phenomenon with impacts that cut across socio-economic, health, and environmental dimensions of the coastal ecosystem. However, comprehensive assessment of oil spill impacts and selection of appropriate remediation approaches have been restricted due to reliance on laboratory experiments which offer limited area coverage and classification accuracy. Thus, this study utilizes multispectral Landsat 8-OLI remote sensing imagery and machine learning models to assess the impacts of oil spills on coastal vegetation and wetland and monitor the recovery pattern of polluted vegetation and wetland in a coastal city. The spatial extent of polluted areas was also precisely quantified for effective management of the coastal ecosystem. Using Johor, a coastal city in Malaysia as a case study, a total of 49 oil spill (ground truth) locations, 54 non-oil-spill locations and Landsat 8-OLI data were utilized for the study. The ground truth points were divided into 70% training and 30% validation parts for the classification of polluted vegetation and wetland. Sixteen different indices that have been used to monitor vegetation and wetland stress in literature were adopted for impact and recovery analysis. To eliminate similarities in spectral appearance of oil-spill-affected vegetation, wetland and other elements like burnt and dead vegetation, Support Vector Machine (SVM) and Random Forest (RF) machine learning models were used for the classification of polluted and nonpolluted vegetation and wetlands. Model optimization was performed using a random search method to improve the models’ performance, and accuracy assessments confirmed the effectiveness of the two machine learning models to identify, classify and quantify the area extent of oil pollution on coastal vegetation and wetland. Considering the harmonic mean (F1), overall accuracy (OA), User’s accuracy (UA), and producers’ accuracy (PA), both models have high accuracies. However, the...
Bao, T, Damtie, MM, Hosseinzadeh, A, Wei, W, Jin, J, Phong Vo, HN, Ye, JS, Liu, Y, Wang, XF, Yu, ZM, Chen, ZJ, Wu, K, Frost, RL & Ni, B-J 2020, 'Bentonite-supported nano zero-valent iron composite as a green catalyst for bisphenol A degradation: Preparation, performance, and mechanism of action', Journal of Environmental Management, vol. 260, pp. 110105-110105.
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Bisphenol A (BPA) is a toxic environmental pollutant commonly found in wastewater. Using non-toxic materials and eco-friendly technology to remove this pollutant from wastewater presents multiple advantages. Treatment of wastewater with clay minerals has received growing interest because of the environment friendliness of these materials. Bentonite is a 2:1 layered phyllosilicate clay mineral that can support nano-metal catalysts. It can prevent the agglomeration of nano-metal catalysts and improve their activity. In this article, a green catalytic nano zero-valent iron/bentonite composite material (NZVI@bentonite) was synthesized via liquid-phase reduction. The average size of NZVI was approximately 40-50 nm. Good dispersion and low aggregation were observed when NZVI was loaded on the surface or embedded into the nanosheets of bentonite. Degradation of BPA, a harmful contaminant widely found in wastewater at relatively high levels, by NZVI@bentonite was then investigated and compared with that by pristine NZVI through batch Fenton-like reaction experiments. Compared with pristine NZVI and bentonite alone, the NZVI@bentonite showed a higher BPA degradation ratio and offered highly effective BPA degradation up to 450 mg/g in wastewater under optimum operating conditions. Adsorption coupled with the Fenton-like reaction was responsible for BPA degradation by NZVI@bentonite. This work extends the application of NZVI@bentonite as an effective green catalyst for BPA degradation in aqueous environments.
Bian, Y, Wang, D, Liu, X, Yang, Q, Liu, Y, Wang, Q, Ni, B-J, Li, H & Zhang, Y 2020, 'The fate and impact of TCC in nitrifying cultures', Water Research, vol. 178, pp. 115851-115851.
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Triclocarban (TCC) is a highly effective antibacterial agent, which is widely used in a variety of applications and present at significant levels (e.g., 760 μg/L) in wastewater worldwide. However, the interaction between TCC and nitrifiers, important microbial cultures in wastewater treatment plants, has not been documented. This work therefore aimed to evaluate the fate of TCC in a nitrifying culture and its impact on nitrifiers in four long-term nitrifiers-rich reactors, which received synthetic wastewater containing 0, 0.1, 1, or 5 mg/L TCC. Experimental results showed that 36.7%-50.7% of wastewater TCC was removed by nitrifying cultures in stable operation. Mass balance analysis revealed that the removal of TCC was mainly achieved through adsorption rather than biodegradation. Adsorption kinetic analysis indicated that inhomogeneous multilayer adsorption was responsible for the removal while fourier transform infrared spectroscopy indicated that several functional groups such as hydroxyl, amide and polysaccharide seemed to be the main adsorption sites. The adsorbed TCC significantly deteriorated settleability and performance of nitrifying cultures. With an increase of influent TCC from 0 to 5 mg/L, reactor volatile suspended solids and effluent nitrate decreased from 1200 ± 90 mg/L and 300.81 ± 7.52 mg/L to 880 ± 80 and 7.35 ± 4.62 mg/L while effluent ammonium and nitrite increased from 0.41 ± 0.03 and 0.45 ± 0.23 mg/L to104.65 ± 3.46 and 182.06 ± 7.54 mg/L, respectively. TCC increased the extracellular polymeric substances of nitrifying cultures, inhibited the specific activities of nitrifiers, and altered the abundance of nitrifiers especially Nitrospira sp.. In particular, TCC at environmentally relevant concentration (i.e., 0.1 mg/L) significantly inhibited NOB activity and reduced NOB population.
Bordbar, M, Neshat, A, Javadi, S, Pradhan, B & Aghamohammadi, H 2020, 'Meta-heuristic algorithms in optimizing GALDIT framework: A comparative study for coastal aquifer vulnerability assessment', Journal of Hydrology, vol. 585, pp. 124768-124768.
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Boyd-Weetman, B & Thomas, P 2020, 'Assessment of the ground aggregate paste (GAP) test for aggregate alkali–silica reactivity screening', Journal of Thermal Analysis and Calorimetry, vol. 142, no. 5, pp. 1635-1641.
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This paper investigates the potential of a laboratory test for the screening of aggregate reactivity to alkali–silica reaction (ASR) through phase analysis of the phases developed in ground aggregate paste (GAP) specimens subjected to accelerated ageing. GAPs were prepared using two aggregates categorised as non-reactive and potentially reactive by standard expansion test methods and were aged at 40, 60 and 80 °C in 1 M NaOH solution over periods up to 84 days. Phase development was monitored using TG, XRD and FTIR, and the reactivity was correlated with quartz and calcium hydroxide consumption. The data demonstrate that this test has the potential to be developed as a screening test, based on the correlation of phase consumption with Australian standard expansion test reactivity categorisation.
Burton, GJ, Sheng, D & Airey, DW 2020, 'Critical state behaviour of an unsaturated high-plasticity clay', Géotechnique, vol. 70, no. 2, pp. 161-172.
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This paper describes a series of tests carried out to examine triaxial compression and shearing of a high-plasticity compacted clay. Reconstituted and compacted samples which were saturated are used as a basis for interpreting the unsaturated test results within a critical state soil mechanics (CSSM) framework. The shear strength behaviour of unsaturated soils have previously been found to be reasonably well captured in a CSSM framework, whereas the volume change behaviour has been more difficult to rationalise. Based on test results presented using the Bishop effective stress, the volume change behaviour during shear suggests that a unique critical state line is approached, independent of the applied suction. The normalised shearing behaviour of the compacted unsaturated soil is interpreted to be analogous to that of saturated-structured soils.
Cai, G, He, X, Dong, L, Liu, S, Xu, Z, Zhao, C & Sheng, D 2020, 'The shear and tensile strength of unsaturated soils by a grain-scale investigation', Granular Matter, vol. 22, no. 1.
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© 2019, Springer-Verlag GmbH Germany, part of Springer Nature. This paper presents a study of the tensile strength of unsaturated soil by a DEM model in a novel uniaxial tensile test device. For validation and comparison, traditional triaxial shear test of unsaturated soil are also conducted. In the DEM model, the capillary effects and some other cementation effects are modelled by a bond, whose strength is a function of the moisture content and void ratio in uniaxial tensile tests and also the confining pressure in triaxial tests. To compare the DEM simulations with experiments, the bond strength function is calibrated through a quantity measurable in both laboratory and DEM simulations such as the shear strength in triaxial tests or the uniaxial tensile strength in uniaxial tensile tests. The comparison shows that the proposed model is able to capture the phenomena observed in experiments. Most importantly, through investigation of the grain-scale data such as the motion, force chains and development of fractures, it is possible to explain some macroscopic observations such as the form of shear bands in the sample, the influence of the moisture content on the shear and tensile strength, etc.
Cai, G, Li, J, Xu, Z, He, X & Zhao, C 2020, 'Three-dimensional Distinct Element Analysis of Shear Properties of Unsaturated Soils', Yingyong Jichu yu Gongcheng Kexue Xuebao/Journal of Basic Science and Engineering, vol. 28, no. 6, pp. 1447-1459.
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Based on the discrete element theory and the existing laboratory experimental results, a method to determine the corresponding relationship between macro parameters and grain-scale parameters of unsaturated soil is proposed, that is, taking the structural yield stress as the intermediate variable, the corresponding relationship between the bond strength and water content between particles is constructed, and a flexible boundary program is compiled and added to PFC3D(particle flow code in three dimensions).Three dimensional discrete element model of unsaturated soil is established in the program of dimensions.The numerical simulation of triaxial consolidation drained shear test of unsaturated soil with different water content is carried out.The internal grain-scale evolution mechanism of macro mechanical properties such as strength, deformation and failure of unsaturated soil is deeply studied.The feasibility of using discrete element method to study unsaturated materials is also discussed.The results show that: with the increase of water content, the smaller the contact force between particles in the sample is, the less the number of soil particles under stress will be, and the earlier the bond failure point will appear.In addition, the change of bond failure number in the shear process can be divided into three stages: slow growth stage, rapid development stage and residual stage. Compared with the laboratory test results of unsaturated soil, the established DEM model and analysis program show good applicability in the aspects of deviatoric stress-strain relationship and strength characteristics.
Cao, S, Wu, C & Wang, W 2020, 'Behavior of FRP confined UHPFRC-filled steel tube columns under axial compressive loading', Journal of Building Engineering, vol. 32, pp. 101511-101511.
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© 2020 Elsevier Ltd Ultra-high performance fiber-reinforced concrete (UHPFRC) has been widely investigated in recent years. This study focusses on the experimental results of FRP confined UHPFRC filled steel tube (UHPFRCFST) specimens under axial compression. In total 37 specimens, both square and circular, were prepared and tested to investigate the axial compressive behaviors of FRP confined UHPFRCFST specimens. The main investigated parameters were the FRP layers, the concrete type and the steel fiber addition. The experimental results indicate that axial load capacity of concrete filled steel tube (CFST) specimens can be effectively enhanced by the FRP confinement. However, the performance enhancement was less significant for square UHPFRCFST specimens as compared to circular UHPFRCFST specimens. Comparisons of these results demonstrate that FRP confined CFST specimens exhibit a higher load-bearing capacity in the post-peak stage than the non-wrapped CFST specimens. Moreover, prediction equations were proposed to predict the ultimate axial load capacity of FRP confined UHPFRCFST specimens, and the predicted results matched well with the experimental results.
Chakrabortty, R, Pradhan, B, Mondal, P & Pal, SC 2020, 'The use of RUSLE and GCMs to predict potential soil erosion associated with climate change in a monsoon-dominated region of eastern India', Arabian Journal of Geosciences, vol. 13, no. 20.
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© 2020, Saudi Society for Geosciences. Soil is one of the most important natural resources; therefore, there is an urgent need to estimate soil erosion. The subtropical monsoon-dominated region also faces a comparatively greater problem due to heavy rainfall with high intensity in a very short time and the presence of longer dry seasons and shorter wet seasons. The Arkosa watershed faces the problem of extreme land degradation in the form of soil erosion; therefore, the rate of soil erosion needs to be estimated according to appropriate models. GCM (general circulation model) data such as MIROC5 (Model for Interdisciplinary Climate Research) of CMIP5 (Coupled Model Intercomparison Project Phase 5) have been used to project future storm rainfall and soil erosion rates following the revised universal soil loss equation (RUSLE) in various influential time frames. Apart from that, different satellite data and relevant primary field-based data for future prediction were considered. The average annual soil erosion of Arkosa watershed ranges from < 1 to > 6 t/ha/year. The very high (> 6 t/ha/year) and high (5–6 t/ha/year) soil loss areas are found in the southern, south-eastern, and eastern part of the watershed. Apart from this, low (1–2 t/ha/year) and very low (< 1 t/ha/year) soil loss areas are associated with the western, northern, southern, and major portion of the watershed. Extreme precipitation rates with high kinetic energy due to climate change are favorable to soil erosion susceptibility. The results of this research will help to implement management strategies to minimize soil erosion by keeping authorities and researchers at risk for future erosion and vulnerability.
Chan, NJ-A, Gu, D, Tan, S, Fu, Q, Pattison, TG, O’Connor, AJ & Qiao, GG 2020, 'Spider-silk inspired polymeric networks by harnessing the mechanical potential of β-sheets through network guided assembly', Nature Communications, vol. 11, no. 1.
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AbstractThe high toughness of natural spider-silk is attributed to their unique β-sheet secondary structures. However, the preparation of mechanically strong β-sheet rich materials remains a significant challenge due to challenges involved in processing the polymers/proteins, and managing the assembly of the hydrophobic residues. Inspired by spider-silk, our approach effectively utilizes the superior mechanical toughness and stability afforded by localised β-sheet domains within an amorphous network. Using a grafting-from polymerisation approach within an amorphous hydrophilic network allows for spatially controlled growth of poly(valine) and poly(valine-r-glycine) as β-sheet forming polypeptides via N-carboxyanhydride ring opening polymerisation. The resulting continuous β-sheet nanocrystal network exhibits improved compressive strength and stiffness over the initial network lacking β-sheets of up to 30 MPa (300 times greater than the initial network) and 6 MPa (100 times greater than the initial network) respectively. The network demonstrates improved resistance to strong acid, base and protein denaturants over 28 days.
Chang, Z, Long, G, Zhou, JL & Ma, C 2020, 'Valorization of sewage sludge in the fabrication of construction and building materials: A review', Resources, Conservation and Recycling, vol. 154, pp. 104606-104606.
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© 2019 Elsevier B.V. With increasing amount of sewage sludge becoming an urgent and inevitable issue for every country, its applications in the production of construction and building materials provide an alternative solution for sludge disposal and resource recovery. Similar to clay and Portland cement, the main oxides in sewage sludge are SiO2 (10–25 %), Al2O3 (5–10 %) and CaO (10–30 %) which are increased in sludge ash after incineration to 25–50 %, 10–20 % and 15–30 %. Therefore, this solid waste can be utilized not only as raw material for the production of eco-cement, bricks, ceramic materials and lightweight aggregates through sintering process, but also as supplementary admixtures in cementitious materials such as pozzolanic component, fine aggregate or filling material. By critically reviewing current utilizations of sewage sludge, it is feasible to replace up to 15 % natural raw materials with sewage sludge in cement production and the manufactured eco-cement clinkers show comparable performance to traditional Portland cement. Whilst as raw feed in the fabrication of bricks, ceramic materials and lightweight aggregates, 20 % of sewage sludge substitution is acceptable to produce good quality products (within 8 % firing shrinkage and 15 % water absorption). Though high content of organic matter in raw sludge causes a decrease in mechanical strength and delay in hydration process, controlled low-strength materials offer an innovative reuse with large amount of sludge. The immobilization of heavy metals in products prevents sewage sludge causing secondary environmental pollution. Furthermore, suggestions for future research are proposed in order to strengthen the high value-added applications of sewage sludge.
Chauviré, B & Thomas, PS 2020, 'DSC of natural opal: insights into the incorporation of crystallisable water in the opal microstructure', Journal of Thermal Analysis and Calorimetry, vol. 140, no. 5, pp. 2077-2085.
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© 2019, Akadémiai Kiadó, Budapest, Hungary. Low-temperature DSC on a wide range of opal-A and opal-CT samples was carried out to estimate the proportion of crystallisable water and to determine the size of water-filled cavities. A wide range of crystallisable water contents in the range 4.9 to 41.9% of the water contained in opals were observed, although the proportion of crystallisable water did not correlate with structure. Pore size and pore size distribution were estimated from the melt temperature depression and heat flow data, respectively. Opal-CT was observed to have smaller water-filled pores (radii < 2 nm) than opal-A (radii from 2.5 to 4.9 nm), suggesting that molecular water may be contained between nanograins in the microstructural units (spheres or lepispheres). A narrower pore size distribution was calculated for opal-CT, and no melting of the crystallisable water was observed where bulk water would be expected to melt, suggesting the absence of larger voids. The melting peaks for opal-A, on the other hand, transitioned into the melting of bulk water suggesting the presence of significantly larger water-filled pores, an observation consistent with the microstructure observed in SEM micrographs.
Che, L, Jin, W, Zhou, X, Cao, C, Han, W, Qin, C, Tu, R, Chen, Y, Feng, X & Wang, Q 2020, 'Biological Reduction of Organic Matter in Buji River Sediment (Shenzhen, China) with Artificial Oxygenation', Water, vol. 12, no. 12, pp. 3592-3592.
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In this work, artificial oxygenation treatment (pure oxygen aeration or oxygen enriched water injection) combined with the introduction of exogenous microorganisms was employed to purify urban river sediment for the first time. Results showed that the developed in situ remediation strategy could increase the dissolved oxygen (DO) concentration and oxidation-reduction potential (ORP) value of the sediments. Benefiting from the increase of DO concentration, the bacterial diversity was enhanced. The highest removal efficiencies of organic matter were 18.4% and 22.3% through pure oxygen aeration and oxygen enriched water injection, respectively. More importantly, overlying water quality was not affected. By comparison, oxygen enriched water injection treatment could achieve better performance on sediment purification. Introducing exogenous microorganisms further reduced the organic matter content of the sediment. In short, the current work not only proposed a promising strategy for controlling urban river sediment pollution, but also provided novel insight for the understanding of river sediment containing highly concentrated organic matter.
Cheah, MY, Ong, HC, Zulkifli, NWM, Masjuki, HH & Salleh, A 2020, 'Physicochemical and tribological properties of microalgae oil as biolubricant for hydrogen-powered engine', International Journal of Hydrogen Energy, vol. 45, no. 42, pp. 22364-22381.
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Chen, H, Qi, C, Shen, L, Fu, Q, Wang, Z, Xiong, Z, Sun, Y & Liu, Y 2020, 'Tunable d-spacing of dry reduced graphene oxide nanosheets for enhancing re-dispersibility in organic solvents', Applied Surface Science, vol. 531, pp. 147375-147375.
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© 2020 Elsevier B.V. The reduced graphene oxide (rGO) nanosheets were modified by using polymeric nanospheres to adjust the d-spacings between dry rGO nanosheets. The experimental and computational studies show that the incorporation of polymeric nanospheres can effectively increase the d-spacing between dry rGO nanosheets, and meanwhile provide good compatibility of rGO with organic solvents. Specifically, when the d-spacing between nanosheets is greater than 14.0 nm, the dried rGO nanosheets can be well redispersed and stabilized in various organic solvents. This study thus provides a new technology that can produce dry rGO nanosheets with good re-dispersibility and stability in various organic solvents on a large-scale in a more environmental friendly manner.
Chen, R-H, Ong, HC & Wang, W-C 2020, 'The optimal blendings of diesel, biodiesel and gasoline with various exhaust gas recirculations for reducing NOx and smoke emissions from a diesel engine', International Journal of Environmental Science and Technology, vol. 17, no. 11, pp. 4623-4654.
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Chen, W, Li, Y, Xue, W, Shahabi, H, Li, S, Hong, H, Wang, X, Bian, H, Zhang, S, Pradhan, B & Ahmad, BB 2020, 'Modeling flood susceptibility using data-driven approaches of naïve Bayes tree, alternating decision tree, and random forest methods', Science of The Total Environment, vol. 701, pp. 134979-134979.
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© 2019 Elsevier B.V. Floods are one of the most devastating types of disasters that cause loss of lives and property worldwide each year. This study aimed to evaluate and compare the prediction capability of the naïve Bayes tree (NBTree), alternating decision tree (ADTree), and random forest (RF) methods for the spatial prediction of flood occurrence in the Quannan area, China. A flood inventory map with 363 flood locations was produced and partitioned into training and validation datasets through random selection with a ratio of 70/30. The spatial flood database was constructed using thirteen flood explanatory factors. The probability certainty factor (PCF) method was used to analyze the correlation between the factors and flood occurrences. Consequently, three flood susceptibility maps were produced using the NBTree, ADTree, and RF methods. Finally, the area under the curve (AUC) and statistical measures were used to validate the flood susceptibility models. The results indicated that the RF method is an efficient and reliable model in flood susceptibility assessment, with the highest AUC values, positive predictive rate, negative predictive rate, sensitivity, specificity, and accuracy for the training (0.951, 0.892, 0.941, 0.945, 0.886, and 0.915, respectively) and validation (0.925, 0.851, 0.938, 0.945, 0.835, and 0.890, respectively) datasets.
Chen, X, Rodríguez, Y, López, JC, Muñoz, R, Ni, B-J & Sin, G 2020, 'Modeling of Polyhydroxyalkanoate Synthesis from Biogas by Methylocystis hirsuta', ACS Sustainable Chemistry & Engineering, vol. 8, no. 9, pp. 3906-3912.
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Copyright © 2020 American Chemical Society. Methylocystis hirsuta, a type II methanotroph, has been experimentally demonstrated to be able to efficiently synthesize polyhydroxyalkanoates (PHA) from biogas under nutrient-limited conditions. A mechanistic model capable of describing the relevant processes of M. hirsuta, which is currently not available, would therefore lay a solid foundation for future practical demonstration and optimization of the PHA synthesis technology using biogas. To this end, dedicated batch tests were designed and conducted to obtain experimental data for different mechanistic processes of M. hirsuta. Through utilizing the experimental data of well-designed batch tests and following a step-wise model calibration/validation protocol, the stoichiometrics and kinetics of M. hirsuta are reported for the first time, including the yields of growth and PHA synthesis on CH4 (0.14 ± 0.01 g COD g-1 COD and 0.25 ± 0.02 g COD g-1 COD), the CH4 and O2 affinity constants (5.1 ± 2.1 g COD m-3 and 4.1 ± 1.7 g O2 m-3), the maximum PHA consumption rate (0.019 ± 0.001 g COD g-1 COD d-1), and the maximum PHA synthesis rate on CH4 (0.39 ± 0.05 g COD g-1 COD d-1). Through applying the developed model, an optimal O2:CH4 molar ratio of 1.6 mol O2 mol-1 CH4 was found to maximize the PHA synthesis by M. hirsuta. Practically, the model and parameters obtained would not only benefit the design and operation of bioreactors performing PHA synthesis from biogas, but also enable specific research on selection for type II methanotrophs in diverse environments.
Chen, X, Yang, L, Sun, J, Wei, W, Liu, Y & Ni, B-J 2020, 'Influences of Longitudinal Heterogeneity on Nitrous Oxide Production from Membrane-Aerated Biofilm Reactor: A Modeling Perspective', Environmental Science & Technology, vol. 54, no. 17, pp. 10964-10973.
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As a promising technology for sustainable nitrogen removal from wastewater, the membrane-aerated biofilm reactors (MABRs) performing autotrophic deammonification are faced with the problem of unwanted production of nitrous oxide (N2O, a potent greenhouse gas). As a common tool to study N2O production from such an MABR, the traditional one-dimensional modeling approach fails to simulate the existence of longitudinal gradients in the reactor and therefore might render N2O production significantly deviated from reality. To this end, this work aims to study the influences of key longitudinal gradients (i.e., in oxygen, liquid-phase components, and biofilm thickness) on the N2O production from a typical MABR performing autotrophic deammonification by applying a modified version of a newly developed compartmental model. Through comparing the modeling results of different reactor configurations, this work reveals that the single impact of the longitudinal gradients studied on the N2O production from the MABR follows the order: oxygen (significant) > liquid-phase components (slight) > biofilm thickness (almost none). When multiple longitudinal gradients are present, they become correlated and would jointly influence the N2O production and nitrogen removal of the MABR. The results also show the need for multispot measurements to get an accurate representation of spatial biofilm features of the MABR configuration with the membrane lumen designed/operated as a plug flow reactor. While the traditional modeling approach is acceptable to evaluate the nitrogen removal in most cases, it might overestimate or underestimate the N2O production from the MABR with at least one of the longitudinal gradients in oxygen and liquid-phase components. For such an MABR, the longitudinal heterogeneity in biofilm thickness and the number of biofilm thickness classes to be included in the model would also make a difference to the simulation results, especially the N2O production. The ...
Chen, Z, Duan, X, Wei, W, Wang, S & Ni, B-J 2020, 'Electrocatalysts for acidic oxygen evolution reaction: Achievements and perspectives', Nano Energy, vol. 78, pp. 105392-105392.
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© 2020 Elsevier Ltd Developing efficient electrocatalysts toward acidic oxygen evolution reaction (AOER) is of vital significance in proton exchange membrane (PEM) water electrolysis, which is a promising technique to tackle the approaching energy crisis by supplying high-purity hydrogen. In this work, we first present a general introduction to the AOER mechanism as well as the most important parameters in evaluation of the catalytic performances of catalysts. Fruitful achievements of noble metal-based catalysts (e.g., metals, alloys, and oxides) and noble metal-free catalysts (e.g., transition metal oxides, chalcogenides, and metal-free materials) are fully described, with an emphasis on advanced strategies of catalyst modification/engineering, structure-catalysis correlations, and evolution of catalyst structures and surface chemistry under operational conditions. The representative electrocatalysts are benchmarked based on their catalytic performances. Finally, the challenges are summarized and future opportunities are directed for the rational design of AOER catalysts toward sustainable fuel production.
Chen, Z, Duan, X, Wei, W, Wang, S & Ni, B-J 2020, 'Iridium-based nanomaterials for electrochemical water splitting', Nano Energy, vol. 78, pp. 105270-105270.
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© 2020 Elsevier Ltd Electrochemical water splitting is an appealing technology to produce high-purity hydrogen as a clean and sustainable energy carrier. The efficiency of water splitting largely depends on the intrinsic activity, selectivity, and stability of the electrocatalysts. Hence, soaring scientific endeavors have been made to develop high-performance electrocatalysts and uncover the underling reaction mechanisms. Iridium (Ir)-based nanomaterials are most promising for water splitting due to their favorable intrinsic activity, wide pH window, and high stability. In this review, we first discussed the mechanisms of various Ir-based catalysts in hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), including metal, alloys, and oxides. Important criteria and methods for precise evaluation of water splitting catalysts are discussed. Then, the applications of Ir-based nanomaterials in the HER, OER and the overall water splitting are comprehensively reviewed, with an emphasis on correlating the structure-function relationships and the advanced strategies for rational design of reaction-oriented Ir catalysts. Lastly, the current challenges in fundamental studies and future directions in this field are presented.
Chen, Z, Duan, X, Wei, W, Wang, S, Zhang, Z & Ni, B-J 2020, 'Boride-based electrocatalysts: Emerging candidates for water splitting', Nano Research, vol. 13, no. 2, pp. 293-314.
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© 2020, Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature. Electrocatalytic water splitting (EWS) is a promising route to produce hydrogen in a sustainable and environment-benign manner. To realize the large-scale hydrogen production, it is paramount to develop desirable electrocatalysts with engineered structure, high catalytic activity, facile accessibility, low cost, and good durability. Of late, boride-based materials, especially transition-metal borides (TMBs), are emerging as promising candidates for the EWS process. However, so far, little attempt has been made to provide a comprehensive summary on these findings. Herein, this review provides the up-to-date status on upgrading the catalytic performance of TMB-based nanomaterials by regulating the internal and external characteristics. The conventional synthetic techniques are first presented for the preparation of TMB-based catalysts. Afterwards, the advanced strategies are summarized to enhance the catalytic performance of TMBs, including morphology control, component regulation, phase engineering, surface oxidation and hybridization. Then, the design principles of TMB-based electrocatalysts for high-performance EWS are outlined. Lastly, the current challenges and future directions in the development of TMB-based materials are proposed. This review article is expected to envisage insights into the TMBs-based water splitting and to provide strategies for design of the next-generation TMB-based electrocatalysts. [Figure not available: see fulltext.].
Chen, Z, Ibrahim, I, Hao, D, Liu, X, Wu, L, Wei, W, Su, D & Ni, B-J 2020, 'Controllable design of nanoworm-like nickel sulfides for efficient electrochemical water splitting in alkaline media', Materials Today Energy, vol. 18, pp. 100573-100573.
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© 2020 Elsevier Ltd Developing cost-effective electrocatalysts for electrochemical water splitting (EWS) is appealing and challenging for sustainable water electrolysis. Currently, nickel sulfides are considered as promising candidates for EWS due to their low cost and high catalytic activity. However, the facile design of nickel sulfides with high catalytic performance is still highly demanded. In this study, we have developed a one-step solvothermal strategy to construct nickel sulfides as efficient water splitting catalysts. By taking advantage of the small size, abundant active sites, large electrochemical surface area, and good conductivity, the nanoworm-like nickel sulfides (NiS-NW/Ni foam [NF]) exhibit better oxygen evolution reaction performance (a low overpotential of 279 mV to achieve 100 mA cm−2, Tafel slope of 38.44 mV dce−1) than the nanoplate-like analogs, as well as most of reported nickel sulfide–based electrocatalysts. In addition, the NiS-NW/NF directly used as bifunctional electrodes for overall water splitting requires a low voltage of 1.563 V to attain a current density of 10 mA cm−2 with good long-term durability. This work provides a facile strategy for the design of efficient nickel sulfide-based electrocatalysts for energy conversion applications.
Chen, Z, Wu, G, Wu, Y, Wu, Q, Shi, Q, Ngo, HH, Vargas Saucedo, OA & Hu, H-Y 2020, 'Water Eco-Nexus Cycle System (WaterEcoNet) as a key solution for water shortage and water environment problems in urban areas', Water Cycle, vol. 1, pp. 71-77.
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Cheng, D, Hao Ngo, H, Guo, W, Wang Chang, S, Duc Nguyen, D, Liu, Y, Zhang, X, Shan, X & Liu, Y 2020, 'Contribution of antibiotics to the fate of antibiotic resistance genes in anaerobic treatment processes of swine wastewater: A review', Bioresource Technology, vol. 299, pp. 122654-122654.
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Antibiotic resistance genes (ARGs) in water environment have become a global health concern. Swine wastewater is widely considered to be one of the major contributors for promoting the proliferation of ARGs in water environments. This paper comprehensively reviews and discusses the occurrence and removal of ARGs in anaerobic treatment of swine wastewater, and contributions of antibiotics to the fate of ARGs. The results reveal that ARGs' removal is unstable during anaerobic processes, which negatively associated with the presence of antibiotics. The abundance of bacteria carrying ARGs increases with the addition of antibiotics and results in the spread of ARGs. The positive relationship was found between antibiotics and the abundance and transfer of ARGs in this review. However, it is necessary to understand the correlation among antibiotics, ARGs and microbial communities, and obtain more knowledge about controlling the dissemination of ARGs in the environment.
Cheng, D, Liu, Y, Ngo, HH, Guo, W, Chang, SW, Nguyen, DD, Zhang, S, Luo, G & Liu, Y 2020, 'A review on application of enzymatic bioprocesses in animal wastewater and manure treatment', Bioresource Technology, vol. 313, pp. 123683-123683.
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Enzymatic processing has been considered an interesting technology as enzymes play important roles in the process of waste bioconversion, whilst heling to develop valuable products from animal wastes. In this paper, the application of enzymes in animal waste management were critically reviewed in short with respect to utilization in: (i) animal wastewater treatment and (ii) animal manure management. The results indicate that the application of enzymes could increase both chemical oxygen demand (COD) removal efficiency and production of biogas. The enzymatic bioprocesses were found to be affected by the type, source and dosage of enzymes and the operating conditions. Further studies on optimizing the operating conditions and developing cost-effective enzymes for the future large-scale application are therefore necessary.
Cheng, D, Ngo, HH, Guo, W, Chang, SW, Nguyen, DD, Li, J, Ly, QV, Nguyen, TAH & Tran, VS 2020, 'Applying a new pomelo peel derived biochar in microbial fell cell for enhancing sulfonamide antibiotics removal in swine wastewater', Bioresource Technology, vol. 318, pp. 123886-123886.
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A sequential anode-cathode double-chamber microbial fuel cell (MFC) is a promising system for simultaneously removing contaminants, recovering nutrients and producing energy from swine wastewater. To improve sulfonamide antibiotics (SMs)'s removal in the continuous operating of MFC, one new pomelo peel-derived biochar was applied in the anode chamber in this study. Results demonstrated that SMs can be absorbed onto the heterogeneous surfaces of biochar through pore-filling and π-π EDA interaction. Adding biochar to a certain concentration (500 mg/L) could enhance the efficiency in removing sulfamethoxazole, sulfadiazine and sulfamethazine to 82.44-88.15%, 53.40-77.53% and 61.12-80.68%, respectively. Moreover, electricity production, COD and nutrients removal were improved by increasing the concentration of biochar. Hence, it is proved that adding biochar in MFC could effectively improve the performance of MFC in treating swine wastewater containing SMs.
Cheng, D, Ngo, HH, Guo, W, Chang, SW, Nguyen, DD, Liu, Y, Shan, X, Nghiem, LD & Nguyen, LN 2020, 'Removal process of antibiotics during anaerobic treatment of swine wastewater', Bioresource Technology, vol. 300, pp. 122707-122707.
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High concentrations of antibiotics in swine wastewater pose potentially serious risks to the environment, human and animal health. Identifying the mechanism for removing antibiotics during the anaerobic treatment of swine wastewater is essential for reducing the serious damage they do to the environment. In this study, batch experiments were conducted to investigate the biosorption and biodegradation of tetracycline and sulfonamide antibiotics (TCs and SMs) in anaerobic processes. Results indicated that the removal of TCs in the anaerobic reactor contributed to biosorption, while biodegradation was responsible for the SMs' removal. The adsorption of TCs fitted well with the pseudo-second kinetic mode and the Freundlich isotherm, which suggested a heterogeneous chemisorption process. Cometabolism was the main mechanism for the biodegradation of SMs and the process fitted well with the first-order kinetic model. Microbial activity in the anaerobic sludge might be curtailed due to the presence of high concentrations of SMs.
Cheng, D, Ngo, HH, Guo, W, Chang, SW, Nguyen, DD, Liu, Y, Wei, Q & Wei, D 2020, 'A critical review on antibiotics and hormones in swine wastewater: Water pollution problems and control approaches', Journal of Hazardous Materials, vol. 387, pp. 121682-121682.
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Swine wastewater (SW) is an important source of antibiotics and hormones (A&H) in the environment due to their large-scale application in swine industry. A&H in SW can be released into the water environment through the direct discharge of SW, effluent from SW treatment plants, and runoff and leaching from farmland polluted by swine wastes. The presence of A&H in the water environment has become an increasing global concern considering their adverse effects to the aquatic organism and human. This review critically discusses: (i) the occurrence of A&H in global water environment and their potential risks to water organisms and human; (ii) the management and technical approaches for reducing the emission of A&H in SW to the water environment. The development of antibiotic alternatives and the enhanced implementation of vaccination and biosecurity are promising management approaches to cut down the consumption of antibiotics during swine production. Through the comparison of different biological treatment technologies for removing A&H in SW, membrane-based bioprocesses have relatively higher and more stable removal efficiencies. Whereas, the combined system of bioprocesses and AOPs is expected to be a promising technology for elimination and mineralization of A&H in swine wastewater. Further study on this system is therefore necessary.
Cheng, D, Ngo, HH, Guo, W, Chang, SW, Nguyen, DD, Zhang, X, Varjani, S & Liu, Y 2020, 'Feasibility study on a new pomelo peel derived biochar for tetracycline antibiotics removal in swine wastewater', Science of The Total Environment, vol. 720, pp. 137662-137662.
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Cheng, D, Ngo, HH, Guo, W, Lee, D, Nghiem, DL, Zhang, J, Liang, S, Varjani, S & Wang, J 2020, 'Performance of microbial fuel cell for treating swine wastewater containing sulfonamide antibiotics', Bioresource Technology, vol. 311, pp. 123588-123588.
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Cheng, H, Liu, Y, Huang, D, Pan, Y & Wang, Q 2020, 'Adaptive Transfer Learning of Cross-Spatiotemporal Canonical Correlation Analysis for Plant-Wide Process Monitoring', Industrial & Engineering Chemistry Research, vol. 59, no. 49, pp. 21602-21614.
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© Multivariate statistical methods have gained significant popularity in past decades. However, process dynamics and insufficient training data usually result in degradation or even failure of a trained model. To deal with these problems, this paper proposes a novel process monitoring method, called cross-spatiotemporal adaptive boosting transfer learning (CS-AdBoostTrLM). Different from the standard methods, CS-AdBoostTrLM has the following advantages: first, source domain (SD) data, which are discarded by the factory, can be re-enabled to alleviate the issue of insufficient training data. Second, cross-spatiotemporal canonical correlation analysis is proposed to achieve the domain adaptation between the SD data and target domain data, so as to overcome the negative transfer. Third, the particle swarm optimization algorithm is used to optimize the local detection model, in such a way that the integrated detection model can converge to the optimality globally. Finally, the data from the wastewater treatment plant and chemical plant are analyzed to demonstrate the effectiveness of the proposed method.
Cheng, Z, Zhao, R, Yuan, Y, Li, F, Castel, A & Xu, T 2020, 'Ageing coefficient for early age tensile creep of blended slag and low calcium fly ash geopolymer concrete', Construction and Building Materials, vol. 262, pp. 119855-119855.
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© 2020 Elsevier Ltd The ageing coefficient is required in the age-adjusted effective modulus method to assess the effect of creep in concrete structures subjected to varied stress history. In this paper, experiments were carried out to calibrate the ageing coefficient for early age tensile creep of blended slag and low calcium fly ash geopolymer concrete. The development of total strains of geopolymer concrete under sustained tension, including instantaneous strain, creep strain and shrinkage strain was monitored by using the dog-bone shaped specimens. The specimens were loaded at the age of 2, 3, 4, 7, 14, 21 days, respectively. The strains of the unloaded companion specimens were monitored as well. The development of the creep coefficient φ(t,τ0) for geopolymer concrete was calculated based on the experimental results. By using the step-by-step numerical analysis, the ageing coefficient for early age tensile creep of geopolymer concrete was assessed. An ageing coefficient of 0.8 is recommended for structural design. The comparison between calculated and measured tensile strains from the restrained concrete ring test shows the validity of the proposed value of the ageing coefficient.
Cheshomi, A, Bakhtiyari, E & Khabbaz, H 2020, 'A comparison between undrained shear strength of clayey soils acquired by “PMT” and laboratory tests', Arabian Journal of Geosciences, vol. 13, no. 14, p. 640.
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© 2020, Saudi Society for Geosciences. A pressuremeter test (PMT) is one of the in situ tests, which is used to evaluate deformation and strength parameters of soils for various projects, including subway projects. The limit pressure (PL) and undrained shear strength (Su) are the key parameters that are obtained directly and indirectly from the pressuremeter testing results. This research was carried out using geotechnical information obtained from a subway project in Qom city, Iran. Based on 44 PMT and uniaxial tests on very stiff to hard saturated clayey soils, a linear empirical equation between Su − PL and Su − PL* = (PL − σH) with R2 = 0.68 was proposed and it was found that σH had an insignificant effect on the proposed relationship. The effect of physical properties of soil, including plastic index (PI), liquid limit (LL), and water content (ω), was evaluated, and a multivariate equation was proposed between them. A comparison between the equations obtained in this research and those proposed by other researchers reveals that the empirical relationships between Su and PL are associated with the consistency of soils; the stiffer the soil is, the slope of relationship between Su and PL is less.
Choi, Y, Naidu, G, Lee, S & Vigneswaran, S 2020, 'Recovery of sodium sulfate from seawater brine using fractional submerged membrane distillation crystallizer', Chemosphere, vol. 238, pp. 124641-124641.
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Seawater reverse osmosis (SWRO) brine contain many valuable resources. In this study, fractional-submerged membrane distillation crystallizer (F-SMDC) was used to recover sodium sulfate (Na2SO4) from SWRO brine. The concentration/temperature gradient (CG/TG) in the reactor enhanced water recovery utilizing MD and Na2SO4 crystallization via a crystallizer. Crystals were not obtained at the bottom section of the F-SMDC due to: firstly, calcium sulfate crystallization occurring on the membrane surface; and secondly, low temperature-sensitivity solubility component such as NaCl exerting a negative influence. In order to obtain supersaturation, a sulfate-rich scenario was created in the reactor through the addition of the following three components: Na2SO4, MgSO4 and (NH4)2SO4. When Na2SO4 and MgSO4 were added, a larger concentration was observed at the top section, resulting in a low concentration gradient (CG) ratio, i.e. around 1.7. Conversely, the addition of (NH4)2SO4 achieved faster Na2SO4 crystallization (VCF 1.42) at the bottom section with a greater CG ratio of more than 2.0. Total water recovery ratio of 72% and 223.73 g Na2SO4 crystals were successfully extracted from simulated SWRO brine using laboratory scale F-SMDC.
Choo, Y, Halat, DM, Villaluenga, I, Timachova, K & Balsara, NP 2020, 'Diffusion and migration in polymer electrolytes', Progress in Polymer Science, vol. 103, pp. 101220-101220.
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Mixtures of neutral polymers and lithium salts have the potential to serve as electrolytes in next-generation rechargeable Li-ion batteries. The purpose of this review is to expose the delicate interplay between polymer-salt interactions at the segmental level and macroscopic ion transport at the battery level. Since complete characterization of this interplay has only been completed in one system: mixtures of poly(ethylene oxide) and lithium bis(trifluoromethanesulfonyl)imide (PEO/LiTFSI), we focus on data obtained from this system. We begin with a discussion of the activity coefficient, followed by a discussion of six different diffusion coefficients: the Rouse motion of polymer segments is quantified by Dseg, the self-diffusion of cations and anions is quantified by Dself,+ and Dself,−, and the build-up of concentration gradients in electrolytes under an applied potential is quantified by Stefan-Maxwell diffusion coefficients, D0+, D0-, and D+-. The Stefan-Maxwell diffusion coefficients can be used to predict the velocities of the ions at very early times after an electric field is applied across the electrolyte. The surprising result is that D0- is negative in certain concentration windows. A consequence of this finding is that at these concentrations, both cations and anions are predicted to migrate toward the positive electrode at early times. We describe the controversies that surround this result. Knowledge of the Stefan-Maxwell diffusion coefficients enable prediction of the limiting current. We argue that the limiting current is the most important characteristic of an electrolyte. Excellent agreement between theoretical and experimental limiting current is seen in PEO/LiTFSI mixtures. What sequence of monomers that, when polymerized, will lead to the highest limiting current remains an important unanswered question. It is our hope that the approach presented in this review will guide the development of such polymers.
Chowdhuri, I, Pal, SC, Arabameri, A, Saha, A, Chakrabortty, R, Blaschke, T, Pradhan, B & Band, SS 2020, 'Implementation of Artificial Intelligence Based Ensemble Models for Gully Erosion Susceptibility Assessment', Remote Sensing, vol. 12, no. 21, pp. 3620-3620.
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The Rarh Bengal region in West Bengal, particularly the eastern fringe area of the Chotanagpur plateau, is highly prone to water-induced gully erosion. In this study, we analyzed the spatial patterns of a potential gully erosion in the Gandheswari watershed. This area is highly affected by monsoon rainfall and ongoing land-use changes. This combination causes intensive gully erosion and land degradation. Therefore, we developed gully erosion susceptibility maps (GESMs) using the machine learning (ML) algorithms boosted regression tree (BRT), Bayesian additive regression tree (BART), support vector regression (SVR), and the ensemble of the SVR-Bee algorithm. The gully erosion inventory maps are based on a total of 178 gully head-cutting points, taken as the dependent factor, and gully erosion conditioning factors, which serve as the independent factors. We validated the ML model results using the area under the curve (AUC), accuracy (ACC), true skill statistic (TSS), and Kappa coefficient index. The AUC result of the BRT, BART, SVR, and SVR-Bee models are 0.895, 0.902, 0.927, and 0.960, respectively, which show very good GESM accuracies. The ensemble model provides more accurate prediction results than any single ML model used in this study.
Chowdhury, FR, Hoque, A, Chowdhury, FUH, Amin, MR, Rahim, A, Rahman, MM, Yasmin, R, Amin, MR, Miah, MT, Kalam, MA & Rahman, MS 2020, 'Convalescent plasma transfusion therapy in severe COVID-19 patients- a safety, efficacy and dose response study: A structured summary of a study protocol of a phase II randomized controlled trial', Trials, vol. 21, no. 1.
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AbstractObjectivesGeneral: To assess the safety, efficacy and dose response of convalescent plasma (CP) transfusion in severe COVID-19 patientsSpecific:a. To identify the appropriate effective dose of CP therapy in severe patientsb. To identify the efficacy of the therapy with their end point based on clinical improvement within seven days of treatment or until discharge whichever is later and in-hospital mortalityc. To assess the clinical improvement after CP transfusion in severe COVID-19 patientsd. To assess the laboratory improvement after CP transfusion in severe COVID-19 patientsTrial DesignThis is a multicentre, multi-arm phase II Randomised Controlled Trial.ParticipantsAge and sex matched COVID-19 positive (by RT-PCR) severe cases will be enrolled in this trial. Severe case is defined by the World Health Organization (W.H.O) clinical case definition. The inclusion criteria are1. Respiratory rate > 30 breaths/min; PLUS2. Severe respiratory distress; or SpO2 ≤ 88% on room air or PaO2/FiO2≤ 300 mm of Hg, PLUS3. Radiological (X-ray or CT scan) evidence of bilateral lung infiltrate, AND OR4. Systolic BP < 90 mm of Hg or diastolic BP <60 mm of Hg.AND/OR5. Criteria 1 to 4 AND or patient in ventilator supportPatients’ below18 years, pregnant and lactating women, previous history of allergic reaction to plasma, patients who have already received plasma from a different source will be excluded. Patients will be enrolled at Bangabandhu Sheikh Mujib Medical University (BSMMU) hospital, Dhaka medical college hospital (DMCH) and Mugda medic...
Chowdhury, MA, Shuvho, MBA, Hossain, MI, Ali, MO, Kchaou, M, Rahman, A, Yeasmin, N, Khan, AS, Rahman, MA & Mofijur, M 2020, 'Multiphysical analysis of nanoparticles and their effects on plants', Biotechnology and Applied Biochemistry.
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Nanoparticles are the magic bullets and at the leading edge in the field of nanotechnology, and their unique properties make these materials indispensable and superior in many areas, including the electronic field. Extensive applications of nanomaterials are incontrovertibly entering our living system. The increasing use of nanomaterials into the ecosystem is one of the crucial environmental factors that human being is facing. Nanomaterials raise noticeable toxicological concerns; particularly their accumulation in plants and the resultant toxicity may affect the food chain. Here, we analyzed the characterization of nanomaterials, such as graphene, Al2 O3 , TiO2 , and semi-insulating or conducting nanoparticles. Quantitative evaluation of the nanomaterials was conducted and their commercialization aspects were discussed. Various characterization techniques, scanning electron microscopy, X-ray diffraction, and ultraviolet rays were utilized to identify the morphology, phase, absorbance, and crystallinity. In addition, we analyzed the effects of nanomaterials on plants. The toxicity of nanoparticles has severe effects on loss of morphology of the plants. Potential mechanisms including physical and physiological effects were analyzed. In future studies, it is indispensable to assess widely accepted toxicity evaluation for safe production and use of nanomaterials.
Chu-Van, T, Surawski, N, Ristovski, Z, Yuan, C-S, Stevanovic, S, Ashrafur Rahman, SM, Hossain, FM, Guo, Y, Rainey, T & Brown, RJ 2020, 'The effect of diesel fuel sulphur and vanadium on engine performance and emissions', Fuel, vol. 261, pp. 116437-116437.
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© 2019 Elsevier Ltd Metallic composition of diesel particulate matter, even though a relatively small proportion of total mass, can reveal important information regarding engine conditions, fuel/lubricating oil characteristics and for health impacts. In this study, a detailed investigation into the metallic elemental composition at different particle diameter sizes has been undertaken. A bivariate statistical analysis was performed in order to investigate the correlation between the metallic element, measured engine performance and engine emission variables. Major sources of metallic elements in the emitted particles are considered in this study, including the fuel and lubricating oil compositions, engine wear emissions and metal-containing dust in the ambient air. Metallic solid ultrafine-particles (Dp < 100 nm) are strongly associated with metallic compounds derived from lubricating oil (Ca, Zn, Mg and K), while the fuel related metallic compounds and engine wear emissions are represented in the accumulation mode particle fraction (>100 nm). Calculated correlation matrices show a clear effect of engine load conditions and fuel S contents on particle number and mass emissions.
Cong Nguyen, N, Cong Duong, H, Chen, S-S, Thi Nguyen, H, Hao Ngo, H, Guo, W, Quang Le, H, Cong Duong, C, Thuy Trang, L, Hoang Le, A, Thanh Bui, X & Dan Nguyen, P 2020, 'Water and nutrient recovery by a novel moving sponge – Anaerobic osmotic membrane bioreactor – Membrane distillation (AnOMBR-MD) closed-loop system', Bioresource Technology, vol. 312, pp. 123573-123573.
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For the first time, a novel sponge-based moving bed-anaerobic osmosis membrane bioreactor/membrane distillation (AnOMBR/MD) system using mixed Na3PO4/EDTA-2Na as the draw solution was employed to treat wastewater for enhanced water flux and reduced membrane fouling. Results indicated that the moving sponge-AnOMBR/MD system obtained a stable water flux of 4.01 L/m2 h and less membrane fouling for a period lasting 45 days. Continuous moving sponge around the FO module is the main mechanism for minimizing membrane fouling during the 45-day AnOMBR operation. The proposed system's nutrient removal was almost 100%, thus showing the superiority of simultaneous FO and MD membranes. Nutrient recovery from the MF permeate was best when solution pH was controlled to 9.5, whereby 17.4% (wt/wt) of phosphorus was contained in precipitated components. Moreover, diluted draw solute following AnOMBR was effectively regenerated using the MD process with water flux above 2.48 L/m2 h and salt rejection > 99.99%.
Cui, Z, Hao Ngo, H, Cheng, Z, Zhang, H, Guo, W, Meng, X, Jia, H & Wang, J 2020, 'Hysteresis effect on backwashing process in a submerged hollow fiber membrane bioreactor (MBR) applied to membrane fouling mitigation', Bioresource Technology, vol. 300, pp. 122710-122710.
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Hysteresis effect on backwashing in a submerged MBR was investigated with dead-end hollow fiber membranes. The out-of-step changes in TMP and flux is the real hysteresis effect which is common but easily overlooked. Methods of visualization and ultrasonic spectrum analysis were implemented. The results showed that fouling layer is just the culprit of hysteresis effect. Fouling level and fiber length were determined as two key factors that affect hysteresis effect by data and model derivation. Moreover, a hysteresis evaluation index "τbw" is proposed to quantify the result of TMP vs time. The relationship between influence factors and "τbw" is interactive. A linear relationship between fouling level and "τbw" was found as well as an extreme value between fiber length and "τbw". A lower fouling level (lower backwashing flow) and optimal backwashing duration will be helpful for an effective backwashing no matter for membrane fouling control or energy cost reduce.
Dadol, GC, Kilic, A, Tijing, LD, Lim, KJA, Cabatingan, LK, Tan, NPB, Stojanovska, E & Polat, Y 2020, 'Solution blow spinning (SBS) and SBS-spun nanofibers: Materials, methods, and applications', Materials Today Communications, vol. 25, pp. 101656-101656.
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© 2020 Elsevier Ltd Solution blow spinning (SBS) is a maturing nanofiber fabrication technology. Over the past decade, there has been a growing interest in employing and developing this facile method of fabricating nanofibers, sourced from different materials to suit varied applications. For the first time, this review will provide a comprehensive overview of solution blow spinning, including the principles, materials, methods, and applications. We start with the principles of the SBS method, followed by a detailed account of the different precursor polymers (i.e., synthetic, biocompatible, and bio-based materials) and composites that have been used in the SBS of nanofibers. The proceeding section presents the known applications of nanofibers obtained through SBS which are discussed primarily in the areas of energy and electronics, biomedical, environmental, membrane separation, and, textile and smart material applications. We highlight the most important and recent advances related to SBS over the last ten years. Lastly, we give perspectives, challenges, opportunities, and new directions of the SBS technology.
Daer, S, Akther, N, Wei, Q, Shon, HK & Hasan, SW 2020, 'Influence of silica nanoparticles on the desalination performance of forward osmosis polybenzimidazole membranes', Desalination, vol. 491, pp. 114441-114441.
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© 2020 Elsevier B.V. Polybenzimidazole (PBI) is a chemically and thermally stable polymer, which is being considered for forward osmosis (FO) seawater desalination in regions with high seawater temperatures and salinities. In this work, FO flat sheet membranes were fabricated using non-solvent induced phase separation (NIPS) method from PBI dope solution incorporated with silica nanoparticles (SNPs) at different concentrations (0, 0.5, 1 and 2 wt%). The influence of draw solution concentration, cross-flow velocity and membrane cell orientation on the performance of pristine PBI and PBI/SNP membranes was examined. Results showed that the performance of the PBI/SNP membranes improved compared to the pristine PBI membrane. Addition of 0.5 wt% of SNPs to PBI membranes (S0.5) reduced the membrane's structural parameter (809.4 μm vs. 1193.2 μm), augmented the tensile strength (31.9 MPa vs. 27.3 MPa), and increased water flux by two folds (16.9 Lm−2 h−1 vs. 7.4 Lm−2 h−1) compared to the pristine PBI membrane (S0). Given the thermal stability of the PBI/SNP membrane along with its improved water permeation performance, the modified membrane offers a promising option for the FO process in hot and arid zones.
Das, S, Pradhan, B, Shit, PK & Alamri, AM 2020, 'Assessment of Wetland Ecosystem Health Using the Pressure–State–Response (PSR) Model: A Case Study of Mursidabad District of West Bengal (India)', Sustainability, vol. 12, no. 15, pp. 5932-5932.
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Wetlands are essential for protein production, water sanctification, groundwater recharge, climate purification, nutrient cycling, decreasing floods and biodiversity preservation. The Mursidabad district in West Bengal (India) is situated in the floodplain of the Ganga–Padma and Bhagirathi rivers. The region is characterized by diverse types of wetlands; however, the wetlands are getting depredated day-by-day due to hydro-ecological changes, uncontrolled human activities and rapid urbanization. This study attempted to explore the health status of the wetland ecosystem in 2013 and 2020 at the block level in the Mursidabad district, using the pressure–state–response model. Based on wetland ecosystem health values, we categorized the health conditions and identified the blocks where the health conditions are poor. A total of seven Landsat ETM+ spaceborne satellite images in 2001, 2013 and 2020 were selected as the data sources. The statistical data included the population density and urbanization increase rate, for all administrative units, and were collected from the census data of India for 2001 and 2011. We picked nine ecosystem indicators for the incorporated assessment of wetland ecosystem health. The indicators were selected considering every block in the Mursidabad district and for the computation of the wetland ecosystem health index by using the analytical hierarchy processes method. This study determined that 26.92% of the blocks fell under the sick category in 2013, but increased to 30.77% in 2020, while the percentage of blocks in the very healthy category has decreased markedly from 11.54% to 3.85%. These blocks were affected by higher human pressure, such as population density, urbanization growth rate and road density, which resulted in the degradation of wetland health. The scientific protection and restoration techniques of these wetlands should be emphasized in these areas.
Delhomme, F, Hajimohammadi, A, Almeida, A, Jiang, C, Moreau, D, Gan, Y, Wang, X & Castel, A 2020, 'Physical properties of Australian hurd used as aggregate for hemp concrete', Materials Today Communications, vol. 24, pp. 100986-100986.
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The purpose of this study is to determine the key properties of Australian hemp particles which are used for manufacturing hempcrete. Hemp characteristics have a wide variability due to the influence of the environment conditions in various farmed areas. This study focuses on the measurements of the mechanical, thermal and acoustic performances of three Australian hemp: unretted hemp hurd, retted hemp hurd, and hemp fines. Hemp hurd is usually used in non-load bearing building walls, and hemp fine, which is the by-product of hemp manufacturing industry, is usually incorporated into a render. The experimental results show that the main impact of the retting process is a decrease in bulk density and leading to an improvement in thermal and acoustic properties. Without compaction, the bulk density is ranged from 97 and 118.8 kg.m−3, the max sound absorption coefficient from 0.88 and 0.99, and the thermal conductivity from 64 to 97 mW.m-1. K-1. Hemp fines have excellent thermal and acoustic properties and appear to be an efficient aggregate to produce an insulating render. Australian hemps investigated in this study have shown very similar characteristics to European hemps.
Deng, L, Guo, W, Ngo, HH, Wang, XC, Hu, Y, Chen, R, Cheng, D, Guo, S & Cao, Y 2020, 'Application of a specific membrane fouling control enhancer in membrane bioreactor for real municipal wastewater treatment: Sludge characteristics and microbial community', Bioresource Technology, vol. 312, pp. 123612-123612.
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Dikshit, A, Pradhan, B & Alamri, AM 2020, 'Short-Term Spatio-Temporal Drought Forecasting Using Random Forests Model at New South Wales, Australia', Applied Sciences, vol. 10, no. 12, pp. 4254-4254.
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Droughts can cause significant damage to agriculture and water resources, leading to severe economic losses and loss of life. One of the most important aspect is to develop effective tools to forecast drought events that could be helpful in mitigation strategies. The understanding of droughts has become more challenging because of the effect of climate change, urbanization and water management; therefore, the present study aims to forecast droughts by determining an appropriate index and analyzing its changes, using climate variables. The work was conducted in three different phases, first being the determination of Standard Precipitation Evaporation Index (SPEI), using global climatic dataset of Climate Research Unit (CRU) from 1901–2018. The indices are calculated at different monthly intervals which could depict short-term or long-term changes, and the index value represents different drought classes, ranging from extremely dry to extremely wet. However, the present study was focused only on forecasting at short-term scales for New South Wales (NSW) region of Australia and was conducted at two different time scales, one month and three months. The second phase involved dividing the data into three sample sizes, training (1901–2010), testing (2011–2015) and validation (2016–2018). Finally, a machine learning approach, Random Forest (RF), was used to train and test the data, using various climatic variables, e.g., rainfall, potential evapotranspiration, cloud cover, vapor pressure and temperature (maximum, minimum and mean). The final phase was to analyze the performance of the model based on statistical metrics and drought classes. Regarding this, the performance of the testing period was conducted by using statistical metrics, Coefficient of Determination (R2) and Root-Mean-Square-Error (RMSE) method. The performance of the model showed a considerably higher value of R2 for both the time scales. However, statistical metrics analyzes the varia...
Dikshit, A, Pradhan, B & Alamri, AM 2020, 'Temporal Hydrological Drought Index Forecasting for New South Wales, Australia Using Machine Learning Approaches', Atmosphere, vol. 11, no. 6, pp. 585-585.
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Droughts can cause significant damage to agriculture and water resources leading to severe economic losses. One of the most important aspects of drought management is to develop useful tools to forecast drought events, which could be helpful in mitigation strategies. The recent global trends in drought events reveal that climate change would be a dominant factor in influencing such events. The present study aims to understand this effect for the New South Wales (NSW) region of Australia, which has suffered from several droughts in recent decades. The understanding of the drought is usually carried out using a drought index, therefore the Standard Precipitation Evaporation Index (SPEI) was chosen as it uses both rainfall and temperature parameters in its calculation and has proven to better reflect drought. The drought index was calculated at various time scales (1, 3, 6, and 12 months) using a Climate Research Unit (CRU) dataset. The study focused on predicting the temporal aspect of the drought index using 13 different variables, of which eight were climatic drivers and sea surface temperature indices, and the remainder were various meteorological variables. The models used for forecasting were an artificial neural network (ANN) and support vector regression (SVR). The model was trained from 1901–2010 and tested for nine years (2011–2018), using three different performance metric scores (coefficient of determination (R2), root mean square error (RMSE), and mean absolute error (MAE). The results indicate that ANN was better than SVR in predicting temporal drought trends, with the highest R2 value of 0.86 for the former compared to 0.75 for the latter. The study also reveals that sea surface temperatures and the climatic index (Pacific Decadal Oscillation) do not have a significant effect on the temporal drought aspect. The present work can be considered as a first step, wherein we only study the temporal trends, towards the use of climatological...
Dikshit, A, Sarkar, R, Pradhan, B, Acharya, S & Alamri, AM 2020, 'Spatial Landslide Risk Assessment at Phuentsholing, Bhutan', Geosciences, vol. 10, no. 4, pp. 131-131.
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Landslides are one of the most destructive and most recurring natural calamities in the Himalayan region. Their occurrence leads to immense damage to infrastructure and loss of land, human lives, and livestock. One of the most affected regions is the Bhutan Himalayas, where the majority of the landslides are rainfall-induced. The present study aims to determine the hazard and risk associated with rainfall-induced landslides for the Phuentsholing region located in the southwestern part of the Bhutan Himalayas. The work involves developing a landslide risk map using hazard and vulnerability maps utilizing landslide records from 2004 to 2014. The landslide hazard map was generated by determining spatial and temporal probabilities for the study region. The spatial probability was computed by analyzing the landslide contributing factors like geology, slope, elevation, rainfall, and vegetation based on comprehensive field study and expertise about the area. The contributing factors were divided into various classes and the percentage of landslide occurrence under each class was calculated to understand its contributing significance. Thereafter, a weighted linear combination approach was used in a GIS environment to develop the spatial probability map which was multiplied with temporal probabilities based on regional rainfall thresholds already determined for the region. Consequently, vulnerability assessment was conducted using key elements at risk (population, land use/land cover, proximity to road, proximity to stream) and the weights were provided based on expert judgment and comprehensive field study. Finally, risk was determined and the various regions in the study area were categorized as high, medium, and low risk. Such a study is necessary for low-economic countries like Bhutan which suffers from unavailability of extensive data and research. The study is conducted for a specific region but can be extended to other areas around the investigate...
Dikshit, A, Sarkar, R, Pradhan, B, Jena, R, Drukpa, D & Alamri, AM 2020, 'Temporal Probability Assessment and Its Use in Landslide Susceptibility Mapping for Eastern Bhutan', Water, vol. 12, no. 1, pp. 267-267.
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Landslides are one of the major natural disasters that Bhutan faces every year. The monsoon season in Bhutan is usually marked by heavy rainfall, which leads to multiple landslides, especially across the highways, and affects the entire transportation network of the nation. The determinations of rainfall thresholds are often used to predict the possible occurrence of landslides. A rainfall threshold was defined along Samdrup Jongkhar–Trashigang highway in eastern Bhutan using cumulated event rainfall and antecedent rainfall conditions. Threshold values were determined using the available daily rainfall and landslide data from 2014 to 2017, and validated using the 2018 dataset. The threshold determined was used to estimate temporal probability using a Poisson probability model. Finally, a landslide susceptibility map using the analytic hierarchy process was developed for the highway to identify the sections of the highway that are more susceptible to landslides. The accuracy of the model was validated using the area under the receiver operating characteristic curves. The results presented here may be regarded as a first step towards understanding of landslide hazards and development of an early warning system for a region where such studies have not previously been conducted.
Dikshit, A, Sarkar, R, Pradhan, B, Segoni, S & Alamri, AM 2020, 'Rainfall Induced Landslide Studies in Indian Himalayan Region: A Critical Review', Applied Sciences, vol. 10, no. 7, pp. 2466-2466.
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Landslides are one of the most devastating and recurring natural disasters and have affected several mountainous regions across the globe. The Indian Himalayan region is no exception to landslide incidences affecting key economic sectors such as transportation and agriculture and often leading to loss of lives. As reflected in the global landslide dataset, most of the landslides in this region are rainfall triggered. The region is prone to 15% of the global rainfall-induced landslides, and thereby a review of the studies in the region is inevitable. The high exposure to landslide risk has made the Indian Himalayas receive growing attention by the landslides community. A review of landslides studies conducted in this region is therefore important to provide a general picture of the state-of-the-art, a reference point for researchers and practitioners working in this region for the first time, and a summary of the improvements most urgently needed to better address landslide hazard research and management. This article focuses on various studies ranging from forecasting and monitoring to hazard and susceptibility analysis. The various factors used to analyze landslide are also studied for various landslide zones in the region. The analysis reveals that there are several avenues where significant research work is needed such as the inclusion of climate change factors or the acquisition of basic data of highest quality to be used as input data for computational models. In addition, the review reveals that, despite the entire region being highly landslide prone, most of the studies have focused on few regions and large areas have been neglected. The aim of the review is to provide a reference for stakeholders and researchers who are currently or looking to work in the Indian Himalayas, to highlight the shortcomings and the points of strength of the research being conducted, and to provide a contribution in addressing the future developments most urge...
Dikshit, A, Satyam, N, Pradhan, B & Kushal, S 2020, 'Estimating rainfall threshold and temporal probability for landslide occurrences in Darjeeling Himalayas', Geosciences Journal, vol. 24, no. 2, pp. 225-233.
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© 2020, The Association of Korean Geoscience Societies and Springer. The Indian Himalayan region has been severely affected by landslides causing an immense loss in terms of human lives and economic loss. The landslides are usually induced by rainfall which can be slow and continuous or heavy downpour. The incidences of landslide events in Indian Himalayas have been further aggravated due to the rapid increase in urbanization and thus its increasing impact on socio-economic aspects. There is a dire need for understanding landslide phenomena, estimating its occurrence potential and formulating strategies to minimize the damage caused by them. One of the most affected area is Kalimpong of Darjeeling Himalayas where significant studies have been conducted on zonation, threshold estimation and other related aspects. However, a comprehensive study in terms of temporal prediction for this region remains unattended. The paper deals with assessing landslide hazard using a rainfall threshold model involving daily and cumulative antecedent rainfall values for landslide events. The threshold values were determined using daily rainfall and antecedent rainfall using precipitation and landslide records for 2010–2016. The results show that 20-day antecedent rainfall provides the best fit for landslide occurrences in the region. The rainfall thresholds were further validated using rainfall and landslide data of 2017, which was not considered for threshold estimation. Finally, the results were used to determine the temporal probability for landslide incidence using a Poisson probability model. The validated results suggest that the model has the potential to be used as a preliminary early warning system.
Ding, A, Zhao, Y, Ngo, HH, Bai, L, Li, G, Liang, H, Ren, N & Nan, J 2020, 'Metabolic uncoupler, 3,3′,4′,5-tetrachlorosalicylanilide addition for sludge reduction and fouling control in a gravity-driven membrane bioreactor', Frontiers of Environmental Science & Engineering, vol. 14, no. 6.
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© 2020, Higher Education Press. The gravity-driven membrane bioreactor (MBR) system is promising for decentralized sewage treatment because of its low energy consumption and maintenance requirements. However, the growing sludge not only increases membrane fouling, but also augments operational complexities (sludge discharge). We added the metabolic uncoupler 3,3′,4′,5-tetrachlorosalicylanilide (TCS) to the system to deal with the mentioned issues. Based on the results, TCS addition effectively decreased sludge ATP and sludge yield (reduced by 50%). Extracellular polymeric substances (EPS; proteins and polysaccharides) decreased with the addition of TCS and were transformed into dissolved soluble microbial products (SMPs) in the bulk solution, leading to the break of sludge flocs into small fragments. Permeability was increased by more than two times, reaching 60–70 L/m2/h bar when 10–30 mg/L TCS were added, because of the reduced suspended sludge and the formation of a thin cake layer with low EPS levels. Resistance analyses confirmed that appropriate dosages of TCS primarily decreased the cake layer and hydraulically reversible resistances. Permeability decreased at high dosage (50 mg/L) due to the release of excess sludge fragments and SMP into the supernatant, with a thin but more compact fouling layer with low bioactivity developing on the membrane surface, causing higher cake layer and pore blocking resistances. Our study provides a fundamental understanding of how a metabolic uncoupler affects the sludge and bio-fouling layers at different dosages, with practical relevance for in situ sludge reduction and membrane fouling alleviation in MBR systems. [Figure not available: see fulltext.].
Do, MH, Ngo, HH, Guo, W, Chang, SW, Nguyen, DD, Deng, L, Chen, Z & Nguyen, TV 2020, 'Performance of mediator-less double chamber microbial fuel cell-based biosensor for measuring biological chemical oxygen', Journal of Environmental Management, vol. 276, pp. 111279-111279.
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Recently, the microbial fuel cell-based biosensor has been considered as an attractive technology for measuring wastewater quality such as biochemical oxygen demand (BOD). In this study, a mediator-less double compartment MFC based biosensor utilizing carbon felt as an anode electrode and inoculated with mixed culture was developed to improve the real application of a rapid BOD detection. This study aims to: (i) establish the effect of the operating conditions (i.e., pH, external resistance, fuel feeding rate) on MFC performance; (ii) investigate the correlation between biochemical oxygen demand (BOD) and signal output, and (iii) evaluate the operational stability of the biosensor. The presented result reveals that the maximum current and power production was obtained while 100 mM NaCl and 50 mM Phosphate buffer saline was used as a catholyte solution, neutral pH condition of media and fuel feeding rate at 0.3 mL min-1. Notably, a wider range of BOD concentration up to 300 mg L -1 can be obtained with the voltage output (R2 > 0.9901). Stable and steady power was produced by running MFC in 30 days when cells operated at 1000 Ω external resistance. Our research has some competition with the previous double chamber MFC in the upper limit of BOD detection. This results might help to increase the real application of MFC based BOD biosensor in real-time measurement.
Do, MH, Ngo, HH, Guo, W, Chang, SW, Nguyen, DD, Liu, Y, Varjani, S & Kumar, M 2020, 'Microbial fuel cell-based biosensor for online monitoring wastewater quality: A critical review', Science of The Total Environment, vol. 712, pp. 135612-135612.
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© 2019 Elsevier B.V. Recently, the application of the microbial fuel cell (MFC)-based biosensor for rapid and real-time monitoring wastewater quality is very innovative due to its simple compact design, disposability, and cost-effectiveness. This review represents recent advances in this emerging technology for the management of wastewater quality, where the emphasis is on biochemical oxygen demand, toxicity, and other environmental applications. In addition, the main challenges of this technology are discussed, followed by proposing possible solutions to those challenges based on the existing knowledge of detection principles and signal processing. Potential future research of MFC-based biosensor has been demonstrated in this review.
Doan, S & Fatahi, B 2020, 'Analytical solution for free strain consolidation of stone column-reinforced soft ground considering spatial variation of total stress and drain resistance', Computers and Geotechnics, vol. 118, pp. 103291-103291.
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© 2019 Elsevier Ltd This paper provides an analytical solution for consolidation problem of a stone column-improved soft soil layer subjected to an instantly applied loading under free strain condition. The radial and vertical consolidation equations are solved in a coupled fashion for both the stone column and its surrounding soil. A general solution of excess pore water pressure at any point of a unit cell model in terms of a Fourier-Bessel series was achieved using the combination of separation of variables method and orthogonal expansion technique. The obtained solution can capture the drain (well) resistance effect and the space-dependent distribution of total vertical stress induced by the external loading. Indeed, since the permeability and size of the stone column are directly utilised in the governing equations and the analytical solution, the drain resistance is directly captured. The capabilities of the proposed solution are exhibited through a comprehensive worked example, while the accuracy of the solution is verified against a finite element simulation and field measurements of a case history with good agreements. To examine the effect of various factors on consolidation behaviour of the composite ground, a parametric study involving column spacing, modulus and permeability of soft soil along with distribution pattern of total stress and thickness of soil layer is also conducted. A decrease in the column spacing or an increase in the modulus or permeability of soft soil led to the acceleration of the consolidation process of the soil region, while the variation of the total stress with depth and the thickness of soil deposit primarily affected the consolidation rate of stone column. Under the free strain condition, the average differential settlement between the stone column and encircling soil was indeed considerable during the consolidation process.
Dodangeh, E, Panahi, M, Rezaie, F, Lee, S, Tien Bui, D, Lee, C-W & Pradhan, B 2020, 'Novel hybrid intelligence models for flood-susceptibility prediction: Meta optimization of the GMDH and SVR models with the genetic algorithm and harmony search', Journal of Hydrology, vol. 590, pp. 125423-125423.
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© 2020 Elsevier B.V. Floods are among the deadliest natural hazards for humans and the environment. Identifying the most flood-susceptible areas is a fundamental step in the development of flood mitigation strategies and for reducing flood damage. There is an ongoing global debate regarding the most suitable model for flood-susceptibility modeling and predictions. There is also a growing interest in the development of parsimonious and precise models for flood-susceptibility prediction. This study proposed several novel hybrid intelligence models based on the meta-optimization of the support vector regression (SVR) and group method of data handling (GMDH) using different meta-heuristic algorithms, i.e., the genetic algorithm (GA) and harmony search (HS). In contrast to the traditional models, in the SVR model computational complexity does not depend on the dimensionality of the input space. GMDH model has also advantage of being appropriate to analyze multi-parametric data sets. The methodology was developed for the Haraz-Neka watershed, one of the most flood-prone areas in the coastal margins of the Caspian Sea. A total of nine geospatial parameters (slope degree, aspect, elevation, plan curvature, profile curvature, distance to the river, land use, lithology, and rainfall) were identified as the main flood-conditioning factors using information gain ratio (IGR) analyses. Based on existing reports, 132 flood locations were identified in the study area, 92 points (70%) were used together with geospatial data for flood-susceptibility modeling, and the remaining 40 points (30%) were used to validate the models. An initial flood-susceptibility model was constructed based on the SVR and GMDH models. The model parameters were optimized using the GA and HS to reproduce the flood-susceptibility maps. The prediction accuracy of the resultant maps was evaluated in terms of various statistical measures, i.e., mean square error (MSE), root mean square error (RMSE),...
Dong, W, Li, W, Guo, Y, He, X & Sheng, D 2020, 'Effects of silica fume on physicochemical properties and piezoresistivity of intelligent carbon black-cementitious composites', Construction and Building Materials, vol. 259, pp. 120399-120399.
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© 2020 Elsevier Ltd Carbon black (CB) filled cementitious composites as cement-based sensors with intrinsic piezoresistivity have the potential applications for structural health monitoring (SHM). Effect of silica fume (SF) replacement ratio on the physicochemical, mechanical and piezoresistive properties, and microstructure of CB-cementitious composite were experimentally investigated in this study. The results show that 5% or 10% replacement ratio of SF can improve the water impermeability, setting time and electrical conductivity, but decrease the fresh flowability. Cementitious composite with 10% SF exhibiteds excellent compressive and flexural strengths. Moreover, cement hydration in the acceleration stage decreased with the increase of SF content in the early stage, but the phase analysis after 28 days curing demonstrates that with the addition of SF, there are more hydrated products and less ettringite. In addition, the microstructures of cementitious composites without SF present more porous structures and CB agglomerations. In contrast, the amount of micropores or voids was significantly reduced by the addition of SF due to the physical filling effect and less CB agglomerations. In terms of piezoresistivity, SF can obviously improve the fractional changes of resistivity (FCR) under cyclic compression. With 10% SF, CB-cementitious composites as cement-based sensors exhibited excellent FCR and electrical stability, which will promote their development and application in the SHM for smart infrastructures.
Dong, W, Li, W, Luo, Z, Guo, Y & Wang, K 2020, 'Effect of layer-distributed carbon nanotube (CNT) on mechanical and piezoresistive performance of intelligent cement-based sensor', Nanotechnology, vol. 31, no. 50, pp. 505503-505503.
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Abstract Agglomerated carbon nanotube (CNT) powder was scattered into a cement paste layer-by-layer to form layer-distributed CNT composite (LDCC) as intelligent cement-based sensor. The characteristic of the CNT agglomerations and its effect on the mechanical and piezoresistive properties of cement paste were investigated in this study, and the results were compared with those of uniformly-dispersed CNT composites (UDCC). Based on the statistics of CNT agglomerations, it was found that the sizes of agglomerations varied from several to dozens of micrometres. The larger sized agglomerations with poorer roundness exhibited a higher possibility to cause the pores or voids accompanied with stress concentration when subjected to external forces. Hence, it is necessary to control the agglomeration sizes to reduce the porosity with edges and corners. The UDCC reached the highest compressive strength, followed by the plain cement paste and then LDCC. The mechanical strength of LDCC decreased with the increase of CNT layers. The piezoresistivity occurred in both the UDCC and LDCC, with the former possessing stable and repeatable performance. In addition, the strain-sensing ability of LDCC with moderate CNT layers presented similar sensing efficiency and repeatability to that of UDCC. The related results provide insight into the intelligent cement-based sensors with layer-distributed CNT and agglomerations, which can improve the efficiency and effectively reduce the cost for practical application.
Dong, W, Li, W, Luo, Z, Long, G, Vessalas, K & Sheng, D 2020, 'Structural response monitoring of concrete beam under flexural loading using smart carbon black/cement-based sensors', Smart Materials and Structures, vol. 29, no. 6, pp. 065001-065001.
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© 2020 IOP Publishing Ltd. The fractional changes of resistivity (FCR) of cement-based sensors with various carbon black (CB) contents were firstly investigated under uniaxial compression in this study. Then the piezoresistive behaviours of embedded cement-based sensors in unreinforced small-scale concrete beams were investigated under flexural bending load. As for the embedded cement-based sensors in the compression zones of the beam, the stress magnitude and crack failure initiation of the beams can be detected and monitored by a gradual decrease and then a sharp increase in the FRC. On the other hand, as for the counterpart sensors in the tension zones of the beam, the stress magnitude and crack failure initiation can be recognized by the gradual increase in resistivity and then a rapid jump in the FRC. During the stress monitoring of the concrete beam, the FCR values of cement-based sensors in both the compression and tension zones were consistent with the flexural stress changes, which exhibit acceptable sensitivity and reversibility. Moreover, very firm and dense interfaces in the boundaries indicate the excellent cohesion between embedded CB/cement-based sensors and beams. The related results demonstrate that the CB/cement-based sensors embedded in concrete exhibit excellent piezoresistive behaviours to potentially monitor the stress magnitude and failure process of concrete structures and pavements.
Dong, W, Li, W, Shen, L, Sun, Z & Sheng, D 2020, 'Piezoresistivity of smart carbon nanotubes (CNTs) reinforced cementitious composite under integrated cyclic compression and impact', Composite Structures, vol. 241, pp. 112106-112106.
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© 2020 Elsevier Ltd The cyclic compression and four series of fixed magnitude impact loads with an increment of 50 times were conducted alternatively on the smart carbon nanotubes (CNTs) reinforced cementitious composites, to evaluate the piezoresistive sensitivity and repeatability of composites after exposed to different drop impact energies. The results show that the impacts procedure suddenly increased in electrical resistivity due to the emerged micro-cracks and pores, and higher impact energy led to faster resistivity increase. On the other hand, when the impact is repeatedly applied, a high impact resistance of the cementitious composites could be observed, which was attributed to the dense microstructures. Moreover, instead of instable and uneven output of electrical resistivity during cyclical compression, more stable and uniform fractional changes of resistivity were achieved after exposed to impact load. However, severe nonlinearity with swift resistivity reduction of cementitious composites under low loads was observed at the beginning and the end of cyclic compression after subjected to many impacts with impact energy of 18.72 × 10−4 J/cm3. The related outcomes of smart conductive cementitious composites subjected to cyclic compression and impact will provide an insight into the stable electrical signal output and promote the applications of cement-based sensors for structural health monitoring under various loading conditions.
Dong, W, Li, W, Vessalas, K & Wang, K 2020, 'Mechanical and Conductive Properties of Smart Cementitious Composites with Conductive Rubber Crumbs', ES Materials & Manufacturing, vol. 7, pp. 51-63.
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Dong, W, Li, W, Wang, K, Guo, Y, Sheng, D & Shah, SP 2020, 'Piezoresistivity enhancement of functional carbon black filled cement-based sensor using polypropylene fibre', Powder Technology, vol. 373, pp. 184-194.
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In this study, different dosages of carbon black (CB) and polypropylene (PP) were added to develop functional cementitious composites as cement-based sensors. The results show that electrical conductivity increased with the amount of PP fibres, due to the enclosed CB nanoparticles and more conductive passages. The compressive strength slightly decreased, while the flexural strength was significantly increased with the increased amount of PP fibres. The improvement is mainly achieved by the reduced CB concentration in cement matrix and the excellent tensile strength of PP fibres. Under the cyclic compression, the piezoresistivity increased by three times for 0.4 wt% PP fibres filled CB/cementitious composite, regardless of the loading rates. The flexural stress sensing efficiency was considerably lower than that of compressive stress sensing, but it increased with the amount of PP fibres. Moreover, fitting formulas were proposed and used to evaluate the self-sensing capacity, with the attempts to apply cement-based sensors for structural health monitoring.
Dong, W, Li, W, Wang, K, Han, B, Sheng, D & Shah, SP 2020, 'Investigation on physicochemical and piezoresistive properties of smart MWCNT/cementitious composite exposed to elevated temperatures', Cement and Concrete Composites, vol. 112, pp. 103675-103675.
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© 2020 Elsevier Ltd Piezoresistivity of smart carbon nanotube/cementitious composite has been experimentally investigated, but the piezoresistive performance had been rarely studied when exposed to elevated temperatures. In this study, the physicochemical and mechanical properties, and piezoresistive behaviours of multi-walled carbon nanotube (MWCNT) reinforced smart cementitious composite were investigated under heat treatments of elevated temperatures of 300 °C and 600 °C. The microstructures, crystal deterioration and thermal gravity relationships were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD) and thermos-gravimetric (TG) analysis. The results show that the compressive strength and elastic modulus of MWCNT/cementitious composite after heat treatments gradually decreased, especially under the high temperature of 600 °C. There was a sudden growth of fractional changes of resistivity (FCR) after heat treatment. The higher temperature treatments led to more extensive sudden increase in the piezoresistivity. In the linear part of the relationship curves of FCR to the strain, the gauge factor even increased at the temperature of 300 °C. Moreover, the mechanism for the altered piezoresistivity was fundamentally explained and discussed by the MWCNT purification and destructions of MWCNT, cement matrix and agglomerations after heat treatments. Therefore, the related outcomes will promote the understanding and application of smart MWCNT/cementitious composite for structural health monitoring (SHM) under extreme environments.
Dong, W, Li, W, Wang, K, Luo, Z & Sheng, D 2020, 'Self-sensing capabilities of cement-based sensor with layer-distributed conductive rubber fibres', Sensors and Actuators A: Physical, vol. 301, pp. 111763-111763.
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Dong, W, Li, W, Wang, K, Vessalas, K & Zhang, S 2020, 'Mechanical strength and self-sensing capacity of smart cementitious composite containing conductive rubber crumbs', Journal of Intelligent Material Systems and Structures, vol. 31, no. 10, pp. 1325-1340.
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The effects of conductive rubber crumbs on the mechanical properties and self-sensing capacities of cementitious composites are investigated in this study. The rubberized cementitious composites with five different contents of conductive rubber crumbs are incorporated, ranging from 0%, 10%, 20%, 30% and 40% by mass of fine aggregate. Under the uniaxial cyclic compression, all the conductive rubber crumbs–filled cement composites exhibit excellent repeatability of piezoresistivity. The mortar with 20% conductive rubber crumbs at a water-to-binder ratio of 0.42 displayed the best piezoresistive sensitivity. Based on the relative positions of conductive rubber crumbs in the rubberized cement mortar, three conductive mechanisms were proposed for the conductive rubber crumbs, including complete isolation state, neighbouring state and the contact state. The isolation state plays a dominant role when the content of the conductive rubber crumbs is low, in which the piezoresistive behaviour is mainly controlled by the resistivity changes in cement matrix. In the neighbouring state, pores or voids in the gaps between nearby conductive rubber crumbs make the conductive rubber crumbs easier to connect, thus decreasing the resistivity under uniaxial compression. As for the contact state, the decreased contact resistance and the absence of sand between conductive rubber crumbs lead to higher resistivity changes under cyclic compression. The related results indicate that conductive rubber crumbs in cement mortar have application potentials for structural health monitoring.
Dong, Y & Fatahi, B 2020, 'Discrete element simulation of cavity expansion in lightly cemented sands considering cementation degradation', Computers and Geotechnics, vol. 124, pp. 103628-103628.
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© 2020 Elsevier Ltd This study aims to investigate the influence of cementation on the stress-strain and strength characteristics of soil during cavity expansion in lightly cemented sand deposit using three-dimensional discrete element simulations. Contact models, simulating the cementation effects of bonded clumps and capturing the interlocking effects between discrete sand particles, are incorporated to mimic the cemented sands with various cement contents. The microscopic parameters are calibrated and validated against existing experimental results. Real scale cylindrical cavity expansion models starting from zero initial cavity radius with different levels of cementation are developed, and each proposed model consists of 150,000 particles with boundary conditions carefully selected to reproduce the realistic scenario. The embedded scripting is utilised to precisely measure both the local and global stress–strain variations, and record and analyse the cementation bond breakage during the cavity expansion process. The results confirm that the cementation enhances the material strength through the increase in cohesion and tensile strength at the contacting interfaces, whereas the friction angle is not altered notably. Hence, the failure envelope of the cemented sand gradually merges with the critical state line due to the cementation degradation, particularly at a high confining pressure. It was found that the failure mode of the lightly cemented sand adopted in this study, was mainly controlled by the shear rather than tensile strength at the contacting interfaces. Referring to the numerical predictions it is evident that the zone with significant cementation degradation due to the cavity expansion extends as far as 4af for all cemented specimens (af being the final cavity radius). In addition, specimens with higher cement content experience a more pronounced dilation at the internal cavity wall, while an inverse trend is captured at a greater radial ...
Dong, Y, Fatahi, B & Khabbaz, H 2020, 'Three dimensional discrete element simulation of cylindrical cavity expansion from zero initial radius in sand', Computers and Geotechnics, vol. 117, pp. 103230-103230.
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© 2019 Elsevier Ltd This study seeks to assess the influence of choice of initial cavity radius on the soil response during cavity expansion in sandy soil adopting three-dimensional discrete element simulations and obtaining the size of the influence zone when the expansion starts from zero initial radius. Sandy soil is modelled adopting rolling resistance contact model to capture the effects of particle interlocking, and the microscopic parameters are calibrated utilising linear model deformability method for both loose and dense sands against experimental results. Four cylindrical cavity expansions that commenced from different initial radii are simulated in dense and loose sand specimens. The large-scale three-dimensional model is proposed with more than 500,000 particles, enabling precise volumetric dilation and contraction predictions using strain rate tensors. During the cavity expansion process, cavity pressure is constantly recorded by appropriate subroutines, while the stress-strain and void ratio variations are continuously monitored using an array of prediction spheres situated close to the internal cavities. The results confirm that the initial cavity radius chosen has conspicuous effects on the cavity pressure, the stress path, the volumetric strain and the deviatoric stress, especially at the initial stage of expansion; however, these effects become less pronounced and are ultimately minor as the cavity reaches full expansion. The results confirmed that given the same expansion volume, the pressure required to create a cavity is significantly larger than expanding an existing cavity in the same soil medium, whereas the pressure needed to maintain an already expanded cavity is not sensitive to the choice of initial cavity radius. The results obtained were further validated adopting the variations of stress path, deviatoric stress and volumetric strain in the vicinity of the cavity wall. The findings from this study may provide practicing en...
Dorji, P, Kim, DI, Hong, S, Phuntsho, S & Shon, HK 2020, 'Pilot-scale membrane capacitive deionisation for effective bromide removal and high water recovery in seawater desalination', Desalination, vol. 479, pp. 114309-114309.
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© 2020 Although seawater desalination is becoming an important technology for freshwater production, the presence of a high concentration of bromide in the seawater presents a major challenge. Bromide is one of the major inorganic precursors for the formation of disinfection by-products such as bromate, which is highly regulated due to its toxicity and carcinogenicity. Hence, a significant reduction of bromide ions is required prior to water disinfection. In Australia, all the desalination plants have to operate a two-stage reverse osmosis system to ensure effective bromide removal, which adds significant cost to the desalination system. In this study, a pilot-scale membrane capacitive deionisation (MCDI) was investigated as a potential alternative to the 2nd stage RO in seawater desalination. Moreover, strategies to enhance water recovery in MCDI was also carried out by using lower flow rates and shorter duration during the desorption stage. In order to reduce energy consumption in MCDI, a combined short-circuit and reverse polarity desorption is introduced. The results showed that MCDI can effectively remove bromide and dissolved salt at a much lower energy consumption compared with membrane process and that MCDI can be operated to achieve high water recovery without increasing the total energy consumption.
Drumond, PDP, Ball, JE, Moura, P & Pinto Coelho, MML 2020, 'Are the current On-site Stormwater Detention (OSD) policies the best solution for source control stormwater management? A case study of Australian and Brazilian cities', Urban Water Journal, vol. 17, no. 3, pp. 273-281.
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Duan, H, Gao, S, Li, X, Ab Hamid, NH, Jiang, G, Zheng, M, Bai, X, Bond, PL, Lu, X, Chislett, MM, Hu, S, Ye, L & Yuan, Z 2020, 'Improving wastewater management using free nitrous acid (FNA)', Water Research, vol. 171, pp. 115382-115382.
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Free nitrous acid (FNA), the protonated form of nitrite, has historically been an unwanted substance in wastewater systems due to its inhibition on a wide range of microorganisms. However, in recent years, advanced understanding of FNA inhibitory and biocidal effects on microorganisms has led to the development of a series of FNA-based applications that improve wastewater management practices. FNA has been used in sewer systems to control sewer corrosion and odor; in wastewater treatment to achieve carbon and energy efficient nitrogen removal; in sludge management to improve the sludge reduction and energy recovery; in membrane systems to address membrane fouling; and in wastewater algae systems to facilitate algae harvesting. This paper aims to comprehensively and critically review the current status of FNA-based applications in improving wastewater management. The underlying mechanisms of FNA inhibitory and biocidal effects are also reviewed and discussed. Knowledge gaps and current limitations of the FNA-based applications are identified; and perspectives on the development of FNA-based applications are discussed. We conclude that the FNA-based technologies have great potential for enhancing the performance of wastewater systems; however, further development and demonstration at larger scales are still required for their wider applications.
Duan, H, van den Akker, B, Thwaites, BJ, Peng, L, Herman, C, Pan, Y, Ni, B-J, Watt, S, Yuan, Z & Ye, L 2020, 'Mitigating nitrous oxide emissions at a full-scale wastewater treatment plant', Water Research, vol. 185, pp. 116196-116196.
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Mitigation of nitrous oxide (N2O) emissions is of primary importance to meet the targets of reducing carbon footprints of wastewater treatment plants (WWTPs). Despite of a large amount of N2O mitigation studies conducted in laboratories, full-scale implementation of N2O mitigation is scarce, mainly due to uncertainties of mitigation effectiveness, validation of N2O mathematical model, risks to nutrient removal performance and additional costs. This study aims to address the uncertainties by investigating the quantification, development and implementation of N2O mitigation strategies at a full-scale sequencing batch reactor (SBR). To achieve this, N2O emission dynamics, nutrient removal performance and operation of the SBR were monitored to quantify N2O emissions, and identify the N2O generation mechanisms. N2O mitigation strategies centered on reducing dissolved oxygen (DO) levels were consequently proposed and evaluated using a multi-pathway N2O production mathematical model before implementation. The implemented mitigation strategy resulted in a 35% reduction in N2O emissions (from the emission factor of 0.89 ± 0.05 to 0.58 ± 0.06%), which was equivalent to annual reduction of 2.35 tonne of N2O from the studied WWTP. This could be mainly attributed to reductions in N2O generated via the NH2OH oxidation pathway due to the lowering of DO level. As the first reported mitigation strategy permanently implemented at a full scale WWTP, it showcased that the mitigation of N2O emissions at full-scale is feasible and that widely accepted N2O mitigation strategies developed in laboratory studies are also likely effective in full-scale plants. Furthermore, the close agreement between the validated and predicted N2O emission factors (0.58% vs 0.55%, respectively), showed that the ...
Duong, HC, Ansari, AJ, Cao, HT, Nguyen, NC, Do, K-U & Nghiem, LD 2020, 'Membrane distillation regeneration of liquid desiccant solution for air-conditioning: Insights into polarisation effects and mass transfer', Environmental Technology & Innovation, vol. 19, pp. 100941-100941.
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© 2020 Membrane distillation (MD) embodies ideal attributes for the regeneration of liquid desiccant solutions used in air-conditioning systems. The MD process has been experimentally proven technically viable for the regeneration of liquid desiccant solutions; however, it suffers severely from temperature and concentration polarisation effects. In this study, for the first time a descriptive mass and heat transfer (DMHT) model is developed to quantitatively describe the mass transfer and the negative impacts of temperature and concentration polarisation during the MD regeneration of the LiCl desiccant solution. The simulation results demonstrate significant reduction in water flux along the membrane due to decreasing mass transfer coefficient (Cm) and transmembrane water vapour pressure gradient (ΔPm). Over the length of the membrane leaf of 0.145 m, water flux reduces by 31% from 11.0 to 7.6 L/m2⋅h. The temperature and concentration polarisation effects cause a substantial decline in the process driving force - ΔPm is only two thirds of the water vapour pressure difference between the bulk feed and distillate (ΔPb). Temperature polarisation is the predominant cause of the reduction in ΔPm compared with ΔPb; however, the negative impact of concentration polarisation is also notable. Finally, amongst the key operating conditions, the inlet feed temperature and concentration exert the most profound influence on the temperature and concentration polarisation during the DCMD regeneration of the hyper saline LiCl solution.
Duong, HC, Ansari, AJ, Hailemariam, RH, Woo, YC, Pham, TM, Ngo, LT, Dao, DT & Nghiem, LD 2020, 'Membrane Distillation for Strategic Water Treatment Applications: Opportunities, Challenges, and Current Status', Current Pollution Reports, vol. 6, no. 3, pp. 173-187.
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© 2020, Springer Nature Switzerland AG. Purpose of Review: Membrane distillation (MD) has been known as a promising water treatment process for many years. However, despite its advantages, MD has never been able to compete with other processes for industrial water treatment and supply. Instead, it has been orientated towards several unique strategic water treatment applications. This review aims to uncover the opportunities and technical challenges pertinent to the MD process and the current status of its strategic water treatment applications most notably including decentralised small-scale desalination for fresh water provision in remote areas, hybridisation with forward osmosis (FO) for treatment of challenging polluted waters, regeneration of liquid desiccant solutions for air conditioning, and treatment of acid effluents for beneficial reuse. Recent Findings: Pilot and small-scale MD systems have been demonstrated for decentralised desalination using various renewable energy sources to supply fresh water in remote, rural areas and on ships where other desalination processes are inefficient or unfeasible. For this strategic desalination application, MD is technically viable, but more works on configuration modification and process optimisation are required to reduce the process energy consumption and water production costs. For the three other strategic applications, the technical viability of the MD process has been proved by extensive lab-scale researches, but its economic feasibility is still questionable due to the lack of large-scale evaluation and the uncertain costs of MD systems. Summary: The orientation of MD towards strategic water treatment applications is clear. However, huge efforts are required to facilitate these applications at commercial and full scale.
Dwi Prasetyo, W, Putra, ZA, Bilad, MR, Mahlia, TMI, Wibisono, Y, Nordin, NAH & Wirzal, MDH 2020, 'Insight into the Sustainable Integration of Bio- and Petroleum Refineries for the Production of Fuels and Chemicals', Polymers, vol. 12, no. 5, pp. 1091-1091.
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A petroleum refinery heavily depends on crude oil as its main feedstock to produce liquid fuels and chemicals. In the long term, this unyielding dependency is threatened by the depletion of the crude oil reserve. However, in the short term, its price highly fluctuates due to various factors, such as regional and global security instability causing additional complexity on refinery production planning. The petroleum refining industries are also drawing criticism and pressure due to their direct and indirect impacts on the environment. The exhaust gas emission of automobiles apart from the industrial and power plant emission has been viewed as the cause of global warming. In this sense, there is a need for a feasible, sustainable, and environmentally friendly generation process of fuels and chemicals. The attention turns to the utilization of biomass as a potential feedstock to produce substitutes for petroleum-derived fuels and building blocks for biochemicals. Biomass is abundant and currently is still low in utilization. The biorefinery, a facility to convert biomass into biofuels and biochemicals, is still lacking in competitiveness to a petroleum refinery. An attractive solution that addresses both is by the integration of bio- and petroleum refineries. In this context, the right decision making in the process selection and technologies can lower the investment and operational costs and assure optimum yield. Process optimization based on mathematical programming has been extensively used to conduct techno-economic and sustainability analysis for bio-, petroleum, and the integration of both refineries. This paper provides insights into the context of crude oil and biomass as potential refinery feedstocks. The current optimization status of either bio- or petroleum refineries and their integration is reviewed with the focus on the methods to solve the multi-objective optimization problems. Internal and external uncertain parameters are importan...
Ekanayake, UGM, Seo, DH, Faershteyn, K, O'Mullane, AP, Shon, H, MacLeod, J, Golberg, D & Ostrikov, KK 2020, 'Atmospheric-pressure plasma seawater desalination: Clean energy, agriculture, and resource recovery nexus for a blue planet', Sustainable Materials and Technologies, vol. 25, pp. e00181-e00181.
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Eldosouky, AM, Pham, LT, Mohmed, H & Pradhan, B 2020, 'A comparative study of THG, AS, TA, Theta, TDX and LTHG techniques for improving source boundaries detection of magnetic data using synthetic models: A case study from G. Um Monqul, North Eastern Desert, Egypt', Journal of African Earth Sciences, vol. 170, pp. 103940-103940.
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© 2020 Elsevier Ltd The boundaries detection techniques have a great role in enhancing and interpreting the geologic features of magnetic data. In the literature, several filters (THG, AS, TA, NTilt, Theta, TDX, TAHG, LTHG) for identifying the boundaries of the magnetic sources have been suggested. These methods are generally performed based on gradients (vertical and horizontal) of the potential field. This paper presents a comparative investigation of different boundary detection filters including THG (total horizontal gradient), AS (analytical signal), TA (tilt angle), Theta (Cos θ), TDX (horizontal tilt angle), and LTHG (Logistic function of the THG). The effect of each filter was examined on two synthetic magnetic data sets. Moreover, the filters are also applied to a real magnetic data set from the Gabal (G) Um Monqul, North Eastern Desert (NED) of Egypt. The obtained results were correlated with known geologic structures of the study area. From the comparison between several applied methods, the horizontal boundaries of geologic sources obtained by the LTHG were found to be sharper and clearer than other ones. The results confirm that the LTHG method is an effective filter for interpreting aeromagnetic data qualitatively and can be applied for enhancing the source edges of different potential field datasets.
Faber, MH, Miraglia, S, Qin, J & Stewart, MG 2020, 'Bridging resilience and sustainability - decision analysis for design and management of infrastructure systems', Sustainable and Resilient Infrastructure, vol. 5, no. 1-2, pp. 102-124.
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The paper proposes a novel decision analysis framework and corresponding probabilistic systems representations allowing for the consistent and integral quantification of systems resilience and sustainability. This facilitates–to the knowledge of the authors, for the first time–that decisions relating to the governance of socio-ecologic-technical systems may be optimized with due consideration of their impacts at both local and short-term time scales as well as on global and long-term time scales. The resilience performance of the interlinked system is modeled through the formulation of resilience failure events which occur if one or more of the capacities of the interlinked system are exhausted. Sustainability failure is analogously introduced as the event that one or more of the Planetary Boundaries are exceeded. A principal example shows there is a trade-off between resilience, generation of benefits, consumption of materials, and emissions to the environment. Resilience provides benefits to society but at the same time imposes material consumption and emissions to the environment. Systems can, however, be designed such that resource consumption and associated environmental impacts are reduced and the resilience performance is increased simultaneously. The example further illustrates that social governance system failure may follow from inadequate design and governance of infrastructure.
Faisal, M, Hannan, MA, Ker, PJ, Rahman, MSA, Begum, RA & Mahlia, TMI 2020, 'Particle swarm optimised fuzzy controller for charging–discharging and scheduling of battery energy storage system in MG applications', Energy Reports, vol. 6, pp. 215-228.
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© 2020 The Authors Aiming at reducing the power consumption and costs of grids, this paper deals with the development of particle swarm optimisation (PSO) based fuzzy logic controller (FLC) for charging–discharging and scheduling of the battery energy storage systems (ESSs) in microgrid (MG) applications. Initially, FLC was developed to control the charging–discharging of the storage system to avoid mathematical calculation of the conventional system. However, to improve the charging–discharging control, the membership function of the FLC is optimised using PSO technique considering the available power, load demand, battery temperature and state of charge (SOC). The scheduling controller is the optimal solution to achieve low-cost uninterrupted reliable power according to the loads. To reduce the grid power demand and consumption costs, an optimal binary PSO is also introduced to schedule the ESS, grid and distributed sources under various load conditions at different times of the day. The obtained results proved that the robustness of the developed PSO based fuzzy control can effectively manage the battery charging–discharging with reducing the significant grid power consumption of 42.26% and the costs of the energy usage by 45.11% which also demonstrates the contribution of the research.
Fang, C, Rajabzadeh, S, Zhang, P, Liu, W, Kato, N, Shon, HK & Matsuyama, H 2020, 'Controlling spherulitic structures at surface and sub-layer of hollow fiber membranes prepared using nucleation agents via triple-orifice spinneret in TIPS process', Journal of Membrane Science, vol. 609, pp. 118229-118229.
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Fang, J, Wu, C, Rabczuk, T, Wu, C, Sun, G & Li, Q 2020, 'Phase field fracture in elasto-plastic solids: a length-scale insensitive model for quasi-brittle materials', Computational Mechanics, vol. 66, no. 4, pp. 931-961.
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Phase-field methods for fracture have been integrated with plasticity for better describing constitutive behaviours. In most of the previous phase-field models, however, the length-scale parameter must be interpreted as a material property in order to match the material strength in experiments. This study presents a phase-field model for fracture coupled with plasticity for quasi-brittle materials with emphasis on insensitivity of the length-scale parameter. The proposed model is formulated using variational principles and implemented numerically in the finite element framework. The effective yield stress is calibrated to vary with the length-scale parameter such that the tensile strength remains the same. Moreover, semi-analytical solutions are derived to demonstrate that the length-scale parameter has a negligible effect on the stress–displacement curve. Five representative examples are considered here to validate the phase-field model for fracture in quasi-brittle materials. The simulated force–displacement curves and crack paths agree well with the corresponding experimental results. Importantly, it is found that the global structural response is insensitive to the length scale though it may influence the size of the failure zone. In most cases, a large length-scale parameter can be used for saving the computational cost by allowing the use of a coarse mesh. On the other hand, a sufficiently small length-scale parameter can be selected to prevent overly diffusive damage, making it possible for the proposed phase-field model to simulate the fracture behaviour with Γ-convergence.
Fanos, AM, Pradhan, B, Alamri, A & Lee, C-W 2020, 'Machine Learning-Based and 3D Kinematic Models for Rockfall Hazard Assessment Using LiDAR Data and GIS', Remote Sensing, vol. 12, no. 11, pp. 1755-1755.
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Rockfall is one of the most hazardous phenomena in mountainous and hilly regions with high and steep terrain. Such incidents can cause massive damage to people, properties, and infrastructure. Therefore, proper rockfall hazard assessment methods are required to save lives and provide a guide for the development of an area. The aim of this research is to develop a method for rockfall hazard assessment at two different scales (regional and local). A high-resolution airborne laser scanning (ALS) technique was utilized to derive an accurate digital terrain model (DTM); next, a terrestrial laser scanner (TLS) was used to capture the topography of the two most critical areas within the study area. A staking machine-learning model based on different classifiers, namely logistic regression (LR), random forest (RF), artificial neural network (ANN), support vector machine (SVM), and k-nearest neighbor (KNN), was optimized and employed to determine rockfall probability by utilizing various rockfall conditioning factors. A developed 3D rockfall kinematic model was used to obtain rockfall trajectories, velocity, frequency, bouncing height, kinetic energy, and impact location. Next, a spatial model combined with a fuzzy analytical hierarchy process (fuzzy-AHP) integrated in the Geographic Information System (GIS) was developed to assess rockfall hazard in two different areas in Ipoh, Malaysia. Additionally, mitigation processes were suggested and assessed to provide a comprehensive information for urban planning management. The results show that, the stacking random forest–k-nearest neighbor (RF-KNN) model is the best hybrid model compared to other tested models with an accuracy of 89%, 86%, and 87% based on training, validation, and cross-validation datasets, respectively. The three-dimension rockfall kinematic model was calibrated with an accuracy of 93% and 95% for the two study areas and subsequently the rockfall trajectories and their characteristics wer...
Fatahi, B, Huang, B, Yeganeh, N, Terzaghi, S & Banerjee, S 2020, 'Three-Dimensional Simulation of Seismic Slope–Foundation–Structure Interaction for Buildings Near Shallow Slopes', International Journal of Geomechanics, vol. 20, no. 1, pp. 04019140-04019140.
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© 2019 American Society of Civil Engineers. Buildings constructed adjacent to the slope crest in seismically active areas might be exposed to serious danger when they are subjected to strong earthquake excitations. The ground conditions can influence the seismic response of structures through a phenomenon known as the slope-foundation-structure interaction. Indeed, the presence of the slope in the vicinity of a building foundation can significantly affect the seismic response of the superstructure. In this study, the impact of shallow slopes on the seismic performance of nearby buildings was numerically assessed. In the adopted three-dimensional finite-element simulation, the nonlinear variations of the soil stiffness and damping with the cyclic shear strain plus varying distances between the edge of the foundation and crest of the slope were employed. A 15-story moment-resisting structure, a 30-m-thick clayey deposit, and a 2-m-high shallow slope were considered as the benchmark model, being simulated using the direct method in the time domain. According to the results of the analyses, the seismic response of a building could be highly sensitive to the distance between the slope crest and foundation. Particularly, the building closer to the slope crest experienced more severe foundation rocking, lateral deformation, and interstory drifts owing to the amplified effect of the slope-foundation-structure interaction. Moreover, the results highlighted the importance of the slope-foundation-structure interaction in altering the natural period and damping of the system. Hence, it is critical for practicing engineers to assess the impact of nearby slopes on the seismic performance of structures with extreme care to ensure the reliability and safety of the design.
Fattah, IMR, Noraini, MY, Mofijur, M, Silitonga, AS, Badruddin, IA, Khan, TMY, Ong, HC & Mahlia, TMI 2020, 'Lipid Extraction Maximization and Enzymatic Synthesis of Biodiesel from Microalgae', Applied Sciences, vol. 10, no. 17, pp. 6103-6103.
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Microalgae has received overwhelming attention worldwide as a sustainable source for energy generation. However, the production of biofuel from microalgae biomass consists of several steps, of which lipid extraction is the most important one. Because of the nature of feedstock, extraction needs special attention. Three different methods were studied to extract algal oil from two different algae variant, Chlorella sp. and Spirulina sp. The highest percentage oil yield was obtained by ultrasonication (9.4% for Chlorella sp., 6.6% for Spirulina sp.) followed by the Soxhlet and solvent extraction processes. Ultrasonication and Soxhlet extraction processes were further optimized to maximize oil extraction as solvent extraction was not effective in extracting lipid. For ultrasonication, an amplitude of 90% recorded the highest percentage yield of oil for Spirulina sp. and a 70% amplitude recorded the highest percentage yield of oil for Chlorella sp. On the other hand, for Soxhlet extraction, a combination of chloroform, hexane, and methanol at a 1:1:1 ratio resulted in the highest yield of algal oil. Afterward, the crude algae oil from the ultrasonication process was transesterified for 5 h using an immobilized lipase (Novozyme 435) at 40 °C to convert triglycerides into fatty acid methyl ester and glycerol. Thus, ultrasonic-assisted lipid extraction was successful in producing biodiesel from both the species.
Feng, Y, Wang, Q, Wu, D, Gao, W & Tin-Loi, F 2020, 'Stochastic nonlocal damage analysis by a machine learning approach', Computer Methods in Applied Mechanics and Engineering, vol. 372, pp. 113371-113371.
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© 2020 Elsevier B.V. A machine learning aided stochastic nonlocal damage analysis framework is proposed for quasi-brittle materials. The uncertain system parameters, including the material properties and loading actions, have been incorporated and analysed within a unified safety assessment framework against various working conditions. A three-dimensional integral-type nonlocal damage model through finite element method (FEM) has been adopted. For the purpose of investigating the probabilistic damage analysis problems, a freshly established machine learning approach, namely the capped-extended-support vector regression method (C-X-SVR), is proposed to eliminate the influences of random outliers in the first step, then establish the relationship between the uncertain systemic inputs and structural responses. Such that the training robustness and computational adaptability of the proposed regression model can be reinforced. Moreover, the proposed approach is competent of efficiently predicting the statistical information (i.e., means, standard deviations, probability density functions and cumulative density functions) of structural behaviours under continuous information update of the uncertain working condition from mercurial environment. One real-life experimental validation and two numerical investigations are implemented to further verify the effectiveness and efficiency of the uncertainty quantification framework against probabilistic damage analysis.
Gan, YY, Chen, W-H, Ong, HC, Sheen, H-K, Chang, J-S, Hsieh, T-H & Ling, TC 2020, 'Effects of dry and wet torrefaction pretreatment on microalgae pyrolysis analyzed by TG-FTIR and double-shot Py-GC/MS', Energy, vol. 210, pp. 118579-118579.
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© 2020 Elsevier Ltd TG-FTIR and double-shot Py-GC/MS were executed to investigate the effects of torrefaction pretreatment on microalga (Chlorella vulgaris ESP-31) pyrolysis. TG-FTIR was performed to analyze the pyrolysis and combustion gas of raw and wet torrefied microalgae, whereas double-shot Py-GC/MS was applied to investigate the product distributions of single and two-stage thermal degradation of the microalgae. From the result, wet torrefaction successfully eliminated the release of CO in the pyrolysis gas. The highest generation of C–H during pyrolysis was achieved by the microalgae pretreated with dilute sulfuric acid. In the combustion gas, the intensity of O–H absorption band was removed in the first stage after wet torrefaction. The Py-GC/MS analysis revealed that the fatty acids (48.22%) were the dominant component in the bio-oil derived from the microalgae pretreated by the dilute sulfuric acid in wet torrefaction. Meanwhile, the productivity of carbohydrate-derived products (anhydrous sugars) decreased from 18.58 to 0.39% in the pyrolytic bio-oil after the wet torrefaction pretreatment. In contrast, carbohydrate- and lipid-derived products were decreased in the bio-oil after the dry torrefaction pretreatment. Similarly, microwave-assisted wet torrefaction in sulfuric acid is an effective pretreatment technique to produce high-quality pyrolytic bio-oil for biofuel production.
Gan, YY, Ong, HC, Chen, W-H, Sheen, H-K, Chang, J-S, Chong, CT & Ling, TC 2020, 'Microwave-assisted wet torrefaction of microalgae under various acids for coproduction of biochar and sugar', Journal of Cleaner Production, vol. 253, pp. 119944-119944.
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Gao, KW, Loo, WS, Snyder, RL, Abel, BA, Choo, Y, Lee, A, Teixeira, SCM, Garetz, BA, Coates, GW & Balsara, NP 2020, 'Miscible Polyether/Poly(ether–acetal) Electrolyte Blends', Macromolecules, vol. 53, no. 14, pp. 5728-5739.
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Gao, P, Huang, Z & Yu, H 2020, 'Exploration of the Dehydrogenation Pathways of Ammonia Diborane and Diammoniate of Diborane by Molecular Dynamics Simulations Using Reactive Force Fields', The Journal of Physical Chemistry A, vol. 124, no. 9, pp. 1698-1704.
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Ammonium aminodiboranate (AADB) and diammoniate of diborane (DADB) are two isomers of ammonia borane (AB), which have been intensively studied for hydrogen storage. Their high hydrogen contents give them the high potential to serve as hydrogen storage materials. To explore their dehydrogenation pathways, molecular dynamics (MD) simulations with a reactive force field (ReaxFF) were applied. Temperature ramping simulations of their thermolysis were carried out. For AADB, at low temperatures, its hydrogen release can be realized mainly via intermolecular dehydrogenations. As the temperature of the simulated system increases, the formations of B-N bonds begin to occur. In the case of DADB, we found that this molecule could release hydrogen at a lower temperature with the cleavage of the B-N bond. The compositional analysis of the simulated systems was also conducted to monitor the potential intermediates along their dehydrogenation pathways. Our current work provides a detailed picture of the initial dehydrogenation steps of AADB and DADB and highlights the difference in their respective dehydrogenation processes.
Garbrecht, M, McCarroll, I, Yang, L, Bhatia, V, Biswas, B, Rao, D, Cairney, JM & Saha, B 2020, 'Thermally stable epitaxial ZrN/carrier-compensated Sc0.99Mg0.01N metal/semiconductor multilayers for thermionic energy conversion', Journal of Materials Science, vol. 55, no. 4, pp. 1592-1602.
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Ghasemkhani, N, Vayghan, SS, Abdollahi, A, Pradhan, B & Alamri, A 2020, 'Urban Development Modeling Using Integrated Fuzzy Systems, Ordered Weighted Averaging (OWA), and Geospatial Techniques', Sustainability, vol. 12, no. 3, pp. 809-809.
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This paper proposes a model to identify the changing of bare grounds into built-up or developed areas. The model is based on the fuzzy system and the Ordered Weighted Averaging (OWA) methods. The proposed model consists of four main sections, which include physical suitability, accessibility, the neighborhood effect, and a calculation of the overall suitability. In the first two parts, physical suitability and accessibility were obtained by defining fuzzy inference systems and applying the required map data associated with each section. However, in order to calculate the neighborhood effect, we used an enrichment factor method and a hybrid method consisting of the enrichment factor with the Few, Half, Most, and Majority quantifiers of the ordered weighted averaging (OWA) method. Finally, the three maps of physical suitability, accessibility, and the neighborhood effect were integrated by the fuzzy system method and the quantifiers of OWA to obtain the overall suitability maps. Then, the areas with high suitability were selected from the overall suitability map to be changed from bare ground into built-up areas. For this purpose, the proposed model was implemented and calibrated in the first period (2004–2010) and was evaluated by being applied to the second period (2010–2016). By comparing the estimated map of changes to the reference data and after the formation of the error matrix, it was determined that the OWA-Majority method has the best estimation compared to those of the other methods. Finally, the total accuracy and the Kappa coefficient for the OWA-Majority method in the second period were 98.98% and 98.98%, respectively, indicating this method’s high accuracy in predicting changes. In addition, the results were compared with those of other studies, which showed the effectiveness of the suggested method for urban development modeling.
Ghobadi, R, Altaee, A, Zhou, JL, McLean, P & Yadav, S 2020, 'Copper removal from contaminated soil through electrokinetic process with reactive filter media', Chemosphere, vol. 252, pp. 126607-126607.
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Ghosh, S, Das, A, Hembram, TK, Saha, S, Pradhan, B & Alamri, AM 2020, 'Impact of COVID-19 Induced Lockdown on Environmental Quality in Four Indian Megacities Using Landsat 8 OLI and TIRS-Derived Data and Mamdani Fuzzy Logic Modelling Approach', Sustainability, vol. 12, no. 13, pp. 5464-5464.
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The deadly COVID-19 virus has caused a global pandemic health emergency. This COVID-19 has spread its arms to 200 countries globally and the megacities of the world were particularly affected with a large number of infections and deaths, which is still increasing day by day. On the other hand, the outbreak of COVID-19 has greatly impacted the global environment to regain its health. This study takes four megacities (Mumbai, Delhi, Kolkata, and Chennai) of India for a comprehensive assessment of the dynamicity of environmental quality resulting from the COVID-19 induced lockdown situation. An environmental quality index was formulated using remotely sensed biophysical parameters like Particulate Matters PM10 concentration, Land Surface Temperature (LST), Normalized Different Moisture Index (NDMI), Normalized Difference Vegetation Index (NDVI), and Normalized Difference Water Index (NDWI). Fuzzy-AHP, which is a Multi-Criteria Decision-Making process, has been utilized to derive the weight of the indicators and aggregation. The results showing that COVID-19 induced lockdown in the form of restrictions on human and vehicular movements and decreasing economic activities has improved the overall quality of the environment in the selected Indian cities for a short time span. Overall, the results indicate that lockdown is not only capable of controlling COVID-19 spread, but also helpful in minimizing environmental degradation. The findings of this study can be utilized for assessing and analyzing the impacts of COVID-19 induced lockdown situation on the overall environmental quality of other megacities of the world.
Gluth, GJG, Arbi, K, Bernal, SA, Bondar, D, Castel, A, Chithiraputhiran, S, Dehghan, A, Dombrowski-Daube, K, Dubey, A, Ducman, V, Peterson, K, Pipilikaki, P, Valcke, SLA, Ye, G, Zuo, Y & Provis, JL 2020, 'RILEM TC 247-DTA round robin test: carbonation and chloride penetration testing of alkali-activated concretes', Materials and Structures, vol. 53, no. 1.
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AbstractMany standardised durability testing methods have been developed for Portland cement-based concretes, but require validation to determine whether they are also applicable to alkali-activated materials. To address this question, RILEM TC 247-DTA ‘Durability Testing of Alkali-Activated Materials’ carried out round robin testing of carbonation and chloride penetration test methods, applied to five different alkali-activated concretes based on fly ash, blast furnace slag or metakaolin. The methods appeared overall to demonstrate an intrinsic precision comparable to their precision when applied to conventional concretes. The ranking of test outcomes for pairs of concretes of similar binder chemistry was satisfactory, but rankings were not always reliable when comparing alkali-activated concretes based on different precursors. Accelerated carbonation testing gave similar results for fly ash-based and blast furnace slag-based alkali-activated concretes, whereas natural carbonation testing did not. Carbonation of concrete specimens was observed to have occurred already during curing, which has implications for extrapolation of carbonation testing results to longer service life periods. Accelerated chloride penetration testing according to NT BUILD 443 ranked the tested concretes consistently, while this was not the case for the rapid chloride migration test. Both of these chloride penetration testing methods exhibited comparatively low precision when applied to blast furnace slag-based concretes which are more resistant to chloride ingress than the other materials tested.
Goh, BHH, Chong, CT, Ge, Y, Ong, HC, Ng, J-H, Tian, B, Ashokkumar, V, Lim, S, Seljak, T & Józsa, V 2020, 'Progress in utilisation of waste cooking oil for sustainable biodiesel and biojet fuel production', Energy Conversion and Management, vol. 223, pp. 113296-113296.
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© 2020 Elsevier Ltd The increase in human consumption of plant and animal oils has led to the rise in waste cooking oil (WCO) production. Instead of disposing the used cooking oil as waste, recent technological advance has enabled the use of WCO as a sustainable feedstock for biofuels production, thereby maximising the value of biowastes via energy recovery while concomitantly solving the disposal issue. The current regulatory frameworks for WCO collection and recycling practices imposed by major WCO producing countries are reviewed, followed by the overview of the progress in biodiesel conversion techniques, along with novel methods to improve the feasibility for upscaling. The factors which influence the efficiency of the reactions such as properties of feedstock, heterogenous catalytic processes, cost effectiveness and selectivity of reaction product are discussed. Ultrasonic-assisted transesterification is found to be the least energy intensive method for producing biodiesel. The production of bio-jet fuels from WCO, while scarce, provide diversity in waste utilisation if problems such as carbon chain length, requirements of bio-jet fuel properties, extreme reaction conditions and effectiveness of selected catalyst-support system can be solved. Technoeconomic studies revealed that WCO biofuels is financially viable with benefit of mitigating carbon emissions, provided that the price gap between the produced fuel and commercial fuels, sufficient supply of WCO and variation in the oil properties are addressed. This review shows that WCO is a biowaste with high potential for advanced transportation fuel production for ground and aviation industries. The advancement in fuel production technology and relevant policies would accelerate the application of sustainable WCO biofuels.
Goh, BHH, Ong, HC, Chong, CT, Chen, W-H, Leong, KY, Tan, SX & Lee, XJ 2020, 'Ultrasonic assisted oil extraction and biodiesel synthesis of Spent Coffee Ground', Fuel, vol. 261, pp. 116121-116121.
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Gokuldas, S, Banerjee, S & Nimbalkar, SS 2020, 'Effects of Tunneling-Induced Ground Movements on Stability of Piled Raft Foundation: Three-Dimensional Finite-Element Approach', International Journal of Geomechanics, vol. 20, no. 8, pp. 04020104-04020104.
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Gomes, SDC, Zhou, JL, Li, W & Qu, F 2020, 'Recycling of raw water treatment sludge in cementitious composites: effects on heat evolution, compressive strength and microstructure', Resources, Conservation and Recycling, vol. 161, pp. 104970-104970.
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Water treatment sludge (WTS) is produced daily and represents a globally significant solid waste stream. The application of this sludge as construction materials has been studied although most studies have modified the sludge before its incorporation, hence involving significant energy consumption. This study aims to use raw sludge as a novel cementitious material, by determining the effects of sludge addition on the composition and performance of cementitious composites. Important aspects such as the physicochemical interaction of the raw sludge with the Portland cement, the heat evolution of the cement paste and the compressive strength of the composite cement were carefully studied. The results show that for 1-2% of WTS addition, the compressive strength and heat evolution of the cement paste was well maintained being close to the reference specimen after 28 days of curing. However, for sludge addition above 5%, a delay in the hydration reaction was observed, together with about 25% reduction in compressive strength at 28 days of curing. The mineralogical and thermal analysis showed decreasing portlandite content and increasing calcite in the WTS-amended composites. Scanning electron microscope analysis demonstrated that the addition of sludge induced more porous and weak surface structures compared to the reference specimen.
Gonzales, RR, Yang, Y, Park, MJ, Bae, T-H, Abdel-Wahab, A, Phuntsho, S & Shon, HK 2020, 'Enhanced water permeability and osmotic power generation with sulfonate-functionalized porous polymer-incorporated thin film nanocomposite membranes', Desalination, vol. 496, pp. 114756-114756.
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Gowri, AK, Karunakaran, MJ, Muthunarayanan, V, Ravindran, B, Nguyen-Tri, P, Ngo, HH, Bui, X-T, Nguyen, XH, Nguyen, DD, Chang, SW & Chandran, T 2020, 'Evaluation of bioremediation competence of indigenous bacterial strains isolated from fabric dyeing effluent', Bioresource Technology Reports, vol. 11, pp. 100536-100536.
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© 2020 Elsevier Ltd In this present assessment, fabric dyeing wastewater was subjected to the characterization of physical-chemical parameters in terms of colour, TDS, COD and chloride. The indigenous bacterial strains were isolated from the effluent and identified as Bacillus velezensis, Chryseomicrobium imtechense, Planococcus maritimus and Sphingobacterium daejeonense by 16S rRNA gene sequencing method. The bioremediation competency of the strains was evaluated by conducting treatment process with monoculture and bacterial consortium. The consortia removed about 98%, 71.5%, 79%, 69.65% of colour, TDS, COD and chloride, respectively. Among the four isolates, monoculture of B. velezensis showed effective diminution of pollutants from the effluent than other strains. The bacterial degradation of pollutants was determined by GC–MS based on the disappearance of certain peaks after bioremediation. The results suggested that the bioremediation efficiency of bacterial strains can be utilized as an eco-friendly and inexpensive method for dyeing effluent treatment.
Gu, X, Li, J & Li, Y 2020, 'Experimental realisation of the real‐time controlled smart magnetorheological elastomer seismic isolation system with shake table', Structural Control and Health Monitoring, vol. 27, no. 1.
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© 2019 John Wiley & Sons, Ltd. Traditional base isolation protects structures against severe seismic events by providing a designated lateral flexibility at the base level of the structures. Due to its inherent passive nature, in the design process, compromises have to be made among performance of different design targets (displacements, interstorey drifts, accelerations, etc.). In addition, as the working principle, the effectiveness of a base isolation relies on the degree of “decoupling” between ground excitation and superstructure. However, a higher degree of decoupling compromises the stability of the structures. In other words, for a base solation system, it possesses inherent conflicts between the effectiveness of the isolation and the lateral stability of the structure. A concept of new smart base isolation system is proposed, in which real-time controllable decoupling for a base isolation structure is achieved by employing magnetorheological elastomer (MRE) base isolators. With controllable lateral stiffness, the smart base isolation system can achieve an optimal decoupling by instantly shifting the structure's natural frequencies to a nonresonant region. This paper aims at experimentally proving and validating this innovative concept, including designing a three-storey shear building model equipped with MRE base isolators, demonstrating the feasibility and evaluating the performance of the proposed system by a series of shake table testing. The comprehensive experimental design and results of shake table testing have concept-proved the proposed smart MRE base isolation system for future development in practical applications.
Guirguis, A, Maina, JW, Zhang, X, Henderson, LC, Kong, L, Shon, H & Dumée, LF 2020, 'Applications of nano-porous graphene materials – critical review on performance and challenges', Materials Horizons, vol. 7, no. 5, pp. 1218-1245.
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A critical review on the potential of nano-porous graphene materials, their key structural and physicochemical properties for applications in the areas of separation and sensing and energy storage.
Guirguis, A, Polaki, SR, Sahoo, G, Ghosh, S, Kamruddin, M, Merenda, A, Chen, X, Maina, JW, Szekely, G & Dumee, L 2020, 'Engineering high-defect densities across vertically-aligned graphene nanosheets to induce photocatalytic reactivity', Carbon, vol. 168, pp. 32-41.
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The fabrication of graphene nanostructures, with a variety of morphologies and densities of defective sites, can be a promising tool to tune their characteristics towards photocatalytic applications, without the need for external dopants. In this study, the impact of morphological properties in terms of the orientation and defect concentrations of graphene nanostructures is demonstrated to support the development of active photocatalytic sites across graphitic structures. Vertically-aligned graphene nanosheets were grown across carbon fibres via electron cyclotron resonance microwave plasma chemical vapour deposition, to yield a range of different wall densities and edge functionalities. The variation of growth conditions was correlated to the photocatalytic activity for the degradation of methylene blue dye under ultra-violet and visible light. The chemical state of oxygen content hybridized with nanosheets was studied by X-ray photoelectron spectroscopy and correlated to the growth conditions and photocatalytic performance. The fastest degradation rate of dye was found on the graphene samples which were grown at 800 °C for 240 min, with a kinetic constant of 46.6 × 10−4 min−1. Such performance has not been observed to date for any graphitic materials and is shown to be on the same order of performance as the conventional photocatalytic materials.
Gul, M, Kalam, MA, Mujtaba, MA, Alam, S, Bashir, MN, Javed, I, Aziz, U, Farid, MR, Hassan, MT & Iqbal, S 2020, 'Multi-objective-optimization of process parameters of industrial-gas-turbine fueled with natural gas by using Grey-Taguchi and ANN methods for better performance', Energy Reports, vol. 6, pp. 2394-2402.
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Gul, M, Masjuki, HH, Kalam, MA, Zulkifli, NWM & Mujtaba, MA 2020, 'A Review: Role of Fatty Acids Composition in Characterizing Potential Feedstock for Sustainable Green Lubricants by Advance Transesterification Process and its Global as Well as Pakistani Prospective', BioEnergy Research, vol. 13, no. 1, pp. 1-22.
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High demand for crop oils is anticipated in the lubricant industry because of their renewable, non-toxic, environment-friendly nature. Crop oils typically offer high viscosities, viscosity indexes, and flashpoints. The unique structure of crop oils provides good lubrication, high flammability, and anti-corrosion ability. In contrast, petroleum-based lubricants face a difficult future because of declining petroleum reservoirs that will increase their prices. This paper reviews green-lubricant feedstock requirements, the effect of fatty acids composition to improve physicochemical properties, chemical modifications of green lubricants by applying transesterification to find suitable environmentally -friendly and cheaper feedstock to replace petroleum lubricants. Moreover, global and Pakistani indigenous crop oils are also analyzed for their potential use in green lubricants by comparing their fatty acid compositions, characteristics and reaction conditions according to applications and standards. This review discovers that cottonseed oil has great potential as a new sustainable and cheaper feedstock for the global and Pakistani green-lubricant markets. Green lubricant production rate can be enhanced significantly after upgrading the conventional production method. It is believed that this review paper will provide useful information to engineers, researchers, chemists, industrialists, and policymakers, who are interested in green-lubricants synthesis.
Guo, W, Nguyen, PD, You, S-J & Lin, C 2020, 'Editorial - Special issue on green technologies for waste treatment', Bioresource Technology Reports, vol. 11, pp. 100495-100495.
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Guo, Y, Karimi, F, Fu, Q, G. Qiao, G & Zhang, H 2020, 'Reduced administration frequency for the treatment of fungal keratitis: a sustained natamycin release from a micellar solution', Expert Opinion on Drug Delivery, vol. 17, no. 3, pp. 407-421.
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Background: Natamycin is the only topical ophthalmic antifungal drug approved by the Food and Drug Administration (FDA) of the United States, but has unsatisfactory factors such as high dosing frequency.Methods: We report the synthesis and preparation of self-assembled poly(ethylene glycol)-block-poly(glycidyl methacrylate) (PEG-b-PGMA) micelles. These nanoparticles exhibit sustained delivery of a hydrophobic natamycin by topical administration on eye due to the hydrolysable properties of PGMA segments of micelle. Hydrolysis of glycidyl groups within a physiologically relevant environment provides an additional driving force for drug release by generation of hydrophilic hydroxyl groups to 'push' the encapsulated hydrophobic drug away from the resultant hydrophilic domains and into surrounding environment.Results: In vitro and in vivo results revealed that the self-assembled micelles and the encapsulated natamycin were not cytotoxic and the released drug have strong antifungal ability to Candida albicans. Importantly, sustained natamycin release from micelles leads to the reduced administration frequency of natamycin from 8 times per day to 3 times per day in rabbits suffering from fungal keratitis (FK).Conclusion: This study demonstrates a facile method that can greatly reduce dosing frequency of natamycin administration and thus improve long-term patient compliance.
Guo, Z, Kang, Y, Hu, Z, Liang, S, Xie, H, Ngo, HH & Zhang, J 2020, 'Removal pathways of benzofluoranthene in a constructed wetland amended with metallic ions embedded carbon', Bioresource Technology, vol. 311, pp. 123481-123481.
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Gupta, A, Pradhan, B & Maulud, KNA 2020, 'Estimating the Impact of Daily Weather on the Temporal Pattern of COVID-19 Outbreak in India', Earth Systems and Environment, vol. 4, no. 3, pp. 523-534.
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AbstractThe COVID-19 pandemic has spread obstreperously in India. The increase in daily confirmed cases accelerated significantly from ~ 5 additional new cases (ANC)/day during early March up to ~ 249 ANC/day during early June. An abrupt change in this temporal pattern was noticed during mid-April, from which can be inferred a much reduced impact of the nationwide lockdown in India. Daily maximum (TMax), minimum (TMin), mean (TMean) and dew point temperature (TDew), wind speed (WS), relative humidity, and diurnal range in temperature and relative humidity during March 01 to June 04, 2020 over 9 major affected cities are analyzed to look into the impact of daily weather on COVID-19 infections on that day and 7, 10, 12, 14, 16 days before those cases were detected (i.e., on the likely transmission days). Spearman’s correlation exhibits significantly lower association with WS,TMax,TMin,TMean,TDew, but is comparatively better with a lag of 14 days. Support Vector regression successfully estimated the count of confirmed cases (R2 > 0.8) at a lag of 12–16 days, thus reflecting a probable incubation period of 14 ± 02 days in India. Approximately 75% of total cases were registered whenTMax,TMean,TMin,TDew, and WS at 12–16 days previously were varying within the range of 33.6–41.3 °C, 29.8–36.5 °C, 24.8–30.4 °C, 18...
Hafiz, M, Hawari, AH, Yasir, AT, Alfahel, R, Hassan, MK & Altaee, A 2020, 'Impact of high turbidity on reverse osmosis: evaluation of pretreatment processes', DESALINATION AND WATER TREATMENT, vol. 208, pp. 96-103.
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This study evaluates the performance of sand filtration (SF) and ultra-filtration (UF) as pretreatment processes for reverse osmosis (RO) for seawater with turbidities of 4.8, 23.2, and 99.7 NTU. For seawater with a turbidity of 4.8 and 23.2 NTU, the average membrane flux and the water recovery rate in the RO process did not improve significantly by pretreating the seawater using SF or UF. However, when the turbidity of seawater was 99.7 NTU, pretreating the seawater with UF improved the average membrane flux and the water recovery rate in the RO process by 5 LMH and 1.7%, respectively. Pretreatment of seawater with a turbidity of 99.7 NTU with UF reduces the specific energy demand and increases the average membrane flux and water recovery rate.
Hafiz, MA, Hawari, AH, Das, P, Khan, S & Altaee, A 2020, 'Comparison of dual stage ultrafiltration and hybrid ultrafiltration-forward osmosis process for harvesting microalgae (Tetraselmis sp.) biomass', Chemical Engineering and Processing - Process Intensification, vol. 157, pp. 108112-108112.
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Hakdaoui, S, Emran, A, Pradhan, B, Qninba, A, Balla, TE, Mfondoum, AHN, Lee, C-W & Alamri, AM 2020, 'Assessing the Changes in the Moisture/Dryness of Water Cavity Surfaces in Imlili Sebkha in Southwestern Morocco by Using Machine Learning Classification in Google Earth Engine', Remote Sensing, vol. 12, no. 1, pp. 131-131.
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Imlili Sebkha is a stable and flat depression in southern Morocco that is more than 10 km long and almost 3 km wide. This region is mainly sandy, but its northern part holds permanent water pockets that contain fauna and flora despite their hypersaline water. Google Earth Engine (GEE) has revolutionized land monitoring analysis by allowing the use of satellite imagery and other datasets via cloud computing technology and server-side JavaScript programming. This work highlights the potential application of GEE in processing large amounts of satellite Earth Observation (EO) Big Data for the free, long-term, and wide spatio-temporal wet/dry permanent salt water cavities and moisture monitoring of Imlili Sebkha. Optical and radar images were used to understand the functions of Imlili Sebkha in discovering underground hydrological networks. The main objective of this work was to investigate and evaluate the complementarity of optical Landsat, Sentinel-2 data, and Sentinel-1 radar data in such a desert environment. Results show that radar images are not only well suited in studying desertic areas but also in mapping the water cavities in desert wetland zones. The sensitivity of these images to the variations in the slope of the topographic surface facilitated the geological and geomorphological analyses of desert zones and helped reveal the hydrological functions of Imlili Sebkha in discovering buried underground networks.
Han, R, Liu, F, Wang, X, Huang, M, Li, W, Yamauchi, Y, Sun, X & Huang, Z 2020, 'Functionalised hexagonal boron nitride for energy conversion and storage', Journal of Materials Chemistry A, vol. 8, no. 29, pp. 14384-14399.
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This review highlights recent research advances in functionalised hexagonal boron nitride for energy conversion and storage applications.
Hannan, MA, Ali, JA, Hossain Lipu, MS, Mohamed, A, Ker, PJ, Indra Mahlia, TM, Mansor, M, Hussain, A, Muttaqi, KM & Dong, ZY 2020, 'Role of optimization algorithms based fuzzy controller in achieving induction motor performance enhancement', Nature Communications, vol. 11, no. 1, p. 3792.
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AbstractThree-phase induction motors (TIMs) are widely used for machines in industrial operations. As an accurate and robust controller, fuzzy logic controller (FLC) is crucial in designing TIMs control systems. The performance of FLC highly depends on the membership function (MF) variables, which are evaluated by heuristic approaches, leading to a high processing time. To address these issues, optimisation algorithms for TIMs have received increasing interest among researchers and industrialists. Here, we present an advanced and efficient quantum-inspired lightning search algorithm (QLSA) to avoid exhaustive conventional heuristic procedures when obtaining MFs. The accuracy of the QLSA based FLC (QLSAF) speed control is superior to other controllers in terms of transient response, damping capability and minimisation of statistical errors under diverse speeds and loads. The performance of the proposed QLSAF speed controller is validated through experiments. Test results under different conditions show consistent speed responses and stator currents with the simulation results.
Hannan, MA, Begum, RA, Al-Shetwi, AQ, Ker, PJ, Al Mamun, MA, Hussain, A, Basri, H & Mahlia, TMI 2020, 'Waste collection route optimisation model for linking cost saving and emission reduction to achieve sustainable development goals', Sustainable Cities and Society, vol. 62, pp. 102393-102393.
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© 2020 Elsevier Ltd Developing an efficient, cost-effective and environmentally friendly solution for solid waste collection (SWC) and transportation system remains a major challenge for municipalities. Waste collection encompasses the largest part of the total budget in current waste management systems. SWC is a crosscutting issue that can be directly or indirectly linked to 10 of the 17 United Nations’ sustainable development goals (SDGs). This study aims to develop an SWC route optimisation model to improve collection efficiency, save collection costs and reduce emissions by considering fixed routing optimisation (FRO) with static data and variable routing optimisation (VRO) with real-time data. To realise the optimisation, a mixed-integer linear programming model utilising FRO and VRO was developed. Results show that VRO improved the collection efficiency by 26.08 % when the minimum filled-up level for collection was 70 %. Moreover, VRO achieved 44.44 % cost savings and 17.60 % carbon emission reduction at 70 % filled level. The proposed system achieved the targeted goals and demonstrated the feasibility of an optimisation model for the waste management sector to build a sustainable smart city. The findings of this study can be used to strengthen efforts towards the achievement of the SDGs related to solid waste collection and management.
Hannan, MA, Lipu, MSH, Hussain, A, Ker, PJ, Mahlia, TMI, Mansor, M, Ayob, A, Saad, MH & Dong, ZY 2020, 'Toward Enhanced State of Charge Estimation of Lithium-ion Batteries Using Optimized Machine Learning Techniques', Scientific Reports, vol. 10, no. 1, p. 4687.
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AbstractState of charge (SOC) is a crucial index used in the assessment of electric vehicle (EV) battery storage systems. Thus, SOC estimation of lithium-ion batteries has been widely investigated because of their fast charging, long-life cycle, and high energy density characteristics. However, precise SOC assessment of lithium-ion batteries remains challenging because of their varying characteristics under different working environments. Machine learning techniques have been widely used to design an advanced SOC estimation method without the information of battery chemical reactions, battery models, internal properties, and additional filters. Here, the capacity of optimized machine learning techniques are presented toward enhanced SOC estimation in terms of learning capability, accuracy, generalization performance, and convergence speed. We validate the proposed method through lithium-ion battery experiments, EV drive cycles, temperature, noise, and aging effects. We show that the proposed method outperforms several state-of-the-art approaches in terms of accuracy, adaptability, and robustness under diverse operating conditions.
Hao Ngo, H, Bui, X-T, Nghiem, LD & Guo, W 2020, 'Green technologies for sustainable water', Bioresource Technology, vol. 317, pp. 123978-123978.
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Hao, D, Liu, C, Xu, X, Kianinia, M, Aharonovich, I, Bai, X, Liu, X, Chen, Z, Wei, W, Jia, G & Ni, B-J 2020, 'Surface defect-abundant one-dimensional graphitic carbon nitride nanorods boost photocatalytic nitrogen fixation', New Journal of Chemistry, vol. 44, no. 47, pp. 20651-20658.
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Defective g-C3N4 nanorods enable to boots the adsorption and cleavage of N2 molecules to achieve higher photocatalytic nitrogen fixation performance.
Hao, Q, Jia, G, Wei, W, Vinu, A, Wang, Y, Arandiyan, H & Ni, B-J 2020, 'Graphitic carbon nitride with different dimensionalities for energy and environmental applications', Nano Research, vol. 13, no. 1, pp. 18-37.
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© 2019, Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature. As a metal-free semiconductor, graphitic carbon nitride (g-C3N4) has received extensive attention due to its high stability, nontoxicity, facile and low-cost synthesis, appropriate band gap in the visible spectral range and wide availability of resources. The dimensions of g-C3N4 can influence the regime of the confinement of electrons, and consequently, g-C3N4 with various dimensionalities shows different properties, making them available for many stimulating applications. Although there are some reviews focusing on the synthesis strategy and applications of g-C3N4, there is still a lack of comprehensive review that systemically summarises the synthesis and application of different dimensions of g-C3N4, which can provide an important theoretical and practical basis for the development of g-C3N4 with different dimensionalities and maximises their potential in diverse applications. By reviewing the latest progress of g-C3N4 studies, we aim to summarise the preparation of g-C3N4 with different dimensionalities using various structural engineering strategies, discuss the fundamental bottlenecks of currently existing methods and their solution strategies, and explore their applications in energy and environmental applications. Furthermore, it also puts forward the views on the future research direction of these unique materials. [Figure not available: see fulltext.]
Hao, Q, Liu, C, Jia, G, Wang, Y, Arandiyan, H, Wei, W & Ni, B-J 2020, 'Catalytic reduction of nitrogen to produce ammonia by bismuth-based catalysts: state of the art and future prospects', Materials Horizons, vol. 7, no. 4, pp. 1014-1029.
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This review provides an up-to-date review on Bi-based nitrogen-fixation materials and future directions for the development of new Bi-based nitrogen-fixation materials under ambient conditions.
Hao, Q, Xie, C, Huang, Y, Chen, D, Liu, Y, Wei, W & Ni, B-J 2020, 'Accelerated separation of photogenerated charge carriers and enhanced photocatalytic performance of g-C3N4 by Bi2S3 nanoparticles', Chinese Journal of Catalysis, vol. 41, no. 2, pp. 249-258.
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© 2020 Dalian Institute of Chemical Physics, the Chinese Academy of Sciences Employing photothermal conversion to improve the photocatalytic activity of g-C3N4 is rarely reported previously. Herein, different ratios of g-C3N4/Bi2S3 heterojunction materials are synthesized by a facile ultrasonic method. Advanced characterizations such as X-ray diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy are employed to analyze the morphology and structure of the prepared materials. Compared with sole counterparts, the heterojunction materials CN-BiS-2 exhibit significantly enhanced photocatalytic performance, which is 2.05-fold as g-C3N4 and 4.42-fold as Bi2S3. A possible degradation pathway of methylene blue (MB) was proposed. Based on the photoproduced high-energy electrons and photothermal effect of Bi2S3, the transfer and separation of electron-hole pairs are greatly enhanced and more active species are produced. In addition, the relatively high utilization efficiency of solar energy has synergistic effect for the better photocatalytic performance.
Hawari, AH, Hafiz, M, Yasir, AT, Alfahel, R & Altaee, A 2020, 'Evaluation of ultrafiltration and multimedia filtration as pretreatment process for forward osmosis', DESALINATION AND WATER TREATMENT, vol. 195, pp. 84-92.
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© 2020 Desalination Publications. All rights reserved. In order to reduce scaling in a multistage flash (MSF) desalination plant, the brine reject can be diluted using forward osmosis (FO) before recycling. In this FO process, the brine is used as the draw solution (DS) and seawater is used as the feed solution (FS). However, the FO process suffers from low water flux owing to membrane fouling. The water flux in FO can be enhanced by reduc-ing the foulant concentration in the FO feed solution (FS). Thus, in this paper seawater, multimedia sand filtered seawater, and ultrafiltrated seawater is being used as feed solution for the FO process. The flowrate of the feed solution was kept constant at 2.0 L/min. However, the flowrate of the draw solution (DS) were tested at 2.0 and 0.8 L/min. When the flowrate of the DS was 0.8 L/min, the highest initial flux of 44.1 L/m2 h were obtained using ultrafiltrated seawater as FS. After the initial run, the membrane was cleaned and during the second run, 83% of the initial flux was recovered using the ultrafiltrated seawater as FS. For ultrafiltrated seawater, the water recovery rate and specific energy consumption was 36.2% and 0.065 kWh/m3, respectively.
Hawchar, L, Naughton, O, Nolan, P, Stewart, MG & Ryan, PC 2020, 'A GIS-based framework for high-level climate change risk assessment of critical infrastructure', Climate Risk Management, vol. 29, pp. 100235-100235.
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The IPCC states that climate change unequivocally impacts on various aspects of the natural and built environment, including our vital critical infrastructure systems (transport, energy, water/wastewater and communications). It is thus essential for countries to gain an understanding of critical infrastructure vulnerability to current and future climate-related threats, in order to develop effective climate adaptation strategies. The first requisite step towards implementing these strategies, before any detailed analysis can commence, is high-level vulnerability or risk assessments. The work in this paper is concerned with such high-level assessments, however the framework presented is GIS-based, facilitating modelling of geographical variability in both climate and asset vulnerability within a country. This permits the identification of potential climate change risk hotspots across a range of critical infrastructure sectors. The framework involves a number of distinct steps. Sectoral information matrices are developed to highlight the key relationships between the infrastructure and climate threats. This information is complemented with sectoral maps showing, on an asset-level, the potential geospatial impacts of climate change, facilitating initial quantification of the vulnerable portions of the infrastructure systems. Finally, the approach allows for development of multi-sectoral semi-quantitative risk ranking maps that account for the geographical proximities of various assets from different critical infrastructure sectors which are vulnerable to a specific climate threat. The framework is presented in the paper and applied as a case study in the context of Irish critical infrastructure. The case-study identified for instance, potentially substantial increases in fluvial flooding risk for Irish critical infrastructure, while the multi-sectoral risk ranking maps highlighted a number of Ireland's urban and rural areas as climate change risk hotspots. These hig...
Hayati, H, Eager, D, Peham, C & Qi, Y 2020, 'Dynamic Behaviour of High Performance of Sand Surfaces Used in the Sports Industry', Vibration, vol. 3, no. 4, pp. 410-424.
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The sand surface is considered a critical injury and performance contributing factor in different sports, from beach volleyball to greyhound racing. However, there is still a significant gap in understanding the dynamic behaviour of sport sand surfaces, particularly their vibration behaviour under impact loads. The purpose of this research was to introduce different measurement techniques to the study of sports sand surface dynamic behaviour. This study utilised an experimental drop test, accelerometry, in-situ moisture content and firmness data, to investigate the possible correlation between the sand surface and injuries. The analysis is underpinned by data gathered from greyhound racing and discussed where relevant.
Hazrat, MA, Rasul, MG, Mofijur, M, Khan, MMK, Djavanroodi, F, Azad, AK, Bhuiya, MMK & Silitonga, AS 2020, 'A Mini Review on the Cold Flow Properties of Biodiesel and its Blends', Frontiers in Energy Research, vol. 8, p. 598651.
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Biodiesels are renewable fuel that may be produced from various feedstock using different techniques. It is endorsed in some countries of the world as a viable substitute to diesel fuel. While biodiesel possesses numerous benefits, the cold flow properties (CFP) of biodiesel in comparison with petro-diesel are significantly less satisfactory. This is due to the presence of saturated and unsaturated fatty acid esters. The poor CFP of biodiesel subsequently affects performance in cold weather and damages the engine fuel system, as well as chokes the fuel filter, fuel inlet lines, and injector nozzle. Previously, attempts were made to minimize the damaging impact of bad cold flow through the reduction of pour point, cloud point, and the cold filter plugging point of biodiesel. This study is focused on the biodiesel CFP-related mechanisms and highlights the factors that initialize and pace the crystallization process. This review indicates that the CFP of biodiesel fuel can be improved by utilizing different techniques. Winterisation of some biodiesel has been shown to improve CFP significantly. Additives such as polymethyl acrylate improved CFP by 3-9 ° C. However, it is recommended that improvement methods in terms of fuel properties and efficiency should be carefully studied and tested before being implemented in industrial applications as this might impact biodiesel yield, cetane number, etc.
He, B, He, N, Xu, BH, Cai, R, Shao, HL & Zhang, QL 2020, 'Tests on distributed monitoring of deflection of concrete faces of CFRDs', Yantu Gongcheng Xuebao/Chinese Journal of Geotechnical Engineering, vol. 42, no. 5, pp. 837-844.
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Ensuring the safety of concrete faces is the key to the safe operation of concrete face rockfill dams (CFRDs). The deflection is an important index to monitor the integrity of a concrete face. Based on the distributed optical fiber sensing technology, a new technology is proposed to monitor the deflection of concrete faces of CFRDs, and systematic tests are carried out to verify the measurement accuracy of this new technology as well as its feasibility. Based on the Matlab program and the quasi-distributed scatter strain test data, a method for calculating deflection is established. The research findings show that the calculated deflection at each measurement point on the concrete face is consistent with the measured one at the corresponding position (the absolute error is 5 mm, and the average relative error is 3%). It is validated that this new technology can monitor the deflection including irregular deflection with millimeter accuracy. It is also suitable for the distributed monitoring of the deflection of the full section of concrete faces and the measurement of large deflection. The proposed advanced technology is proved to be applicable to monitoring the deflection of the entire concrete face of a 300-meter level CFRD in a distributed manner.
He, X, Wu, W, Cai, G, Qi, J, Kim, JR, Zhang, D & Jiang, M 2020, 'Work–energy analysis of granular assemblies validates and calibrates a constitutive model', Granular Matter, vol. 22, no. 1.
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He, X, Xu, H, Li, W & Sheng, D 2020, 'An improved VOF-DEM model for soil-water interaction with particle size scaling', Computers and Geotechnics, vol. 128, pp. 103818-103818.
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© 2020 This study presents an improved VOF-DEM model where the Darcian velocity and a compound variable are treated as unknowns in the pressure-velocity calculation procedure such that the use of interpolated porosity at cell faces is minimised and stability is ensured even if the porosity field is not smooth or even ragged. A higher-order porosity estimation method is also used such that the porosity and interaction force are evaluated correctly when the CFD cell size is of the same order as the DEM particle size. Additionally, a particle size scaling technique is proposed to let the DEM particle size different from the real soil particle size and soil-water interaction forces are the same as when the real soil particle size is used. This is achieved by modifying the calculation of drag force. The solution scheme is verified in two case where analytical solutions exist. Particle size scaling technique is also used and tested in permeability tests and wave interaction with porous structure. Subsequently, the settling and collision of particles in water, dambreak of soil-water mixture and submerged landslides are simulated. With the present improvements and the particle size scaling, the capability of the VOF-DEM is extended in soil-water interaction problems.
He, X, Xu, H, Sabetamal, H & Sheng, D 2020, 'Machine learning aided stochastic reliability analysis of spatially variable slopes', Computers and Geotechnics, vol. 126, pp. 103711-103711.
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© 2020 This paper presents machine learning aided stochastic reliability analysis of spatially variable slopes, which significantly reduces the computational efforts and gives a complete statistical description of the factor of safety with promising accuracy compared with traditional methods. Within this framework, a small number of traditional random finite-element simulations are conducted. The samples of the random fields and the calculated factor of safety are, respectively, treated as training input and output data, and are fed into machine learning algorithms to find mathematical models to replace finite-element simulations. Two powerful machine learning algorithms used are the neural networks and the support-vector regression with their associated learning strategies. Several slopes are examined including stratified slopes with 3 or 4 layers described by 4 or 6 random fields. It is found that with 200 to 300 finite-element simulations (finished in about 5 ~ 8 h), the machine-learning generated model can predict the factor of safety accurately, and a stochastic analysis of 105 samples takes several minutes. However, the same traditional analysis would require hundreds of days of computation.
He, Z, Teng, J, Yang, Z, Liang, L, Li, H & Zhang, S 2020, 'An analysis of vapour transfer in unsaturated freezing soils', Cold Regions Science and Technology, vol. 169, pp. 102914-102914.
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Helwani, Z, Ramli, M, Rusyana, A, Marlina, M, Fatra, W, Idroes, GM, Suhendra, R, Ashwie, V, Mahlia, TMI & Idroes, R 2020, 'Alternative Briquette Material Made from Palm Stem Biomass Mediated by Glycerol Crude of Biodiesel Byproducts as a Natural Adhesive', Processes, vol. 8, no. 7, pp. 777-777.
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Recently, the global population has increased sharply, unfortunately, the availability of fossil fuel resources has significantly decreased. This phenomenon has become an attractive issue for many researchers in the world so that various studies in the context of finding renewable energy are developing continuously. Relating to this challenge, this research has been part of scientific work in the context of preparing an energy briquette employing palm oil stems and glycerol crude of biodiesel byproducts as inexpensive and green materials easily found in the Riau province, Indonesia. Technically, the palm oil stems are used for the production of charcoal particles and the glycerol crude as an adhesive compound in the production of energy briquettes. The heating value of palm oil stem is 17,180 kJ/kg, which can be increased to an even higher value through a carbonization process followed by a densification process so that it can be used as a potential matrix to produce energy briquettes. In detail, this study was designed to find out several parameters including the effect of sieve sizes consisting of 60, 80, and 100 mesh, respectively, which are used for the preparation of charcoal particles as the main matrix for the manufacture of the briquettes; the effect of charcoal-adhesive ratios (wt) of 60:40, 70:30, and 80:20; and the effect of varied pressures of 100, 110, and 120 kg/cm2 on the briquette quality. The quality of the obtained briquettes is analyzed through the observation of important properties which involve the heating value and the compressive strength using Response Surface Methodology (RSM). The results showed that the produced briquettes had an optimum heating value of 30,670 kJ/kg, while their loaded charcoal particles resulted from the mesh sieve of 80, in which there was a charcoal loading of 53 g and it pressed at 93.1821 bar, whereas, the compressive strength value of the briquette was 100,608 kg/cm2, which loaded charcoal part...
Helwani, Z, Ramli, M, Saputra, E, Bahruddin, B, Yolanda, D, Fatra, W, Idroes, GM, Muslem, M, Mahlia, TMI & Idroes, R 2020, 'Impregnation of CaO from Eggshell Waste with Magnetite as a Solid Catalyst (Fe3O4/CaO) for Transesterification of Palm Oil Off-Grade', Catalysts, vol. 10, no. 2, pp. 164-164.
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In this work, calcium oxide (CaO) extracted from eggshell impregnated with magnetite (Fe3O4) is prepared successfully and it had been applied on transesterification of palm oil off-grade. Prior experiment, the eggshells material are powdered and calcined at 900 °C then impregnated with Fe3O4 and recalcined. The obtained Fe3O4/CaO catalyst is characterized using X-ray diffraction and Braunaeur–Emmet–Teller (BET) surface area. The influence of various parameters including recalcined time and temperature are investigated. The prepared catalyst is tested for transesterification of palm oil off-grade to produce biodiesel in which the optimal conditions of a methanol/palm oil off-grade molar ratio of 10:1, the catalyst weight of 6%, the reaction temperature of 70 °C, and the reaction time of 2 h. The transesterification product was analyzed using GC-MS, which showed the biodiesel yield of 90% at the recalcined temperature of 600 °C and reaction time of 2 h. It has been noted that the catalyst activity is achieved when the moderate recalcination temperature is applied and the disordered structure of the catalyst is maintained. This study also confirms that CaO impregnated with Fe3O4 could be a solid catalyst for the biodiesel synthesis through transesterification reaction of palm oil off-grade.
Hien, NT, Nguyen, LH, Van, HT, Nguyen, TD, Nguyen, THV, Chu, THH, Nguyen, TV, Trinh, VT, Vu, XH & Aziz, KHH 2020, 'Heterogeneous catalyst ozonation of Direct Black 22 from aqueous solution in the presence of metal slags originating from industrial solid wastes', Separation and Purification Technology, vol. 233, pp. 115961-115961.
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© 2019 Elsevier B.V. This study developed a low cost catalyst, namely, zinc slag (Zn-S) for the ozonation process of Direct Black 22 (DB22) from aqueous solutions. Among five different kind of low cost metal slags including Fe-S, Cu-S, Cd-S, Pb-S and Zn-S, the Zn-S slag was selected as an efficient catalyst in this study. Zn-S contained mainly zinc (Zn) and calcium (Ca) discharged from zinc slag waste in Vietnam. It was found that Zn-S could effectively decolonize and mineralize DB22 through heterogeneous catalytic ozonation. The degradation kinetic of DB22 followed the pseudo-first order model. The best removal efficiency of DB22 (Zn-S/O3/H2O2 (76%) > Zn-S/O3 (69%) > O3/H2O2 (66%) > O3 (55% for COD) occurred at pH 11 for heterogeneous catalytic ozonation processes with Zn-S as the catalyst as well as ozone alone and perozone processes due to fast decomposition of O3 in alkaline solution to generate powerful and non-selective OH radicals. An increase in decolonization and mineralization rate was observed when increasing the Zn-S dosage from 0.125 g/L to 0.75 g/L for Zn-S/O3 and 0.125 g/L to 1.0 g/L for Zn-S/O3/H2O2. The K values of the pseudo-first order model followed the same sequence as mineralization rates of DB22 in term of COD removal. Ca and Zn constituents in the Zn-S catalyst contributed to the increase in O3 decomposition and improvement of reaction rate with H2O2. Subsequently, the degradation of DB22 by the ozonation process with Zn-S catalyst was enhanced through the enrichment mechanism of hydroxyl radicals (*OH) and surface adsorption. The degradation mechanism of DB22 by hydroxyl radicals was surely affirmed by tests with the decrease in degradation percentage of DB22 in case of the presence t-butanol, Cl− and CO32−.
Hirsimaki, C, Outram, JG, Millar, GJ & Altaee, A 2020, 'Process simulation of high pH reverse osmosis systems to facilitate reuse of coal seam gas associated water', Journal of Environmental Chemical Engineering, vol. 8, no. 5, pp. 104122-104122.
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Hoang, LP, Nguyen, TMP, Van, HT, Hoang, TKD, Vu, XH, Nguyen, TV & Ca, NX 2020, 'Cr(VI) Removal from Aqueous Solution Using a Magnetite Snail Shell', Water, Air, & Soil Pollution, vol. 231, no. 1.
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© 2020, Springer Nature Switzerland AG. In this study, magnetic snail shell (MSS) prepared by impregnating of iron oxide onto snail shell (SS) powder was used for removing Cr(VI) from aqueous solution. Among six different mass ratios of Fe/SS powder studied, the MSS25 produced at a ratio of 25% achieved the highest Cr(VI) adsorption capacity. Batch adsorption experiments were conducted to investigate the adsorption isotherm, kinetics, and mechanism of Cr(VI) onto MSS25. The results illustrated that adsorption of Cr(VI) onto MSS25 reached equilibrium after 150 min at pH 3. The adsorption kinetics could be well described by the pseudo-second order model (R2 = 0.986). The Langmuir model (R2 = 0.971) was the best-fitting model that described the adsorption isotherm of Cr(VI) onto MSS25. The maximum adsorption capacity was 46.08 mg Cr(VI) per gram of MSS25. Ion exchange, electrostatic attraction, and adsorption-coupled reduction were determined as the main adsorption mechanisms of Cr(VI) onto MSS25. The high percentages of CaCO3 and Fe3O4 found in the MSS25 structure made a significant contribution to the Cr(VI) adsorption process.
Hong, L, Ju, S, Yang, Y, Zheng, J, Xia, G, Huang, Z, Liu, X & Yu, X 2020, 'Hollow-shell structured porous CoSe2 microspheres encapsulated by MXene nanosheets for advanced lithium storage', Sustainable Energy & Fuels, vol. 4, no. 5, pp. 2352-2362.
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Cobalt diselenide (CoSe2), a representative transition-metal chalcogenide (TMC), is attracting intensive interest as an anode material for lithium ion batteries (LIBs), in view of its high specific capacity based on the conversion reaction mechanism.
Hoque, MA-A, Pradhan, B & Ahmed, N 2020, 'Assessing drought vulnerability using geospatial techniques in northwestern part of Bangladesh', Science of The Total Environment, vol. 705, pp. 135957-135957.
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Horry, MJ, Chakraborty, S, Paul, M, Ulhaq, A, Pradhan, B, Saha, M & Shukla, N 2020, 'COVID-19 Detection Through Transfer Learning Using Multimodal Imaging Data', IEEE Access, vol. 8, pp. 149808-149824.
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Hossain, N, Hasan, MH, Mahlia, TMI, Shamsuddin, AH & Silitonga, AS 2020, 'Feasibility of microalgae as feedstock for alternative fuel in Malaysia: A review', Energy Strategy Reviews, vol. 32, pp. 100536-100536.
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© 2020 The Authors Biodiesel is an attractive fuel replacement for diesel engine in Malaysia. The application of biodiesel as fuel-blend has been implemented commercially in transport sector in the country. Among various potential feedstock for biodiesel production, microalgae have been appeared as a promising source since a decade due to its' high biomass productivity, rapid growth rate, large amount of lipid content, capability of high CO2 capture and sequestration as well as suitable geographical location to be harvested. The main objective of this study was to determine the feasibility of microalgae harvesting in Malaysia to produce biodiesel and potential to implement microalgae-biodiesel as commercial transportation fuel. This study demonstrated the current scenario of overall biodiesel production and application in Malaysia. Since Malaysia is the world's second-largest oil palm producer, exploitation of edible palm oil for the making of biodiesel is to be blamed as the cause of soaring food price; therefore, the country is currently looking for 3rd generation biofuel sources and microalgae has been preferred for this purpose. Therefore, insight of the significance of microalgae cultivation for this purpose, suitable microalgae candidates and possible feasibility of microalgae biodiesel have been delineated in this review study. Prospects and challenges to implement microalgae biodiesel have also been emphasized in this study. Therefore, the advantages and limitations of this biodiesel can be transparent to government and non-government sectors. Thus, this study can re-direct both sectors in future. Consequently, it may contribute setting an appropriate government policy to encourage microalgae for biodiesel production to sustain the local biofuel and secure economic growth, energy security and improve environmental conditions in near future.
Hossain, N, Nizamuddin, S, Griffin, G, Selvakannan, P, Mubarak, NM & Mahlia, TMI 2020, 'Synthesis and characterization of rice husk biochar via hydrothermal carbonization for wastewater treatment and biofuel production', Scientific Reports, vol. 10, no. 1, p. 18851.
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AbstractThe recent implication of circular economy in Australia spurred the demand for waste material utilization for value-added product generations on a commercial scale. Therefore, this experimental study emphasized on agricultural waste biomass, rice husk (RH) as potential feedstock to produce valuable products. Rice husk biochar (RB) was obtained at temperature: 180 °C, pressure: 70 bar, reaction time: 20 min with water via hydrothermal carbonization (HTC), and the obtained biochar yield was 57.9%. Enhancement of zeta potential value from − 30.1 to − 10.6 mV in RB presented the higher suspension stability, and improvement of surface area and porosity in RB demonstrated the wastewater adsorption capacity. Along with that, an increase of crystallinity in RB, 60.5%, also indicates the enhancement of the catalytic performance of the material significantly more favorable to improve the adsorption efficiency of transitional compounds. In contrast, an increase of the atomic O/C ratio in RB, 0.51 delineated high breakdown of the cellulosic component, which is favorable for biofuel purpose. 13.98% SiO2 reduction in RB confirmed ash content minimization and better quality of fuel properties. Therefore, the rice husk biochar through HTC can be considered a suitable material for further application to treat wastewater and generate bioenergy.
Hossain, SM, Park, H, Kang, H-J, Kim, JB, Tijing, L, Rhee, I, Jun, Y-S, Shon, HK & Kim, J-H 2020, 'Preparation and Characterization of Photoactive Anatase TiO2 from Algae Bloomed Surface Water', Catalysts, vol. 10, no. 4, pp. 452-452.
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The purpose of the study was to effectively treat algae bloomed water while using a Ti-based coagulant (TiCl4) and recover photoactive novel anatase TiO2 from the flocculated sludge. Conventional jar tests were conducted in order to evaluate the coagulation efficiency, and TiCl4 was found superior compared to commercially available poly aluminum chloride (PAC). At a dose of 0.3 g Ti/L, the removal rate of turbidity, chemical oxygen demand (COD), and total phosphorus (TP) were measured as 99.8%, 66.7%, and 96.9%, respectively. Besides, TiO2 nanoparticles (NPs) were recovered from the flocculated sludge and scanning electron microscope (SEM), energy dispersive X-ray spectroscope (EDX), and X-ray diffraction (XRD) analysis confirmed the presence of only anatase phase. The recovered TiO2 was found to be effective in removing gaseous CH3CHO and NOx under UV-A lamp at a light intensity of 10 W/m2. Additionally, the TiO2 mixed mortar blocks that were prepared in this study successfully removed atmospheric nitrogen oxide (NOx) under UV irradiance. This study is one of the first to prepare anatase TiO2 from flocculated algal sludge and it showed promising results. Further research on this novel TiO2 concerning internal chemical bonds and shift in the absorbance spectrum could explore several practical implications.
Hossain, SM, Park, H, Kang, H-J, Mun, JS, Tijing, L, Rhee, I, Kim, J-H, Jun, Y-S & Shon, HK 2020, 'Modified Hydrothermal Route for Synthesis of Photoactive Anatase TiO2/g-CN Nanotubes from Sludge Generated TiO2', Catalysts, vol. 10, no. 11, pp. 1350-1350.
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Titania nanotube was prepared from sludge generated TiO2 (S-TNT) through a modified hydrothermal route and successfully composited with graphitic carbon nitride (g-CN) through a simple calcination step. Advanced characterization techniques such as X-ray diffraction, scanning and transmission electron microscopy, infrared spectroscopy, X-ray photoelectron spectroscopy, UV/visible diffuse reflectance spectroscopy, and photoluminescence analysis were utilized to characterize the prepared samples. A significant improvement in morphological and optical bandgap was observed. The effective surface area of the prepared composite increased threefold compared with sludge generated TiO2. The optical bandgap was narrowed to 3.00 eV from 3.18 in the pristine sludge generated TiO2 nanotubes. The extent of photoactivity of the prepared composites was investigated through photooxidation of NOx in a continuous flow reactor. Because of extended light absorption of the as-prepared composite, under visible light, 19.62% of NO removal was observed. On the other hand, under UV irradiation, owing to bandgap narrowing, although the light absorption was compromised, the impact on photoactivity was compensated by the increased effective surface area of 153.61 m2/g. Hence, under UV irradiance, the maximum NO removal was attained as 32.44% after 1 h of light irradiation. The proposed facile method in this study for the heterojunction of S-TNT and g-CN could significantly contribute to resource recovery from water treatment plants and photocatalytic atmospheric pollutant removal.
Hosseinzadeh, A, Baziar, M, Alidadi, H, Zhou, JL, Altaee, A, Najafpoor, AA & Jafarpour, S 2020, 'Application of artificial neural network and multiple linear regression in modeling nutrient recovery in vermicompost under different conditions', Bioresource Technology, vol. 303, pp. 122926-122926.
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© 2020 Elsevier Ltd Vermicomposting is one of the best technologies for nutrient recovery from solid waste. This study aims to assess the efficiency of Artificial Neural Network (ANN) and Multiple Linear Regression (MLR) models in predicting nutrient recovery from solid waste under different vermicompost treatments. Seven chemical and biological indices were studied as input variables to predict total nitrogen (TN) and total phosphorus (TP) recovery. The developed ANN and MLR models were compared by statistical analysis including R-squared (R2), Adjusted-R2, Root Mean Square Error and Absolute Average Deviation. The results showed that vermicomposting increased TN and TP proportions in final products by 1.5 and 16 times. The ANN models provided better prediction for TN and TP with R2 of 0.9983 and 0.9991 respectively, compared with MLR models with R2 of 0.834 and 0.729. TN and C/N ratio were key factors for TP and TN prediction by ANN with percentages of 17.76 and 18.33.
Hosseinzadeh, A, Zhou, JL, Altaee, A, Baziar, M & Li, D 2020, 'Effective modelling of hydrogen and energy recovery in microbial electrolysis cell by artificial neural network and adaptive network-based fuzzy inference system', Bioresource Technology, vol. 316, pp. 123967-123967.
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Hosseinzadeh, A, Zhou, JL, Altaee, A, Baziar, M & Li, X 2020, 'Modeling water flux in osmotic membrane bioreactor by adaptive network-based fuzzy inference system and artificial neural network', Bioresource Technology, vol. 310, pp. 123391-123391.
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Osmotic Membrane Bioreactor (OMBR) is an emerging technology for wastewater treatment with membrane fouling as a major challenge. This study aims to develop Adaptive Network-based Fuzzy Inference System (ANFIS) and Artificial Neural Network (ANN) models in simulating and predicting water flux in OMBR. Mixed liquor suspended solid (MLSS), electrical conductivity (EC) and dissolved oxygen (DO) were used as model inputs. Good prediction was demonstrated by both ANFIS models with R2 of 0.9755 and 0.9861, and ANN models with R2 of 0.9404 and 0.9817, for thin film composite (TFC) and cellulose triacetate (CTA) membranes, respectively. The root mean square error for TFC (0.2527) and CTA (0.1230) in ANFIS models was lower than in ANN models at 0.4049 and 0.1449. Sensitivity analysis showed that EC was the most important factor for both TFC and CTA membranes in ANN models, while EC (TFC) and MLSS (CTA) are key parameters in ANFIS models.
Hou, J, Li, B, Tong, Y, Ma, L, Ball, J, Luo, H, Liang, Q & Xia, J 2020, 'Cause analysis for a new type of devastating flash flood', Hydrology Research, vol. 51, no. 1, pp. 1-16.
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Abstract This work introduces an unprecedented flash flood that resulted in nine casualties in Shimen Valley, China, 2015. Through field survey and numerical simulation the causes of the disaster are systematically analyzed, finding that the intense storm, terrain features, and the large woody debris (LWD) played important roles. The intense storm induced fast runoff and, in turn, high discharges as a result of the steep catchment surfaces and channels. The flood flushed LWD and boulders downstream until blockage occurred in a contraction section, forming a debris lake. When the debris dam broke, a dam break wave rapidly propagated to the valley mouth, washing people away. After considering the disaster-inducing factors, measures for preventing similar floods are proposed. The analysis presented herein should help others manage flash floods in mountain areas.
Hu, X, Zhang, X, Ngo, HH, Guo, W, Wen, H, Li, C, Zhang, Y & Ma, C 2020, 'Comparison study on the ammonium adsorption of the biochars derived from different kinds of fruit peel', Science of The Total Environment, vol. 707, pp. 135544-135544.
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Application of biochars to remove inorganic nitrogen (NH4+, NO2-, NH3, NO, NO2, N2O) from wastewater and agricultural fields has gained a significant interest. This study aims to investigate the relationship between ammonium sorption and physicochemical properties of biochars derived from different kinds of fruit peel. Biochars from three species of fruit peel (orange, pineapple and pitaya) were prepared at 300, 400, 500 and 600 °C with the residence time of 2 h and 4 h. Their characteristics and sorption for ammonium was evaluated. The results show a clear effect of pyrolysis conditions on physicochemical properties of biochars, including elemental composition, functional groups and pH. The maximum NH4+ adsorption capacities were associated with biochars of orange peel (4.71 mg/g) and pineapple peel (5.60 mg/g) produced at 300 °C for 2 h. The maximum NH4+ adsorption capacity of the pitaya peel biochar produced at 400 °C for 2 h was 2.65 mg/g. For all feedstocks, biochars produced at low temperatures showed better NH4+ adsorption capacity. It was found that biochars had better adsorption efficiency on ammonium at a pH of 9. Adsorption kinetics of ammonium on biochars followed the pseudo-second-order kinetic model while Langmuir isotherm model could well simulate the adsorption behavior of ammonium on biochars. The adsorption mechanism of ammonium on biochars predominantly involved surface complexation, cation exchange and electrostatic attraction. Conclusively, the fruit peel-derived biochars can be used as an alternative to conventional sorbents in water treatment.
Hu, Y, Zang, Y, Yang, Y, Duan, A, Wang, XC, Ngo, HH, Li, Y-Y & Du, R 2020, 'Zero-valent iron addition in anaerobic dynamic membrane bioreactors for preconcentrated wastewater treatment: Performance and impact', Science of The Total Environment, vol. 742, pp. 140687-140687.
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Wastewater preconcentration to capture abundant organics is promising for facilitating subsequent anaerobic digestion (AD) to recover bioenergy, however research efforts are still needed to verify the effectiveness of such an emerging strategy as carbon capture plus AD. Therefore, lab-scale anaerobic dynamic membrane bioreactors (AnDMBRs) without and with the addition of zero-valent iron (ZVI) (i.e., AnDMBR1 versus AnDMBR2) were developed for preconcentrated domestic wastewater (PDW) treatment, and the impact of ZVI addition on process performance and associated mechanisms were investigated. The stepwise addition of ZVI from 2 to 4 to 6 g/L improved the treatment performance as COD removal slightly increased and TP removal and methane production were enhanced by 53.3%-62.9% and 22.6%-31.3%, respectively, in consecutive operational phases. However, the average increasing rate of the transmembrane pressure (TMP) in AnDMBR2 (0.18 kPa/d) was obviously higher than that in AnDMBR1 (0.05 kPa/d), indicating an unfavorable impact of dosing ZVI on the dynamic membrane (DM) filtration performance. ZVI that has transformed to iron ions (mainly Fe2+) can behave as a coagulant, electron donor or inorganic foulant, thus enabling the excellent removal of dissolved phosphorous, enhancing the enrichment and activities of specific methanogens and causing the formation of a compact DM layer. Morphological, componential, and microbial community analyses provided new insights into the functional mechanisms of ZVI added to membrane-assisted anaerobic digesters, indicating that ZVI has the potential to improve bioenergy production and resource recovery, while optimizing the ZVI dosage should be considered to alleviate membrane fouling.
Huang, Q-S, Wang, C, Wei, W & Ni, B-J 2020, 'Magnetic poly(aniline-co-5-sulfo-2-anisidine) as multifunctional adsorbent for highly effective co-removal of aqueous Cr(VI) and 2,4-Dichlophenol', Chemical Engineering Journal, vol. 387, pp. 124152-124152.
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© 2020 Elsevier B.V. The common coexistence of heavy metal ions (HMIs) and toxic organic matters (OMs) arouses public concerns for their combined toxicity and carcinogenicity. The magnetic poly[aniline(AN)-co-5-sulfo-2-anisidine(SA)] (AN-SA/Fe3O4) was synthesized by an oxidative copolymerization method for the highly-effectively simultaneous removal of Cr(VI) and 2,4-dichlorophenol (2,4-DCP) from aqueous solution. The novel adsorbent exhibited ultra-strong adsorption capacities for sole Cr(VI) and sole 2,4-DCP. The mechanism studies revealed that Cr(VI) species (HCrO4− and Cr2O72− in solution pH as 5) were reduced to Cr(III) by the –NH–/–NH2 groups after attaching to the protonated binding sites of AN-SA/Fe3O4 through electrostatic attraction. By contrast, multiple reactions involving the n-π electron donor-acceptor (EDA) interaction, π-π stacking and hydrogen bond contributed to the elimination of 2,4-DCP. In binary system, the coexistent Cr(VI) and 2,4-DCP elevated mutual adsorption capacities by 88.1% and 102.1%, respectively. Specially, 2,4-DCP can form bridge interactions with both Cr(VI) and Cr(III) due to conjugate effect. This property enabled Cr(VI) to additionally link to the hydrophobic sites, except for the hydrophilic sites, via 2,4-DCP bridges. Moreover, the produced Cr(III) can forcefully captured 2,4-DCP with the electron-rich groups (i.e., [sbnd]NH[sbnd], [sbnd]N[dbnd], [sbnd]SO3H, [sbnd]OCH3) on AN-SA/Fe3O4 to form the multi-components complexes. The bridge interactions (i.e., n-π EDA interaction, complexation) created the newly available sites for Cr(VI) and 2,4-DCP, resulting in enlarged adsorbance and synchronous removal on AN-SA/Fe3O4 in coexisting system. In addition, the high proportion of [sbnd]N[dbnd] groups generated by Cr(VI) oxidation also devoted to the uptake enhancement due to its strong affinity for 2,4-DCP. Overall, the high-performance and synergistic removal qualified AN-SA/Fe3O4 as a multifunctional adsorbent for the...
Huang, Q-S, Wu, W, Wei, W, Song, L, Sun, J & Ni, B-J 2020, 'Highly-efficient Pb2+ removal from water by novel K2W4O13 nanowires: Performance, mechanisms and DFT calculation', Chemical Engineering Journal, vol. 381, pp. 122632-122632.
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© 2019 Elsevier B.V. As one of the most toxic heavy metals, lead ions (Pb2+) contamination arouses increasing public concern for high carcinogenicity and neurotoxicity. In this study, a modified hydrothermal method was designed to fabricate novel hexagonal K2W4O13 nanowires to achieve highly-efficient Pb2+ removal from water. Attractively, the as-prepared K2W4O13 exhibited large uptake capacity (228.83 mg/g), fast kinetic (141.67 mg/g in 30 min), superior acid-resistance (75% of removal at pH = 2) and excellent reusability (over 95% of removal after 5 runs) toward Pb2+ adsorption. The Langmuir isotherm and pseudo-second-order kinetic model gave a better fit to the adsorption experimental data. The Pb2+ adsorption process on K2W4O13 was revealed to be a spontaneous, exothermic, film diffusion limited chemisorption reaction. The mechanism studied elucidated that both ion-exchange and complexation were involved in Pb2+ adsorption, with each accounting for approximate 50% of Pb2+ elimination. Through density functional theory (DFT) calculation, the equatorial oxygen was found to be more accessible for Pb attachment than the axial corner oxygen from [WO6] octahedra. Electron pairs from the adjacent O atoms would transfer to the empty orbitals of Pb atoms after adsorption, causing the Pb2+ removal via metal-ligand complexation.
Huang, Y, Mok, W-C, Yam, Y-S, Zhou, JL, Surawski, NC, Organ, B, Chan, EFC, Mofijur, M, Mahlia, TMI & Ong, HC 2020, 'Evaluating in-use vehicle emissions using air quality monitoring stations and on-road remote sensing systems', Science of The Total Environment, vol. 740, pp. 139868-139868.
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Huang, Y, Ng, ECY, Surawski, NC, Yam, Y-S, Mok, W-C, Liu, C-H, Zhou, JL, Organ, B & Chan, EFC 2020, 'Large eddy simulation of vehicle emissions dispersion: Implications for on-road remote sensing measurements', Environmental Pollution, vol. 259, pp. 113974-113974.
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© 2020 Elsevier Ltd On-road remote sensing technology measures the concentration ratios of pollutants over CO2 in the exhaust plume in half a second when a vehicle passes by a measurement site, providing a rapid, non-intrusive and economic tool for vehicle emissions monitoring and control. A key assumption in such measurement is that the emission ratios are constant for a given plume. However, there is a lack of study on this assumption, whose validity could be affected by a number of factors, especially the engine operating conditions and turbulence. To guide the development of the next-generation remote sensing system, this study is conducted to investigate the effects of various factors on the emissions dispersion process in the vehicle near-wake region and their effects on remote sensing measurement. The emissions dispersion process is modelled using Large Eddy Simulation (LES). The studied factors include the height of the remote sensing beam, vehicle speed, acceleration and side wind. The results show that the measurable CO2 and NO exhaust plumes are relatively short at 30 km/h cruising speed, indicating that a large percentage of remote sensing readings within the measurement duration (0.5 s) are below the sensor detection limit which would distort the derived emission ratio. In addition, the valid measurement region of NO/CO2 emission ratio is even shorter than the measurable plume and is at the tailpipe height. The effect of vehicle speed (30–90 km/h) on the measurable plume length is insignificant. Under deceleration condition, the length of the valid NO/CO2 measurement region is shorter than under cruising and acceleration conditions. Side winds from the far-tailpipe direction have a significant effect on remote sensing measurements. The implications of these findings are discussed and possible solutions to improve the accuracy of remote sensing measurement are proposed.
Huang, Y, Surawski, NC, Yam, Y-S, Lee, CKC, Zhou, JL, Organ, B & Chan, EFC 2020, 'Re-evaluating effectiveness of vehicle emission control programmes targeting high-emitters', Nature Sustainability, vol. 3, no. 11, pp. 904-907.
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© 2020, The Author(s), under exclusive licence to Springer Nature Limited. Estimating emission distribution within a vehicle fleet is critical for air pollution control. Previous studies reported that more than half of total fleet emissions were produced by only the highest 10% emitters, making repairing or deregistering a small percentage of high-emitters the most cost-effective measure to control vehicle emissions. With diesel emissions data from chassis dynamometer testing and on-road remote sensing, we show that such a strategy may be oversimplified.
Huang, Y, Yu, Y, Yam, Y-S, Zhou, JL, Lei, C, Organ, B, Zhuang, Y, Mok, W-C & Chan, EFC 2020, 'Statistical evaluation of on-road vehicle emissions measurement using a dual remote sensing technique', Environmental Pollution, vol. 267, pp. 115456-115456.
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On-road remote sensing (RS) is a rapid, non-intrusive and economical tool to monitor and control the emissions of in-use vehicles, and currently is gaining popularity globally. However, a majority of studies used a single RS technique, which may bias the measurements since RS only captures a snapshot of vehicle emissions. This study aimed to use a unique dual RS technique to assess the characteristics of on-road vehicle emissions. The results show that instantaneous vehicle emissions are highly dynamic under real-world driving conditions. The two emission factors measured by the dual RS technique show little correlation, even under the same driving condition. This indicates that using the single RS technique may be insufficient to accurately represent the emission level of a vehicle based on one measurement. To increase the accuracy of identifying high-emitting vehicles, using the dual RS technique is essential. Despite little correlation, the dual RS technique measures the same average emission factors as the single RS technique does when a large number of measurements are available. Statistical analysis shows that both RS systems demonstrate the same Gamma distribution with ≥200 measurements, leading to converged mean emission factors for a given vehicle group. These findings point to the need for a minimum sample size of 200 RS measurements in order to generate reliable emission factors for on-road vehicles. In summary, this study suggests that using the single or dual RS technique will depend on the purpose of applications. Both techniques have the same accuracy in calculating average emission factors when sufficient measurements are available, while the dual RS technique is more accurate in identifying high-emitters based on one measurement only.
Huang, Y, Zhou, J, Yu, Y, Mok, W-C, Lee, C & Yam, Y-S 2020, 'Uncertainty in the Impact of the COVID-19 Pandemic on Air Quality in Hong Kong, China', Atmosphere, vol. 11, no. 9, pp. 914-914.
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Strict social distancing rules are being implemented to stop the spread of COVID-19 pandemic in many cities globally, causing a sudden and extreme change in the transport activities. This offers a unique opportunity to assess the effect of anthropogenic activities on air quality and provides a valuable reference to the policymakers in developing air quality control measures and projecting their effectiveness. In this study, we evaluated the effect of the COVID-19 lockdown on the roadside and ambient air quality in Hong Kong, China, by comparing the air quality monitoring data collected in January–April 2020 with those in 2017–2019. The results showed that the roadside and ambient NO2, PM10, PM2.5, CO and SO2 were generally reduced in 2020 when comparing with the historical data in 2017–2019, while O3 was increased. However, the reductions during COVID-19 period (i.e., February–April) were not always higher than that during pre-COVID-19 period (i.e., January). In addition, there were large seasonal variations in the monthly mean pollutant concentrations in every year. This study implies that one air pollution control measure may not generate obvious immediate improvements in the air quality monitoring data and its effectiveness should be evaluated carefully to eliminate the effect of seasonal variations.
Huang, Z, Wang, S, Dewhurst, RD, Ignat'ev, NV, Finze, M & Braunschweig, H 2020, 'Bor in energiebezogenen Prozessen und Anwendungen', Angewandte Chemie, vol. 132, no. 23, pp. 8882-8900.
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AbstractDirekt an der Grenze zwischen Metallen und Nichtmetallen angesiedelt, nimmt das Element Bor eine einzigartige Position im Periodensystem ein. Diese besondere Stellung ermöglicht eine enorme Vielfalt an chemischen Reaktionen und Anwendungen. Auch in Hinblick auf die stetig steigende Nachfrage an erneuerbaren und sauberen Energien bzw. energieeffizienten Prozessen ist das Element Bor mehr und mehr in den Fokus der energiebezogenen Forschung gerückt und umfasst mittlerweile Bereiche wie 1) die Aktivierung und Synthese kleiner energiereicher Moleküle, 2) die Speicherung von chemischer und elektrischer Energie und 3) die Umwandlung von elektrischer Energie zu Licht. Diese Anwendungen basieren hierbei auf den besonderen Eigenschaften des Elements Bor, d. h. vor allem auf dessen Elektronenmangel in Verbindung mit der Gegenwart eines unbesetzten p‐Orbitals, was die Ausbildung unzähliger Verbindungen mit gezielt beeinflussbaren chemischen und physikalischen Eigenschaften ermöglicht. So erreicht Bor beispielsweise mit vier kovalenten Bindungen und einer negativen Ladung relativ einfach ein Elektronenoktett, wodurch die Verbindungsklasse der Boratanionen zugänglich wird, welche eine außergewöhnlich hohe chemische und elektrochemische Stabilität aufweisen. Besonders hervorzuheben ist in diesem Zusammenhang die synthetisch wertvolle Klasse der schwach‐koordinierenden Anionen. Dieser Aufsatz soll die Bedeutung von Borverbindungen für energiebezogene Prozesse und Anwendungen verdeutlichen und fasst die Fortschritte der letzten Jahre auf diesem Gebiet zusammen.
Huang, Z, Wang, S, Dewhurst, RD, Ignat'ev, NV, Finze, M & Braunschweig, H 2020, 'Boron: Its Role in Energy‐Related Processes and Applications', Angewandte Chemie International Edition, vol. 59, no. 23, pp. 8800-8816.
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AbstractBoron's unique position in the Periodic Table, that is, at the apex of the line separating metals and nonmetals, makes it highly versatile in chemical reactions and applications. Contemporary demand for renewable and clean energy as well as energy‐efficient products has seen boron playing key roles in energy‐related research, such as 1) activating and synthesizing energy‐rich small molecules, 2) storing chemical and electrical energy, and 3) converting electrical energy into light. These applications are fundamentally associated with boron's unique characteristics, such as its electron‐deficiency and the availability of an unoccupied p orbital, which allow the formation of a myriad of compounds with a wide range of chemical and physical properties. For example, boron's ability to achieve a full octet of electrons with four covalent bonds and a negative charge has led to the synthesis of a wide variety of borate anions of high chemical and electrochemical stability—in particular, weakly coordinating anions. This Review summarizes recent advances in the study of boron compounds for energy‐related processes and applications.
Hussain, F, Soudagar, MEM, Afzal, A, Mujtaba, MA, Fattah, IMR, Naik, B, Mulla, MH, Badruddin, IA, Khan, TMY, Raju, VD, Gavhane, RS & Rahman, SMA 2020, 'Enhancement in Combustion, Performance, and Emission Characteristics of a Diesel Engine Fueled with Ce-ZnO Nanoparticle Additive Added to Soybean Biodiesel Blends', Energies, vol. 13, no. 17, pp. 4578-4578.
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This study considered the impacts of diesel–soybean biodiesel blends mixed with 3% cerium coated zinc oxide (Ce-ZnO) nanoparticles on the performance, emission, and combustion characteristics of a single cylinder diesel engine. The fuel blends were prepared using 25% soybean biodiesel in diesel (SBME25). Ce-ZnO nanoparticle additives were blended with SBME25 at 25, 50, and 75 ppm using the ultrasonication process with a surfactant (Span 80) at 2 vol.% to enhance the stability of the blend. A variable compression ratio engine operated at a 19.5:1 compression ratio (CR) using these blends resulted in an improvement in overall engine characteristics. With 50 ppm Ce-ZnO nanoparticle additive in SBME25 (SBME25Ce-ZnO50), the brake thermal efficiency (BTE) and heat release rate (HRR) increased by 20.66% and 18.1%, respectively; brake specific fuel consumption (BSFC) by 21.81%; and the CO, smoke, and hydrocarbon (HC) decreased by 30%, 18.7%, and 21.5%, respectively, compared to SBME25 fuel operation. However, the oxides of nitrogen slightly rose for all the nanoparticle added blends. As such, 50 ppm of Ce-ZnO nanoparticle in the blend is a potent choice for the enhancement of engine performance, combustion, and emission characteristics.
Huy Tran, V, Lim, S, Jun Park, M, Suk Han, D, Phuntsho, S, Park, H, Matsuyama, H & Kyong Shon, H 2020, 'Fouling and performance of outer selective hollow fiber membrane in osmotic membrane bioreactor: Cross flow and air scouring effects', Bioresource Technology, vol. 295, pp. 122303-122303.
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© 2019 Elsevier Ltd This study assessed impacts of cross-flow velocity (CFV) and air scouring on the performance and membrane fouling mitigation of a side-stream module containing outer-selective hollow fiber thin film composite forward osmosis membrane in osmosis membrane bioreactor (OMBR) system for urban wastewater treatment. CFV of draw solution was optimized, followed by the impact assessment of three CFVs on feed solution (FS) stream and periodic injection of air scouring into the side-stream module. Overall, the OMBR system exhibited high and stable performance with initial water flux of approximately 15 LMH, high removal efficiencies of bulk organic matter and nutrients. While FS's CFVs insignificantly affected the performance and membrane fouling, regular air scouring showed substantial impact with better performance and high efficiency in mitigating membrane fouling. These results indicated that periodic air scouring can be applied into the side-stream membrane module for efficient fouling mitigation without interruption the operation of the OMBR system.
Ibrar, I, Altaee, A, Zhou, JL, Naji, O & Khanafer, D 2020, 'Challenges and potentials of forward osmosis process in the treatment of wastewater', Critical Reviews in Environmental Science and Technology, vol. 50, no. 13, pp. 1339-1383.
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© 2019, © 2019 Taylor & Francis Group, LLC. An emerging osmotically driven membrane process, forward osmosis has attracted growing attention in the field of desalination and wastewater treatment. The present study provides a critical review of the forward osmosis process for wastewater treatment focusing on most recent studies. Forward osmosis is one of the technologies that has been widely studied for the treatment of a wide range of wastewater because of its low fouling and energy consumption compared to conventional techniques for wastewater treatment. To date, forward osmosis has limited applications in the field of wastewater treatment due to several technical and economic concerns. Although membrane cost is one of the critical issues that limit the commercial application of forward osmosis, there are other obstacles such as membrane fouling, finding an ideal draw solution that can easily be recycled, concentration polarization and reverse salt diffusion. Innovative technologies for in-situ real-time fouling monitoring can give us new insights into fouling mechanisms and fouling control strategies in forward osmosis. This study evaluated recent advancements in forward osmosis technology for wastewater treatment and the main challenges that need to be addressed in future research work.
Ibrar, I, Yadav, S, Altaee, A, Hawari, A, Nguyen, V & Zhou, J 2020, 'A novel empirical method for predicting concentration polarization in forward osmosis for single and multicomponent draw solutions', Desalination, vol. 494, pp. 114668-114668.
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Ibrar, I, Yadav, S, Altaee, A, Samal, AK, Zhou, JL, Nguyen, TV & Ganbat, N 2020, 'Treatment of biologically treated landfill leachate with forward osmosis: Investigating membrane performance and cleaning protocols', Science of The Total Environment, vol. 744, pp. 140901-140901.
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This study presents systematic investigations to evaluate the performance, rejection rate, fouling, cleaning protocols and impact of physical and chemical cleaning strategies on the performance of commercial cellulose triacetate (CTA) membrane. The treatment of landfill leachate (LFL) solution was performed in the active layer facing feed solution and support layer facing the draw solution (AL-FS mode), and active layer facing the draw solution and support layer facing the feed solution (AL-DS mode). Compared to the AL-FS mode, a higher flux for AL-DS mode was achieved, but membrane fouling was more severe in the latter. In both membrane orientations, the rejection rate of the FO membrane to heavy ions and contaminants in the wastewater was between 93 and 99%. Physical and chemical cleaning strategies were investigated to recover the performance of the FO membrane and to study the impact of cleaning methods on the membrane rejection rate. Physical cleaning with hot water at 35 °C and osmotic backwashing with 1.5 M NaCl demonstrated excellent water flux recovery compared to chemical cleaning. In the chemical cleaning, an optimal concentration of 3% hydrogen peroxide was determined for 100% flux recovery of the fouled membrane. However, slight membrane damage was achieved at this concentration on the active layer side. Alkaline cleaning at pH 11 was more effective than acid cleaning at pH 4, although both protocols compromised the membrane rejection rate for some toxic ions. A comparison of the membrane long-term performance found that cleaning with osmotic backwashing and hot water were effective methods to restore water flux without comprising the membrane rejection rate. Overall, it was found that physical cleaning protocols are superior to chemical cleaning protocols for forward osmosis membrane fouled by landfill leachate wastewater.
Indraratna, B, Israr, J & Vaughan, LPR 2020, 'From Particles to Constrictions: Scientific Evolution of Enhanced Criteria for Internal Stability Assessment of Soils', Geotechnical Engineering, vol. 51, no. 3, pp. 65-72.
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Internal instability occurs when steady seepage forces erode the finer fractions from non-uniform soils along pre-existing openings such as cracks in cohesive soils and voids in non-cohesive soil to induce permanent changes in the original particle size distribution. Given that the drainage characteristics of soils are significantly influenced by the shape, packing arrangement, compaction, and size distribution of their particles, even limited erosion can markedly alter their drainage characteristics. The geometrical assessment of internal instability potential is normally conducted using classical filter retention criterion based on mere particle size distribution and without giving due consideration to the above factors. These methods would determine the risk of instability by approximating the soil’s constrictions based on its particle size distribution; these constrictions are pore channels connecting neighbouring void spaces that would control both permeability and retention phenomena. However, recent advances in mathematical computations have facilitated the exact delineation of constriction sizes and the introduction of more accurate constriction based methods. This study purports to shed light on the scientific evolution of particle and constriction based methods over the past four decades, including the enhanced accuracy, reduced bias, and robustness associated with the latter. An interesting case study from our experience of using these approaches for a permeable barrier design at Bomaderry, NSW (Australia) for subsurface flow treatment is presented, and recommendations for their use by practicing engineers are made to conclude this study.
Indraratna, B, Korkitsuntornsan, W & Nguyen, TT 2020, 'Influence of Kaolin content on the cyclic loading response of railway subgrade', Transportation Geotechnics, vol. 22, pp. 100319-100319.
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© 2020 Elsevier Ltd Rail tracks passing through saturated subgrade soil often face a serious deterioration of bearing capacity and excessive deformation. One major reason is the excessive cyclic pore pressure that accumulates under the track that leads to soil softening and infiltration over the surface, i.e., subgrade mud pumping (fluidization). Although this issue has received considerable attention in recent decades, how the cyclic stress ratio and soil properties such as plasticity and void ratio influence the cyclic loading response of soft subgrade soil is still not properly understood. In this study, Kaolin – an artificial cohesive fines soil is used to modify a low plasticity subgrade soil to examine how the Kaolin content (cK) can affect its cyclic response. Soil specimens including the original soil and its mixture with 10 and 30% of Kaolin have been subjected to undrained cyclic testing. A cyclic stress ratio (CSR) varying from 0.2 to 1.2 is used and a low initial confining pressure of 20 kPa is applied. The results show 3 different responses of soil, i.e., (i) stable, (ii) cyclic undrained failure, and (iii) fluidization, depending on the magnitude of CSR. Where fluidization becomes imminent, the shear stress rapidly decreases at early stages. Adding cohesive fines, i.e., Kaolin reduces the static undrained shear strength and increases the plasticity index. This enables the test specimen to undergo a larger number of cycles (N) before failure, thus enhancing its resistance to fluidization. Specimens with a smaller initial void ratio, i.e., greater level of compaction, are less susceptible to fluidization because they can withstand larger CSR and N. Moreover, this study shows where there is potential fluidization upon cyclic loading, a significant redistribution of the water content seems to occur over the height of the test specimens.
Indraratna, B, Medawela, S, Rowe, K, Thamwattana, N & Heitor, A 2020, 'Bio-Geochemical clogging of Permeable Reactive Barriers in Acid Sulphate Soil Floodplain', Journal of Geotechnical and Geoenvironmental Engineering, vol. 146, no. 5.
Indraratna, B, Medawela, S, Rowe, RK, Thamwattana, N & Heitor, A 2020, 'Biogeochemical Clogging of Permeable Reactive Barriers in Acid-Sulfate Soil Floodplain', Journal of Geotechnical and Geoenvironmental Engineering, vol. 146, no. 5, pp. 04020015-04020015.
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Column experiments that investigate the use of calcitic limestone as a potential material for permeable reactive barriers (PRBs), as well as its clogging behavior, are conducted under conditions that involve continuous acidic flow containing Al, Fe, and acidophilic bacteria. Results show that nonhomogenous biogeochemical clogging occurred toward the outlet, resulting in a 45% reduction of hydraulic conductivity at the inlet and 10% reduction at the outlet after the bicarbonate buffering period. A mathematical model developed to capture the reductions in longevity is presented. The model, which considers the effects of time-varying porosity, hydraulic conductivity, and head at a particular point on the horizontal flow path, is used for assessing the effect of coupled clogging in a calcitic porous medium.
Indraratna, B, Ngo, T & Rujikiatkamjorn, C 2020, 'Performance of Ballast Influenced by Deformation and Degradation: Laboratory Testing and Numerical Modeling', International Journal of Geomechanics, vol. 20, no. 1, pp. 04019138-04019138.
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© 2019 American Society of Civil Engineers. This paper presents a study on the deformation and degradation responses of railway ballast using large-scale laboratory testing and computational modeling approaches. A series of large-scale triaxial tests were carried out to investigate the ballast breakage responses under cyclic train loading subjected to varying frequencies, f=10-40 Hz. The role of recycled rubber energy-absorbing mats (REAMs) on reducing ballast breakage was also examined. Laboratory test results show that the ballast experiences significant degradation (breakage) and deformation, while the inclusion of REAMs can reduce the ballast breakage up to about 35%. Numerical modeling using the coupled discrete-continuum approach [coupled discrete-element method-finite-difference method (DEM-FDM)] is introduced to provide insightful understanding on the deformation and breaking of ballast under cyclic loading. Discrete ballast grains were simulated by bonding of many circular elements together at appropriate sizes and locations. Selected cylinders located at corners, surfaces, and sharp edges of the simulated particles were connected by parallel bonds; and when those bonds were broken, they were considered to represent ballast breakage. The subgrade and rubber mat were simulated as a continuum media using FDM. The predicted axial strain ϵa and volumetric strain ϵv obtained from the coupled DEM-FDM model are in good agreement with those measured in the laboratory. The model was then used to explore micromechanical aspects of ballast aggregates including the evolution of particle breakage, contact force distributions, and orientation of contacts during cyclic loading. These findings are imperative for a more insightful understanding of the breakage behavior of ballast from the perspective of microstructure characteristics of discrete particle assemblies.
Indraratna, B, Ngo, T, Bessa Ferreira, F, Rujikiatkamjorn, C & Shahkolahi, A 2020, 'Laboratory examination of ballast deformation and degradation under impact loads with synthetic inclusions', Transportation Geotechnics, vol. 25, pp. 100406-100406.
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© 2020 Elsevier Ltd This paper presents a laboratory study on alleviating the deformation and degradation (breakage) of ballast subjected to impact loads using geogrids and rubber mats. A series of drop hammer impact tests are carried out to determine how well the geogrid, under-ballast mat (UBM) or under-sleeper pad (USP) can attenuate impact loads and mitigate ballast degradation. Geogrids to be placed at different locations in a ballast assembly, in combination either with a UBM or a USP are tested. Laboratory test results prove that the inclusion of rubber mats and geogrids decrease the dynamic impact loads transferred to the ballast aggregates and subsequently decrease the degradation (breakage) and deformation of ballast. The tensile strength of geogrids and subgrade stiffness are found to considerably influence the performance of geogrid-reinforced ballast under impact loading conditions. The measured impact forces and accelerations of ballast with and without an artificial inclusion show that rubber mats definitely reduce track vibration (acceleration) and the subsequent deformation and breakage of ballast. These inclusions will not only increase safety and passenger comfort they will also lead to more economical and efficient track designs.
Indraratna, B, Singh, M & Nguyen, TT 2020, 'The mechanism and effects of subgrade fluidisation under ballasted railway tracks', Railway Engineering Science, vol. 28, no. 2, pp. 113-128.
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AbstractThe rapid growth in railway infrastructure and the construction of high-speed heavy-haul rail network, especially on ground that is basically unsuitable, poses challenges for geotechnical engineers because a large part of the money invested in the development of railway lines is often spent on track maintenance. In fact around the world, the mud pumping of subgrade fines is one of the common reasons why track performance deteriorates and track stability is hindered. This article presents a series of laboratory tests to examine following aspects of mud pumping: (1) the mechanisms of subgrade fluidisation under undrained condition, (2) the effects of mud pumping on the engineering characteristics of ballast, and (3) the use of vertical drains to stabilize subgrade under cyclic loads. The undrained cyclic triaxial testing on vulnerable soft subgrade was performed by varying the cyclic stress ratio (CSR) from 0.2 to 1.0 and the loading frequency f from 1.0 to 5.0 Hz. It is seen from the test results that for a specimen compacted at an initial dry density of 1790 kg/m3, the top portion of the specimen fluidises at CSR = 0.5, irrespective of the applied loading frequency. Under cyclic railway loading, the internal redistribution of water at the top of the subgrade layer softens the soil and also reduces its stiffness. In response to these problems, this paper explains how the inclusion of vertical drains in soft subgrade will help to prevent mud pumping by alleviating the build-up of excess pore pressures under moving train loads.
Indraratna, B, Singh, M, Nguyen, TT, Leroueil, S, Abeywickrama, A, Kelly, R & Neville, T 2020, 'Laboratory study on subgrade fluidization under undrained cyclic triaxial loading', Canadian Geotechnical Journal, vol. 57, no. 11, pp. 1767-1779.
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A long-term issue that has hampered the efficient operation of heavy-haul tracks is the migration of fluidized fines from the shallow soft subgrade to the overlying ballast, i.e., mud pumping. This paper presents a series of undrained cyclic triaxial tests where realistic cyclic loading conditions were simulated at low confining pressure that is typical of shallow subgrade beneath a ballast track. Subgrade soil specimens with a low-plasticity index collected from a field site with recent history of mud pumping were tested at frequencies from 1.0 to 5.0 Hz and a cyclic stress ratio (CSR) from 0.1 to 1.0. The experimental results indicate that under adverse loading conditions of critical cyclic stress ratio (CSRc) and frequency, there is upward migration of moisture and the finest particles towards the specimen top and this causes the uppermost part of the soil specimen to soften and fluidize. Conversely, a smaller value of CSR tends to maintain stability of the specimen despite the increasing number of loading cycles. It is noteworthy that for any given combination of CSR and frequency, the relative compaction has a significant influence on the cyclic behaviour of the soil and its potential for fluidization.
Jamil, S, Loganathan, P, Kandasamy, J, Listowski, A, McDonald, JA, Khan, SJ & Vigneswaran, S 2020, 'Removal of organic matter from wastewater reverse osmosis concentrate using granular activated carbon and anion exchange resin adsorbent columns in sequence', Chemosphere, vol. 261, pp. 127549-127549.
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Reverse osmosis concentrate (ROC) generated as a waste stream during reverse osmosis treatment of reclaimed wastewater, presents significant disposal challenges. This is because it causes environmental pollution when it is disposed to lands and natural water bodies. A long-term dynamic adsorption experiment was conducted by passing ROC from a wastewater reclamation plant, firstly through a granular activated carbon (GAC) column, and subsequently through an anion exchange resin (Purolite) column, for the removal of two major ROC pollutants, namely dissolved organic carbon (DOC) and microorganic pollutants (MOP). GAC removed most of the smaller-sized low molecular weight neutrals and building block fractions as well as the hydrophobic fraction of DOC with much less removal by the subsequent Purolite column. In contrast, the humics fraction was less well removed by the GAC column; however, Purolite column removed all that was remaining of this fraction. This study demonstrated that combining adsorbents having different affinities towards a variety of DOC fractions constitute an effective method of taking advantage of their different properties and achieving larger DOC removals. Almost 100% of all 17 MOPs were removed by the GAC column, even after 2880 bed volumes of continuous use. This contrasted with the DOC fractions' removal which was much lower.
Jayasuriya, C, Indraratna, B & Ferreira, FB 2020, 'The Use of Under Sleeper Pads to Improve the Performance of Rail Tracks', Indian Geotechnical Journal, vol. 50, no. 2, pp. 204-212.
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© 2020, Indian Geotechnical Society. In recent years, with the growing demand for both passenger and freight mobility, faster and heavier rail traffic has been the norm rather than the exception in many countries. As a result, track geometry and the safety of ballasted rail tracks have been adversely affected, leading to exacerbated maintenance costs. Increased stresses in granular foundation induce progressive track degradation, which can result in excessive vertical and lateral deformation, ballast and subballast fouling and impeded drainage. These effects tend to be more severe at specific locations, such as bridges, level crossings and tunnels (i.e. over stiff subgrade). Finding an economical strategy to mitigate ballast degradation has been a challenging task for practitioners, and the inclusion of energy-absorbing rubber pads underneath the sleepers (under sleeper pads—USPs) to minimise track damage is an attractive solution. This paper presents a laboratory study conducted at the University of Wollongong to investigate the use of USPs as resilient elements in ballasted rail tracks involving a stiff subgrade. Test results have shown a significant improvement in track performance resulting from the use of USPs, whereby it is demonstrated that ballast damage induced by the applied cyclic loads can be reduced due to the favourable damping characteristics of these rubber pads. A significant attenuation in particle breakage was observed along with a reduction in both the vertical settlement and lateral movement of the ballast layer, thereby suggesting that USPs can be an effective means of improving the stability and serviceability of the track system.
Jayawardane, VS, Anggraini, V, Li-Shen, AT, Paul, SC & Nimbalkar, S 2020, 'Strength Enhancement of Geotextile-Reinforced Fly-Ash-Based Geopolymer Stabilized Residual Soil', International Journal of Geosynthetics and Ground Engineering, vol. 6, no. 4.
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© 2020, Springer Nature Switzerland AG. Soils in their natural form are often deemed unsatisfactory to be directly used as a construction material for their respective applications. Under such circumtances, employment of ground improvement techniques to better suit the soil for its function is typically the most economical approach. Consequently, the present research investigated into the beneficial effect of modernized soil treatment techniques, i.e., geopolymer stabilization using fly ash as the precursor and geotextile reinforcement, on the strength enhancement of natural residual soil. A series of unconsolidated undrained (UU) triaxial compression tests were carried out to assess variation of geopolymer stabilized residual soil strength based on the varying number of geotextile layers, geotextile arrangement, and confining pressures. It was found that the increase in the number of geotextile layers resulted in a corresponding rise in soil strength and stiffness. It was also discovered that placement of geotextile layers at sample regions which suffered the maximum tensile stress–strain during loading was more effective compared to random placement. Soil strength was observed to reduce with increasing confining pressure which demonstrated the effectiveness of utilizing geotextile reinforcement at greater depths below the ground to be less. Failure patterns showed that while unreinforced soil resulted in failure along a shear plane at an approximate angle of 45 + φ/2 (φ: angle of internal friction), reinforced samples demonstrated a bulging failure where the soil between adjacent layers of geotextiles appeared to bulge. The findings deemed the employment of geopolymer stabilization and geotextile reinforcement on natural residual soil very effective with regards to the enhancement of soil strength and stiffness.
Jena, R & Pradhan, B 2020, 'A Model for Visual Assessment of Fault Plane Solutions and Active Tectonics Analysis Using the Global Centroid Moment Tensor Catalog', Earth Systems and Environment, vol. 4, no. 1, pp. 197-211.
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In this study, individual fault plane solutions are developed using various methods to improve the understanding of active tectonics on a regional scale. The comparative analysis of a focal mechanism solution (FMS) has not elicited the attention of researchers. Therefore, this study aims (1) to visually analyze the fault plane solution for 20 local faults that are responsible for all the earthquakes that occurred using visualization techniques such as: fault parameters, the linked Bingham method, the ad hoc pressure (P) axis and tension (T) axis method, and the moment tensor method; (2) to identify the best method for FMS; and (3) to understand the active tectonics of a fault population. A comparative analysis of the models is systematically documented to improve the understanding of the methods. An analysis of the overall fault mechanism is conducted for the analytic determination of fault movement using fault population data from the Global Centroid Moment Tensor catalog. The approach used in this work is a newly designed method for analyzing the reliability of various techniques for fault mechanism and overall fault movement research. Findings show that for the fault mechanism analysis, the P and T axes method and the moment tensor method are better than the fault plane solution from the fault parameters and the linked Bingham method based on the input parameters, output information, model outfit, and accuracy. The moment tensor method is one of the best approaches for analyzing fault mechanism because the errors in the nine components used as input data for the modeling are negligible. Meanwhile, the P and T axes method is one of the best techniques for the overall analysis of fault movement. P and T dihedral analysis using Kamb contouring is modeled. It indicates that the overall mechanisms of compression and dilation are features at the NW–SE and E–W directions, respectively. This comprehensive and consistent analysis of the fault mechanism provides an over...
Jena, R & Pradhan, B 2020, 'Integrated ANN-cross-validation and AHP-TOPSIS model to improve earthquake risk assessment', International Journal of Disaster Risk Reduction, vol. 50, pp. 101723-101723.
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© 2020 Elsevier Ltd The current study presents a novel combination of artificial neural network cross-validation (fourfold ANN-CV) with a hybrid analytic hierarchy process-Technique for Order of Preference by Similarity to Ideal Solution (AHP-TOPSIS) method to improve the earthquake risk assessment (ERA) and applied it to Aceh, Indonesia, to test the model. Recent studies have suggested that neural networks improve probability mapping in a city scale. The network architecture design with probability index remains unexplored in earthquake-based probability studies. This study explored and specified the major indicators needed to improve the predictive accuracy in probability mapping. First, probability mapping was conducted and used for hazard assessment in the next step. Second, a vulnerability map was created based on social and structural factors. Finally, hazard and vulnerability indices were multiplied to produce the ERA, and the population and areas under risk were calculated. Results show that the proposed model achieves 85.4% accuracy, and its consistency ratio is 0.06. Risk varies from very high to high in the city center, approximately covering an area of 23% (14.82 km2) and a total population of 54,695. The model's performance changes on the basis of the input parameters, indicating the selection and importance of input layers on network architecture selection. The proposed model is found to generalize better results than traditional and some existing probabilistic models. The proposed model is simple and transferable to other regions by localizing the input parameters that contribute to earthquake risk mitigation and prevention planning.
Jena, R, Pradhan, B & Alamri, AM 2020, 'Geo-structural stability assessment of surrounding hills of Kuala Lumpur City based on rock surface discontinuity from geological survey data', Arabian Journal of Geosciences, vol. 13, no. 2.
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Jena, R, Pradhan, B & Alamri, AM 2020, 'Susceptibility to Seismic Amplification and Earthquake Probability Estimation Using Recurrent Neural Network (RNN) Model in Odisha, India', Applied Sciences, vol. 10, no. 15, pp. 5355-5355.
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The eastern region of India, including the coastal state of Odisha, is a moderately seismic-prone area under seismic zones II and III. However, no major studies have been conducted on earthquake probability (EPA) and hazard assessment (EHA) in Odisha. This paper had two main objectives: (1) to assess the susceptibility of seismic wave amplification (SSA) and (2) to estimate EPA in Odisha. In total, 12 indicators were employed to assess the SSA and EPA. Firstly, using the historical earthquake catalog, the peak ground acceleration (PGA) and intensity variation was observed for the Indian subcontinent. We identified high amplitude and frequency locations for estimated PGA and the periodograms were plotted. Secondly, several indicators such as slope, elevation, curvature, and amplification values of rocks were used to generate SSA using predefined weights of layers. Thirdly, 10 indicators were implemented in a developed recurrent neural network (RNN) model to create an earthquake probability map (EPM). According to the results, recent to quaternary unconsolidated sedimentary rocks and alluvial deposits have great potential to amplify earthquake intensity and consequently lead to acute ground motion. High intensity was observed in coastal and central parts of the state. Complicated morphometric structures along with high intensity variation could be other parameters that influence deposits in the Mahanadi River and its delta with high potential. The RNN model was employed to create a probability map (EPM) for the state. Results show that the Mahanadi basin has dominant structural control on earthquakes that could be found in the western parts of the state. Major faults were pointed towards a direction of WNW–ESE, NE–SW, and NNW–SSE, which may lead to isoseismic patterns. Results also show that the western part is highly probable for events while the eastern coastal part is highly susceptible to seismic amplification. The RNN model achieved an accura...
Jena, R, Pradhan, B & Beydoun, G 2020, 'Earthquake vulnerability assessment in Northern Sumatra province by using a multi-criteria decision-making model', International Journal of Disaster Risk Reduction, vol. 46, pp. 101518-101518.
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© 2020 Elsevier Ltd The prerequisite for earthquake risk estimation is vulnerability assessment. Therefore, estimating vulnerability is necessary to reduce future fatalities. This study aims to evaluate the earthquake vulnerability assessment (EVA) in Banda Aceh by using the multi-criteria decision-making approach through an analytical hierarchy process and VIseKriterijumska Optimizacija I Kompromisno Resenje method using a geographical information system. Banda Aceh City is located close to the Great Sumatran Fault in North Sumatra. Several factors were used to produce social vulnerability, structural vulnerability, and geotechnical vulnerability indices. Subsequently, the adopted approaches were integrated and applied to estimate the criteria weight, priority ranking, and alternatives of criterion by applying the pair-wise comparison at all levels. Finally, vulnerability layers were superimposed to estimate the earthquake vulnerability index and produce the vulnerability map. Results showed that the central part of the city exhibits high to very high vulnerability. A tiny part of the northern–central part is under severe vulnerability conditions. The consistency ratios for all three vulnerability layers were 1.9%, 4.6% and 5.5%. The consistency ratios for the final EVA was 1.9%. The developed map revealed that 3.39% of Banda Aceh City falls under very high, 11.86% high, 23.73% medium, 28.82% low, and 32.20% of very low vulnerability areas. The proposed method for the EVA provides useful information that could assist in earthquake disaster mitigation.
Jena, R, Pradhan, B, Al-Amri, A, Lee, CW & Park, H-J 2020, 'Earthquake Probability Assessment for the Indian Subcontinent Using Deep Learning', Sensors, vol. 20, no. 16, pp. 4369-4369.
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Earthquake prediction is a popular topic among earth scientists; however, this task is challenging and exhibits uncertainty therefore, probability assessment is indispensable in the current period. During the last decades, the volume of seismic data has increased exponentially, adding scalability issues to probability assessment models. Several machine learning methods, such as deep learning, have been applied to large-scale images, video, and text processing; however, they have been rarely utilized in earthquake probability assessment. Therefore, the present research leveraged advances in deep learning techniques to generate scalable earthquake probability mapping. To achieve this objective, this research used a convolutional neural network (CNN). Nine indicators, namely, proximity to faults, fault density, lithology with an amplification factor value, slope angle, elevation, magnitude density, epicenter density, distance from the epicenter, and peak ground acceleration (PGA) density, served as inputs. Meanwhile, 0 and 1 were used as outputs corresponding to non-earthquake and earthquake parameters, respectively. The proposed classification model was tested at the country level on datasets gathered to update the probability map for the Indian subcontinent using statistical measures, such as overall accuracy (OA), F1 score, recall, and precision. The OA values of the model based on the training and testing datasets were 96% and 92%, respectively. The proposed model also achieved precision, recall, and F1 score values of 0.88, 0.99, and 0.93, respectively, for the positive (earthquake) class based on the testing dataset. The model predicted two classes and observed very-high (712,375 km2) and high probability (591,240.5 km2) areas consisting of 19.8% and 16.43% of the abovementioned zones, respectively. Results indicated that the proposed model is superior to the traditional methods for earthquake probability assessment in terms of accuracy. Asid...
Jena, R, Pradhan, B, Beydoun, G, Al-Amri, A & Sofyan, H 2020, 'Seismic hazard and risk assessment: a review of state-of-the-art traditional and GIS models', Arabian Journal of Geosciences, vol. 13, no. 2.
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© 2020, Saudi Society for Geosciences. The historical records of earthquakes play a vital role in seismic hazard and risk assessment. During the last decade, geophysical, geotechnical, geochemical, topographical, geomorphological, geological data, and various satellite images have been collected, processed, and well-integrated into qualitative and quantitative spatial databases using geographical information systems (GIS). Various types of modeling approaches, such as traditional and GIS-based models, are used. Progressively, seismic studies can improve and modify systematic models and standardize the inventory map of earthquake-susceptible regions. Therefore, this paper reviews different approaches, which are organized and discussed on various models primarily used to create an earthquake scenario focusing on hazard and risk assessment. The reviews are divided into two major parts. The first part is the basic principles, data, and the methodology of various models used for seismic hazard and risk assessment. In the second part, a comparative analysis in terms of the limitations and strengths of the models, as well as application variability is presented. Furthermore, the paper includes the descriptions of software, data resources, and major conclusions. The main findings of this review explain that the capability of machine learning techniques regularly enhances the state of earthquake research, which will provide research opportunities in the future. The model suitability depends on the improvement of parameters, data, and methods that could help to prevent future risk. This paper will help researchers further understand the models based on their strengths, limitations, and applicability.
Jena, R, Pradhan, B, Beydoun, G, Alamri, AM, Ardiansyah, Nizamuddin & Sofyan, H 2020, 'Earthquake hazard and risk assessment using machine learning approaches at Palu, Indonesia', Science of The Total Environment, vol. 749, pp. 141582-141582.
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© 2020 Elsevier B.V. On 28th September 2018, a very high magnitude of earthquake Mw 7.5 struck the Palu city in the Island of Sulawesi, Indonesia. The main objective of this research is to estimate the earthquake risk based on probability and hazard in Palu region using cross-correlation among the derived parameters, Silhouette clustering (SC), pure locational clustering (PLC) based on hierarchical clustering analysis (HCA), convolutional neural network (CNN) and analytical hierarchy process (AHP) techniques. There is no specific or simple way of identifying risks as the definition of risk varies with time and space. The main aim of this study is: i) to conduct the clustering analysis to identify the earthquake-prone areas, ii) to develop a CNN model for probability estimation, and iii) to estimate and compare the risk using two calculation equations (Risk A and B). Owing to its high prediction ability, the CNN model assessed the probability while SC and PLC were implemented to understand the spatial clustering, Euclidean distance among clusters, spatial relationship and cross-correlation among the estimated Mw, PGA and intensity including events depth. Finally, AHP was implemented for the vulnerability assessment. To this end, earthquake probability assessment (EPA), susceptibility to seismic amplification (SSA) and earthquake vulnerability assessment (EVA) results were employed to generate risk A, while earthquake hazard assessment (EHA), SSA and EVA were used to generate risk B. The risk maps were compared and the differences in results were obtained. This research concludes that in the case of earthquake risk assessment (ERA), results obtained in Risk B are better than the risk A. This study achieved 89.47% accuracy for EPA while for EVA a consistency ratio of 0.07. These results have important implications for future large-scale risk assessment, land use planning and hazard mitigation.
Jena, R, Pradhan, B, Beydoun, G, Nizamuddin, Ardiansyah, Sofyan, H & Affan, M 2020, 'Integrated model for earthquake risk assessment using neural network and analytic hierarchy process: Aceh province, Indonesia', Geoscience Frontiers, vol. 11, no. 2, pp. 613-634.
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© 2019 China University of Geosciences (Beijing) and Peking University Catastrophic natural hazards, such as earthquake, pose serious threats to properties and human lives in urban areas. Therefore, earthquake risk assessment (ERA) is indispensable in disaster management. ERA is an integration of the extent of probability and vulnerability of assets. This study develops an integrated model by using the artificial neural network–analytic hierarchy process (ANN–AHP) model for constructing the ERA map. The aim of the study is to quantify urban population risk that may be caused by impending earthquakes. The model is applied to the city of Banda Aceh in Indonesia, a seismically active zone of Aceh province frequently affected by devastating earthquakes. ANN is used for probability mapping, whereas AHP is used to assess urban vulnerability after the hazard map is created with the aid of earthquake intensity variation thematic layering. The risk map is subsequently created by combining the probability, hazard, and vulnerability maps. Then, the risk levels of various zones are obtained. The validation process reveals that the proposed model can map the earthquake probability based on historical events with an accuracy of 84%. Furthermore, results show that the central and southeastern regions of the city have moderate to very high risk classifications, whereas the other parts of the city fall under low to very low earthquake risk classifications. The findings of this research are useful for government agencies and decision makers, particularly in estimating risk dimensions in urban areas and for the future studies to project the preparedness strategies for Banda Aceh.
Jena, R, Pradhan, B, Jung, HS, Rai, AK & Rizeei, HM 2020, 'Seasonal water change assessment at Mahanadi River, India using multi-temporal data in Google Earth engine', Korean Journal of Remote Sensing, vol. 36, no. 1, pp. 1-13.
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Seasonal changes in river water vary seasonally as well as locationally, and the assessment is essential. In this study, we used the recent technique of post-classification by using the Google earth engine (GEE) to map the seasonal changes in Mahanadi river of Odisha. However, some fixed problems results during the rainy season that affects the livelihood system of Cuttack such as flooding, drowning of children and waste material deposit. Therefore, this study conducted 1) to map and analyse the water density changes and 2) to analyse the seasonal variation of river water to resolve and prevent problem shortcomings. Our results showed that nine types of variation can be found in the Mahanadi River each year. The increase and decrease of intensity of surface water analysed, and it varies in between -130 to 70 m3/nf. The highest frequency change is 2900 Hz near Cuttack city. The pi diagram provides the percentage of seasonal variation that can be observed as permanent water (30%), new seasonal (28%), ephemeral (12%), permanent to seasonal (7%) and seasonal (10%). The analysis is helpful and effective to assess the seasonal variation that can provide a platform for the development of Cuttack city that lies in Mahanadi delta.
Jenifer A, A, Chandran, T, Muthunarayanan, V, Ravindran, B, Nguyen, VK, Nguyen, XC, Bui, X-T, Ngo, HH, Nguyen, XH, Chang, SW & Nguyen, DD 2020, 'Evaluation of efficacy of indigenous acidophile- bacterial consortia for removal of pollutants from coffee cherry pulping wastewater', Bioresource Technology Reports, vol. 11, pp. 100533-100533.
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The efficiency of indigenous bacteria to remove colour, TDS and COD pollutants from coffee cherry pulping wastewater (CCPWW) in an acidic pH without any manipulation of the effluent was studied. For the removal of such pollutants, the CCPWW was subjected to treatment with four indigenous microbial test strains isolated from CCPWW and characterised using 16S rRNA molecular technique, namely Enterobacter ludwigii, Bacilllus cereus, Enterobacter aerogenes and Enterobacter cloacae. Among the individual microbial treatments, the Enterobacter cloacae bacterial strain removed higher amount of TDS (37.6%) and COD (40.1%). Treatment with the bacterial consortia removed about 40.9% TDS, 48.7% COD from CCPWW after 48 h. The correlation coefficient ‘r’ between TDS and COD removal for each individual treatment was 1, showed the positive linear relationship. The microbes had endured in the harsh–low pH environment of the effluent and effectively removed the pollutants without any addition of other nutrient support.
Ji, M, Hu, Z, Hou, C, Liu, H, Ngo, HH, Guo, W, Lu, S & Zhang, J 2020, 'New insights for enhancing the performance of constructed wetlands at low temperatures', Bioresource Technology, vol. 301, pp. 122722-122722.
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Constructed wetlands (CWs) have been widely utilized for various types of wastewater treatment due to their merits, including high cost-effectiveness and easy operation. However, a few intrinsic drawbacks have always restricted their application and long-term stability, especially their weak performance at temperatures under 10 °C (low temperatures) due to the deterioration of microbial assimilation and plant uptake processes. The existing modifications to improve CWs performance from the direct optimization of internal components to the indirect adjunction of external resources promoted the wastewater treatment efficiency to a certain degree, but the sustainability and sufficiency of pollutants removal remains a challenge. With the goal of optimizing CW components, the integrity of the CW ecosystem and the removal of emerging pollutants, future directions for research should include radiation plant breeding, improvements to CW ecosystems, and the combination or integration of certain treatment processes with CWs to enhance wastewater treatment effects at low temperatures.
Jiang, Y, He, N, Zhou, Y, Xu, B, Zhan, X & Ding, Y 2020, 'Investigation on in situ test and measurement technique of groundwater level in vacuum preloading', Bulletin of Engineering Geology and the Environment, vol. 79, no. 3, pp. 1209-1223.
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Jung, H-S, Lee, S & Pradhan, B 2020, 'Sustainable Applications of Remote Sensing and Geospatial Information Systems to Earth Observations', Sustainability, vol. 12, no. 6, pp. 2390-2390.
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The Special Issue on “Sustainable Applications of Remote Sensing and Geospatial Information Systems to Earth Observations” is published. A total of 20 qualified papers are published in this Special Issue. The topics of the papers are the application of remote sensing and geospatial information systems to Earth observations in various fields such as (1) object change detection, (2) air pollution, (3) earthquakes, (4) landslides, (5) mining, (6) biomass, (7) groundwater, and (8) urban development using the techniques of remote sensing and geospatial information systems. More than 100 researchers have participated in this Special Issue. We hope that this Special Issue is helpful for sustainable applications.
Karimidastenaei, Z, Torabi Haghighi, A, Rahmati, O, Rasouli, K, Rozbeh, S, Pirnia, A, Pradhan, B & Kløve, B 2020, 'Fog-water harvesting Capability Index (FCI) mapping for a semi-humid catchment based on socio-environmental variables and using artificial intelligence algorithms', Science of The Total Environment, vol. 708, pp. 135115-135115.
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Fog is an important component of the water cycle in northern coastal regions of Iran. Having accurate tools for mapping the precise spatial distribution of fog is vital for water harvesting within integrated water resources management in this semi-humid region. In this study, environmental variables were considered in prediction mapping of areas with high concentrations of fog in the Vazroud watershed, Iran. Fog probability maps were derived from four artificial intelligence algorithms (Generalized Linear Model, Generalized Additive Model, Generalized Boosted Model, and Generalized Dissimilarity Model). Models accuracy were assessed using Receiver Operating characteristic Curve (ROC). Three social variables were also selected according to their relevance for fog suitability mapping. Finally, Fog-water harvesting Capability Index (FCI) maps were produced by multiplying fog probability by fog suitability maps. The results showed high accuracy in fog probability mapping for the study area, with all models proving capable of identifying areas with high fog concentrations in the south and southeast. For all models, the highest values of importance were obtained for sky view factor and the lowest for slope curvature. Analytic Hierarchy Process results showed the relative importance of social conditioning factors in fog suitability mapping, with the highest weight given to distance to residential area, followed by distance to livestock buildings and distance to road. Based on the fog suitability map, southeast and southern parts of the study area are most suitable for fog water harvesting. The fog spatial distribution maps obtained can increase fog water harvesting efficiency. They also indicate areas for future study with regions where fog is a critical component in the water cycle.
Khaleque, A, Alam, MM, Hoque, M, Mondal, S, Haider, JB, Xu, B, Johir, MAH, Karmakar, AK, Zhou, JL, Ahmed, MB & Moni, MA 2020, 'Zeolite synthesis from low-cost materials and environmental applications: A review', Environmental Advances, vol. 2, pp. 100019-100019.
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Zeolites with the three-dimensional structures occur naturally or can be synthesized in the laboratory. Zeolites have versatile applications such as environmental remediation, catalytic activity, biotechnological application, gas sensing and medicinal applications. Although, naturally occurring zeolites are readily available, nowadays, more emphasis is given on the synthesis of the zeolites due to their easy synthesis in the pure form, better ion exchange capabilities and uniform in size. Recently, much attention has also been paid on how zeolite is being synthesized from low-cost material (e.g., rice husk), particularly, by resolving the major environmental issues. Hence, the main purpose of this review is to make an effective resolution of zeolite synthesis methods together with potential applications in environmental engineering. Among different synthesis methods, hydrothermal method is commonly found to be used widely in the synthesis of various zeolites from inexpensive raw materials such as fly ash, rice husk ash, blast furnace slag, municipal solid waste, paper sludge, lithium slag and kaolin. Besides, future expectation in the field of synthetic zeolites research is also included.
Khan, HA, Castel, A & Khan, MSH 2020, 'Corrosion investigation of fly ash based geopolymer mortar in natural sewer environment and sulphuric acid solution', Corrosion Science, vol. 168, pp. 108586-108586.
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© 2020 Elsevier Ltd The objective of this research is to estimate the durability of low-calcium fly ash based geopolymer mortar (FA-GPm) in comparison with sulphate resistant Portland cement mortars (SRPCm) exposed to natural sewer environment. Their performance is also investigated in the sulphuric acid (H2SO4) solution to highlight the difference in the corrosion mechanisms between these two exposure conditions. Mortar samples were removed from natural sewer and 1.5 % sulphuric acid solution after 12, 24 months and 6 months of exposure, respectively. Visual and physical analyses showed greater neutralization and loss in alkalinity in FA-GPm compared to SRPCm. However, mass loss and strength reduction observed for SRPCm was greater compared to FA-GPm. Microstructural analysis showed widespread gypsum crystallization within SRPCm matrix compared to FA-GPm, leading to more severe matrix deterioration. Differences in corrosion mechanism were identified between natural and sulphuric acid exposure conditions which led to the variation in estimated corrosion depth. Data collected from these microstructural and physical investigations were utilized to develop simplified linear models to express the depth of corrosion, surface pH, mass loss and neutralization depth of FA-GPm and SRPCm as a dependent of exposure time, temperature and H2S concentration in natural sewer environments.
Khan, I, Xu, T, Khan, MSH, Castel, A & Gilbert, RI 2020, 'Effect of Various Supplementary Cementitious Materials on Early-Age Concrete Cracking', Journal of Materials in Civil Engineering, vol. 32, no. 4, pp. 04020049-04020049.
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© 2020 American Society of Civil Engineers. This paper focuses on the effect of supplementary cementitious materials on early-age mechanical and viscoelastic properties of concrete, restrained shrinkage-induced cracking, and time to cracking. Compressive strength, indirect tensile strength, and the elastic modulus were measured with different percentage of ordinary portland cement (OPC) replacement using either fly ash, ground-granulated blast-furnace slag (GGBFS), or ferronickel slag (FNS). Tensile creep and drying shrinkage were measured on dog-bone-shaped specimens. Restrained shrinkage-induced stresses and concrete cracking age were assessed by using the ring test. Results revealed that early-age strength development of fly ash-, GGBFS-, and FNS-blended concrete is lower than that of the corresponding OPC concrete. Similar tensile creep coefficients were observed for fly ash-blended concrete and OPC reference concrete whereas GGBFS- and FNS-blended concretes showed significantly higher tensile creep. Drying shrinkage was not altered to a great extent when OPC was replaced by fly ash. However, concrete containing GGBFS and FNS showed more shrinkage than OPC concrete. Partial replacement of OPC by supplementary cementitious materials resulted in a shorter time to cracking. 30% OPC replacement by FNS had the lowest influence on time to cracking with only 20% reduction compared to the reference OPC concrete. 20% replacement by fly ash and 30% replacement by GGBFS led to a reduction in time to cracking of about 33% and 40%, respectively, compared to the reference OPC concrete.
Khan, MSH, Nguyen, QD & Castel, A 2020, 'Performance of limestone calcined clay blended cement-based concrete against carbonation', Advances in Cement Research, vol. 32, no. 11, pp. 481-491.
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The aim of this work is to investigate the carbonation resistance of limestone and calcined clay blended cement-based concrete. Two limestone and calcined clay concretes with an average 28 d compressive strength of about 36 MPa were considered. Limestone and calcined clay (with a ratio of 2 : 1) were blended with a general purpose (GP) cement. The GP cement substitution rates considered were 30% and 45%.A low-grade calcined clay was used with about 50% amorphous phase. Accelerated and natural carbonation tests were performed. Mercury intrusion porosimetry and X-ray diffraction were carried out, to assist in the analysis of the experimental results. Results show that the early-age compressive strength is only marginally affected by the limestone and calcined clay substitution up to 45% and a significant refinement of the pore structure was observed compared to the reference GP cement concrete. The resistance of concrete against carbonation reduces with increase in the GP cement substitution rate. Overall, this study shows that a limestone and calcined clay blend used as a simple substitution for GP cement in concrete can provide adequate protection against carbonation-induced steel reinforcement corrosion if the ordinary Portland cement content in the mix is at least 60%.
Khandaker, T, Hossain, M, Dhar, P, Rahman, M, Hossain, M & Ahmed, M 2020, 'Efficacies of Carbon-Based Adsorbents for Carbon Dioxide Capture', Processes, vol. 8, no. 6, pp. 654-654.
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Carbon dioxide (CO2), a major greenhouse gas, capture has recently become a crucial technological solution to reduce atmospheric emissions from fossil fuel burning. Thereafter, many efforts have been put forwarded to reduce the burden on climate change by capturing and separating CO2, especially from larger power plants and from the air through the utilization of different technologies (e.g., membrane, absorption, microbial, cryogenic, chemical looping, and so on). Those technologies have often suffered from high operating costs and huge energy consumption. On the right side, physical process, such as adsorption, is a cost-effective process, which has been widely used to adsorb different contaminants, including CO2. Henceforth, this review covered the overall efficacies of CO2 adsorption from air at 196 K to 343 K and different pressures by the carbon-based materials (CBMs). Subsequently, we also addressed the associated challenges and future opportunities for CBMs. According to this review, the efficacies of various CBMs for CO2 adsorption have followed the order of carbon nanomaterials (i.e., graphene, graphene oxides, carbon nanotubes, and their composites) < mesoporous -microporous or hierarchical porous carbons < biochar and activated biochar < activated carbons.
Khanzada, NK, Farid, MU, Kharraz, JA, Choi, J, Tang, CY, Nghiem, LD, Jang, A & An, AK 2020, 'Removal of organic micropollutants using advanced membrane-based water and wastewater treatment: A review', Journal of Membrane Science, vol. 598, pp. 117672-117672.
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© 2019 Elsevier B.V. The rising consumption of pharmaceuticals, personal care products, and endocrine disruptive compounds for healthcare purposes and improving living standards has resulted in the widespread occurrence of organic micropollutants (MPs) in water and wastewater. Conventional water/wastewater treatment plants are faced with inherent limitations in tackling these compounds, leading to difficulties in the provision of secure and safe water supplies. In this context, membrane technology has been found to be a promising method for resolving this emerging concern. To ensure the suitability of membrane-based treatment processes in full-scale applications, we first need to develop a better understanding of the behavior of MPs and the mechanisms behind their removal using advanced membrane technologies. This review provides a thorough overview of the advanced membrane-based treatment methods available for the effective removal of MPs, including reverse osmosis, nanofiltration, ultrafiltration, forward osmosis, and membrane distillation.
Khlaifat, N, Altaee, A, Zhou, J & Huang, Y 2020, 'A review of the key sensitive parameters on the aerodynamic performance of a horizontal wind turbine using Computational Fluid Dynamics modelling', AIMS Energy, vol. 8, no. 3, pp. 493-524.
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© 2020 the Author(s), licensee AIMS Press. Renewable energy technologies are receiving much attention to replacing power plants operated by fossil and nuclear fuels. Of all the renewable technologies, wind power has been successfully implemented in several countries. There are several parameters in the aerodynamic characteristics and design of the horizontal wind turbine. This paper highlights the key sensitive parameters that affect the aerodynamic performance of the horizontal wind turbine, such as environmental conditions, blade shape, airfoil configuration and tip speed ratio. Different turbulence models applied to predict the flow around the horizontal wind turbine using Computational Fluid Dynamics modeling are reviewed. Finally, the challenges and concluding remarks for future research directions in wind turbine design are discussed.
Khlaifat, N, Altaee, A, Zhou, J & Huang, Y 2020, 'A review of the key sensitive parameters on the aerodynamic performance of a horizontal wind turbine using computational fluid dynamics modelling', AIMS Energy, vol. 8, no. 3, pp. 493-524.
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© 2020 the Author(s), licensee AIMS Press. Renewable energy technologies are receiving much attention to replacing power plants operated by fossil and nuclear fuels. Of all the renewable technologies, wind power has been successfully implemented in several countries. There are several parameters in the aerodynamic characteristics and design of the horizontal wind turbine. This paper highlights the key sensitive parameters that affect the aerodynamic performance of the horizontal wind turbine, such as environmental conditions, blade shape, airfoil configuration and tip speed ratio. Different turbulence models applied to predict the flow around the horizontal wind turbine using Computational Fluid Dynamics modeling are reviewed. Finally, the challenges and concluding remarks for future research directions in wind turbine design are discussed.
Khlaifat, N, Altaee, A, Zhou, J & Huang, Y 2020, 'Evaluation of wind resource potential using statistical analysis of probability density functions in New South Wales, Australia', Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, pp. 1-18.
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Wind energy is a vital part of Australia's energy mix. The first step in a wind power project at a particular site is to assess the wind resource potential and feasibility for wind energy production. Research on wind potential and statistical analysis has been done throughout the world. Currently, recent potential wind studies are lacking, especially in New South Wales (NSW), Australia. This study highlighted the feasibility of wind potential at four sites in NSW, namely Ballina, Merriwa, Deniliquin, and the Bega region. The type of wind speed distribution function dramatically affects the output of the available wind energy and wind turbine performance at a particular site. Therefore, the accuracy of four probability density functions was evaluated, namely Rayleigh, Weibull, Gamma, and Lognormal distributions. The outcomes showed Weibull provided the most accurate distribution. The annual average scale and shape parameters of Weibull distribution varied between 2.935-5.042 m/s and 1.137-2.096, respectively. The maximum shape and scale factors were at Deniliquin, while the minimum shape and scale factors were at Bega area. Assessment of power density indicated that Deniliquin had a marginal wind speed resource, while Ballina, Bega, and Merriwa had poor wind resources.
Khlaifat, N, Altaee, A, Zhou, J, Huang, Y & Braytee, A 2020, 'Optimization of a Small Wind Turbine for a Rural Area: A Case Study of Deniliquin, New South Wales, Australia', Energies, vol. 13, no. 9, pp. 2292-2292.
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The performance of a wind turbine is affected by wind conditions and blade shape. This study aimed to optimize the performance of a 20 kW horizontal-axis wind turbine (HAWT) under local wind conditions at Deniliquin, New South Wales, Australia. Ansys Fluent (version 18.2, Canonsburg, PA, USA) was used to investigate the aerodynamic performance of the HAWT. The effects of four Reynolds-averaged Navier–Stokes turbulence models on predicting the flows under separation condition were examined. The transition SST model had the best agreement with the NREL CER data. Then, the aerodynamic shape of the rotor was optimized to maximize the annual energy production (AEP) in the Deniliquin region. Statistical wind analysis was applied to define the Weibull function and scale parameters which were 2.096 and 5.042 m/s, respectively. The HARP_Opt (National Renewable Energy Laboratory, Golden, CO, USA) was enhanced with design variables concerning the shape of the blade, rated rotational speed, and pitch angle. The pitch angle remained at 0° while the rising wind speed improved rotor speed to 148.4482 rpm at rated speed. This optimization improved the AEP rate by 9.068% when compared to the original NREL design.
Khosravi, K, Panahi, M, Golkarian, A, Keesstra, SD, Saco, PM, Bui, DT & Lee, S 2020, 'Convolutional neural network approach for spatial prediction of flood hazard at national scale of Iran', Journal of Hydrology, vol. 591, pp. 125552-125552.
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Kim, DI, Gonzales, RR, Dorji, P, Gwak, G, Phuntsho, S, Hong, S & Shon, H 2020, 'Efficient recovery of nitrate from municipal wastewater via MCDI using anion-exchange polymer coated electrode embedded with nitrate selective resin', Desalination, vol. 484, pp. 114425-114425.
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Kim, SY, Choo, Y, Bilodeau, RA, Yuen, MC, Kaufman, G, Shah, DS, Osuji, CO & Kramer-Bottiglio, R 2020, 'Sustainable manufacturing of sensors onto soft systems using self-coagulating conductive Pickering emulsions', Science Robotics, vol. 5, no. 39, p. eaay3604.
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An ethanol-based Pickering emulsion that spontaneously forms conductive composites is used to sustainably manufacture compliant strain sensors.
Korniejenko, K, Miernik, K, Lin, W-T & Castel, A 2020, 'The influence of microstructure on mechanical properties of 3D printable geopolymer composites', MATEC Web of Conferences, vol. 322, pp. 01011-01011.
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The additive manufacturing technologies are fast-developing industrial sector and, potentially, a ground-breaking technology. They have many advantages such as the saving of resources and energy efficiency. However, the full exploitation of 3D printing technology for ceramic materials is currently limited; a lot of research is being conducted in this area. A promising solution seems to be geopolymers, but its application requires a better understanding of the behaviour this group of materials. This article analyses the influence of microstructure on mechanical properties whilst taking the production method into consideration. The paper is based on comparative analysis – the investigation is focused on the influence of material structure on the mechanical properties and fracture mechanism of these kinds of composites, including those reinforced with different kind of fibres. As a raw material for the matrix, fly ash from the Skawina coal power plant (located in: Skawina, Lesser Poland, Poland) was used. The investigation was made by SEM analysis. The results show that the microstructural analysis did not sufficiently explain the underlying reasons for the observed differences in the mechanical properties of the composites.
Kulandaivelu, J, Choi, PM, Shrestha, S, Li, X, Song, Y, Li, J, Sharma, K, Yuan, Z, Mueller, JF, Wang, C & Jiang, G 2020, 'Assessing the removal of organic micropollutants from wastewater by discharging drinking water sludge to sewers', Water Research, vol. 181, pp. 115945-115945.
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Discharging drinking water treatment sludge (DWTS) to sewers could be an efficient waste management strategy with the potential to replace chemical dosing for pollutant control. This study for the first time investigated the fate of 28 different organic micropollutants (MPs) due to the dosing of iron-rich and aluminum-rich DWTS in a pilot rising main sewer. Nine MPs had an initial rapid removal within 1-hr (i.e., 10-80%) due to Fe-DWTS dosing. The formation of FeS particles due to Fe-DWTS dosing was responsible for the removal of dissolved sulfides (80% reduction comparing to control sewer). Further particle characterization using SEM-EDS, XRD and ATR-FTIR confirmed that FeS particles formation played an important role in the removal of MPs from wastewater. Adsorption of MPs onto the FeS particles was likely the possible mechanism for their rapid removal. In comparison to iron-rich DWTS, aluminum-rich DWTS had very limited beneficial effects in removing MPs from wastewater. The degradability of degradable MPs, including caffeine, paraxanthine, paracetamol, metformin, cyclamate, cephalexin, and MIAA were not affected by the DWTS dosing. Some non-degradable MPs, including cotinine, hydroxycotinine, tramadol, gabapentin, desvenlafaxine, hydrochlorothiazide, carbamazepine, fluconazole, sulfamethoxazole, acesulfame, saccharin and sucralose were also not impacted by the DWTS dosing. This study systematically assessed the additional benefits of discharging Fe-DWTS to the sewer network i.e., the removal of MPs from the liquid phase thereby reducing its load to the treatment plant. The results corroborate the discharge of Fe-rich DWTS in sewers as an effective and beneficial way of managing the waste by-product.
Kumari, N, Saco, PM, Rodriguez, JF, Johnstone, SA, Srivastava, A, Chun, KP & Yetemen, O 2020, 'The Grass Is Not Always Greener on the Other Side: Seasonal Reversal of Vegetation Greenness in Aspect‐Driven Semiarid Ecosystems', Geophysical Research Letters, vol. 47, no. 15.
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AbstractOur current understanding of semiarid ecosystems is that they tend to display higher vegetation greenness on polar‐facing slopes (PFS) than on equatorial‐facing slopes (EFS). However, recent studies have argued that higher vegetation greenness can occur on EFS during part of the year. To assess whether this seasonal reversal of aspect‐driven vegetation is a common occurrence, we conducted a global‐scale analysis of vegetation greenness on a monthly time scale over an 18‐year period (2000–2017). We examined the influence of climate seasonality on the normalized difference vegetation index (NDVI) values of PFS and EFS at 60 different catchments with aspect‐controlled vegetation located across all continents except Antarctica. Our results show that an overwhelming majority of sites (70%) display seasonal reversal, associated with transitions from water‐limited to energy‐limited conditions during wet winters. These findings highlight the need to consider seasonal variations of aspect‐driven vegetation patterns in ecohydrology, geomorphology, and Earth system models.
Lau, AKS, Bilad, MR, Nordin, NAHM, Faungnawakij, K, Narkkun, T, Wang, DK, Mahlia, TMI & Jaafar, J 2020, 'Effect of membrane properties on tilted panel performance of microalgae biomass filtration for biofuel feedstock', Renewable and Sustainable Energy Reviews, vol. 120, pp. 109666-109666.
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© 2019 Elsevier Ltd Efficient membrane-based technology for microalgae harvesting can be achieved via application effective membrane fouling control coupled with appropriate membrane materials. This study explores the combined impact of membrane properties and the tilted panel system on filterability of Euglena sp broth, a potential source of biofuel feedstock. Four membranes from polyvinylidene difluoride (PVDF) and polysulfone (PSF) of PVDF-1, PVDF-3, PSF-1 and PSF-3 were evaluated. Generally, increasing aeration rate, tilting angle and lowering switching period enhance the system performance for all the tested membranes to give the highest permeances of 660, 724, 743 L/m2 h bar, respectively. Those values are among the highest reported in literature. The magnitude of the effect is affected by the membrane properties, mainly by pore size. Tilting without switching configuration is desirable for the membrane with a large pore size (PVDF-1, 0.42 μm) which produced the highest panel permeability of 724.3 (L/m2 h bar), which is >23% higher than the tilted with switching. For this membrane, intermittent aeration applied under switching mode worsened the pore blocking. Membranes with low pore sizes (0.11, 0.04 and 0.03 μm for PVDF-3, PSF-1 and PSF-3, respectively) excelled under switching mode since they are less prone to pore blocking due to smaller pore apertures. Overall results suggest that to gain the full benefit of the tilted panel, operational system of either one-sided without switching or two-sided involving switching must be tailored in conjunction with the desirable properties of the membranes. This finding can help to lower the energy input for microalgae-based biofuel production.
Lazaar, A, Hammouti, KE, Naiji, Z, Pradhan, B, Gourfi, A, Andich, K & Monir, A 2020, 'The manifestation of VIS-NIRS spectroscopy data to predict and map soil texture in the Triffa plain (Morocco)', Kuwait Journal of Science, vol. 48, no. 1, pp. 111-121.
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The use of standard laboratory methods to estimate the soil texture is complicated, expensive, and time-consuming and needs considerable effort. The reflectance spectroscopy represents an alternative method for predicting a large range of soil physical properties and provides an inexpensive, rapid, and reproducible analytical method. This study aimed to assess the feasibility of Visible (VIS: 350-700 nm) and Near-Infrared and Short-Wave-Infrared (NIRS: 701-2500 nm) spectroscopy for predicting and mapping the clay, silt, and sand fractions of the soils of Triffa plain (north-east of Morocco). A total of 100 soil samples were collected from the non-root zone of soil (0-20 cm) and then analyzed for texture using the VIS-NIRS spectroscopy and the traditional laboratory method. The partial least squares regression (PLSR) technique was used to assess the ability of spectral data to predict soil texture. The results of prediction models showed excellent performance for the VIS-NIRS spectroscopy to predict the sand fraction with a coefficient of determination R2 = 0.93 and Root Mean Squares Error (RMSE) =3.72, good prediction for the silt fraction (R2=0.87; RMSE = 4.55), and acceptable prediction for the clay fraction (R2 = 0.53; RMSE = 3.72). Moreover, the range situated between 2150 and 2450 nm is the most significant for predicting the sand and silt fractions, while the spectral range between 2200 and 2440 nm is the optimal to predict the clay fraction. However, the maps of predicted and measured soil texture showed an excellent spatial similarity for the sand fraction, a certain difference in the variability of clay fraction, while the maps of silt fraction show a lower difference.
Lazaar, A, Mouazen, AM, EL Hammouti, K, Fullen, M, Pradhan, B, Memon, MS, Andich, K & Monir, A 2020, 'The application of proximal visible and near-infrared spectroscopy to estimate soil organic matter on the Triffa Plain of Morocco', International Soil and Water Conservation Research, vol. 8, no. 2, pp. 195-204.
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© 2020 Soil organic matter (SOM) is a fundamental soil constituent. The estimation of this parameter in the laboratory using the classical method is complex time-consuming and requires the use of chemical reagents. The objectives of this study were to assess the accuracy of two laboratory measurement setups of the VIS-NIR spectroscopy in estimating SOM content and determine the important spectral bands in the SOM estimation model. A total of 115 soil samples were collected from the non-root zone (0–20 cm) of soil in the study area of the Triffa Plain and then analysed for SOM in the laboratory by the Walkley–Black method. The reflectance spectra of soil samples were measured by two protocols, Contact Probe (CP) and Pistol Grip (PG)) of the ASD spectroradiometer (350–2500 nm) in the laboratory. Partial least squares regression (PLSR) was used to develop the prediction models. The results of coefficient of determination (R2) and the root mean square error (RMSE) showed that the pistol grip offers reasonable accuracy with an R2 = 0.93 and RMSE = 0.13 compared to the contact probe protocol with an R2 = 0.85 and RMSE = 0.19. The near-Infrared range were more accurate than those in the visible range for predicting SOM using the both setups (CP and PG). The significant wavelengths contributing to the prediction of SOM for (PG) setup were at: 424, 597, 1432, 1484, 1830,1920, 2200, 2357 and 2430 nm, while were at 433, 587, 1380, 1431, 1929, 2200 and 2345 nm for (CP) setup.
Lee, C, Nguyen, T-T, Adha, RS, Shon, HK & Kim, IS 2020, 'Influence of hydrodynamic operating conditions on organic fouling of spiral-wound forward osmosis membranes: Fouling-induced performance deterioration in FO-RO hybrid system', Water Research, vol. 185, pp. 116154-116154.
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© 2020 Elsevier Ltd The forward osmosis-reverse osmosis (FO-RO) hybrid process has been extensively researched as part of attempts to reduce the high energy consumption of conventional seawater reverse osmosis in recent years. FO operating conditions play a substantial role in the hybrid process, dictating not only the performance of the entire system but also the propensity for fouling, which deteriorates performance in long-term field operations. Therefore, determining the optimal FO operating conditions with regard to membrane fouling may promote sustainable operation through efficient fouling control. This study thus evaluated the influence of each hydrodynamic operating condition (feed flowrate, draw flowrate, and hydraulic pressure difference) and their synergistic effects on fouling propensity in a pilot-scale FO operation under seawater and municipal wastewater conditions. Fouling-induced variation in water flux, channel pressure drop, diluted concentration, and the resulting specific energy consumption (SEC) were comparatively analyzed and utilized to project performance variation in a full-scale FO-RO system. Fouling-induced performance reduction significantly varied depending on hydrodynamic operating conditions and the resultant fouling propensity during 15 days of continuous operation. A high feed flowrate demonstrated a clear ability to mitigate fouling-induced performance deterioration in all conditions. A high draw flowrate turned out to be detrimental for fouling propensity since its high reverse solute flux accelerated fouling growth. Applying additional hydraulic pressure during FO operation caused a faster reduction of water flux, and thus feed recovery and water production; however, these drawbacks could be compensated for by a 10% reduction in the required FO membrane area and an additional reduction in RO SEC.
Lee, D, Woo, YC, Park, KH, Phuntsho, S, Tijing, LD, Yao, M, Shim, W-G & Shon, HK 2020, 'Polyvinylidene fluoride phase design by two-dimensional boron nitride enables enhanced performance and stability for seawater desalination', Journal of Membrane Science, vol. 598, pp. 117669-117669.
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© 2019 The instability of polyvinylidene fluoride (PVDF) membranes in membrane distillation (MD) for seawater desalination is still a problem, despite the tremendous effort expended to resolve this issue. Here, a simple and feasible approach for improving desalination performance through the incorporation of two-dimensional boron nitride nanosheets (BNNSs) in polyvinylidene fluoride-co-hexafluoropropene (PVDF-co-HFP) electrospun nanofiber membrane (BNs-PH) is proposed as well as demonstrate its origin for fundamental understanding. The BNs-PH membrane exhibits a stable water vapor flux (18 LMH) and superior salt rejection (99.99%), even after operation for 280 h (commercial PVDF: steep decay within 28 h; neat PH: wetting within 4 h). From structural/chemical analyses, the BNNSs play a crucial role in forming favorable phases of the PH polymer crystal structure, inducing a superhydrophobic surface with greater nanoporosity and higher heterogeneity as well as enhanced mechanical properties (increase of UTS: 13.4%; modulus: 1.2%) for long-term operation. Theoretical modeling results of an air-gap MD system are consistent with our experimental results. The approach introduced in this study can be applied to other desalination systems to boost various water treatment applications.
Lee, XJ, Ong, HC, Gan, YY, Chen, W-H & Mahlia, TMI 2020, 'State of art review on conventional and advanced pyrolysis of macroalgae and microalgae for biochar, bio-oil and bio-syngas production', Energy Conversion and Management, vol. 210, pp. 112707-112707.
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© 2020 Elsevier Ltd Algal biomass including macroalgae and microalgae show great potential as pyrolysis feedstock in generating energy-dense and valuable pyrolytic products such as bio-oil, biochar and bio-syngas. The chemical constituents of macroalgae and microalgae show great variations, especially their lipid, carbohydrate and protein contents, which could affect the qualities of the pyrolytic products. From the established conventional pyrolysis, the products produced from both macroalgae and microalgae show moderate energy contents (<34 MJ/kg). The review identifies the issues associated with development of conventional pyrolysis such as flash and intermediate pyrolysis. To enhance the production of biofuels from algal biomass, advanced or non-conventional pyrolysis techniques have been employed. Catalytic pyrolysis on algal biomass could reduce the nitrogenates and oxygenates in the biofuels. On top of that, co-pyrolysis with suitable feedstock shows great enhancement on the bio-oil yield. As for hydropyrolysis of algal biomass, their generated biofuels can produce up to 48 MJ/kg with high yield of bio-oil up to 50 wt%, comparable to conventional fuels. Microwave-assisted pyrolysis of algal biomass greatly shortens the processing time through advanced heating; however, favours the formation of bio-syngas by improving the yield up to 84 wt% depending on the feedstock used. Therefore, formation of biofuel fraction suitable for energy generation highly depends on the selected pyrolysis technologies.
Lei, B, Li, W, Liu, H, Tang, Z & Tam, VWY 2020, 'Synergistic Effects of Polypropylene and Glass Fiber on Mechanical Properties and Durability of Recycled Aggregate Concrete', International Journal of Concrete Structures and Materials, vol. 14, no. 1.
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AbstractTo better understand the synergistic effects of combined fibers on mechanical properties and durability of recycled aggregate concrete (RAC), different types of fibers with various lengths and mass ratios were adopted in this study. Experimental investigations were conducted to study the 28-day compressive strength and strength loss after exposed to salt-solution freeze–thaw cycles and the coupled action of mechanical loading and salt-solution freeze–thaw cycles. The microstructure was also characterized to evaluate the mechanism of this synergistic effect. To determine the effectiveness of the combined fibers on improving the mechanical properties and durability of RAC, the synergistic coefficient was proposed and applied for various combinations of fibers. The results indicate that the incorporation of fibers slightly decreased the 28-day compressive strength of RAC, but combining different sizes and types of fibers can mitigate this negative effect. Moreover, the incorporation of fibers greatly improves the freeze–thaw resistance of RAC. The combining different fibers exhibited a synergistic effect on the enhancement in properties of RAC, which could not be predicted with only one simplistic rule of fibre mixtures. In addition, microstructural characterization shows that the bonding strength of the interfacial transition zone (ITZ) between the fiber and cement matrix is mainly determined by the chemical bonding force which is due to the hydration reaction between fiber surface and cement matrix.
Lei, B, Li, W, Luo, Z, Tam, VWY, Dong, W & Wang, K 2020, 'Performance Enhancement of Permeable Asphalt Mixtures With Recycled Aggregate for Concrete Pavement Application', Frontiers in Materials, vol. 7.
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© Copyright © 2020 Lei, Li, Luo, Tam, Dong and Wang. The incorporation of recycled concrete aggregate (RCA) in permeable asphalt mixtures (PAMs) is an efficient method of utilizing construction demolished waste. It not only conforms to the trend of building sponge cities, but also alleviates the problem of overexploitation of natural aggregate resources. As the performance of PAM containing recycled aggregate is not comparable to natural aggregate, modification treatments and the addition of hybrid fibers are adopted as two enhancement methods to improve the performance of PAM with RAC in this study. It is found that replacing natural aggregate with recycled aggregate increases the optimum asphalt content (OAC) but decreases the residual stability. The OAC is increased by 45% when the RCA ratio is 100%, whereas applying silicone resin can give a 16.2% decrease in the OAC. Enhancing RCA with silicone resin can increase the water stability to be comparable with natural aggregate. Moreover, with modification treatment using calcium hydroxide solution, the mechanical strength of PAM is enhanced to even higher than that of natural coarse aggregate mixture alone. Improvements in both mechanical strength and water stability are also achieved by strengthening recycled aggregate with cement slurry, although the performance is less effective than using silicone resin. With the increase in the content of RCA, the permeability coefficients of PAM first decrease and then exhibit an increasing trend. The results indicate that the PAM with RCA and modification treatments can perform satisfactorily as a pavement material in practice. Applying probable modification, PAM incorporating RCA meets the criteria for use in concrete pavement applications.
Lei, B, Li, W, Tang, Z, Li, Z & Tam, VWY 2020, 'Effects of environmental actions, recycled aggregate quality and modification treatments on durability performance of recycled concrete', Journal of Materials Research and Technology, vol. 9, no. 6, pp. 13375-13389.
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© 2020 The Author(s). The durability performance of recycled concrete (RC) subjected to different environmental actions, including salt-solution, mechanical load, salt-solution freeze-thaw cycles, and coupled mechanical load and salt-solution freeze-thaw cycles was investigated in this paper. To evaluate the effects of recycled aggregate (RA) quality on the RC durability, modeled recycled concrete (MRC) containing modeled recycled aggregate (MRA) with various thickness and coverage of old mortar, along with different degrees of initial damage, was fabricated and tested. Moreover, several modification treatments were employed to study the effects of modification treatments on the RC durability, which included the impregnation of RA with polyvinyl alcohol (PVA) emulsion or nano-SiO2 solutions, and the enhancement of RC with the incorporations of fly ash or hybrid fly ash and silica fume. The results reveal that the deterioration of RC under coupled actions of mechanical load and salt-solution freeze-thaw cycles was the most severe, which was followed by the salt-solution freeze-thaw cycles, mechanical load and salt-solution. The old interface in RA was determined as the weakest zone in RC. With the increase in the thickness or coverage of old mortar, or the initial damage of RA, the durability performance of RC declined, and the effect of initial damage of RA was more significant compared to the thickness or coverage of old mortar. Additionally, modifying RC with 1.5% nano-SiO2 solution or PVA emulsion, and replacing cement with 10% fly ash can significantly enhance the RC durability.
Lei, F, Lv, X, Fang, J, Sun, G & Li, Q 2020, 'Multiobjective discrete optimization using the TOPSIS and entropy method for protection of pedestrian lower extremity', Thin-Walled Structures, vol. 152, pp. 106349-106349.
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Li, H, Li, Y & Li, J 2020, 'Negative stiffness devices for vibration isolation applications: A review', Advances in Structural Engineering, vol. 23, no. 8, pp. 1739-1755.
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In recent years, negative stiffness vibration isolation device with nonlinear characteristic has become an emerging research area and attracted a significant amount of attentions in the community due to the promising potentials it brought into the field. Its high-static-low-dynamic stiffness property endows the capacity to realize effective vibration isolation and in the meantime to maintain the system stability. This article presents a comprehensive review of the recent research and developments on negative stiffness vibration isolation device. It begins with an introduction on the concept of negative stiffness and then provides a summary and discussion regarding the realization and characteristics of negative stiffness vibration isolation device. The article places its special interest on the principles, structure design, and device characterisation of different types of negative stiffness vibration isolation devices, including spring type, pre-bucked beam type, magnetism type, geometrically nonlinear structural type, and composite structural type. Besides, the applications of negative stiffness vibration isolation device, as well as negative stiffness damper, are summarized and discussed based on the current state-of-the-art. Finally, the conclusions and further discussion provide highlights of the investigation.
Li, J, Zhu, X, Law, S-S & Samali, B 2020, 'A Two-Step Drive-By Bridge Damage Detection Using Dual Kalman Filter', International Journal of Structural Stability and Dynamics, vol. 20, no. 10, pp. 2042006-2042006.
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Drive-by bridge inspection using acceleration responses of a passing vehicle has great potential for bridge structural health monitoring. It is, however, known that the road surface roughness is a big challenge for the practical application of this indirect approach. This paper presents a new two-step method for the bridge damage identification from only the dynamic responses of a passing vehicle without the road surface roughness information. A state-space equation of the vehicle model is derived based on the Newmark-[Formula: see text] method. In the first step, the road surface roughness is estimated from the dynamic responses of a passing vehicle using the dual Kalman filter (DKF). In the second step, the bridge damage is identified based on the interaction force sensitivity analysis with Tikhonov regularization. A vehicle–bridge interaction model with a wireless monitoring system has been built in the laboratory. Experimental investigation has been carried out for the interaction force and bridge surface roughness identification. Results show that the proposed method is effective and reliable to identify the interaction force and bridge surface roughness. Numerical simulations have also been conducted to study the effectiveness of the proposed method for bridge damage detection. The vehicle is modeled as a 4-degrees-of-freedom half-car and the bridge is modeled as a simply-supported beam. The local bridge damage is simulated as an elemental flexural stiffness reduction. Effects of measurement noise, surface roughness and vehicle speed on the identification are discussed.The results show that the proposed drive-by inspection strategy is efficient and accurate for a quick review on the bridge conditions.
Li, J, Zhu, X, Law, S-S & Samali, B 2020, 'Time-varying characteristics of bridges under the passage of vehicles using synchroextracting transform', Mechanical Systems and Signal Processing, vol. 140, pp. 106727-106727.
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© 2020 Elsevier Ltd The vehicle and bridge responses in a vehicle-bridge interaction (VBI) system have been widely studied with some aiming at the bridge health monitoring. The extraction of bridge modal frequencies from bridge or vehicle responses was mostly conducted with the assumption of an invariant vehicle and bridge system and/or the responses are stationary during the interaction. This assumption may be appropriate when the vehicle mass is negligible compared with the bridge mass. The vehicle and bridge frequencies are time-varying in practice during the VBI process and these time-varying characteristics are potential indicators for bridge condition assessment. This paper presents a new method to extract the time-varying characteristics of the bridge under the passage of vehicles. A time-frequency (TF) analysis method, the synchroextracting transform, is adopted for the purpose. It is a post-processing procedure with short-time Fourier transform to improve the TF resolution on the time-varying features of the signal. The instantaneous frequency of mono-components related to the vehicle and bridge frequencies can then be extracted from the time-frequency representation of the responses. Numerical investigation is conducted to study the effect of measurement noise, vehicle properties and road surface roughness on the identified results. Laboratory and field tests are also conducted to validate the proposed approach. Results show that the time-varying characteristics are good indicators for bridge condition assessment.
Li, L, Ju, N, He, C, Li, C & Sheng, D 2020, 'A computationally efficient system for assessing near-real-time instability of regional unsaturated soil slopes under rainfall', Landslides, vol. 17, no. 4, pp. 893-911.
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© 2019, Springer-Verlag GmbH Germany, part of Springer Nature. The objective of this paper is to obtain an applicable assessment method and a Web-GIS-based prediction system for regional landslides. The traditional Richards function is reconstructed using the soil-water characteristic curve (SWCC) and the coordinate transformation technique. The analytical pore pressure for a slope model is derived by solving the modified Richard equation via the Green function and Fourier transformation. The obtained transient pore pressure field is then incorporated with Brakensiek’s matric suction theory, to build a conceptual model for rainfall-induced shallow landslides. The safety factor is obtained by solving the limit equilibrium equation of the conceptual model. The method is then implemented in a Web-GIS system, considering influence of slope geometry features, geology parent material, and near-real-time rainfall intensity of the study area. It is verified that this method is computationally efficient and reliable for gentle slopes and short rainfall durations. Moreover, an extensive parameter study shows that the two commonly used coefficients in the intensity-duration equation are both correlated to rainfall inter-event time via exponential functions, and rainfall event time via power functions. The primary influential factor for regional landslides is the initial water content, followed by the rainfall duration and intensity, and least by soil thickness.
Li, L, Song, K, Yeerken, S, Geng, S, Liu, D, Dai, Z, Xie, F, Zhou, X & Wang, Q 2020, 'Effect evaluation of microplastics on activated sludge nitrification and denitrification', Science of The Total Environment, vol. 707, pp. 135953-135953.
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A large amount of microplastics have entered conventional wastewater treatment plants, and their effects on activated sludge nitrification and denitrification are rarely reported. This study investigated the effects of microplastics on activated sludge nitrification and denitrification using five typical microplastics, namely, polyvinyl chloride (PVC), polypropylene, polyethylene, polystyrene, and polyester (PES) with concentrations of 0, 1000, 5000, and 10,000 particles/L. Results indicated that microplastics had negative effects on ammonia oxidation rate and low effect on nitrite oxidation rate during nitrification. The total inorganic nitrogen did not have much difference during 3 h nitrification under all the tested conditions. The addition of microplastics showed positive effects on denitrification, especially for PVC and PES at microplastic concentration of 5000 particles/L. Nitrification and denitrification did not evidently stop under all the tested conditions, indicating that the selected microplastic types and concentrations were not toxic to nitrification and denitrification within 3 h. The high abundance of PVC microplastics remarkably increased the nitrous oxide (N2O) emission during denitrification. The N2O emission in the test with 10,000 particle/L of PVC was 4.6times higher than the blank control. This study indicated that microplastics with <10,000 particle/L concentration in wastewater had low effects on nitrification and denitrification, whereas they had high effects on the N2O emission during denitrification.
Li, P, Gao, X, Wang, K, Tam, VWY & Li, W 2020, 'Hydration mechanism and early frost resistance of calcium sulfoaluminate cement concrete', Construction and Building Materials, vol. 239, pp. 117862-117862.
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© 2019 Elsevier Ltd This study investigated the hydration mechanism and mechanical properties of ordinary Portland cement (OPC) blended with calcium sulfoaluminate (CSA) cement. Heat evolution, hydration products, pore size distribution, and microstructure were investigated for OPC-CSA blends concrete with different contents of CSA cement. Macroscopic properties, such as internal temperature, dynamic elastic modulus, and compressive strength, are also studied through concrete subjected to early frost conditions. The results show that the OPC-CSA blended cement displayed a higher early strength and exhibited enhanced resistance to the early frost damage compared to OPC. The OPC-CSA blended cement also exhibits a higher hydration rate and a larger amount of heat of hydration than that in the OPC at the early stage. The increased heat of hydration can effectively prolong the hydration duration at sub-zero temperatures. However, incorporating CSA delayed the hydration of C3S at the late stage, thus affecting the development of compressive strength and dynamic elastic modulus. On the other hand, the hardened blended cement exhibited an higher porosity, which was corresponding to the increasing proportion of macropores (diameter over 1000 nm). If concrete directly is suffered from early frost after casting, blended cement with 20% of CSA can effectively reduce strength loss from frost damage by 100% at −5 °C, and that from frost damage by 80% at −15 °C respectively. Furthermore, when the calcium nitrite is incorporated as the antifreeze admixture with OPC-CSA blended concrete, the early stage frost resistance of concrete infrastructures can be significantly improved.
Li, P, Li, W, Yu, T, Qu, F & Tam, VWY 2020, 'Investigation on early-age hydration, mechanical properties and microstructure of seawater sea sand cement mortar', Construction and Building Materials, vol. 249, pp. 118776-118776.
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© 2020 Elsevier Ltd Using seawater for concrete manufacturing promisingly provides significant economical and environmental benefits. In this study, ordinary Portland cement (OPC) hydration in distilled water and seawater and the corresponding evolution of solid phases was investigated by heat evolution, hydrated phase, hydration kinetics, and microstructure characterization. The results show that seawater can promote the early hydration of tricalcium silicate (C3S) during the hydration acceleration period. The hydrated phase assemblage was affected by the dissolved ions in seawater. Friedel's salt was detected as a specific hydration phase in seawater, which was formed by chemical combination between the aluminate ferrite monosulfate (AFm) phase and chloride ions. The monocarboaluminate can be converted into a stable phase as Friedel's salt in the seawater, due to the reaction with chloride ions. Furthermore, the ettringite becomes more stable when coexists with Friedel's salt than that with monocarboaluminate, and thus ettringite formed in seawater remains 67% higher than that formed in distilled water at the later curing age. Moreover, additional unhydrated cement and less amorphous calcium silicate hydrate (C-S-H) were formed in seawater, which might be responsible for the slightly lower compressive strength of cement mortar prepared by seawater and sea sand. A modeled evolution of the solid phase and pore solution have been established, which agrees well with the characteristics of the dissolution of mineral phase, precipitation of hydration products and changes of pore solution. The related results can provide an insight into the applications of seawater and sea sand concrete for marine infrastructures.
Li, Q, Wu, D, Gao, W & Tin-Loi, F 2020, 'Size-dependent instability of organic solar cell resting on Winkler–Pasternak elastic foundation based on the modified strain gradient theory', International Journal of Mechanical Sciences, vol. 177, pp. 105306-105306.
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© 2019 The present study employs the modified strain gradient theory (MSGT) in conjunction with the refined shear deformation plate theory to explore the buckling behaviour of simply supported and clamped OSC. The Winkler-Pasternak elastic foundation is implemented to idealise the foundation. The size-dependent effect of the OSC is captured by the three length scale parameters within the MSGT. The Hamilton principle is used to derive the equations of motion and the boundary conditions, and the Galerkin procedure is subsequently implemented to obtain the critical buckling load. Subsequently, the framework is extended to the thermally induced buckling behaviour, and three types of temperature rise patterns, namely uniform, linear and nonlinear temperature variations, along the thickness of the OSC are considered. Several verification studies are conducted to illustrate the accuracy of the present method. Besides, size-dependent material properties are taken into consideration during the numerical experiments. Thorough studies are conducted to demonstrate the difference between critical buckling loads obtained from the MSGT, the modified couple stress theory (MCST), and the classical plate theory (CPT) models. Furthermore, the effects of length scale parameter (h/l), the aspect ratio (a/b), the length-to-thickness ratio (a/h) and the Winkler-Pasternak elastic foundation parameters on the buckling behaviour of the OSC are also revealed by the numerical results.
Li, S, Liang, Y, Li, Y, Li, J & Zhou, Y 2020, 'Investigation of dynamic properties of isotropic and anisotropic magnetorheological elastomers with a hybrid magnet shear test rig', Smart Materials and Structures, vol. 29, no. 11, pp. 114001-114001.
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Abstract Magnetorheological elastomers (MREs) exhibit instantaneous and reversible adaptability of stiffness and damping properties under the influence of magnetic field, which can be implemented in the development of controllable devices. The main MRE components are normally elastomeric matrix and magnetisable particles. Depending on the distribution of the particles in the matrix, MREs can be classified into isotropic and anisotropic. This work experimentally explored, compared, and modelled the dynamic characteristics of both isotropic and anisotropic MREs with different iron particle weight fractions (17%, 22%, and 32%). A novel shear test rig was designed with hybrid magnets system, i.e. permanent magnet and electromagnets, to fulfil the characterisation tasks. The involvement of the hybrid magnets effectively cuts down the maximum electric current and energy consumption of the rig. The tests were conducted under sinusoidal shear motions with excitation frequency ranging from 0.1 Hz to 2 Hz and shear strain varying from 20% to 60% to record the force-displacement hysteresis of MRE samples. Four different levels of magnetic field (0.02, 0.54, 0.77, 1.01 T) were supplied by the hybrid magnetic system and were considered in the tests to evaluate the influence of the magnetic fields. Furthermore, characterised hysteretic behaviours for both isotropic and anisotropic MRE were modelled by a strain stiffening phenomenological model with ideal accuracy under the shear excitation inputs and magnetic fields considered.
Li, S, Tian, T, Wang, H, Li, Y, Li, J, Zhou, Y & Wu, J 2020, 'Development of a four-parameter phenomenological model for the nonlinear viscoelastic behaviour of magnetorheological gels', Materials & Design, vol. 194, pp. 108935-108935.
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Li, S, Watterson, PA, Li, Y, Wen, Q & Li, J 2020, 'Improved magnetic circuit analysis of a laminated magnetorheological elastomer device featuring both permanent magnets and electromagnets', Smart Materials and Structures, vol. 29, no. 8, pp. 085054-085054.
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As an essential and critical step, magnetic circuit modelling is usually implemented in the design of efficient and compact magnetorheological (MR) devices, such as MR dampers and MR elastomer isolators. Conventional magnetic circuit analysis simplifies the analysis by ignoring the magnetic flux leakage and magnetic fringing effect. These assumptions are sufficiently accurate in dealing with less complicated designs, featuring short magnetic path lengths such as in an MR damper. However, when dealing with MR elastomer devices, such simplification in magnetic circuit analysis results in inaccuracy of dimensioning and performance estimation of the devices due to their sophisticated design and complex magnetic paths. Modelling permanent magnets also imposes challenges in the magnetic circuit analysis. This work proposes an improved approach to include magnetic flux fringing effect in magnetic circuit analysis for MR elastomer devices. An MRE-based isolator containing multiple MRE layers and both a permanent magnet and an exciting coil was designed and built as a case study. The results of the proposed method are compared to those of conventional magnetic circuit modelling, finite element analysis and experimental measurements to demonstrate the effectiveness of the proposed approach.
Li, W, Dong, W, Shen, L, Castel, A & Shah, SP 2020, 'Conductivity and piezoresistivity of nano-carbon black (NCB) enhanced functional cement-based sensors using polypropylene fibres', Materials Letters, vol. 270, pp. 127736-127736.
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© 2020 Elsevier B.V. The cement-based sensors have a great potential for structural health monitoring, especially functional sensors filled with nano-carbon black (NCB) particles. To improve the sensing efficiency of NCB filled cementitious composite, polypropylene (PP) fibres were premixed with NCB during the manufacturing of cement-based sensor. Although the compressive strength is slightly decreased, the electrical conductivity and piezoresistivity of the NCB filled cementitious composite are improved by PP fibres. Microstructural characterization indicated that NCB attached to the surface of PP fibres significantly promotes the generation of conductive paths and contact points in cement-based sensors. The results can provide a new insight into the application of nonconductive fibres to enhance the conductivity and piezoresistivity of spherical conductors filled cement-based sensor.
Li, W, Tang, Z, Tam, VWY, Zhao, X & Wang, K 2020, 'A Review on Durability of Alkali-activated System from Sustainable Construction Materials to Infrastructures', ES Materials & Manufacturing, vol. 4, pp. 2-19.
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Li, W, Wen, W, Chen, X, Ni, B, Lin, X & Fan, W 2020, 'Functional Evolving Patterns of Cortical Networks in Progression of Alzheimer’s Disease: A Graph-Based Resting-State fMRI Study', Neural Plasticity, vol. 2020, pp. 1-11.
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AD is a common chronic progressive neurodegenerative disorder. However, the understanding of the dynamic longitudinal change of the brain in the progression of AD is still rough and sometimes conflicting. This paper analyzed the brain networks of healthy people and patients at different stages (EMCI, LMCI, and AD). The results showed that in global network properties, most differences only existed between healthy people and patients, and few were discovered between patients at different stages. However, nearly all subnetwork properties showed significant differences between patients at different stages. Moreover, the most interesting result was that we found two different functional evolving patterns of cortical networks in progression of AD, named ‘temperature inversion’ and “monotonous decline,” but not the same monotonous decline trend as the external functional assessment observed in the course of disease progression. We suppose that those subnetworks, showing the same functional evolving pattern in AD progression, may have something the same in work mechanism in nature. And the subnetworks with ‘temperature inversion’ evolving pattern may play a special role in the development of AD.
Li, X, Bond, PL, O’Moore, L, Wilkie, S, Hanzic, L, Johnson, I, Mueller, K, Yuan, Z & Jiang, G 2020, 'Increased Resistance of Nitrite-Admixed Concrete to Microbially Induced Corrosion in Real Sewers', Environmental Science & Technology, vol. 54, no. 4, pp. 2323-2333.
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Microbially induced concrete corrosion is a major deterioration process in sewers, causing a huge economic burden, and improved mitigating technologies are required. This study reports a novel and promising effective solution to attenuate the corrosion in sewers using calcium nitrite-admixed concrete. This strategy aims to suppress the development and activity of corrosion-inducing microorganisms with the antimicrobial free nitrous acid, which is generated in situ from calcium nitrite that is added to the concrete. Concrete coupons with calcium nitrite as an admixture were exposed in a sewer manhole, together with control coupons that had no nitrite admixture, for 18 months. The corrosion process was monitored by measuring the surface pH, corrosion product composition, concrete corrosion loss, and the microbial community on the corrosion layer. During the exposure, the corrosion loss of the admixed concrete coupons was 30% lower than that of the control coupons. The sulfide uptake rate of the admixed concrete was also 30% lower, leading to a higher surface pH (0.5-0.6 unit), in comparison to that of the control coupons. A negative correlation between the calcium nitrite admixture in concrete and the abundance of sulfide-oxidizing microorganisms was determined by DNA sequencing. The results obtained in this field study demonstrated that this novel use of calcium nitrite as an admixture in concrete is a promising strategy to mitigate the microbially induced corrosion in sewers.
Li, X, Chen, L, Ji, Y, Li, M, Dong, B, Qian, G, Zhou, J & Dai, X 2020, 'Effects of chemical pretreatments on microplastic extraction in sewage sludge and their physicochemical characteristics', Water Research, vol. 171, pp. 115379-115379.
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© 2019 Elsevier Ltd Sewage sludge is a primary pathway for microplastics (MPs) entering into terrestrial ecosystems. However, a standardized method to analyze MP in sludge is lacking due to its high organic matter. This study investigated the extraction efficiency of six MPs in five solid matrices, i.e. sewage sludge, cattle manure, soil, sediment and silicon dioxide. Results show lower extraction efficiency of 87.2% for MPs in sludge compared with that in other matrices, especially polyethylene terephthalate (PET) (only 27.8%). The possible reason was that the presence of extracellular polymeric substances within the sludge hinders the MPs to float. Therefore, five protocols, i.e. hydrogen peroxide (H2O2), Fenton, nitric acid (HNO3), hydrochloric acid (HCl) and sodium hydroxide (NaOH) were used to pretreat the sludge and optimize the MP extraction. The sludge pretreated by H2O2, Fenton and 1 M of acids had higher MP extraction efficiency than the raw sludge due to higher extraction of the PET. The MP extraction efficiency in the sludge first increased, and subsequently decreased with the soluble chemical oxygen demand (SCOD) content, implying that moderate dissolution of sludge organic matter is beneficial to the MP extraction. Quantitative analysis of the changes in the MP physicochemical characteristics after the pretreatments indicated that polyamide (PA) and PET are not resistant to acid and alkali treatment, respectively. Principal component analysis shows that the effect of pretreatments on the MPs follows a decreasing sequence: alkali > high concentration of acids > low concentration of acids > H2O2 and Fenton. Additionally, the susceptibility of the MPs to the pretreatments follows a decreasing sequence: PET, PA and polymethyl methacrylate (PMMA) > polystyrene (PS) > polyethylene (PE) and polypropylene (PP). The findings supply novel insights into the effect of chemical pretreatments on MP extraction in sewage sludge.
Li, X, Ji, M, Nghiem, LD, Zhao, Y, Liu, D, Yang, Y, Wang, Q, Trinh, QT, Vo, D-VN, Pham, VQ & Tran, NH 2020, 'A novel red mud adsorbent for phosphorus and diclofenac removal from wastewater', Journal of Molecular Liquids, vol. 303, pp. 112286-112286.
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© 2019 Elsevier B.V. The ubiquitous occurrence of nutrients (e.g. phosphorus) and micropollutants (e.g. pharmaceuticals and endocrine disrupting chemicals) in wastewater and urban stormwater runoff sources may cause adverse effects on aquatic ecosystems and human health. Therefore, the removal of these pollutants from wastewater, treated effluent, and urban stormwater runoff is critically needed. In this study, a novel modified red mud with polypyrrole (RM-PPy) was successfully synthesized with improved functional groups (–OH, –N=, –NH–, N+), specific area (SBET 102.24 m2/g), and mesopore structure (i.e. average pore diameter of 3.29 nm), which are assumed to enhance the adsorptive removal of diclofenac (DCF) and phosphorus (P) in aqueous solution. The measured maximum adsorption capacity of RM-PPy towards diclofenac (195 mg/g) in single adsorbate system was higher than that (115.7 mg/g) in the binary adsorbates system (i.e. in the presence of P), indicating that the presence of pollutants such as P in water hampered the adsorptive removal of DCF. The adsorption of DCF and P was largely dependent on solution pH values. Higher adsorptive removals of DCF and P were observed at acidic conditions (pH 2–5). Adsorption isotherm of DCF and P was better fitted to Freundlich model compared to Langmuir isotherm model, suggesting multilayer coverage. Adsorption of DCF onto RM-PPy might take place via anion exchange and electrostatic interactions. For P adsorption, apart from anion exchange and electrostatic interactions, the chemical precipitation via ligand exchange between P and hydroxyl (–OH) in RM-PPy can be considered as one of the main adsorption mechanisms. Further studies on the competitive adsorption of other anionic micropollutants at environmentally relevant concentrations (ng/L–μg/L) in water samples by RM-PPy are needed to evaluate the potential application of RM-PPy for the removal of other anionic micropollutants (i.e. antibiotics) in treated wastew...
Li, X, Kuang, Z, Zhang, J, Liu, X, Hu, J, Xu, Q, Wang, D, Liu, Y, Wang, Q, Yang, Q & Li, H 2020, 'Performance and Mechanism of Potassium Ferrate(VI) Enhancing Dark Fermentative Hydrogen Accumulation from Waste Activated Sludge', ACS Sustainable Chemistry & Engineering, vol. 8, no. 23, pp. 8681-8691.
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© 2020 American Chemical Society. Potassium ferrate (K2FeO4, PF), as a multifunctional green oxidant, has been used for oxidative degradation of pollutants and recovery of resources in sludge. However, its impact on the generation of hydrogen in anaerobic fermentation of waste activated sludge (WAS) is still unclear. The purpose of this work is to study the influence of PF on the dark fermentative hydrogen production. Experimental result suggested that as PF increased from 0 to 0.09 g/g of TSS (total suspended solids), the maximal hydrogen production increased from 1.47 to 8.35 mL/g VSS (volatile suspended solids). A further increase to 0.12 g/g of TSS resulted in a decrease in hydrogen yield. Mechanism studies revealed that that the addition of PF not only facilitated the disruption of sludge cell and extracellular polymeric substances (EPS) but also increased the proportion of biodegradable organics, providing more bioavailable organics for subsequent reactions involved in hydrogen accumulation. Although the activities of microorganisms relevant to dark fermentation were suppressed to a certain extent in the presence of PF, the induced suppression to hydrogen consumers was more severe. Microbial studies indicated that the relative abundances of hydrogen producers (such as Petrimonas and Proteiniborus) were augmented while hydrogen consumers (such as Methanosaeta and Methylocaldum) decreased in the presence of PF.
Li, X, Li, J, Zhang, X, Gao, J & Zhang, C 2020, 'Simplified analysis of cable-stayed bridges with longitudinal viscous dampers', Engineering, Construction and Architectural Management, vol. 27, no. 8, pp. 1993-2022.
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PurposeViscous dampers are commonly used in large span cable-stayed bridges to mitigate seismic effects and have achieved great success.Design/methodology/approachHowever, the nonlinear analysis on damper parameters is usually computational intensive and nonobjective. To address these issues, this paper proposes a simplified method to determine the viscous damper parameters for double-tower cable-stayed bridges. An empirical formula of the equivalent damping ratio of viscous dampers is established through decoupling nonclassical damping structures and linearization of nonlinear viscous dampers. Shaking table tests are conducted to verify the feasibility of the proposed method. Moreover, this simplified method has been proved in long-span cable-stayed bridges.FindingsThe feasibility of this method is verified by the simplified model shaking table test. This simplified method for determining the parameters of viscous dampers is verified in cable-stayed bridges with different spans.Originality/valueThis simplified method has been validated in cable-stayed bridges with various spans.
Li, Y, Wang, D, Yang, G, Yuan, X, Xu, Q, Yang, Q, Liu, Y, Wang, Q, Ni, B-J, Tang, W & Jiang, L 2020, 'Enhanced dewaterability of anaerobically digested sludge by in-situ free nitrous acid treatment', Water Research, vol. 169, pp. 115264-115264.
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As the protonated form of nitrite, free nitrous acid (FNA) is a renewable chemical that can be produced on site from the anaerobic digestion liquor by nitritation, and has been widely employed to improve the fermentation of waste activated sludge (WAS). However, it is not clear whether and how FNA improves the dewaterability of anaerobically digested sludge (ADS). This work therefore aims to provide such supports through comparing the dewaterability of ADS treated by nitrite at different concentrations (0-250 mg/L) under three pH values (5.5, 6.3, or 7.2). Environmental results showed that nitrite was completely denitrified within 12 h, and its addition improved the dewaterability of ADS in all the cases. The optimal normalized capillary suction time of 18.0 ± 0.4 s L/g VSS was obtained at nitrite 50 mg/L and pH 5.5 (equivalent of 0.35 mg/L FNA) in comparison with corresponding value of 23.2 ± 0.4 s L/g·VSS at pH 5.5 (equivalent of 0 mg/L FNA). Under this scenario, 80.5% ± 2.0% of water content was obtained in the FNA-treated sample after press filtration while the corresponding value was 88.5% ± 1.7% in the control. The mechanism investigations showed that FNA treatment reduced surface negative charge of ADS flocs and caused disruption of extracellular polymeric substances and release of intracellular substances, which enhanced the flocculability, hydrophobicity, and flowability, but decreased the bound water content, fractal dimension, and viscosity of ADS. Additionally, FNA treatment altered the secondary structure of proteins through destroying the hydrogen bond, which led to a loose structure of protein, benefiting the exposure of hydrophobic sites or groups in EPS proteins. The findings obtained deepen our understanding of FNA affecting sludge dewatering and provide strong supports to sustainable operation of wastewater treatment plants.
Li, Y, Zeng, X, Zhou, J, Liu, H, Gu, Y, Pan, Z, Zeng, Y & Zeng, Y 2020, 'Incorporation of disposed oil-contaminated soil in cement-based materials', Resources, Conservation and Recycling, vol. 160, pp. 104838-104838.
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© 2020 Elsevier B.V. To realize the win-win objective of environmental conservation and waste recycling, oil-contaminated soil was utilized as an additive in cement-based materials. The effect of diesel and engine oil and the corresponding oil-contaminated soil on cement-based materials were studied, including the heat release of cement hydration, rheological and flow properties, flexural and compressive strength, hydration products and oil leaching values. The results showed that oil-contaminated soil increased the heat release of hydration of unit mass cement and reduced rheological and flow properties of cement paste and mortars. However, when the dosage of oil-contaminated soil is about 4%, the optimum values of the flexural and compressive strength of mortar, in standard curing 7 and 28 days, were obtained. The leaching values of oil in the disposition satisfied the requirement of China standards. The results confirmed that utilizing an appropriate dosage of oil-contaminated soil in cement-based materials improved the flexural and compressive strength, which is stable to dispose of the waste. This shows that using disposed oil-contaminated soil in cement-based materials will serve as a cost-effective and environmental solution.
Li, Y, Zhu, Y, Wang, D, Yang, G, Pan, L, Wang, Q, Ni, B-J, Li, H, Yuan, X, Jiang, L & Tang, W 2020, 'Fe(II) catalyzing sodium percarbonate facilitates the dewaterability of waste activated sludge: Performance, mechanism, and implication', Water Research, vol. 174, pp. 115626-115626.
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In this work, Fe(II) catalyzing sodium percarbonate (Fe(II)/SPC) was managed to facilitate waste activated sludge (WAS) dewatering for the first time. The results showed that after WAS was treated by 20 mg/g total suspended solids (TSS) Fe(II) and 50 mg/g TSS SPC, the water content of sludge cake (WCSC) by press filtration and capillary suction time (CST) dropped from 90.8% ± 1.6% and 96.1 ± 4.0 s (the control) to 55.6% ± 1.4% and 30.1 ± 2.5 s, respectively. The mechanism investigations indicated that four intermediates or products (i.e., •OH, H2O2, Fe(II), and Fe(III)) generated in the Fe(II)/SPC process were responsible for the improved WAS dewaterability, and •OH and Fe(III) were the two major contributors. It was found that •OH collapsed and fragmented extracellular polymeric substances, damaged cell wall and permeabilized cytoplasmic membrane, and transformed conformation of the extracellular proteins secondary structure via both affecting the hydrogen bond maintaining α-helix and cracking disulfide bond in cysteine residues while Fe(III), the oxidization product of Fe(II), decreased the surface electronegativity and water-affinity surface areas of WAS flocs. As a result, the bound water release, flocculability, surface hydrophobicity, drain capability, and flowability of WAS flocs were strengthened whereas the compact surface structure, colloidal forces, network strength, gel-like structure, and apparent viscosity of WAS flocs were weakened. In addition, Fe(II)/SPC process also reduced the recalcitrant organics and fecal coliforms in sludge, which facilitated land application of dewatered sludge. The findings acquired in this work not only deepens our understanding of Fe(II)/SPC-involved WAS treatment process but also may guide engineers to develop both effective and promising strategies to better condition WAS for dewatering in the future.
Li, Z, Tao, M, Du, K, Cao, W & Wu, C 2020, 'Dynamic stress state around shallow-buried cavity under transient P wave loads in different conditions', Tunnelling and Underground Space Technology, vol. 97, pp. 103228-103228.
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Lim, S, Akther, N, Tran, VH, Bae, T-H, Phuntsho, S, Merenda, A, Dumée, LF & Shon, HK 2020, 'Covalent organic framework incorporated outer-selective hollow fiber thin-film nanocomposite membranes for osmotically driven desalination', Desalination, vol. 485, pp. 114461-114461.
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Lim, S, Park, KH, Tran, VH, Akther, N, Phuntsho, S, Choi, JY & Shon, HK 2020, 'Size-controlled graphene oxide for highly permeable and fouling-resistant outer-selective hollow fiber thin-film composite membranes for forward osmosis', Journal of Membrane Science, vol. 609, pp. 118171-118171.
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© 2020 Elsevier B.V. Size-controlled graphene oxide (SGO) nanosheets, which are uniform and smaller in size than 2 μm, were successfully incorporated into a polyamide (PA) layer for preparing an outer-selective hollow fiber (OSHF) thin-film nanocomposite (TFN) membrane for forward osmosis (FO) applications by vacuum-assisted interfacial polymerization (VAIP). Here, we specifically demonstrate that the SGO nanosheets in amine aqueous solution were horizontally aligned and stacked on the surface of a membrane substrate by vacuum suction from outside to inside in the VAIP; the SGO nanosheets were then well-incorporated into the thin PA layer with less physical damage. In addition, the SGO nanosheets' effective loading inside the PA layer under the VAIP was much higher than that under the typical interfacial polymerization (IP), since there is no issue about the particle loss from air or nitrogen blowing to remove excess amine solution. The benefit would be highly cost-effective in terms of the nanomaterial's use in a TFN membrane production. As a result, the optimum OSHF TFN membrane incorporated with SGO at 0.0005 wt% (SGO5) exhibited outstanding FO performance, including higher water flux at 39.0 L m-2 h-1 and lower specific reverse solute flux at 0.16 g L-1, using a 1 M NaCl draw solution. Furthermore, this study demonstrates the effect of graphene oxide (GO)'s lateral size toward the short water pathway, and GO's stable incorporation and hydrophilicity of the PA thin film. In the fouling test using artificial wastewater, SGO-incorporated membranes exhibited enhanced fouling resistance and cleaning efficiency against the foulant-rich solution. This novel TFN membrane is therefore a good candidate to address FO's challenges for wastewater treatment or desalination.
Liu, K, Li, Q, Wu, C, Li, X & Li, J 2020, 'Optimization of spherical cartridge blasting mode in one-step raise excavation using pre-split blasting', International Journal of Rock Mechanics and Mining Sciences, vol. 126, pp. 104182-104182.
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© 2019 Elsevier Ltd In one-step raise excavation, spherical cartridge blasting mode is easy to be implemented due to minimal requirement of the hole-deviation. Nevertheless, it may induce cumulative damage to the country rock. This study firstly uses a validated rock model (Johnson-Holmquist model) to simulate the damage evolution process of a raise by spherical cartridge blasting mode in LS-DYNA software. Then a field test is carried out to examine the numerical results of spherical cartridge blasting mode. Both the numerical and test results indicate that because of highly confined rock mass and restricted free face in deep raise, a large charge is required in spherical cartridge blasting mode which leads to extensive damage on the wall of the raise. In order to solve such a problem, the pre-split blasting technique is developed to optimize spherical cartridge blasting mode. According to the subsequent numerical results, the improved spherical cartridge blasting mode is successfully applied in another filling raise. This study provides an effective solution to the difficulties that are encountered in one-step raise excavation by spherical cartridge blasting mode.
Liu, K, Wu, C, Li, X, Li, Q, Fang, J & Liu, J 2020, 'A modified HJC model for improved dynamic response of brittle materials under blasting loads', Computers and Geotechnics, vol. 123, pp. 103584-103584.
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Liu, M, Lu, X, Nothling, MD, Doherty, CM, Zu, L, Hart, JN, Webley, PA, Jin, J, Fu, Q & Qiao, GG 2020, 'Physical Aging Investigations of a Spirobisindane-Locked Polymer of Intrinsic Microporosity', ACS Materials Letters, vol. 2, no. 8, pp. 993-998.
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Polymers of intrinsic microporosity (PIMs) have exceptional gas separation performance for a broad range of applications. However, PIMs are highly susceptible to physical aging, which drastically reduces their long-term performance over time. In this work, we leverage complementary experimental and density functional theory (DFT) studies to decipher the inter-/intrachain changes that occur during aging of the prototypical PIM-1 and its rigidified analogue PIM-C1. By elucidating this hereto unexplored aging behavior, we reveal that the dramatic decrease in gas permeability of PIM materials during aging stems from a loss of fractional free volume (FFV) due to PIM chain relaxations induced by π-πinteractions, hydrogen bonding, or van der Waals' forces. While the PIM-1 based membranes displayed enhanced gas pair selectivities after aging, the PIM-C1 based membranes showed an opposite trend with unexpected reductions for CO2/N2 and CO2/CH4. This is due to the reductions in CO2/N2 and CO2/CH4 solubility (S) selectivities and, unlike PIM-1, the spirobisindane locked PIM-C1 (i.e., maintenance of micropore sizes) has a stable diffusivity (D) selectivities that cannot offset such reductions. These fundamental insights into the intrinsic relaxation of different PIM polymer chains during physical aging can guide the future design of high-performance PIM materials with enhanced anti-aging properties.
Liu, M, Nothling, MD, Tan, SSL, Webley, PA, Qiao, GG & Fu, Q 2020, 'Polyrotaxane-based thin film composite membranes for enhanced nanofiltration performance', Separation and Purification Technology, vol. 246, pp. 116893-116893.
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© 2020 An urgent need exists for the development of advanced water purification technologies to meet the increasing global demand being placed on freshwater resources. Membrane-based separation technologies for size-selective contaminant removal represent a promising approach to achieve this goal. Here, a novel thin film composite nanofiltration membrane is prepared via interfacial polymerization of α-cyclodextrin on a commercially available polyacrylonitrile substrate. Subsequent in-situ inclusion complexation of alkyne-functionalized poly(ethylene glycol) (PEG) is then used to tune the polyrotaxane-based pores for size-dependent filtration. The resultant membrane shows excellent size-selective rejection rates for organic dye (e.g. rhodamine B, >99%) as well as heavy-metal ions (e.g. Co(II), >90%), while crucially maintaining high water permeance (e.g. H2O: 7.1 L h−1 m−2 bar−1). The facile and straightforward synthetic approach to the fabrication of polyrotaxane nanofiltration membranes, combined with their strong nanofiltration separation performance, holds significant promise for membrane-based water purification applications.
Liu, M, Nothling, MD, Webley, PA, Jin, J, Fu, Q & Qiao, GG 2020, 'High-throughput CO2 capture using PIM-1@MOF based thin film composite membranes', Chemical Engineering Journal, vol. 396, pp. 125328-125328.
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© 2020 Elsevier B.V. Carbon capture from power plants represents a powerful technique to mitigate increasing greenhouse gas emissions. In this work, we describe a thin film composite (TFC) membrane incorporating a polymer of intrinsic microporosity (PIM-1) and metal organic framework (MOF) nanoparticles for post-combustion CO2 capture. The novel TFC membrane design consists of three layers: (1) a CO2 selective layer composed of a PIM-1@MOF mixed matrix; (2) an ultrapermeable PDMS gutter layer doped with MOF nanosheets; and (3) a porous polymeric substrate. Notably, the PDMS@MOF gutter layer incorporating amorphous nanosheets provides a CO2 permeance of 10,000–11,000 GPU, suggesting less gas transport resistance in comparison with pristine PDMS gutter layers. In addition, by blending nanosized MOF particles (MOF-74-Ni and NH2-UiO-66) into PIM-1 to afford a selective layer, the resultant TFC membrane assembly delivered improved CO2 permeance of 4660–7460 GPU and CO2/N2 selectivity of 26–33, compared with a pristine PIM-1 counterpart (CO2 permeance of 4320 GPU and CO2/N2 selectivity of 19). Furthermore, PIM-1@MOF based TFC membranes displayed an enhanced resistance to aging effect, maintaining a stable CO2 permeance of 900–1200 GPU and CO2/N2 selectivity of 26–30 after aging for 8 weeks. To the best of our knowledge, the high CO2 separation performance presented here is unprecedented for PIM-1 based TFC membranes reported in the open literature.
Liu, MD, Airey, DW, Indraratna, B, Zhuang, Z & Horpibulsuk, S 2020, 'An extended modified cam clay model for improved accuracy at low and high-end stress levels', Marine Georesources & Geotechnology, vol. 38, no. 4, pp. 423-436.
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Liu, Q, Liufu, K, Cui, Z, Li, J, Fang, J & Li, Q 2020, 'Multiobjective optimization of perforated square CFRP tubes for crashworthiness', Thin-Walled Structures, vol. 149, pp. 106628-106628.
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Liu, X, He, D, Wu, Y, Xu, Q, Wang, D, Yang, Q, Liu, Y, Ni, B-J, Wang, Q & Li, X 2020, 'Freezing in the presence of nitrite pretreatment enhances hydrogen production from dark fermentation of waste activated sludge', Journal of Cleaner Production, vol. 248, pp. 119305-119305.
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© 2019 Elsevier Ltd Due to the poor biodegradability of released organics and the rapid consumption of hydrogen, hydrogen production from the untreated waste activated sludge (WAS) and/or inocula is still limited. In this study, it was found that the dark fermentative hydrogen production was largely enhanced from WAS pretreated by freezing in the presence of nitrite. With an increase of nitrite addition from 100 to 400 mg NO2−-N/L during freezing pretreatment (−5 °C for 4 h), the maximal hydrogen yield increased from 7.96 to 19.40 mL/g VS (volatile solids), which was 5.5–13.4 times of that in the control (without freezing and nitrite addition). Mechanism explorations revealed that the proposed pretreatment not only accelerated the disintegration of sludge but also promoted the proportion of biodegradable organics released, thereby provided more bio-available substrates for subsequent hydrogen production. Proposed pretreatment severely suppressed the sludge microorganisms responding to homoacetogenesis (−32.1%), methanogenesis (−58.4%), and sulfate-reducing process (−51.5%), inhibited the consumption of hydrogen. Moreover, there was more acetic and butyric (76% versus 57.5%) but less propionic acid (22.6% versus 13.4%) in this pretreated fermenter, which was in correspondence with the theory of fermentation type affecting hydrogen production. Long-term fermentation experiments indicated that the proposed pretreatment boosted the [FeFe]-hydrogenase activities while suppressed the activities of carbon monoxide dehydrogenase, coenzyme F420, and adenylyl sulfate reductase.
Liu, X, Huang, X, Wu, Y, Xu, Q, Du, M, Wang, D, Yang, Q, Liu, Y, Ni, B-J, Yang, G, Yang, F & Wang, Q 2020, 'Activation of nitrite by freezing process for anaerobic digestion enhancement of waste activated sludge: Performance and mechanisms', Chemical Engineering Journal, vol. 387, pp. 124147-124147.
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© 2020 Elsevier B.V. Nitrite-based pretreatment was demonstrated to effectively improve anaerobic digestion of waste activated sludge. It was found in this work that the freezing activated nitrite pretreatment could further enhance the performances. With the increase of nitrite addition from 0 to 600 mg NO2−-N/L during freezing process, the biochemical methane potential of pretreated-sludge gradually increased from 191.3 ± 8.0 to 233.2 ± 10.6 mL per gram volatile solid (VS), while only 178.6 ± 7.3 mL/g VS was obtained in the raw sludge. Mechanism explorations revealed that the freezing activated nitrite pretreatment remarkably facilitated the disintegration of sludge. Excitation emission matrix and fluorescence regional integration analyses further revealed that nitrite addition during freezing process promoted the proportion of biodegradable organics released, thereby providing more bio-available substrates for subsequent anaerobic digestion. Freezing condition induced reactive derivatives from nitrite (e.g., free nitrite acid, NO2[rad], N2O3) were assumed to be the major contributors to the enhanced sludge disintegration and recalcitrant organics (e.g., humic acid-like substances) degradation. It was also found that 600 mg NO2−-N/L addition activated by freezing pretreatment produced an anaerobically digested sludge with an improved dewaterability, as indicated by the decrease of the specific resistance to filterability and moisture content of dewatered cake. Moreover, 600 mg NO2−-N/L addition activated by freezing pretreatment and subsequent anaerobic digestion largely inactivated the pathogens to the levels below Class A biosolids requirements. Considering that nitrite can be in-situ produced in wastewater treatment plants through nitritation of the digestion liquid, this nitrite-based freezing process for sludge pretreatment was environmental-friendly and economically attractive.
Liu, X, Wei, W, Xu, J, Wang, D, Song, L & Ni, B-J 2020, 'Photochemical decomposition of perfluorochemicals in contaminated water', Water Research, vol. 186, pp. 116311-116311.
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Perfluorochemicals (PFCs) are a set of chemicals containing C-F bonds, which are concerned due to their bioaccumulation property, persistent and toxicological properties. Photocatalytic approaches have been widely studied for the effective removal of PFCs due to the mild operation conditions. This review aims to provide a comprehensive and up-to-date summary on the homogenous and heterogeneous photocatalytic processes for PFCs removal. Specifically, the homogenous photocatalytic methods for remediating PFCs are firstly discussed, including generation of hydrated electrons (eaq‒) and its performance and mechanisms for photo-reductive destruction of PFCs, the active species responsible for photo-oxidative degradation of PFCs and the corresponding mechanisms, and metal-ion-mediated (Fe(III) mainly used) processes for the remediation of PFCs. The influences of molecular structures of PFCs and water matrix, such as dissolved oxygen, humic acid, nitrate, chloride on the homogenous photocatalytic degradation of PFCs are also discussed. For heterogeneous photocatalytic processes, various semiconductor photocatalysts used for the decomposition of perfluorooctanoic acid (PFOA) are then discussed in terms of their specific properties benefiting photocatalytic performances. The preparation methods for optimizing the performance of photocatalysts are also overviewed. Moreover, the photo-oxidative and photo-reductive pathways are summarized for remediating PFOA in the presences of different semiconductor photocatalysts, including active species responsible for the degradation. We finally put forward several key perspectives for the photocatalytic removal of PFCs to promote its practical application in PFCs-containing wastewater treatment, including the treatment of PFCs degradation products such as fluoride ion, and the development of noble-metal free photocatalysts that could efficiently remove PFCs under solar light irradiation.
Liu, X, Zhou, A, Shen, S-L, Li, J & Sheng, D 2020, 'A micro-mechanical model for unsaturated soils based on DEM', Computer Methods in Applied Mechanics and Engineering, vol. 368, pp. 113183-113183.
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© 2020 Elsevier B.V. A micro-mechanical model to study the microscopic and macroscopic behavior of unsaturated soils under different suctions is proposed in this study. In the model, a novel pore-scale numerical method for simulating the liquid–solid interfaces is proposed first. A discretization of the particle surface using Fibonacci-Lattice is then introduced to calculate the capillary forces from the complex liquid–solid interfaces. The joint influence of capillary forces and the interparticle contact forces on the motion of the particles are handled by the discrete element method (DEM). The effective stress parameter estimated by the model is compared with the experimental results for unsaturated soils, which confirms the validity of the proposed micro-mechanical model. The microscopic responses (liquid–solid interfaces, capillary forces, contact forces and coordination numbers) and macroscopic responses (strength, stress–strain relationship and volume change) of unsaturated soils in desaturation tests and triaxial tests are studied by the proposed model.
Liu, Y, Li, H-W & Huang, Z 2020, 'Editorial: Metal Hydride-Based Energy Storage and Conversion Materials', Frontiers in Chemistry, vol. 8, p. 675.
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Liu, Y, Luo, G, Ngo, HH, Guo, W & Zhang, S 2020, 'Advances in thermostable laccase and its current application in lignin-first biorefinery: A review', Bioresource Technology, vol. 298, pp. 122511-122511.
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© 2019 Elsevier Ltd As the most abundant aromatic polymers on the Earth, lignin has great potential to produce biofuels and aromatic chemicals due to their high carbon content and low oxygen content. Lignin-first biorefinery methods have attracted increasing attention recently for their high-value of aromatic chemicals, and high biofuels productivity from lignocellulosic wastes. Thermostable laccase has proven to be an excellent alternative catalyst in degrading lignin for its versatile catalytic abilities under industrial conditions and pollution-free by-products. Thermostable laccases can be found in native extreme environments or modified by biologically based technologies such as gene recombination expression and enzyme direct evolution. This review demonstrated thermostable laccases and their application in lignin degradation. Future research should focus more on the investigation of the reaction of thermostable laccases with lignin substrates.
Liu, Y, Ngo, HH, Guo, W, Wang, D, Peng, L, Wei, W & Ni, B-J 2020, 'Impact of coexistence of sludge flocs on nitrous oxide production in a granule-based nitrification system: A model-based evaluation', Water Research, vol. 170, pp. 115312-115312.
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© 2019 Elsevier Ltd A common operational status of granule-based reactor is the inevitable coexistence of sludge flocs. Such hybrid system could have a profound impact on nitrous oxide (N2O) production in nitrifying process. In this work, a mathematical model is employed to evaluate the key role of the coexistence of sludge flocs on N2O production in a granule-based nitrifying system for the first time, by considering both nitrifier denitrification and hydroxylamine oxidation pathways. The modelling results show that the N2O production gradually decreases with the increase of the percentage of sludge flocs in the total biomass (10–60%). More N2O is tended to be generated in sludge flocs which has lower N2O production capacity compared to granular biomass, thus lowering the total N2O production. The relative contributions of two N2O production pathways are only affected by bulk dissolved oxygen (DO) for the sludge flocs in the hybrid system, whereas those are affected by both bulk DO and the fractions of sludge flocs for the granular biomass. The results reveal a substantial effect of the coexistence of sludge flocs on N2O production in granule-based nitrifying process, which should not be ignored in future design and operation.
Liu, Y, Zhao, T, Su, Z, Zhu, T & Ni, B-J 2020, 'Evaluating the roles of coexistence of sludge flocs on nitrogen removal and nitrous oxide production in a granule-based autotrophic nitrogen removal system', Science of The Total Environment, vol. 730, pp. 139018-139018.
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Certain levels of sludge flocs would always coexist in granule-based reactors due to the biomass detachment from granules. Such inevitable coexistence could affect both total nitrogen (TN) removal and nitrous oxide (N2O) production in autotrophic nitrogen removal systems. This work utilized a mathematical approach to systematically study the influence of the coexisting sludge flocs on TN removal and N2O production in a granular nitritation-anaerobic ammonium oxidation (Anammox) process for the first time, based on a 2-pathway N2O production model concept. The modelling results reveal that the highest TN removal efficiency decreases from ca. 87-88% to ca. 41-49% as the fraction of sludge flocs in the system increases from 10% to 40%, while the N2O production rate gradually increases with such increase. Meanwhile, both bulk dissolved oxygen (DO, 0.05-0.3 mg/L) and the size of granule (200-400 μm) could also influence the TN removal efficiency and N2O production. As the fraction of sludge flocs increases from 10% to 40%, the contribution of granular biomass to total N2O production is reduced due to increase of N2O-producing ammonia-oxidizing bacteria (AOB) in the sludge flocs, and the increase of granule size could intensify such decrease. In addition, the hydroxylamine oxidation pathway dominates the nitrifier denitrification pathway in both granules and sludge flocs under various testing conditions, whereas the increasing contribution of the latter would occur at a certain DO range, higher fraction of sludge flocs and smaller granule size. These results disclose an important influence of the coexisting sludge flocs on the performance of granular nitritation-Anammox systems.
Liyanaarachchi, S, Jegatheesan, V, Shu, L, Shon, HK, Muthukumaran, S & Li, CQ 2020, 'Evaluating the Feasibility of Forward Osmosis in Diluting RO Concentrate Using Pretreatment Backwash Water', Membranes, vol. 10, no. 3, pp. 35-35.
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Forward osmosis (FO) is an excellent membrane process to dilute seawater (SW) reverse osmosis (RO) concentrate for either to increase the water recovery or for safe disposal. However, the low fluxes through FO membranes as well the biofouling/scaling of FO membranes are bottlenecks of this process requiring larger membrane area and membranes with anti-fouling properties. This study evaluates the performance of hollow fibre and flat sheet membranes with respect to flux and biofouling. Ferric hydroxide sludge was used as impaired water mimicking the backwash water of a filter that is generally employed as pretreatment in a SWRO plant and RO concentrate was used as draw solution for the studies. Synthetic salts are also used as draw solutions to compare the flux produced. The study found that cellulose triacetate (CTA) flat sheet FO membrane produced higher flux (3–6 L m−2 h−1) compared to that produced by polyamide (PA) hollow fibre FO membrane (less than 2.5 L m−2 h−1) under the same experimental conditions. Therefore, long-term studies conducted on the flat sheet FO membranes showed that fouling due to ferric hydroxide sludge did not allow the water flux to increase more than 3.15 L m−2 h−1.
Loganathan, P, Gradzielski, M, Bustamante, H & Vigneswaran, S 2020, 'Progress, challenges, and opportunities in enhancing NOM flocculation using chemically modified chitosan: a review towards future development', Environmental Science: Water Research & Technology, vol. 6, no. 1, pp. 45-61.
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Natural organic matter (NOM) occurs ubiquitously in water bodies and this can greatly affect feed or raw water quality (taste, colour, odour, bacterial growth). Chemically modified chitosan can effectively remove NOM by the flocculation process.
Logeswaran, J, Shamsuddin, AH, Silitonga, AS & Mahlia, TMI 2020, 'Prospect of using rice straw for power generation: a review', Environmental Science and Pollution Research, vol. 27, no. 21, pp. 25956-25969.
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With the ever-increasing energy demands, fossil fuels are gradually depleting and eventually, these nonrenewable sources of energy will be exhausted. Hence, there is an urgent need to formulate alternative fuels that are both renewable and sustainable. Biomass is one of the reliable sources of energy because it is replenishable. Rice is the staple food in many countries, particularly in Asia. The number of paddy fields has increased tremendously over the years and is expected to increase in the future in response to the growing world population. This will lead to significant amounts of agricultural wastes annually, particularly rice straw. In some countries, open burning and soil incorporation are used to manage agricultural wastes. Open burning is the preferred method because it is inexpensive. However, this method is highly undesirable because of its detrimental impact on the environment resulting from the release of carbon dioxide and methane gas. Hence, it is important to develop an energy-harvesting method from rice straw for power generation. More studies need to be carried out on the availability and characteristics of rice straw as well as logistic analysis to assess the potential of rice straw for power generation. This paper is focused on reviewing studies pertaining to the characteristics and potential of rice straw for power generation, current rice straw management practices, and logistic analysis in order to develop a suitable energy-harvesting method from rice straw in Malaysia.
Long, G, Xie, Y, Luo, Z, Qu, L, Zhou, JL & Li, W 2020, 'Deterioration mechanism of steam-cured concrete subjected to coupled environmental acid and drying action', Journal of Infrastructure Preservation and Resilience, vol. 1, no. 1, p. 5.
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AbstractIn order to investigate the deterioration mechanism of steam-cured concrete under severe environmental actions such as acid rain corrosion, salt corrosion, and cyclic thermal loading, accelerated corrosion tests were conducted in this study. Surface damage as well as deteriorative kinetics of steam-cured concrete and cement paste suffering from coupled acid-thermal actions was investigated by soaking-drying cycle experiments. The effects of mineral admixture, curing regime and corrosion condition on the durability were all comparatively studied, and the X-ray diffractograms and nanoindentation were applied to analyse the mechanism of corrosion deterioration. The results revealed that compared with the cementitious materials under standard curing, larger depth and faster corrosion were observed for steam-cured concrete and cement paste, which might be partly attributed to the lower content of hydrated production presented in steam-cured specimens. Besides, under acid solution soaking-drying cycle regime, there was significant higher corrosion depth compared to only soaking in acid solution. The corrosion depth under steam curing and soaking-drying condition increased by 156.68% and 44.17%, respectively, compared with those under standard curing and only soaking treatment. In addition, fly ash effectively decreased the corrosion depth of steam-cured cement paste and concrete by 64.98% and 16.33%, respectively.
Lu, Z-H, Wang, H-J, Qu, F, Zhao, Y-G, Li, P & Li, W 2020, 'Novel empirical model for predicting residual flexural capacity of corroded steel reinforced concrete beam', Frontiers of Structural and Civil Engineering, vol. 14, no. 4, pp. 888-906.
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© 2020, Higher Education Press. In this study, a total of 177 flexural experimental tests of corroded reinforced concrete (CRC) beams were collected from the published literature. The database of flexural capacity of CRC beam was established by using unified and standardized experimental data. Through this database, the effects of various parameters on the flexural capacity of CRC beams were discussed, including beam width, the effective height of beam section, ratio of strength between longitudinal reinforcement and concrete, concrete compressive strength, and longitudinal reinforcement corrosion ratio. The results indicate that the corrosion of longitudinal reinforcement has the greatest effect on the residual flexural capacity of CRC beams, while other parameters have much less effect. In addition, six available empirical models for calculating the residual flexural strength of CRC beams were also collected and compared with each other based on the established database. It indicates that though five of six existing empirical models underestimate the flexural capacity of CRC beams, there is one model overestimating the flexural capacity. Finally, a newly developed empirical model is proposed to provide accurate and effective predictions in a large range of corrosion ratio for safety assessment of flexural failure of CRC beams confirmed by the comparisons.
Luo, Z, Li, W, Gan, Y, Mendu, K & Shah, SP 2020, 'Applying grid nanoindentation and maximum likelihood estimation for N-A-S-H gel in geopolymer paste: Investigation and discussion', Cement and Concrete Research, vol. 135, pp. 106112-106112.
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© 2020 Elsevier Ltd Static nanoindentation and Maximum Likelihood Estimation (MLE) were applied for the nano/micromechanical properties investigation of alkali-activated fly ash (AAFA) in this study. Some critical issues of statistical nanoindentation were fully discussed, including properties of pure gel phase, influence of bin size when using least-square estimation (LSE), and suitable number of components for deconvolution. Results indicate that the model estimated by MLE method can effectively reflect the micromechanical distribution of AAFA. The number of components needed to separate sodium aluminosilicate hydrate (N-A-S-H) gels is sometimes more than the normally used 3 or 4, depending on the sample and testing factors. The gel phase does not always display as a prominent peak in the histogram and is easy to be mixed with other adjacent peaks even if the bin size is small, indicating the challenges of employing the LSE method to investigate the gel phase in highly heterogeneous materials, such as geopolymer.
Luo, Z, Li, W, Gan, Y, Mendu, K & Shah, SP 2020, 'Maximum likelihood estimation for nanoindentation on sodium aluminosilicate hydrate gel of geopolymer under different silica modulus and curing conditions', Composites Part B: Engineering, vol. 198, pp. 108185-108185.
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© 2020 Elsevier Ltd As an important inorganic material, geopolymer has been widely used for ceramics and sustainable cement in concrete. Sodium aluminosilicate hydrate (N-A-S-H) gel known as the zeolite precursor gel has the most critical impact on the performance of geopolymer. The nano/micromechanical properties of N-A-S-H have been investigated in several studies, but the resutls are always inconsistent. A novel “compromise approach” using Maximum Likelihood Estimation (MLE) for deconvolution of nanoindentation data is introduced to fundamentally further understand this issue in this study. Correlation and difference of different statistical techniques are compared to clarify the rationality of this method. Multiple characterization techniques including microstructure observation at micro -and nano-scale, element analysis, and crystal identification are applied to reveal the mechanisms. The results indicate that the elastic modulus and hardness of the N-A-S-H gel in geopolymer under different silica modulus and curing conditions vary in a small range from 10.50 to 14.30 GPa and from 0.40 to 0.57 GPa, respectively. When applying statistical nanoindentation in geopolymer, two kinds of spurious phases, mixed phases and sub-phases are unavoidable. For the MLE method adopted, the errors generated from analytical technique were estimated to be only 0.68 and 0.13 GPa for elastic modulus and hardness, respectively.
Ly, QV, Matindi, C, Kuvarega, AT, Ngo, HH, Le, QV, Nam, VH & Li, J 2020, 'Exploring the novel PES/malachite mixed matrix membrane to remove organic matter for water purification', Chemical Engineering Research and Design, vol. 160, pp. 63-73.
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Ma, C, Gao, Y, Degano, M, Wang, Y, Fang, J, Gerada, C, Zhou, S & Mu, Y 2020, 'Eccentric position diagnosis of static eccentricity fault of external rotor permanent magnet synchronous motor as an in‐wheel motor', IET Electric Power Applications, vol. 14, no. 11, pp. 2263-2272.
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Ma, C, Zhou, S, Yang, N, Degano, M, Gerada, C, Fang, J & Liu, Q 2020, 'Characteristic analysis and direct measurement for air gap magnetic field of external rotor permanent magnet synchronous motors in electric vehicles', IET Electric Power Applications, vol. 14, no. 10, pp. 1784-1794.
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In this study, the air gap magnetic field characteristics of external rotor permanent magnet synchronous motors (PMSMs) under both the stator and rotor coordinate systems considering low-order current harmonics and high-order sideband current harmonics are analysed. A direct measurement technique (DMT) for air-gap magnetic field is proposed. First, an analytical model of air gap magnetic field of external rotor PMSMs is established. The spatial order and frequency characteristics of stator/rotor air gap magnetic field are revealed. Then, a 24-pole 27-slot external rotor PMSM is taken as an example. The analytical and finite element (FE) results are compared and analysed. The difference of the spatial order and frequency characteristics between the stator and rotor air gap magnetic field are verified. Next, a new DMT is proposed, which can detect the precise distribution and local microscopic characteristics on the order of 10 -1 mm with high resolution. The accuracy of analytical and FE model are verified by the DMT and an indirect experimental test of no-load back electromotive force. Finally, the mechanical challenges of in-wheel motors and the practicablility of DMT for eccentricity detection are further discussed
Ma, M, Tam, VWY, Le, KN & Li, W 2020, 'Challenges in current construction and demolition waste recycling: A China study', Waste Management, vol. 118, pp. 610-625.
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China produced a large amount of construction and demolition (C&D) waste, owing to the rapid development of construction industry. Although a set of policies and regulations are being drafted in China for promoting C&D waste recycling, execution of these policies in practice seems to be far from effective. Currently, approximately 75% of Chinese cities are still surrounded by large volumes of C&D waste. Therefore, identification of challenges in the development of C&D waste management, specially recycling, is essential. This paper employs site visits to 10 recycling plants in 10 Chinese cities (Shanghai, Hangzhou, Suzhou, Chongqing, Chengdu, Xi'an, Changsha, Shenzhen, Nanjing, and Zhoukou) and interviews with 25 industry practitioners for examining the challenges. Eight challenges are identified: (1) unstable source of C&D waste for recycling, (2) absence of subsidies for recycling activities and high cost for land use, (3) insufficient attention paid to design for waste minimisation, (4) absence of regulations on on-site sorting, (5) unregulated landfill activities, (6) a lack of coordination among different government administration departments, (7) a lack of accurate estimation of waste quantity and distribution, and (8) a lack of an effective waste tracing system. Recommendations to address these challenges are presented. The results of this study are expected to aid policy makers in formulation of proper C&D waste management in China and provide a useful reference for researchers who are interested in C&D waste recycling industry.
Ma, XY, Dong, K, Tang, L, Wang, Y, Wang, XC, Ngo, HH, Chen, R & Wang, N 2020, 'Investigation and assessment of micropollutants and associated biological effects in wastewater treatment processes', Journal of Environmental Sciences, vol. 94, pp. 119-127.
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Currently, the wastewater treatment plants (WWTPs) attempt to achieve the shifting from general pollution parameters control to reduction of organic micropollutants discharge. However, they have not been able to satisfy the increasing ecological safety needs. In this study, the removal of micropollutants was investigated, and the ecological safety was assessed for a local WWTP. Although the total concentration of 31 micropollutants detected was reduced by 83% using the traditional biological treatment processes, the results did not reflect chemicals that had poor removal efficiencies and low concentrations. Of the five categories of micropollutants, herbicides, insecticides, and bactericides were difficult to remove, pharmaceuticals and UV filters were effectively eliminated. The specific photosynthesis inhibition effect and non-specific bioluminescence inhibition effect from wastewater were detected and evaluated using hazardous concentration where 5% of aquatic organisms are affected. The photosynthesis inhibition effect from wastewater in the WWTP was negligible, even the untreated raw wastewater. However, the bioluminescence inhibition effect from wastewater which was defined as the priority biological effect, posed potential ecological risk. To decrease non-specific biological effects, especially of macromolecular dissolved organic matter, overall pollutant reduction strategy is necessary. Meanwhile, the ozonation process was used to further decrease the bioluminescence inhibition effects from the secondary effluent; ≥ 0.34 g O3/g DOC of ozone dose was recommended for micropollutants elimination control and ecological safety.
Mahlia, TMI, Syazmi, ZAHS, Mofijur, M, Abas, AEP, Bilad, MR, Ong, HC & Silitonga, AS 2020, 'Patent landscape review on biodiesel production: Technology updates', Renewable and Sustainable Energy Reviews, vol. 118, pp. 109526-109526.
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© 2019 Elsevier Ltd Biodiesel is a renewable fuel made from vegetable oils and animal fats. Compared with fossil fuels, it has the potential to alleviate environmental pressures and achieve sustainable development. In this paper, 1660 patents related to biodiesel production were reviewed. They were published between January 1999 and July 2018 and were retrieved from the Derwent Innovation patent database. The patents were grouped into five categories depending on whether they related to starting materials, pre-treatment methods, catalysts, reactors and processing methods, or testing methods. Their analysis shows that the availability of biodiesel starting materials depends on climate, geographical location, local soil conditions, and local agricultural practices. Starting materials constitute 75% of overall production costs and, therefore, it is crucial to select the best feedstock. Pre-treatment of feedstock can improve its suitability for processing and increase extraction effectiveness and oil yield. Catalysts can enhance the solubility of alcohol, leading to higher reaction rates, faster biodiesel production processes, and lower biodiesel production costs. Moreover, the apparatus and processes used strongly affect the oil yield and quality, and production cost. In order to be commercialized and marketed, biodiesel should pass either the American Society for Testing and Materials (ASTM) standards or European Standards (EN). Due to increases in environmental awareness, it is likely that the number of published patents on biodiesel production will remain stable or even increase.
Mahmood, AH, Foster, SJ & Castel, A 2020, 'Development of high-density geopolymer concrete with steel furnace slag aggregate for coastal protection structures', Construction and Building Materials, vol. 248, pp. 118681-118681.
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© 2020 Elsevier Ltd Anticipated changes in coastal wave conditions due to various climate change impact scenarios along coastlines may expose coastal protection structures to greater wave energies and higher damage rates than designed for, especially during episodic storm events. Some existing coastal breakwaters need upgrading to withstand the projected conditions. Breakwater armour unit design equations and physical model tests predict a large gain in stability with a modest increase in the armour material density and indicate reduced armour unit size requirements when utilising high-density concrete. In this study, a high-density geopolymer concrete mix with steel furnace slag (SFS) aggregate was developed based on several trials; the material properties were evaluated for on-site applications under ambient curing conditions. The use of SFS aggregate offers higher bulk density to concrete and mixes were proportioned to achieve good workability and setting time. Most importantly, the fly ash-blast furnace slag blended binder used in this study leads to adequate strength gain in ambient curing and allows the diffusion of the free lime associated with the SFS aggregate into the geopolymer matrix to eliminate the delayed hydration and expansion of the aggregate. This research provides a pathway to both upgradings of existing breakwaters and construction of new structures with a reduction to the carbon footprint in breakwater construction.
Mahmood, AH, Foster, SJ & Castel, A 2020, 'High-density geopolymer concrete for Port Kembla breakwater upgrade', Construction and Building Materials, vol. 262, pp. 120920-120920.
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© 2020 Elsevier Ltd Marine environments can pose continuous threats to coastal infrastructure, especially during episodic storm events. Thus, monitoring and maintenance of rock or concrete units-armoured coastal breakwaters are required, especially under present climate change scenarios, where changes in wave behaviour are anticipated and coastal structures are likely to be exposed to even greater wave energy resulting in higher rates of damage. A possible pathway towards the upgrading of existing breakwaters is to introduce high-density armour units, suggested by theoretical estimates and physical model test findings. In this project, a unique, sustainable high-density geopolymer concrete (GPC) mix was developed and trialled in fabricating armour units for upgrading existing coastal breakwaters. The system developed in laboratories was upscaled for field applications and is being tested at the Northern breakwater of NSW Ports’ Port Kembla Harbour. The concrete uses steel furnace slag (SFS) aggregate in an alkali-activated blended fly ash-blast furnace slag binder proportioned to facilitate the elimination of delayed expansion of the aggregate. The concrete properties were measured and microstructural analyses undertaken. The results show that SFS aggregate offers higher bulk density to the concrete alongside satisfactory strength in on-site curing and can reduce armour mass requirements at the same level of structural stability. Microstructural analyses confirm the elimination of SFS aggregate free-lime expansion. This important result provides a novel approach to both repair of existing structures and construction of new structures with reductions to both cost and carbon footprint.
Malisetty, RS, Indraratna, B & Vinod, J 2020, 'Behaviour of ballast under principal stress rotation: Multi-laminate approach for moving loads', Computers and Geotechnics, vol. 125, pp. 103655-103655.
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© 2020 Elsevier Ltd Railway tracks are subjected to millions of loading cycles over time and at high speeds, these moving trains induce dynamic amplification of vertical stresses and rotation of principal stress axes in the track layers. It is important to predict and analyse the behaviour of ballast under these loads with complex stress paths involving principal stress rotation. In this paper, a constitutive model based on a multi-laminate framework is used to predict the deformation and degradation of ballast under complex stress paths. The yield and plastic potential surfaces are developed based on a non-linear critical state and bounding surface plasticity concepts. The proposed model is validated with independent test data to capture the influence of confining stress, loading frequency, Cyclic Stress Ratio (CSR) and Shear Stress Ratio (ητ) on the permanent strain response. Furthermore, the response of ballast under traffic loading stress paths with different CSR and ητ is analysed. These model predictions show that higher CSRand ητ values lead to exacerbated particle breakage of ballast, large and unstable axial strains and dilatant volumetric strains. Furthermore, a stability surface is proposed based on model predictions, to estimate the allowable CSR and ητ for a stable response.
Malisetty, RS, Indraratna, B & Vinod, JS 2020, 'Multilaminate Mathematical Framework for Analyzing the Deformation of Coarse Granular Materials', International Journal of Geomechanics, vol. 20, no. 6, pp. 06020004-06020004.
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© 2020 American Society of Civil Engineers. Coarse granular materials such as railway ballast and rockfill are often subjected to three-dimensional (3D) stress conditions including the influence of intermediate principal stress. Modeling the deformation and breakage of these materials under the presence of intermediate principal stress is important for assessing their long-term performance. This paper presents a mathematical model to describe the mechanical behavior of granular materials incorporating the intermediate principal stress and capture particle breakage. The model formulation encompasses interparticle contact planes using a multilaminate mathematical framework based on generalized plasticity and associated critical state concepts. The model that has been calibrated based on recent experimental data on latite basalt, captures the stress-strain and volumetric strain behavior for a range of confining pressures under triaxial compression. This paper also describes the influence of intermediate principal stress on the strength and deformation response of selected granular materials following 3D stress paths. It is evident from the results that the current modeling technique successfully captured the effects of particle breakage, intermediate principal stress, and confining pressure on the shear behavior of various granular assemblies. The results also highlight the influence of intermediate principal stress in reducing the peak deviatoric strength of the material. The model predictions were validated using four independent sets of past experimental data on crushed basalt, limestone, sandstone, and granite aggregates.
Mannina, G, Ni, B-J, Ferreira Rebouças, T, Cosenza, A & Olsson, G 2020, 'Minimizing membrane bioreactor environmental footprint by multiple objective optimization', Bioresource Technology, vol. 302, pp. 122824-122824.
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This paper presents a modelling study aimed at minimizing the environmental foot print of a membrane bioreactor (MBR) for wastewater treatment. Specifically, an integrated model for MBR was employed in view of the management optimization of an MBR biological nutrient removal (BNR) pilot plant in terms of operational costs and direct greenhouse gases emissions. The influence of the operational parameters (OPs) on performance indicators (PIs) was investigated by adopting the Extended-FAST sensitivity analysis method. Further, a multi-objective analysis was performed by applying the Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS). The results show-up that the sludge retention time is the OP mostly affecting all the investigated PIs. By applying the set of optimal OPs, there was a reduction of 48% and 10% of the operational costs and direct emissions, respectively.
Manzoor, H, Selam, MA, Adham, S, Shon, HK, Castier, M & Abdel-Wahab, A 2020, 'Energy recovery modeling of pressure-retarded osmosis systems with membrane modules compatible with high salinity draw streams', Desalination, vol. 493, pp. 114624-114624.
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McCauley, JI, Labeeuw, L, Jaramillo-Madrid, AC, Nguyen, LN, Nghiem, LD, Chaves, AV & Ralph, PJ 2020, 'Management of Enteric Methanogenesis in Ruminants by Algal-Derived Feed Additives', Current Pollution Reports, vol. 6, no. 3, pp. 188-205.
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© 2020, Springer Nature Switzerland AG. Purpose of Review: In this paper, we critically review the current state of nutritional management strategies to reduce methane emissions resulting from enteric fermentation in livestock production. In this context, it highlights the novel strategy regarding the use of macroalgal- and microalgal-derived feed additives. Recent Findings: Several feed management strategies for ruminants focus on the inclusion of nutritional supplements, increasing proportion of starch, or supplementation with high-energy lipids. These strategies aim to improve animal productivity, whilst at the same time reduce methane emissions. Algae supplements are currently investigated as novel ingredients for decreasing methanogenesis, with the potential production of algal biomass also contributing to reducing greenhouse gas emissions. Thus, utilisation of algal biomass as a feed concentrate in dietary supplementation presents a sustainable and environmentally friendly strategy. Summary: This review summarises the current stage of research on dietary strategies and their influences on the metabolic processes during enteric fermentation. This information is essential for developing strategies to mitigate methane emissions in the livestock industry. We specifically present the opportunities that algae could offer as a feed additive for methanogenic reduction in cattle. The data compiled from the peer-reviewed literature revealed synergistic effects of algal biomass on methane reduction and animal productivity. However, the challenges regarding the mass cultivation of macro- and microalgae were noticed. Considering the diversity of algal species, future research should increase screening efforts to include more species and dosage evaluation, along with efforts to see if such effects are sustained over time.
Medawela, S & Indraratna, B 2020, 'Computational modelling to predict the longevity of a permeable reactive barrier in an acidic floodplain', Computers and Geotechnics, vol. 124, pp. 103605-103605.
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Meena, NK, Nimbalkar, S, Fatahi, B & Yang, G 2020, 'Effects of soil arching on behavior of pile-supported railway embankment: 2D FEM approach', Computers and Geotechnics, vol. 123, pp. 103601-103601.
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Mehrabi, M, Pradhan, B, Moayedi, H & Alamri, A 2020, 'Optimizing an Adaptive Neuro-Fuzzy Inference System for Spatial Prediction of Landslide Susceptibility Using Four State-of-the-art Metaheuristic Techniques', Sensors, vol. 20, no. 6, pp. 1723-1723.
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Four state-of-the-art metaheuristic algorithms including the genetic algorithm (GA), particle swarm optimization (PSO), differential evolutionary (DE), and ant colony optimization (ACO) are applied to an adaptive neuro-fuzzy inference system (ANFIS) for spatial prediction of landslide susceptibility in Qazvin Province (Iran). To this end, the landslide inventory map, composed of 199 identified landslides, is divided into training and testing landslides with a 70:30 ratio. To create the spatial database, thirteen landslide conditioning factors are considered within the geographic information system (GIS). Notably, the spatial interaction between the landslides and mentioned conditioning factors is analyzed by means of frequency ratio (FR) theory. After the optimization process, it was shown that the DE-based model reaches the best response more quickly than other ensembles. The landslide susceptibility maps were developed, and the accuracy of the models was evaluated by a ranking system, based on the calculated area under the receiving operating characteristic curve (AUROC), mean absolute error, and mean square error (MSE) accuracy indices. According to the results, the GA-ANFIS with a total ranking score (TRS) = 24 presented the most accurate prediction, followed by PSO-ANFIS (TRS = 17), DE-ANFIS (TRS = 13), and ACO-ANFIS (TRS = 6). Due to the excellent results of this research, the developed landslide susceptibility maps can be applied for future planning and decision making of the related area.
Meng, Q, Wu, C, Hao, H, Li, J, Wu, P, Yang, Y & Wang, Z 2020, 'Steel fibre reinforced alkali-activated geopolymer concrete slabs subjected to natural gas explosion in buried utility tunnel', Construction and Building Materials, vol. 246, pp. 118447-118447.
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© 2020 Elsevier Ltd Accidental gas explosions in the buried utility tunnels around the world have caused massive losses in economy and human lives. The buried utility tunnel with adequate blast resistance capacity is therefore required to withstand the possible accidental gas explosions. In this study, a novel construction material, alkali-activated steel fibre reinforced geopolymer composite is introduced and the blast resistance capacity of slabs made of this material is studied in a full-scale buried utility tunnel. Fly ash and S95 grade ground granulated blast-furnace slag powder (GGBS) were used as the major binders in this geopolymer concrete. The plain geopolymer concrete had a compressive strength of 61 MPa and the steel fibre reinforced geopolymer concrete had a compressive strength of 74 MPa. The elastic modulus of the plain geopolymer concrete was found to be lower than the conventional C30 concrete. The methane gas explosion test was conducted in a full-scale (12 m × 1.8 m × 0.6 m) tunnel segment to investigate the structural performance of selected slab specimen (1.8 m × 0.4 m × 0.09 m). The test results and numerical simulations of structural responses subjected to methane gas explosion are presented. The results indicate the fibre reinforced geopolymer concrete slab has good capacity to resist methane gas explosion load.
Meng, Q, Wu, C, Li, J, Liu, Z, Wu, P, Yang, Y & Wang, Z 2020, 'Steel/basalt rebar reinforced Ultra-High Performance Concrete components against methane-air explosion loads', Composites Part B: Engineering, vol. 198, pp. 108215-108215.
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© 2020 Elsevier Ltd Ultra-High Performance Concrete (UHPC) is a relatively new construction material, which has been investigated over the past few decades. Despite its exceptional mechanical strength, UHPC still requires passive steel reinforcement to maximise its bending capacity and the overall material cost will be high. The basalt fibre rebar has a higher mechanical strength than steel rebar with lower cost. In addition, it also has better alkali resistance and good cost-effectiveness. The basalt fibre rebar is therefore considered as a potential alternative reinforcement in the structural member. In this study, a recently developed UHPC formula was adopted, the conventional steel rebar and basalt fibre rebar were used as reinforcement. The developed components were tested against static flexural and methane-air explosion loads. In the four-point flexural tests, the basalt fibre rebar reinforced specimen (400 mm × 100 mm × 100 mm) performed more ductile structural behaviour with higher flexural strength. Two large scale methane-air explosion tests were conducted in buried utility tunnels with different length (i.e., 12000 mm × 1800 mm × 600 mm and 20000 mm × 1800 mm × 600 mm). The experimental test in shorter tunnel yielded lower explosion pressure [1] with marginal structural response. The test in longer tunnel achieved a higher explosion pressure on concrete elements. The C30 and UHPC specimens (1800 mm × 400 mm × 90 mm) with steel/basalt fibre rebar reinforcement were tested. The pressure and deflection data revealed that basalt fibre rebar reinforced UHPC component had a more ductile structural behaviour against accidental gas explosion.
Messaoud, M, Trabelsi, F, Kumari, P, Merenda, A & Dumée, LF 2020, 'Recrystallization and coalescence kinetics of TiO2 and ZnO nano-catalysts towards enhanced photocatalytic activity and colloidal stability within slurry reactors', Materials Chemistry and Physics, vol. 252, pp. 123235-123235.
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Advanced oxidation processes rely on the development of stable photocatalytic materials, offering specific band-gap attained upon reaching appropriate crystalline phases. A key research gap is related to the recrystallization of nano-catalysts and their impact on performance. This paper describes the systematic preparation of TiO2 and ZnO nanoparticles by hydrothermal-assisted sol-gel method followed by systematic calcination steps with the aim to shed light on the recrystallization process to engineer higher photocatalytic activity. Spherical anatase-TiO2 nanoparticles with a 20 nm diameter size present higher photocatalytic activity than 70 nm of ZnO NPs calcined at 500 °C. A photocatalytic yield of 84% within 30 min of irradiation for the degradation of model dyes was observed for the titania particles, which were also less sensitive to a gglomeration, a key challenge when designing slurry reactors. The variation in zeta potential of TiO2 and ZnO with pH exhibited isoelectric points (IEP) in aqueous media at 5.1 and 6.5, respectively, suggesting amphoteric behaviors while X ray photo-electron spectroscopy and diffusive reflectance spectroscopy data were used to characterize the changes in surface vacancies and the band gap of the materials. These data open the door to the development of advanced oxidation processes in complex industrial environments.
Mi, Y, Liu, Z, Wang, W, Yang, Y & Wu, C 2020, 'Experimental study on residual axial bearing capacity of UHPFRC-filled steel tubes after lateral impact loading', Structures, vol. 26, pp. 549-561.
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Mishra, B, Varjani, S, Agrawal, DC, Mandal, SK, Ngo, HH, Taherzadeh, MJ, Chang, J-S, You, S & Guo, W 2020, 'Engineering biocatalytic material for the remediation of pollutants: A comprehensive review', Environmental Technology & Innovation, vol. 20, pp. 101063-101063.
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Mishra, B, Varjani, S, Pradhan, I, Ekambaram, N, Teixeira, JA, Ngo, HH & Guo, W 2020, 'Insights into Interdisciplinary Approaches for Bioremediation of Organic Pollutants: Innovations, Challenges and Perspectives', Proceedings of the National Academy of Sciences, India Section B: Biological Sciences, vol. 90, no. 5, pp. 951-958.
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© 2020, The National Academy of Sciences, India. Modern industrialization has originated a tremendous industrial growth. Discharge of industrial effluent is a critical threat to a safe environment. Removal of various pollutants from industrial wastewater is obligatory for controlling environmental pollution. Bioremediation using biotechnological interventions has attracted greater attention among the researchers in the field of control and abatement of environmental pollution. This review is aimed to introduce methods for bioremediation on the removal of organic pollutants from industrial wastewater that have been discussed, and the kinetic models that are related to it have been introduced. In addition, biotechnological interventions on bioremediation of pollutants have been discussed fingerprinting of microbial sp. present at polluted sites. Microbial electrochemical technologies such as a green technology for the removal of pollutants from industrial effluents and simultaneous resource recovery from industrial waste have been discussed to generate up-to-date scientific literature. This review also provides detailed knowledge gaps, challenges and research perspectives related to the topic.
Mishra, PN, Zhang, Y, Bhuyan, MH & Scheuermann, A 2020, 'Anisotropy in volume change behaviour of soils during shrinkage', Acta Geotechnica, vol. 15, no. 12, pp. 3399-3414.
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Moayedi, H, Mehrabi, M, Bui, DT, Pradhan, B & Foong, LK 2020, 'Fuzzy-metaheuristic ensembles for spatial assessment of forest fire susceptibility', Journal of Environmental Management, vol. 260, pp. 109867-109867.
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Forests are important dynamic systems which are widely affected by fire worldwide. Due to the complexity and non-linearity of the forest fire problem, employing hybrid evolutionary algorithms is a logical task to achieve a reliable approximation of this environmental threat. Three fuzzy-metaheuristic ensembles, based on adaptive neuro-fuzzy inference systems (ANFIS) incorporated with genetic algorithm (GA), particle swarm optimization (PSO), and differential evolution (DE) evolutionary algorithms are used to produce the forest fire susceptibility map (FFSM) of a fire-prone region in Iran. A sensitivity analysis is also executed to evaluate the effectiveness of the proposed ensembles in terms of time and complexity. The results revealed that all models produce FFSMs with acceptable accuracy. However, the superiority of the GA-ANFIS was shown in both recognizing the pattern (AUROCtrain = 0.912 and Error = 0.1277) and predicting unseen fire events (AUROCtest = 0.850 and Error = 0.1638). The optimized structures of the proposed GA-ANFIS and PSO-ANFIS ensembles could be good alternatives to traditional forest fire predictive models, and their FFSMs can be promisingly used for future planning and decision making in the proposed area.
Mofijur, M, Kusumo, F, Fattah, IMR, Mahmudul, HM, Rasul, MG, Shamsuddin, AH & Mahlia, TMI 2020, 'Resource Recovery from Waste Coffee Grounds Using Ultrasonic-Assisted Technology for Bioenergy Production', Energies, vol. 13, no. 7, pp. 1770-1770.
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Biodiesel is a proven alternative fuel that can serve as a substitute for petroleum diesel due to its renewability, non-toxicity, sulphur-free nature and superior lubricity. Waste-based non-edible oils are studied as potential biodiesel feedstocks owing to the focus on the valorisation of waste products. Instead of being treated as municipal waste, waste coffee grounds (WCG) can be utilised for oil extraction, thereby recovering an energy source in the form of biodiesel. This study evaluates oil extraction from WCG using ultrasonic and Soxhlet techniques, followed by biodiesel conversion using an ultrasonic-assisted transesterification process. It was found that n-hexane was the most effective solvent for the oil extraction process and ultrasonic-assisted technology offers a 13.5% higher yield compared to the conventional Soxhlet extraction process. Solid-to-solvent ratio and extraction time of the oil extraction process from the dried waste coffee grounds (DWCG) after the brewing process was optimised using the response surface methodology (RSM). The results showed that predicted yield of 17.75 wt. % of coffee oil can be obtained using 1:30 w/v of the mass ratio of DWCG-ton-hexane and 34 min of extraction time when 32% amplitude was used. The model was verified by the experiment where 17.23 wt. % yield of coffee oil was achieved when the extraction process was carried out under optimal conditions. The infrared absorption spectrum analysis of WCG oil determined suitable functional groups for biodiesel conversion which was further treated using an ultrasonic-assisted transesterification process to successfully convert to biodiesel.
Mofijur, M, Rizwanul Fattah, IM, Saiful Islam, ABM, Uddin, MN, Ashrafur Rahman, SM, Chowdhury, MA, Alam, MA & Uddin, MA 2020, 'Relationship between Weather Variables and New Daily COVID-19 Cases in Dhaka, Bangladesh', Sustainability, vol. 12, no. 20, pp. 8319-8319.
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The present study investigated the relationship between the transmission of COVID-19 infections and climate indicators in Dhaka, Bangladesh, using coronavirus infections data available from the Institute of Epidemiology, Disease Control and Research (IEDCR), Bangladesh. The Spearman rank correlation test was carried out to study the association of seven climate indicators, including humidity, air quality, minimum temperature, precipitation, maximum temperature, mean temperature, and wind speed with the COVID-19 outbreak in Dhaka, Bangladesh. The study found that, among the seven indicators, only two indicators (minimum temperature and average temperature) had a significant relationship with new COVID-19 cases. The study also found that air quality index (AQI) had a strong negative correlation with cumulative cases of COVID-19 in Dhaka city. The results of this paper will give health regulators and policymakers valuable information to lessen the COVID-19 spread in Dhaka and other countries around the world.
Mojiri, A, Zhou, J, Vakili, M & Van Le, H 2020, 'Removal performance and optimisation of pharmaceutical micropollutants from synthetic domestic wastewater by hybrid treatment', Journal of Contaminant Hydrology, vol. 235, pp. 103736-103736.
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Occurrence of pharmaceutical micropollutants in aquatic environments has been one amongst serious environmental problems. During this study, two reactors, including a sequencing batch reactor (SBR) + powdered composite adsorbent (CA) (first reactor, SBR + CA) and a sequencing batch reactor (second reactor, SBR), were designed to treat synthetic wastewater. Powdered CA was added with a dosage of 4.8 g L-1 to the first reactor. Tap water was contaminated with chemical oxygen demand (COD), ammonia and three pharmaceuticals, namely, atenolol (ATN), ciprofloxacin (CIP) and diazepam (DIA) to produce synthetic wastewater. The SBR + CA illustrated a better performance during synthetic municipal wastewater treatment. Up to 138.6 mg L-1 (92.4%) of COD and up to 114.2 mg L-1 (95.2%) of ammonia were removed by the first reactor. Moreover, optimisation of pharmaceuticals removal was conducted through response surface methodology (RSM) and artificial neural network (ANN). Based on the RSM, the best elimination of ATN (90.2%, 2.26 mg L-1), CIP (94.0%, 2.35 mg L-1) and DIA (95.5%, 2.39 mg L-1) was detected at the optimum initial concentration of MPs (2.51 mg L-1) and the contact time (15.8 h). In addition, ANN represented a high R2 value (>0.99) and a rational mean squared error (<1.0) during the optimisation of micropollutants removal by both reactors. Moreover, adsorption isotherm study showed that the Freundlich isotherm could justify the abatement of micropollutants by using CA better than the Langmuir isotherm.
Mojiri, A, Zhou, JL, Robinson, B, Ohashi, A, Ozaki, N, Kindaichi, T, Farraji, H & Vakili, M 2020, 'Pesticides in aquatic environments and their removal by adsorption methods', Chemosphere, vol. 253, pp. 126646-126646.
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Although pesticides are widely used in agriculture, industry and households, they pose a risk to human health and ecosystems. Based on target organisms, the main types of pesticides are herbicides, insecticides and fungicides, of which herbicides accounted for 46% of the total pesticide usage worldwide. The movement of pesticides into water bodies occurs through run-off, spray drift, leaching, and sub-surface drainage, all of which have negative impacts on aquatic environments and humans. We sought to define the critical factors affecting the fluxes of contaminants into receiving waters. We also aimed to specify the feasibility of using sorbents to remove pesticides from waterways. In Karun River in Iran (1.21 × 105 ng/L), pesticide concentrations are above regulatory limits. The concentration of pesticides in fish can reach 26.1 × 103 μg/kg, specifically methoxychlor herbicide in Perca fluviatilis in Lithuania. During the last years, research has focused on elimination of organic pollutants, such as pesticides, from aqueous solution. Pesticide adsorption onto low-cost materials can effectively remediate contaminated waters. In particular, nanoparticle adsorbents and carbon-based adsorbents exhibit high performance (nearly 100%) in removing pesticides from water bodies.
Mong, GR, Chong, CT, Ng, J-H, Chong, WWF, Lam, SS, Ong, HC & Ani, FN 2020, 'Microwave pyrolysis for valorisation of horse manure biowaste', Energy Conversion and Management, vol. 220, pp. 113074-113074.
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© 2020 Elsevier Ltd Biomass-based feedstock is an attractive alternative to fossil fuel due to its sustainability and potential as a clean energy source. The present work focuses on the valorisation of horse manure biowaste to produce bioenergy via microwave-assisted pyrolysis technique. The thermal decomposition process is conducted by considering the effects of pyrolysis temperature, catalyst loading and carrier gas flow rate on the yield and quality of end products. The pyrolysed gaseous product contains up to 73.1 vol% of syngas components. The solid biochar obtained contains a heating value of 35.5 MJ/kg with high surface to pore volume ratio. The relatively high specific energy contents of gaseous products and biochar indicate their potential as biofuels. The liquid product is found to contain oxygenated phenolic compound of up to 79.4 wt%. In spite of an overall energy deficit achieved when comparing the total energy of end products with the feedstock, the energy balance analysis indicates the optimum production parameters. The least energy deficit is achieved at the reactive conditions of 350–450 °C and manure-to-catalyst ratio of 1:1. A reaction mechanism pathway for the pyrolysis of horse manure is presented to show the production route for bioenergy and valuable chemicals.
Moon, DH, Chung, WJ, Chang, SW, Lee, SM, Kim, SS, Jeung, JH, Ro, YH, Ahn, JY, Guo, W, Ngo, HH & Nguyen, DD 2020, 'Fabrication and characterization of Ni-Ce-Zr ternary disk-shaped catalyst and its application for low-temperature CO2 methanation', Fuel, vol. 260, pp. 116260-116260.
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Mortazavi, M, Sharafi, P, Kildashti, K & Samali, B 2020, 'Prefabricated hybrid steel wall panels for mid-rise construction in seismic regions', Journal of Building Engineering, vol. 27, pp. 100942-100942.
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Mujtaba, MA, Kalam, MA, Masjuki, HH, Gul, M, Soudagar, MEM, Ong, HC, Ahmed, W, Atabani, AE, Razzaq, L & Yusoff, M 2020, 'Comparative study of nanoparticles and alcoholic fuel additives-biodiesel-diesel blend for performance and emission improvements', Fuel, vol. 279, pp. 118434-118434.
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© 2020 Elsevier Ltd This study aims to investigate a CI diesel engine characteristic of diesel-biodiesel blend with oxygenated alcohols and nanoparticle fuel additives. Biodiesel was synthesized from a complementary palm-sesame oil blend using an ultrasound-assisted transesterification process. B30 was mixed with fuel additives as the base fuel to form ternary blends in different proportions before engine testing. The oxygenated alcohols (DMC and DEE) and nanoparticles (CNT and TiO2) were used to improve both the fuel characteristics and engine emission and performance parameters. B30 fuel was mixed with 5% (DEE) and 10% (DMC) by volume and 100 ppm concentration of CNT and TiO2 nanoparticles, respectively, which are kept constant during this study. Engine performance and emissions characteristics were studied using a CI diesel engine with variable engine rpm at full load condition. The results were compared with B30 fuel and B10 (commercial diesel). The main findings indicated that the B30 + TiO2 ternary blend shows an overall decrease in brake specific fuel consumption up to 4.1% among all tested fuels. B30 + DMC produced a higher 9.88% brake thermal efficiency, among other fuels. B30 + DMC ternary blend showed a maximum decrease in CO and HC emissions by 29.9% and 21.4%, respectively, collated to B30. B30 + CNT ternary blend showed a maximum reduction of 3.92% in NOx emissions compared to B30.
Mujtaba, MA, Masjuki, HH, Kalam, MA, Noor, F, Farooq, M, Ong, HC, Gul, M, Soudagar, MEM, Bashir, S, Rizwanul Fattah, IM & Razzaq, L 2020, 'Effect of Additivized Biodiesel Blends on Diesel Engine Performance, Emission, Tribological Characteristics, and Lubricant Tribology', Energies, vol. 13, no. 13, pp. 3375-3375.
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This research work focuses on investigating the lubricity and analyzing the engine characteristics of diesel–biodiesel blends with fuel additives (titanium dioxide (TiO2) and dimethyl carbonate (DMC)) and their effect on the tribological properties of a mineral lubricant. A blend of palm–sesame oil was used to produce biodiesel using ultrasound-assisted transesterification. B30 (30% biodiesel + 70% diesel) fuel was selected as the base fuel. The additives used in the current study to prepare ternary fuel blends were TiO2 and DMC. B30 + TiO2 showed a significant reduction of 6.72% in the coefficient of friction (COF) compared to B30. B10 (Malaysian commercial diesel) exhibited very poor lubricity and COF among all tested fuels. Both ternary fuel blends showed a promising reduction in wear rate. All contaminated lubricant samples showed an increment in COF due to the dilution of combustible fuels. Lub + B10 (lubricant + B10) showed the highest increment of 42.29% in COF among all contaminated lubricant samples. B30 + TiO2 showed the maximum reduction (6.76%) in brake-specific fuel consumption (BSFC). B30 + DMC showed the maximum increment (8.01%) in brake thermal efficiency (BTE). B30 + DMC exhibited a considerable decline of 32.09% and 25.4% in CO and HC emissions, respectively. The B30 + TiO2 fuel blend showed better lubricity and a significant improvement in engine characteristics.
Mujtaba, MA, Masjuki, HH, Kalam, MA, Ong, HC, Gul, M, Farooq, M, Soudagar, MEM, Ahmed, W, Harith, MH & Yusoff, MNAM 2020, 'Ultrasound-assisted process optimization and tribological characteristics of biodiesel from palm-sesame oil via response surface methodology and extreme learning machine - Cuckoo search', Renewable Energy, vol. 158, pp. 202-214.
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© 2020 Elsevier Ltd The purpose of this study was the improvement of cold flow and lubricity characteristics of biodiesel produced from the palm-sesame oil blend. Extreme learning machine (ELM) and response surface methodology (RSM) techniques were used to model the production process and the input variables (time, catalyst amount, methanol to oil ratio, and duty cycle) were optimized using cuckoo search algorithm. The mean absolute percentage error (MAPE), coefficient of determination (R2), mean square error (MSE), root mean square error (RMSE), and standard error of prediction (SEP) were calculated to evaluate the performance of RSM and ELM. The results showed that ELM model had better performance in prediction than RSM model. The optimum yield of P50S50 biodiesel obtained was 96.6138% under operating parameters of time (38.96 min), duty cycle (59.52%), methanol to oil ratio (60 V/V %) and catalyst amount (0.70 wt%). The cold flow characteristics of P50S50 biodiesel are significantly improved like cloud point (7.89 °C), pour point (3.80 °C), and cold filter plugging point (- 1.77 °C) with better oxidation stability 6.89 h. The average coefficient of friction P50S50 biodiesel was lower than palm biodiesel (B100) and B10 commercial diesel by 2.29% and 12.37% respectively.
Mujtaba, MA, Muk Cho, H, Masjuki, HH, Kalam, MA, Ong, HC, Gul, M, Harith, MH & Yusoff, MNAM 2020, 'Critical review on sesame seed oil and its methyl ester on cold flow and oxidation stability', Energy Reports, vol. 6, pp. 40-54.
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© 2019 The demand for renewable energy is steadily increasing due to rapid population growth and economic development worldwide. An additional reason is that fossil fuel reserves are limited, and this situation results in their non-uniform availability globally. Furthermore, the attitudes of the society, energy policies and technology choices are constantly changing. Thus, renewable energy resources are now considered good alternatives to fossil fuels. In the meantime, liquid energy, such as methyl ester from locally produced vegetable oils, is well accepted by many countries, even though it is currently being blended up to 20% with petroleum fuels. Recently, the industrialisation of biodiesel is a major problem because of its poor cold flow properties and oxidative stability. Vegetable oils are also being blended in an appropriate proportion before transesterification to obtain the desired properties in biodiesel. Similarly, poor cold flow properties and oxidative stability can be improved by choosing suitable vegetable oils for making blends. Amongst all available vegetable oils, sesame seed oil (SSO) has unique cold flow properties and oxidation stability, particularly because of naturally occurring antioxidants and preservatives, which enhance the stability of oil towards rancidity. Therefore, SSO can be used as a potential feedstock for blending with other vegetable oils to enhance the overall cold flow and oxidation stability properties. This overview summarises sesame cultivation, SSO production, the physicochemical properties of SSO and its potential as an alternative renewable fuel source. In this review, the physicochemical properties of sesame biodiesel are compared with those of biodiesel derived from other vegetable oils. Results show that blending SSO with palm oil before transesterification will successfully improve the cold flow properties and oxidation stability of palm methyl ester (biodiesel).
Munadi, K, Muchtar, K, Maulina, N & Pradhan, B 2020, 'Image Enhancement for Tuberculosis Detection Using Deep Learning', IEEE Access, vol. 8, pp. 217897-217907.
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Muniyasamy, A, Sivaporul, G, Gopinath, A, Lakshmanan, R, Altaee, A, Achary, A & Velayudhaperumal Chellam, P 2020, 'Process development for the degradation of textile azo dyes (mono-, di-, poly-) by advanced oxidation process - Ozonation: Experimental & partial derivative modelling approach', Journal of Environmental Management, vol. 265, pp. 110397-110397.
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Naghibi, SA, Vafakhah, M, Hashemi, H, Pradhan, B & Alavi, SJ 2020, 'Water Resources Management Through Flood Spreading Project Suitability Mapping Using Frequency Ratio, k-nearest Neighbours, and Random Forest Algorithms', Natural Resources Research, vol. 29, no. 3, pp. 1915-1933.
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Naidu, G, Tijing, L, Johir, MAH, Shon, H & Vigneswaran, S 2020, 'Hybrid membrane distillation: Resource, nutrient and energy recovery', Journal of Membrane Science, vol. 599, pp. 117832-117832.
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© 2020 Elsevier B.V. Membrane distillation (MD) is a promising alternative thermal-based membrane process that can achieve high-quality freshwater across various impaired water sources. However, the performance of MD as a stand-alone system remains a challenge for attaining commercialization. Hybrid MD - the integration of MD with other processes, offers a practical approach for performance enhancement as well as the possibility to achieve valuable resource recovery. This review details the performance and related challenges of various hybrid MD systems with a focus on resource recovery. On the basis of recovering valuable salt/element from impaired water sources, hybrid MD-crystallizer is limited to the recovery of major salts. Comparatively, MD-adsorbent exhibits potential for selectively recovering valuable elements, which may offset treatment cost. Meanwhile, hybrid MD-bioreactor (MDBR) and MD-forward osmosis (MD-FO) are especially favorable combinations for attaining water reclamation from the wastewater industry and recovering nutrients and biogas that mitigates environmental pollution. Simultaneous recovery of water and energy can be attained with hybrid MD-pressure retarded osmosis (MD-PRO) and MD-reverse electrodialysis (MD-RED). Overall, this review highlights the favorable potential of hybrid MD for recovering resources in niche applications. Future suggestions for improving hybrid MD are discussed, specifically pilot-scale application, module configuration and membrane development.
Nakagawa, K, Uchida, K, Wu, JLC, Shintani, T, Yoshioka, T, Sasaki, Y, Fang, L-F, Kamio, E, Shon, HK & Matsuyama, H 2020, 'Fabrication of porous polyketone forward osmosis membranes modified with aromatic compounds: Improved pressure resistance and low structural parameter', Separation and Purification Technology, vol. 251, pp. 117400-117400.
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Nasser, A, Castel, A & Merimi, I 2020, 'Influence of steel-concrete interface and pre-existing oxides layer on passive reinforcing steel corrosion', ARPN Journal of Engineering and Applied Sciences, vol. 15, no. 15, pp. 1622-1631.
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This paper deals with the influence of the steel-concrete interface quality and preexisting oxides layer on reinforcement corrosion in passive state. In passive state, steel corrosion rate in concrete is considered null for conventional civil engineering structures due to the relatively short design service life time. On the contrary, for the nuclear waste facilities, due to a very long design life time, this low corrosion rate can become a risk. Previous studies, dealing with chloride induced steel corrosion in concrete, have clearly shown that the quality of the steel-concrete interface is a predominant factor for corrosion propagation. The purpose of this work is to study the influence of steel-concrete interface defaults and preexisting oxides layer on steel passivity and the consequences on the corrosion rate. Electrochemical methods and destructive surface analysis techniques were used to assess the corrosion rate of the embedded steel bars. Results confirm that the quality of the steel-concrete interface and the preexisting oxides layer affect the steel corrosion rate in passive state.
Navaratnarajah, SK & Indraratna, B 2020, 'Stabilisation of Stiffer Rail Track Substructure Using Artificial Inclusion', Indian Geotechnical Journal, vol. 50, no. 2, pp. 196-203.
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© 2020, Indian Geotechnical Society. The railway transport system in many countries plays a significant role in the passage of bulk freight and passengers. However, increased train speeds and higher freight loads (large dynamic wheel loads) accelerate the deterioration of rail track substructure. This problem is more critical in isolated rail track locations where the track substructure is much stiffer than the regular surface track assembly such as track at the bridges and tunnels. Ballast is a key track foundation material placed underneath the sleepers which provides structural support against high cyclic and impact stresses caused by moving trains. Inclusion of rubber mats called under ballast mats (UBMs) placed between the ballast and stiffer base layer is one of the measures to minimise the ballast deterioration. In this study, cyclic loads representing fast and heavy haul trains were simulated on stiffer track foundation condition using a large-scale process simulation prismoidal triaxial apparatus to investigate the mitigation of strain, stress and degradation characteristics of ballast stabilised with UBM. These UBMs were locally manufactured from recycled tyre wastes. The results show that ballast on a stiff foundation substructure stabilised with UBM experienced significantly less vertical and lateral deformation, ballast interface and inter-particle stresses and degradation. This study also confirmed that the recycled tyre UBMs used in this study had adequate damping to absorb the energy transmitted to the moving train to the track, thus preventing excessive plastic deformation and degradation of the ballast layer.
Ngo, T & Indraratna, B 2020, 'Analysis of Deformation and Degradation of Fouled Ballast: Experimental Testing and DEM Modeling', International Journal of Geomechanics, vol. 20, no. 9, pp. 06020020-06020020.
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© 2020 American Society of Civil Engineers. The deformation and degradation of fouled ballast have been examined by large-scale triaxial tests and discrete element modeling (DEM) to understand how clay fouling changes the shear strength and micromechanical aspects of ballast. Particle shape analysis using 3D aggregate imaging and a laser scanner is introduced to construct more realistic polyhedral discrete elements that will represent natural ballast particles. Shear stress-strain and volumetric changes of fresh and clay-fouled ballast are analyzed. Micromechanical analysis of the fouled ballast is carried out and the effects of fines are quantified by considering the changes of ballast breakage, particle connectivity number Cn, and the associated distribution of contact forces that could not be measured experimentally. These findings enable a more insightful understanding of the load-deformation of fouled ballast from a micromechanical perspective.
Ngo, T & Indraratna, B 2020, 'Mitigating ballast degradation with under-sleeper rubber pads: Experimental and numerical perspectives', Computers and Geotechnics, vol. 122, pp. 103540-103540.
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© 2020 Elsevier Ltd This paper presents a study on mitigating the degradation of ballast by placing an under-sleeper rubber pad (USP) beneath a sleeper. Large-scale track process simulation apparatus (TPSA) tests have been carried out on ballast assemblies (with and without USP) subjected to cyclic loadings. Numerical modelling has been performed using a coupled discrete-continuum modelling (coupled DEM-FDM) approach to investigate the role of USP from a micromechanical perspective. Ballast grains are simulated in DEM by bonding of many cylinders together at appropriate sizes and locations; and when those bonds break, they are considered to represent ballast breakage. The capping and subgrade layers are simulated as continuum media using the finite difference method (FDM). Interface elements were developed for transmitting forces and displacements between the discrete and continuum domains. The coupled model is validated by comparing the predicted load-deformation responses with those measured from large-scale TPSA tests. The model is then used to explore changes in the micromechanical aspects of ballast subjected to cyclic loading, including particle connectivity number, contact force distributions, and contact orientations and associated particle breakage. These findings are needed to gain a better insight as to how USPs help to attenuate the load applied in a ballast assembly.
Ngoc, TP, Fatahi, B, Khabbaz, H & Sheng, D 2020, 'Impacts of matric suction equalization on small strain shear modulus of soils during air drying', Canadian Geotechnical Journal, vol. 57, no. 12, pp. 1982-1997.
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In this study, a weight-control bender element system has been developed to investigate the impact of matric suction equalization on the measurement of small strain shear modulus (Gmax) during an air-drying process. The setup employed is capable of measuring the shear wave velocity and the corresponding Gmax of the soil sample in either an open system in which the soil sample evaporates freely or in a closed system that allows the process of matric suction equalization. The comparison between measurements of Gmax in the open and closed systems revealed underestimations of Gmax when matric suction equalization was ignored due to the nonuniform distribution of water content across the sample cross-sectional area. This study also investigated the time required for matric suction equalization tse to be established for samples with different sizes. The experimental results indicated two main mechanisms driving the matric suction equalization in a closed system during an air-drying process, namely the hydraulic flow of water and the flow of vapour. While the former played the key role when the micropores were still saturated at the high range of water content, effects of the latter increased and finally dominated when more air invaded the micropores at lower water contents.
Nguyen, AQ, Nguyen, LN, Johir, MAH, Ngo, H-H, Chaves, AV & Nghiem, LD 2020, 'Derivation of volatile fatty acid from crop residues digestion using a rumen membrane bioreactor: A feasibility study', Bioresource Technology, vol. 312, pp. 123571-123571.
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Nguyen, DM, Ding, G & Runeson, G 2020, 'Energy and economic analysis of environmental upgrading of existing office buildings', Construction Economics and Building, vol. 20, no. 4, pp. 82-102.
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Over many decades, buildings have been recognised as a significant area contributing to the negative impacts on the environment over their lifecycle, accelerating climate change. In return, climate change also impacts on buildings with extreme heatwaves occurring more frequently and raising the earth’s temperature. The operation phase is the most extended period over a building’s lifespan. In this period, office buildings consume most energy and emit the highest amount of greenhouse gas pollution into the environment. Building upgrading to improve energy efficiency seems to be the best way to cut pollution as the existing building stock is massive. The paper presents an economic analysis of energy efficiency upgrade of buildings with a focus of office buildings. The paper identifies upgrading activities that are commonly undertaken to upgrade energy efficiency of office buildings and a case study of three office buildings in Sydney, Australia has been used to analyse the results. The upgrading activities can improve the energy performance of the case study buildings from 3 stars to 5 stars NABERS energy rating in compliance with the mandatory requirement in the Australian government’s energy policy. With the potential increase in energy price, energy efficiency upgrading will become more affordable, but currently, most of them, except solar panels and motion sensors show a negative return and would not be undertaken if they did not also contribute to higher rental income and an increased life span of the building. The upgrading discussed in the paper represent a potentially attractive alternative to demolition and building anew.
Nguyen, HC, Ong, HC, Pham, TTT, Dinh, TKK & Su, C 2020, 'Microwave‐mediated noncatalytic synthesis of ethyl levulinate: A green process for fuel additive production', International Journal of Energy Research, vol. 44, no. 3, pp. 1698-1708.
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Nguyen, HC, Wang, F-M, Dinh, KK, Pham, TT, Juan, H-Y, Nguyen, NP, Ong, HC & Su, C-H 2020, 'Microwave-Assisted Noncatalytic Esterification of Fatty Acid for Biodiesel Production: A Kinetic Study', Energies, vol. 13, no. 9, pp. 2167-2167.
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This study developed a microwave-mediated noncatalytic esterification of oleic acid for producing ethyl biodiesel. The microwave irradiation process outperformed conventional heating methods for the reaction. A highest reaction conversion, 97.62%, was achieved by performing esterification with microwave irradiation at a microwave power of 150 W, 2:1 ethanol:oleic acid molar ratio, reaction time of 6 h, and temperature of 473 K. A second-order reaction model (R2 of up to 0.997) was established to describe esterification. The reaction rate constants were promoted with increasing microwave power and temperature. A strong linear relation of microwave power to pre-exponential factors was also established, and microwave power greatly influenced the reaction due to nonthermal effects. This study suggested that microwave-assisted noncatalytic esterification is an efficient approach for biodiesel synthesis.
Nguyen, LN, Commault, AS, Kahlke, T, Ralph, PJ, Semblante, GU, Johir, MAH & Nghiem, LD 2020, 'Genome sequencing as a new window into the microbial community of membrane bioreactors – A critical review', Science of The Total Environment, vol. 704, pp. 135279-135279.
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Recent developed sequencing techniques have resulted in a new and unprecedented way to study biological wastewater treatment, in which most organisms are uncultivable. This review provides (i) an insight on state-of-the-art sequencing techniques and their limitations; (ii) a critical assessment of the microbial community in biological reactor and biofouling layer in a membrane bioreactor (MBR). The data from high-throughput sequencing has been used to infer microbial growth conditions and metabolisms of microorganisms present in MBRs at the time of sampling. These data shed new insight to two fundamental questions about a microbial community in the MBR process namely the microbial composition (who are they?) and the functions of each specific microbial assemblage (what are their function?). The results to date also highlight the complexity of the microbial community growing on MBRs. Environmental conditions are dynamic and diverse, and can influence the diversity and structural dynamics of any given microbial community for wastewater treatment. The benefits of understanding the structure of microbial communities on three major aspects of the MBR process (i.e. nutrient removal, biofouling control, and micropollutant removal) were symmetrically delineated. This review also indicates that the deployment of microbial community analysis for a practical engineering context, in terms of process design and system optimization, can be further realized.
Nguyen, LN, Truong, MV, Nguyen, AQ, Johir, MAH, Commault, AS, Ralph, PJ, Semblante, GU & Nghiem, LD 2020, 'A sequential membrane bioreactor followed by a membrane microalgal reactor for nutrient removal and algal biomass production', Environmental Science: Water Research & Technology, vol. 6, no. 1, pp. 189-196.
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A hybrid process combining a single compartment aerobic membrane bioreactor (MBR) and a membrane microalgal reactor (MMR) was evaluated for nutrient removal and microalgal biomass production.
Nguyen, LN, Vu, MT, Johir, MAH, Pathak, N, Zdarta, J, Jesionowski, T, Semblante, GU, Hai, FI, Khanh Dieu Nguyen, H & Nghiem, LD 2020, 'A Novel Approach in Crude Enzyme Laccase Production and Application in Emerging Contaminant Bioremediation', Processes, vol. 8, no. 6, pp. 648-648.
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Laccase enzyme from white-rot fungi is a potential biocatalyst for the oxidation of emerging contaminants (ECs), such as pesticides, pharmaceuticals and steroid hormones. This study aims to develop a three-step platform to treat ECs: (i) enzyme production, (ii) enzyme concentration and (iii) enzyme application. In the first step, solid culture and liquid culture were compared. The solid culture produced significantly more laccase than the liquid culture (447 vs. 74 µM/min after eight days), demonstrating that white rot fungi thrived on a solid medium. In the second step, the enzyme was concentrated 6.6 times using an ultrafiltration (UF) process, resulting in laccase activity of 2980 µM/min. No enzymatic loss due to filtration and membrane adsorption was observed, suggesting the feasibility of the UF membrane for enzyme concentration. In the third step, concentrated crude enzyme was applied in an enzymatic membrane reactor (EMR) to remove a diverse set of ECs (31 compounds in six groups). The EMR effectively removed of steroid hormones, phytoestrogen, ultraviolet (UV) filters and industrial chemical (above 90%). However, it had low removal of pesticides and pharmaceuticals.
Nguyen, NC, Duong, HC, Nguyen, HT, Chen, S-S, Le, HQ, Ngo, HH, Guo, W, Duong, CC, Le, NC & Bui, XT 2020, 'Forward osmosis–membrane distillation hybrid system for desalination using mixed trivalent draw solution', Journal of Membrane Science, vol. 603, pp. 118029-118029.
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Nguyen, QD & Castel, A 2020, 'Reinforcement corrosion in limestone flash calcined clay cement-based concrete', Cement and Concrete Research, vol. 132, pp. 106051-106051.
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© 2020 Elsevier Ltd Limestone calcined clay cement (LC3) concrete has attracted world-wide attention as a newly promising low-carbon concrete. In this study, long-term reinforcement corrosion in LC3 concrete was investigated. Both chloride and carbonation-induced reinforcing bar corrosion were examined. Open circuit corrosion potential, polarization resistance, Tafel constants were monitored at regular intervals up to 500 days. Gravimetric mass loss was measured and compared to the loss of mass calculated using electrochemical methods. The performance of concrete with flash calcined clay and limestone was similar to that of traditional Portland cement concrete in long-term investigation. Traditional corrosion methods and classifications used widely to assess of steel in concrete can be applied to concrete containing LC3 providing a recalibration of polarization resistance range for passitivity condition.
Nguyen, QD, Afroz, S & Castel, A 2020, 'Influence of Calcined Clay Reactivity on the Mechanical Properties and Chloride Diffusion Resistance of Limestone Calcined Clay Cement (LC3) Concrete', Journal of Marine Science and Engineering, vol. 8, no. 5, pp. 301-301.
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Calcined clay plays an important role in the performance of limestone calcined clay cement (LC3) concrete. In this study, the performance of two different types of calcined clay produced from different calcination processes were investigated in chloride environment. The characteristics of the calcined clays, including mineral composition, chemical composition, particle size distribution, specific surface area and particle morphology, were evaluated. Based on the reactivity of the calcined clays, the compressive strength of concretes after up to 28 days of curing was adopted as the best measure to determine the appropriate replacement levels of Portland cement by LC3 to satisfy standards requirements for concrete in chloride environments. The chloride bulk diffusion test was conducted to investigate the performance of LC3 concretes in comparison with reference Portland cement concrete. Similar chloride diffusion resistance could be achieved by using the two different calcined clays in LC3 concrete. The performance of both LC3 concretes was much better than that of reference concrete. However, the Portland cement substitution rate for each calcined clay was governed by the compressive strength standard requirements.
Nguyen, QD, Khan, MSH & Castel, A 2020, 'Chloride Diffusion in Limestone Flash Calcined Clay Cement Concrete', ACI Materials Journal, vol. 117, no. 6.
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Nguyen, QD, Khan, MSH & Castel, A 2020, 'Chloride Diffusion in Limestone Flash Calcined Clay Cement Concrete', ACI Materials Journal, vol. 117, no. 6, pp. 165-175.
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Nguyen, QD, Kim, T & Castel, A 2020, 'Mitigation of alkali-silica reaction by limestone calcined clay cement (LC3)', Cement and Concrete Research, vol. 137, pp. 106176-106176.
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© 2020 Elsevier Ltd The study aims to investigate the influence of limestone calcined clay cement (LC3) on the alkali-silica reaction (ASR). Kinetics and sequence of ASR formation were monitored using the model reactant method. Accelerated mortar bar test (AMBT) was also conducted to evaluate the effect LC3 in the ASR expansion. 30 wt% replacement by flash calcined clay and limestone in binder reduced the mortar expansion lower than the limit of Australian Standard. From the model reactant method, the additional calcium rich phases in LC3 model reactant system seem to delay the ASR gel formation or produce high Ca/Si ASR products, relatively rigid C-S-H and C-A-S-H that has less expansive capability. The current results reveal the possibility to utilize model reactant experiments to monitor the formation sequence of ASR gels with the presence of calcined clay and limestone due to the consistent results observed between model reactant experiments and real LC3-based specimens.
Nguyen, TAH, Ngo, HH, Guo, WS, Nguyen, THH, Soda, S, Vu, ND, Bui, TKA, Vo, TDH, Bui, XT, Nguyen, TT & Pham, TT 2020, 'White hard clam (Meretrix lyrata) shells media to improve phosphorus removal in lab-scale horizontal sub-surface flow constructed wetlands: Performance, removal pathways, and lifespan', Bioresource Technology, vol. 312, pp. 123602-123602.
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This work examined the phosphorus (P) removal from the synthetic pretreated swine wastewater using lab-scale horizontal sub-surface flow constructed wetlands (HSSF-CWs). White hard clam (Meretrix lyrata) shells (WHC) and Paspalum atratum were utilized as substrate and plant, respectively. The focus was placed on treatment performance, removal mechanisms and lifespan of the HSSF-CWs. Results indicated that WHC-based HSSF-CW with P. atratum exhibited a high P removal (89.9%). The mean P efluent concentration and P removal rate were 1.34 ± 0.95 mg/L and 0.32 ± 0.03 g/m2/d, respectively. The mass balance study showed that media sorption was the dominant P removal pathway (77.5%), followed by microbial assimilation (14.5%), plant uptake (5.4%), and other processes (2.6%). It was estimated the WHC-based bed could work effectively for approximately 2.84 years. This WHC-based HSSF-CWs technology will therefore pave the way for recycling Ca-rich waste materials as media in HSSF-CWs to enhance P-rich wastewater purification.
Nguyen, TAH, Ngo, HH, Guo, WS, Nguyen, TT, Vu, ND, Soda, S, Nguyen, THH, Nguyen, MK, Tran, TVH, Dang, TT, Nguyen, VH & Cao, TH 2020, 'White hard clam (Meretrix lyrata) shells as novel filter media to augment the phosphorus removal from wastewater', Science of The Total Environment, vol. 741, pp. 140483-140483.
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It is well recognized that filter media play a crucial role in constructed wetlands (CWs) for decontamination of phosphorus (P)-rich wastewater. This study investigates the suitability of raw white hard clam shells (WHC) and white hard clam shells thermally modified at 800 °C (WHC-M800) as potential media to enhance P treatment performance in CWs. The results indicated that both WHC and WHC-M800 displayed appropriate physicochemical properties, such as high porosity, excellent hydraulic conductivity, and rich Ca content. WHC-M800 exhibited a superior P adsorption capacity (38.7 mg/g) to WHC (12.8 mg/g). However, the practical utilization of WHC-M800 as filter media in CWs may be compromised, due to certain limitations, for example: extremely high pH values in the post-adsorption solutions; high weight losses during calcination and adsorption processes; low mechanical strength; and intensive energy consumption. In contrast, the WHC demonstrated significant advantages of reasonably high P adsorption capacity, locally abundant availability, low cost, and marginal side effects. The fractionation of inorganic P of WHC and WHC-M800 revealed that Ca-bounded P was the most dominant binding form, followed by loosely bound P, Fe-P, occluded P, and Al-P. The present study demonstrates that recycling of WHC shells as a potential substrate in CWs provides a feasible method for upgrading P removal in CWs. Additionally, it helps to reduce waste WHC shells in a simple, cheap, and eco-friendly way, thus can double environmental benefits.
Nguyen, TH, Tran, HN, Vu, HA, Trinh, MV, Nguyen, TV, Loganathan, P, Vigneswaran, S, Nguyen, TM, Trinh, VT, Vu, DL & Nguyen, THH 2020, 'Laterite as a low-cost adsorbent in a sustainable decentralized filtration system to remove arsenic from groundwater in Vietnam', Science of The Total Environment, vol. 699, pp. 134267-134267.
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© 2019 Elsevier B.V. In the Red River Delta, Vietnam, arsenic (As) contamination of groundwater is a serious problem where more than seventeen million people are affected. Millions of people in this area are unable to access clean water from the existing centralized water treatment systems. They also cannot afford to buy expensive household water filters. Similar dangerous situations exist in many other countries and for this reason there is an urgent need to develop a cost-effective decentralized filtration system using new low-cost adsorbents for removing arsenic. In this study, seven locally available low-cost materials were tested for arsenic removal by conducting batch adsorption experiments. Of these materials, a natural laterite (48.7% Fe2O3 and 18.2% Al2O3) from Thach That (NLTT) was deemed the most suitable adsorbent based on arsenic removal performance, local availability, stability/low risk and cost (US$ 0.10/kg). Results demonstrated that the adsorption process was less dependent on the solution pH from 2.0 to 10. The coexisting anions competed with As(III) and As(V) in the order, phosphate > silicate > bicarbonate > sulphate > chloride. The adsorption process reached a fast equilibrium at approximately 120–360 min, depending on the initial arsenic concentrations. The Langmuir maximum adsorption capacities of NLTT at 30 °C were 512 μg/g for As(III) and 580 μg/g for As(V), respectively. Thermodynamic study conducted at 10 °C, 30 °C, and 50 °C suggested that the adsorption process of As(III) and As(V) was spontaneous and endothermic in nature. A water filtration system packed with NLTT was tested in a childcare centre in the most disadvantaged community in Ha Nam province, Vietnam, to determine arsenic removal performance in an operation lasting six months. Findings showed that the system reduced total arsenic concentration in groundwater from 122 to 237 μg/L to below the Vietnam drinking water standard of 10 μg/L.
Nguyen, TKL, Ngo, HH, Guo, W, Chang, SW, Nguyen, DD, Nguyen, TV & Nghiem, DL 2020, 'Contribution of the construction phase to environmental impacts of the wastewater treatment plant', Science of The Total Environment, vol. 743, pp. 140658-140658.
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This study aims to investigate the environmental issues regarding the construction phase of the wastewater treatment plant (WWTP) and explore the roles of different materials through their environmental impacts. Detailed inventories of the two WWTPs were conducted by involving materials and transportation for civil works undertaken. EPD 2018 and ReCiPe life cycle impact assessment methods were employed to measure all the impact categories. Five treatment processes - (1) pumping, (2) primary treatment, (3) secondary treatment, (4) sludge line, and (5) building landscape - were considered for the assessment. It was found that concrete and reinforcing steel played similarly vital roles in most of the EPD 2018 impacts. The significant score of reinforcing steel was found on human cancer toxicity, which contributed more than 90% of the impacts. The contribution of diesel on ozone formation was 5% higher than that of reinforcing steel. Glassfiber was responsible for 70% of the burdens on ozone depletion, showing much higher than the total share of concrete and reinforcing steel. Primary treatment units only contributed 9.5% of the construction impacts in the Girona WWTP but up to 43.8% in Mill Creek WWTP mainly because of the proportion of consumed materials. In short, the comprehensive data inventories were necessary when evaluating the total environmental impacts of the WWTP.
Nguyen, TKL, Ngo, HH, Guo, WS, Chang, SW, Nguyen, DD, Nghiem, LD & Nguyen, TV 2020, 'A critical review on life cycle assessment and plant-wide models towards emission control strategies for greenhouse gas from wastewater treatment plants', Journal of Environmental Management, vol. 264, pp. 110440-110440.
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© 2020 Elsevier Ltd For decades, there has been a strong interest in mitigating greenhouse gas (GHG) emissions from wastewater treatment plants (WWTPs). Numerous models were developed to measure the emissions and propose the quantification. Existing studies looked at the relationship between GHG emissions and operational cost (OCI), which is one of the most important indicators for decision-makers. Other parameters that can influence the control strategies include the effluent quality (EQI) and total environmental impacts. Plant-wide models are reliable methods to examine the OCI, EQI and GHG emissions while Life cycle assessment (LCA) works to assess the potential environmental impacts. A combined LCA and plant-wide model proved to be a valuable tool evaluating and comparing strategies for the best performance of WWTPs. For this study involving a WWTP, the benchmark model is used while LCA is the decision tool to find the most suitable treatment strategy. LCA adds extra criteria that complement the existing criteria provided by such models. Complementing the cost/performance criteria is proposed for plant-wide models, including environmental evaluation, based on LCA, which provides an overall better assessment of WWTPs. It can capture both the dynamic effects and potential environmental impacts. This study provides an overview of the integration between plant-wide models and LCA.
Nguyen, TN, Emre Erkmen, R, Sanchez, LFM & Li, J 2020, 'Stiffness Degradation of Concrete Due to Alkali-Silica Reaction: A Computational Homogenization Approach', ACI Materials Journal, vol. 117, no. 6, pp. 65-76.
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Alkali-silica reaction (ASR) is one of the most harmful distress mechanisms affecting concrete infrastructure worldwide. ASR is a chemical reaction that generates a secondary product, which induces expansive pressure within the reacting aggregate material and adjacent cement paste upon moisture uptake, leading to cracking, loss of material integrity, and functionality of the affected structure. In this work, a computational homogenization approach is proposed to model the impact of ASR-induced cracking on concrete stiffness as a function of its development. A representative volume element (RVE) of the material at the mesoscale is developed, which enables the input of the cracking pattern and extent observed from a series of experimental testing. The model is appraised on concrete mixtures presenting different mechanical properties and incorporating reactive coarse aggregates. The results have been compared with experimental results reported in the literature. The case studies considered for the analysis show that stiffness reduction of ASR-affected concrete presenting distinct damage degrees can be captured using the proposed mesoscale model as the predictions of the proposed methodology fall in between the upper and lower bounds of the experimental results.
Nguyen, TT & Indraratna, B 2020, 'A Coupled CFD–DEM Approach to Examine the Hydraulic Critical State of Soil under Increasing Hydraulic Gradient', International Journal of Geomechanics, vol. 20, no. 9, pp. 04020138-04020138.
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© 2020 American Society of Civil Engineers. Increasing hydraulic gradients and associated seepage in a soil foundation accompanied by a reduction in effective stress, degradation of soil stiffness, and diminished internal stability contribute to adverse conditions in engineered earth structures, including dams and transport infrastructure. Although much attention has been drawn into these geotechnical challenges, most previous analytical and experimental studies could not properly capture the detailed response of fluid and soil particles, especially the localized or microscopic fluid-soil perspectives. In this regard, this paper aims to apply a numerical approach to analyze the response of a soil-fluid system under increasing hydraulic gradients. Soils with different gradation properties and porosities are created using the discrete element method (DEM), which is then coupled with computational fluid dynamics (CFD) based on Navier-Stokes equations. This numerical investigation reveals different stages in the development of hydraulic critical state, that is, from localized erosion (e.g., piping) to overall heave and fluidization. The transformation of fluid and particle characteristics, such as particle migration, the erosion rate, and hydraulic conductivity associated with porosity when soil approaches critical state, is discussed in detail. Micromechanical degradation within the contact network and the associated reduction in effective stress of soil due to an increasing hydraulic gradient are also analyzed in this study. A number of key factors that govern the soil response, such as friction, porosity, and grain uniformity, are addressed through numerical investigations. This study demonstrates acceptable numerical predictions for hydraulic behavior and erosion rates that are in good agreement with previous experimental data.
Nguyen, TT & Indraratna, B 2020, 'The energy transformation of internal erosion based on fluid-particle coupling', Computers and Geotechnics, vol. 121, pp. 103475-103475.
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© 2020 Elsevier Ltd The transformation of energy is an intrinsic process that is needed to trigger the internal erosion of soils subjected to a fluid flow, but how to capture this process is not understood very well. This is why this study aims to address these complex processes through a numerical fluid-particle coupling simulation. The computational fluid dynamics (CFD) is used to model fluid flows which is coupled with the discrete element method (DEM) employed to simulate soil particles. Detailed migration of particles and fluid variables are recorded to enable their kinetic energy to be computed. Successful experiments are used to demonstrate how the numerical method can be used to model the internal erosion associated with energy computation. This study shows a good agreement between the numerical and experimental results in terms of the hydraulic conductivity and erosion rate of soils subjected to upward flows. A significant loss in energy is also found as fluid flows through the soil whereas only a small amount of kinetic energy is needed to make particles migrate at a considerable degree. The influence that the porosity and uniformity of soils has on the transformation of energy is also discussed in the paper.
Nguyen, TT & Indraratna, B 2020, 'The role of particle shape on hydraulic conductivity of granular soils captured through Kozeny–Carman approach', Géotechnique Letters, vol. 10, no. 3, pp. 398-403.
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Previous studies indicate that particle shape plays an important role in the hydraulic conductivity (k) of granular materials, often represented through the Kozeny–Carman (KC) concept. Several recent studies have improved the accuracy of the KC approach using the particle-size distribution (PSD) to estimate the specific surface area of particles but overly simplifying the effect of particle shape. This current study innovatively adopts the micro-computed tomography technique to compute particle shape parameters of different granular materials (e.g. glass beads, sand and crushed gravel) and then incorporate these parameters into the KC equation to estimate k more accurately, which is then validated with experimental data. The results indicate that k varies significantly according to different particle shapes even if the same mean porosity and PSD are retained. Particles that are less spherical and rounded have a larger fluid–particle contact area (i.e. larger shape factor), hence a smaller hydraulic conductivity. The study suggests a shape factor of 1·28–1·52 for natural sand and 1·84–2·1 for crushed sand and gravel can be used for KC method to estimate k while a porosity-dependent equation is proposed to estimate the tortuosity for different shaped materials.
Nguyen, TT, Indraratna, B & Baral, P 2020, 'Biodegradable prefabricated vertical drains: From laboratory to field studies', Geotechnical Engineering, vol. 51, no. 2, pp. 39-46.
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Biodegradable prefabricated vertical drains (BPVDs) made from natural fibres have been in use for several decades to improve soft soil, especially in East and Southeast Asia despite the fact that this type of drain has still not been fully addressed and evaluated. This study presents a series of laboratory tests where a drain made from coconut cores wrapped in Indian jute sheath filters is compared to conventional synthetic prefabricated vertical drains (SPVDs). Discharge volume tests are carried out with and without soil clogging to understand how jute drains can resist soil clogging under increasing confining pressure. Along with these macro-hydraulic tests, the influence that the micro-characteristics of natural fibre drains can have on their hydraulic conductivity is also examined using micro-CT scanning and an optical microscopic to capture the micro-details of these drains. This study shows that the porous structure of BPVDs is much more complex than SPVDs, which causes them to have a lower discharge capacity. Unlike SPVDs, micro-properties also play an important role in the hydraulic properties of BPVDs. A pilot project in soft soil at Ballina, Australia, where BPVDs were installed in parallel to SPVDs, was used to evaluate their performance in assisting soil consolidation considering the biodegradation of natural fibres. The identical performance of these two types of PVDs added further evidence to prove how well BPVDs can facilitate soil consolidation.
Nguyen, TT, Ngo, HH, Guo, W & Wang, XC 2020, 'A new model framework for sponge city implementation: Emerging challenges and future developments', Journal of Environmental Management, vol. 253, pp. 109689-109689.
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© 2019 Sponge City concept is emerging as a new kind of integrated urban water systems, which aims to address urban water problems. However, its implementation has encountered a variety of challenges. The lack of an integrated comprehensive model to assist Sponge City planning, implementation and life cycle assessment is one of the most challenging factors. This review briefly analyses the opportunity of existing urban water management models and discusses the limitation of recent studies in the application of current integrated models for Sponge City implementation. Furthermore, it proposes a new Sponge City model framework by integrating four main sub-models including MIKE-URBAN, LCA, W045-BEST, and MCA in which environmental, social, and economic aspects of Sponge City infrastructure options are simulated. The new structure of Sponge City model that includes the sub-model layer, input layer, module layer, output layer, and programing language layer is also illustrated. Therefore, the proposed model could be applied to optimize different Sponge City practices by not only assessing the drainage capacity of stormwater infrastructure but also pays attention to multi-criteria analysis of urban water system (including the possibility of assessing Sponge City ecosystem services for urban areas and watershed areas) as well. Balancing between simplification and innovation of integrated models, increasing the efficiency of spatial data sharing systems, defining the acceptability of model complexity level and improving the corporation of multiple stakeholders emphasizing on possible future directions of a proper Sponge City design and construction model.
Nguyen, TT, Ngo, HH, Guo, W, Nguyen, HQ, Luu, C, Dang, KB, Liu, Y & Zhang, X 2020, 'New approach of water quantity vulnerability assessment using satellite images and GIS-based model: An application to a case study in Vietnam', Science of The Total Environment, vol. 737, pp. 139784-139784.
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Water deficiency due to climate change and the world's population growth increases the demand for the water industry to carry out vulnerability assessments. Although many studies have been done on climate change vulnerability assessment, a specific framework with sufficient indicators for water vulnerability assessment is still lacking. This highlights the urgent need to devise an effective model framework in order to provide water managers and authorities with the level of water exposure, sensitivity, adaptive capacity and water vulnerability to formulate their responses in implementing water management strategies. The present study proposes a new approach for water quantity vulnerability assessment based on remote sensing satellite data and GIS ModelBuilder. The developed approach has three layers: (1) data acquisition mainly from remote sensing datasets and statistical sources; (2) calculation layer based on the integration of GIS-based model and the Intergovernmental Panel on Climate Change's vulnerability assessment framework; and (3) output layer including the indices of exposure, sensitivity, adaptive capacity and water vulnerability and spatial distribution of remote sensing indicators and these indices in provincial and regional scale. In total 27 indicators were incorporated for the case study in Vietnam based on their availability and reliability. Results show that the most water vulnerable is the South Central Coast of the country, followed by the Northwest area. The novel approach is based on reliable and updated spatial-temporal datasets (soil water stress, aridity index, water use efficiency, rain use efficiency and leaf area index), and the incorporation of the GIS-based model. This framework can then be applied effectively for water vulnerability assessment of other regions and countries.
Nguyen, T-T-D, Nguyen, T-T, An Binh, Q, Bui, X-T, Ngo, HH, Vo, HNP, Andrew Lin, K-Y, Vo, T-D-H, Guo, W, Lin, C & Breider, F 2020, 'Co-culture of microalgae-activated sludge for wastewater treatment and biomass production: Exploring their role under different inoculation ratios', Bioresource Technology, vol. 314, pp. 123754-123754.
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In this study, mixed culture (microalgae:activated sludge) of a photobioreactor (PBR) were investigated at different inoculation ratios (1:0, 9:1, 3:1, 1:1, 0:1 wt/wt). This work was not only to determine the optimal ratio for pollutant remediation and biomass production but also to explore the role of microorganisms in the co-culture system. The results showed high total biomass concentrations were obtained from 1:0 and 3:1 ratio being values of 1.06, 1.12 g L-1, respectively. Microalgae played a dominant role in nitrogen removal via biological assimilation while activated sludge was responsible for improving COD removal. Compared with the single culture of microalgae, the symbiosis between microalgae and bacteria occurred at 3:1 and 1:1 ratio facilitated a higher COD removal by 37.5-45.7 %. In general, combined assessment based on treatment performance and biomass productivity facilitated to select an optimal ratio of 3:1 for the operation of the co-culture PBR.
Nguyen, TTQ, Loganathan, P, Nguyen, TV & Vigneswaran, S 2020, 'Removing arsenate from water using modified manganese oxide ore: Column adsorption and waste management', Journal of Environmental Chemical Engineering, vol. 8, no. 6, pp. 104491-104491.
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© 2020 Elsevier Ltd. There is a need to remove arsenic (As) in drinking water supplies by simple and cost-effective techniques. A column adsorption study was conducted to remove As(V) from water employing an iron (Fe) and zirconium (Zr) grafted Vietnamese manganese oxide ore (Fea-VMO and Zra-VMO). At a flow rate of 0.15 L/h, the bed volumes of water (As(V) concentration 0.1 mg/L) treated by Zra-VMO and Fea-VMO to produce water with As(V) concentration below the WHO guideline concentration (10 μg/L) were 6 and 8 times higher than for VMO, respectively. An increase in influent As concentration increased the adsorption capacity, but the increase of flow rate reduced the adsorption capacity. The maximum adsorption capacities derived from the Thomas model for VMO, Fea-VMO, and Zra-VMO at an influent concentration of 0.25 mg As(V)/L and flow rate of 0.15 L/h were 0.151, 1.145, and 0.925 mg/g, respectively. These values fell when influent As concentration decreased or the flow rate increased. Solidification/stabilisation method was applied to immobilise As(V) in the exhausted absorbent wastes by replacing 5, 10, 15, and 20 % of sand in a sand/cement concrete mixture by the adsorbent waste. This solidified material had satisfactory compressive strength, rapid chloride penetrability test, and volume of permeable voids, which indicated the material had good stability, making it suitable for use as a building material in construction work. The As(V) leaching from these materials, as measured by Method 1313 of the Leaching Environmental Assessment Framework of USEPA, proved to be very negligible.
Nguyen, TTQ, Loganathan, P, Nguyen, TV & Vigneswaran, S 2020, 'Removing arsenic from water with an original and modified natural manganese oxide ore: batch kinetic and equilibrium adsorption studies', Environmental Science and Pollution Research, vol. 27, no. 5, pp. 5490-5502.
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© 2019, Springer-Verlag GmbH Germany, part of Springer Nature. Arsenic contamination of drinking water is a serious water quality problem in many parts of the world. In this study, a low-cost manganese oxide ore from Vietnam (Vietnamese manganese oxide (VMO)) was firstly evaluated for its performance in arsenate (As(V)) removal from water. This material contains both Mn (25.6%) and Fe (16.1%) mainly in the form of cryptomelane and goethite minerals. At the initial As(V) concentration of 0.5 mg/L, the adsorption capacity of original VMO determined using the Langmuir model was 0.11 mg/g. The modified VMOs produced by coating VMO with iron oxide (Fea-VMO) and zirconium oxide (Zra-VMO) at 110 °C and 550 °C achieved the highest As(V) adsorption capacity when compared to three other methods of VMO modifications. Langmuir maximum adsorption capacities of Fea-VMO and Zra-VMO at pH 7.0 were 2.19 mg/g and 1.94 mg/g, respectively, nearly twenty times higher than that of the original VMO. Batch equilibrium adsorption data fitted well to the Langmuir, Freundlich, and Temkin models and batch kinetics adsorption data to pseudo-first order, pseudo-second order, and Elovich models. The increase of pH progressively from 3 to 10 reduced As(V) adsorption with a maximum reduction of 50–60% at pH 10 for both original and modified VMOs. The co-existing oxyanions considerably weakened the As(V) removal efficiency because they competed with As(V) anions. The competition order was PO43− > SiO32− > CO32− > SO42−. The characteristics of the original and modified VMOs evaluated using SEM, FTIR, XRD, XRF, surface area, and zeta potential explained the As(V) adsorption behaviour.
Nguyen, TTQ, Loganathan, P, Nguyen, TV, Vigneswaran, S & Ngo, HH 2020, 'Iron and zirconium modified luffa fibre as an effective bioadsorbent to remove arsenic from drinking water', Chemosphere, vol. 258, pp. 127370-127370.
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Porous luffa plant fibre (LF) was grafted with Fe and Zr, and the ability of the fabricated adsorbents to remove arsenate (As(V)) from water was investigated in batch and column adsorption experiments. The Langmuir adsorption capacity (mg g-1) at pH 7 of LF was found to be 0.035, which increased to 2.55 and 2.89 after being grafted with Fe (FLF-3) and Zr (ZLF-3), respectively. Grafting with Fe and Zr increased the zeta potential and zero point of charge (ZPC) of LF (from pH 3.9 to 7.4 for Fe grafting and to 7.6 for Zr grafting), due to chemical bonding of the metals, possibly with the hydroxyl and carboxylic groups in LF as indicated in FTIR peaks. Zeta potential and ZPC decreased after As adsorption owing to inner-sphere complexation mechanism of adsorption. The increase of pH from 3 to 10 progressively reduced the adsorbents' adsorption capacity. Co-existing anions weakened the As(V) removal efficiency in the order, PO43- > SiO32- > CO32- > SO42-. Adsorption kinetics data fitted well to the Weber and Morris model, which revealed initial fast and subsequent slow rates of intra-particle As diffusion into the bigger pores and smaller pores, respectively. Column adsorption data fitted well to the Thomas model with the predicted adsorption capacities in the same order as in the batch adsorption experiment (ZLF-3 > FLF-3 > LF).
Nguyen, XC, Tran, TCP, Hoang, VH, Nguyen, TP, Chang, SW, Nguyen, DD, Guo, W, Kumar, A, La, DD & Bach, Q-V 2020, 'Combined biochar vertical flow and free-water surface constructed wetland system for dormitory sewage treatment and reuse', Science of The Total Environment, vol. 713, pp. 136404-136404.
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A two-stage treatment system that included vertical flow (VF) and free-water surface (FWS) constructed wetlands was investigated for the dual purposes of sewage treatment and reuse. The VF included four layers (biochar, sand, gravel, and sandy soil), and the FWS was installed after the VF and used as a polishing tank. Two types of local plants, namely Colocasia esculenta and Canna indica, were planted in the VF and FWS, respectively. The system operated for approximately six months, and the experimental period was categorized into four stages that corresponded to changes in the hydraulic loading rate (HLR) (0.02-0.12 m/d). The removal efficiencies for total suspended solids (TSS), chemical oxygen demand (COD), biological oxygen demand (BOD5), ammonia (NH4-N), and total coliform (Tcol) were 71 ± 11%, 73 ± 13%, 79 ± 11%, 91 ± 3%, and 70 ± 20%, respectively. At HLRs of 0.04-0.06 m/d, the COD and BOD5 levels satisfied Vietnam's irrigation standards, with removable rates of 64% and 88%, respectively, and the TSS and Tcol levels satisfied Vietnam's standards for potable water. Furthermore, the NO3-N levels satisfied the reuse limits, whereas the NH4-N levels exceeded the reuse standards. At high HLRs (e.g., 0.12 m/d), all the effluent parameters, except Tcol and NO3-N, exceeded the standards.
Ni, B-J, Yan, X, Dai, X, Liu, Z, Wei, W, Wu, S-L, Xu, Q & Sun, J 2020, 'Ferrate effectively removes antibiotic resistance genes from wastewater through combined effect of microbial DNA damage and coagulation', Water Research, vol. 185, pp. 116273-116273.
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The widespread of antibiotic resistance genes (ARGs) in the environment can pose severe threats to public health. The wastewater treatment plant (WWTP) is regarded as an important hotspot of ARGs in the urban environment, but the removal of ARGs through conventional treatment techniques has been proven not sufficient. In this study, ferrate (Fe(VI)) was applied for the first time to remove intracellular ARGs from the secondary effluent of the WWTP. The results showed that Fe(VI) treatment could effectively remove 15 ARGs covering eight different types as well as intI1, the most common integron important to ARGs horizontal transfer. The removal efficiencies of tested genes could reach 1.10-4.37 log at the Fe(VI) dosage of 10 mg-Fe/L, which is significantly higher than those achieved through traditional disinfection methods. The DNA gel electrophoresis suggested that Fe(VI) could induce microbial DNA damage and consequently resulted in ARGs elimination. The presence of ARGs in settled residues indicated that coagulation initiated by Fe(VI) reduction products also contributed to ARGs removal from wastewater. In addition, the viability and relative abundances of potential ARGs hosts in the wastewater were decreased after Fe(VI) treatment. This study suggested a promising prospect for applying Fe(VI) to efficiently remove ARGs from wastewater, and consequently to control their proliferation and transfer in the environment.
Ni, B-J, Zeng, S, Wei, W, Dai, X & Sun, J 2020, 'Impact of roxithromycin on waste activated sludge anaerobic digestion: Methane production, carbon transformation and antibiotic resistance genes', Science of The Total Environment, vol. 703, pp. 134899-134899.
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The macrolide antibiotic roxithromycin is widely detected in varying aquatic environments, especially in the wastewater systems, as an emerging contaminant and leads to significant impacts on the microorganisms involved. In this study, the impact of a shock load of roxithromycin on waste activated sludge (WAS) anaerobic digestion was comprehensively investigated. The biochemical methane potential tests showed that the methane production from WAS anaerobic digestion was significantly inhibited by roxithromycin. With the dosage of roxithromycin increasing from 0 to 1000 μg/L, the maximum cumulative methane production decreased from 163.5 ± 2.6 mL/g VS to 150.9 ± 4.5 mL/g VS. In particular, roxithromycin inhibited the acidogenesis and methanogenesis in WAS anaerobic digestion, leading to the decreased methane production. The methanogenic archaea in the studied system mainly belonged to the genera of Methanoseata, Candidatus Methanofastidiosum and Methanolinea and their relative abundances also decreased with roxithromycin addition. The analysis of antibiotic resistance genes (ARGs) in the digested sludge indicated that the abundances of most ARGs detected in this study were increased with roxithromycin exposure, suggesting the potential of growing antibiotic resistance, which was probably caused by enhancing the effect of esterases, methylases and phosphorylases. This work reveals how roxithromycin affects the WAS anaerobic digestion and the change of ARGs in the anaerobic digestion with roxithromycin exposure, and provides useful information for practical operation.
Ni, B-J, Zhu, Z-R, Li, W-H, Yan, X, Wei, W, Xu, Q, Xia, Z, Dai, X & Sun, J 2020, 'Microplastics Mitigation in Sewage Sludge through Pyrolysis: The Role of Pyrolysis Temperature', Environmental Science & Technology Letters, vol. 7, no. 12, pp. 961-967.
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© 2020 American Chemical Society. All rights reserved. Sewage sludge is an important source of introducing microplastics into the environment, and thus, effective mitigation of microplastics in the sludge is in urgent need. Herein, the effect of pyrolysis on microplastics reduction in sewage sludge was investigated through a lab-scale study. The micro-Raman analysis showed that the microplastics concentrations in sludge residues decreased significantly from 550.8 to 960.9 particles/g to 1.4-2.3 particles/g with the pyrolysis temperature increasing to 500 °C, and no tiny (10-50 μm) microplastics remained. Polyethylene and polypropylene, the two most abundant microplastics in sewage sludge, were entirely degraded when the pyrolysis temperature reached 450 °C. However, during the pyrolysis process, new plastic polymers could be produced through the reaction between original microplastics with organics in sludge, and heavy metals in sludge can also be combined. Moreover, scanning electron microscopy analysis of spiked microplastics showed that incomplete pyrolysis at low temperatures could result in rough surface morphology of microplastics, making it more readily to adsorb contaminants. Overall, the results of this study provide the first insight into the effectiveness of microplastics control in sewage sludge through pyrolysis, but to avoid potential environmental risks induced by incomplete pyrolysis, a pyrolysis temperature of 450 °C should be reached at least.
Nimbalkar, S, Kolay, PK & Sun, Y 2020, 'Editorial: Geotechnical Innovation for Transport Infrastructures', Frontiers in Built Environment, vol. 6.
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Nimbalkar, S, Pain, A & Annapareddy, VSR 2020, 'A Strain Dependent Approach for Seismic Stability Assessment of Rigid Retaining Wall', Geotechnical and Geological Engineering, vol. 38, no. 6, pp. 6041-6055.
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© 2020, Springer Nature Switzerland AG. A new method is proposed to evaluate the seismic stability of a rigid retaining wall undergoing translation or rotational failure. In the present method, strain-dependent dynamic properties are used to assess the seismic stability of rigid retaining walls against sliding and overturning failure conditions. The effect of foundation soil properties on the stability of retaining walls is also considered. From the parametric study, it is observed that the foundation soil properties have a significant effect on both sliding and rotational stability of rigid retaining walls. This can be attributed to the use of strain-dependent dynamic properties and the consideration of foundation soil properties. The predictions of the proposed method are compared and verified against the results from other methods proposed in the past. The percentage increase in the results compared to the existing literature is a maximum of 10 and 28% for rigid (bedrock) and flexible (sand deposit) foundation, respectively.
Noushini, A, Castel, A, Aldred, J & Rawal, A 2020, 'Chloride diffusion resistance and chloride binding capacity of fly ash-based geopolymer concrete', Cement and Concrete Composites, vol. 105, pp. 103290-103290.
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© 2019 This study evaluated the chloride diffusion resistance of low-calcium fly ash-based geopolymer concrete through electrical and bulk diffusion techniques. The geopolymer concretes were prepared using 12 different heat curing conditions; three temperatures of 60, 75 and 90 °C and four curing durations of 8, 12, 18 and 24 h, as well as ambient curing. The mechanical and transport properties and microstructural characteristics of the geopolymer concretes were examined. NT BUILD 492 chloride migration and ASTM C1556 bulk diffusion tests were carried out. Results showed that the chloride diffusion resistance and the chloride binding capacity of fly ash-based geopolymer concrete is very low. The fly ash-based geopolymer concrete appears to be suitable for applications where there are little or no chloride-related durability concerns.
Nuruzzaman, M, Ren, J, Liu, Y, Rahman, MM, Shon, HK & Naidu, R 2020, 'Hollow Porous Silica Nanosphere with Single Large Pore Opening for Pesticide Loading and Delivery', ACS Applied Nano Materials, vol. 3, no. 1, pp. 105-113.
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Ogie, R & Pradhan, B 2020, 'Social vulnerability to natural hazards in Wollongong: Comparing strength-based and traditional methods', Australian Journal of Emergency Management, vol. 35, no. 1, pp. 60-68.
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Social vulnerability is a widely recognised way of assessing the sensitivity of a population to natural hazards and its ability to respond to and recover from them. In the traditional approach to computing social vulnerability, the emphasis is mainly on the weaknesses only (e.g. old age, low income, language barriers). This study presents a strengthbased social vulnerability index that identifies the strengths that communities have that help minimise disaster risk exposure. The strength-based social vulnerability index method is compared with the traditional approach using various statistical procedures like the one-sample T-test and the Wilcoxon signed rank test. This is performed through a case study measuring the social vulnerability for the 108 suburbs of Wollongong in New South Wales. The results show there is a significant difference between the values obtained from measurements using the strength-based social vulnerability index technique and those generated by the traditional approach. The implications of the results for emergency and disaster management are broadly discussed.
Ong, HC, Mofijur, M, Silitonga, AS, Gumilang, D, Kusumo, F & Mahlia, TMI 2020, 'Physicochemical Properties of Biodiesel Synthesised from Grape Seed, Philippine Tung, Kesambi, and Palm Oils', Energies, vol. 13, no. 6, pp. 1319-1319.
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The production of biodiesel using vegetable oil is an effective way to meet growing energy demands, which could potentially reduce the dependency on fossil fuels. The aim of this study was to evaluate grape seed (Vitis vinifera), Philippine tung (Reutealis trisperma), and kesambi (Schleichera oleosa) oils as potential feedstocks for biodiesel production to meet this demand. Firstly, biodiesels from these oils were produced and then their fatty acid methyl ester profiles and physicochemical properties were evaluated and compared with palm biodiesel. The results showed that the biodiesel produced from grape seed oil possessed the highest oxidation stability of 4.62 h. On the other hand, poor oxidation stability was observed for Philippine tung biodiesel at 2.47 h. The poor properties of Philippine tung biodiesel can be attributed to the presence of α-elaeostearic fatty acid. Furthermore, synthetic antioxidants (pyrogallol) and diesel were used to improve the oxidation stability. The 0.2 wt.% concentration of pyrogallol antioxidant could increase the oxidation stability of grape seed biodiesel to 6.24 h, while for kesambi and Philippine tung, biodiesels at higher concentrations of 0.3% and 0.4 wt.%, respectively, were needed to meet the minimum limit of 8 h. The blending of biodiesel with fossil diesel at different ratios can also increase the oxidation stability.
Organ, B, Huang, Y, Zhou, JL, Yam, Y-S, Mok, W-C & Chan, EFC 2020, 'Simulation of engine faults and their impact on emissions and vehicle performance for a liquefied petroleum gas taxi', Science of The Total Environment, vol. 716, pp. 137066-137066.
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© 2020 Elsevier B.V. The deterioration of emissions control systems in a spark ignition engine is predominantly a gradual process of wear and tear occurring as vehicles accumulate mileage. As new innovations in engine and emissions technology have been progressively introduced to meet lower emissions targets, the impact of gradual deterioration of hardware has become more challenging to identify and quantify in the repair industry. When a pioneering emissions control programme utilising remote sensing to detect high emitting gasoline and liquefied petroleum gas (LPG) vehicles was to be introduced in Hong Kong, it became apparent the repair industry needed specialised training to assist with identifying the types of failures which would lead to high vehicle emissions. To identify the impact of hardware deterioration and failures, a Toyota Crown Comfort LPG taxi was used to demonstrate simulated failures of engine hardware systems to measure their impact on emissions, fuel consumption and drivability using a chassis dynamometer. This novel study simulated a broad range of deterioration and failures covering the intake, fuel supply, ignition, and exhaust systems. The results of the study showed significant THC and CO increases of up to 317% (0.604 g/km) and 782% (5.351 g/km) respectively for a simulated oxygen sensor high voltage fault and a sticky mixture control valve. The largest increase in NOx emissions was for restricted main fuel supply in the LPG vapouriser, producing an increase of 282% (1.41 g/km). Fuel consumption varied with increases of up to 15.5%. Drivability was impacted with poor idle from a number of faults and especially by a worn throttlebody which produced rough acceleration characteristics as well. This study clearly highlights the importance of having properly maintained emissions and engine hardware systems to achieve optimal fuel economy and compliant emissions levels, which could be reproduced in other regions for prescribed emiss...
Ou, T, Wang, D, Xin, Z, Tan, J, Wu, C, Guo, Q & Zhang, Y 2020, 'Full-scale tests on the mechanical behaviour of a continuously welded stainless steel roof under wind excitation', Thin-Walled Structures, vol. 150, pp. 106680-106680.
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© 2020 Elsevier Ltd The wind uplift performance of the continuously welded stainless steel roof (CWSSR) system adopted in the Zhaoqing New District Sports (ZNDS) Center of China is investigated in this study. To determine the optimal welding program and examine the mechanical properties of the continuously welded stainless steel joints, uniaxial tensile testing is first conducted on 27 specimens with tension-shear and tension-bending types. Two CWSSR specimens, one that is square-shaped with a horizontal layout and one that is rectangular-shaped with an inclination layout of 10.71°, are further tested under dynamic and static ultimate wind uplift loadings to explore the wind uplift capacity. All specimens are full-size, and the corresponding materials, structural details and construction technologies are kept the same as the actual building to ensure the authenticity of the testing investigations. The testing results indicate that the integrated and sealed CWSSR system has a clear force transmission mechanism and a remarkable wind resistance performance. The welded joints achieve the best performance, and the mechanical behaviours are equivalent to those of the base material under the continuously welded conditions including an electric current of 65 A and a moving velocity of 750 mm/s. An excellent dynamic wind suction performance is achieved under 5000 five-level cumulative loading cycles with a maximum pressure of 5400 Pa. The static ultimate pressure reaches 9400 Pa for the square specimen and 10,400 Pa for the rectangular specimen. Damage observations show that no tearing or rupture failures are observed for the CWSSR system. The investigation results contribute the most to the safe design of the ZNDS Center and are expected to provide guidelines for future applications of the CWSSR system.
Pain, A, Nimbalkar, S & Hussain, M 2020, 'Applicability of Bouc-Wen Model to Capture Asymmetric Behavior of Sand at High Cyclic Shear Strain', International Journal of Geomechanics, vol. 20, no. 6, pp. 06020009-06020009.
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Pardeshi, V, Nimbalkar, S & Khabbaz, H 2020, 'Field Assessment of Gravel Loss on Unsealed Roads in Australia', Frontiers in Built Environment, vol. 6, pp. 1-11.
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The gravel loss is a major limitation for unsealed roads and it needs major maintenance annually. The continual process of gravel loss leads to the unsustainability of these roads. The unsealed road management faces several issues, viz., difficulty to forecast behavior, huge data collection needs, and a vulnerability in the service and maintenance practices. The quality of gravel material also plays a major role in the process of gravel loss. In view of the aforementioned, appropriate revisions to ARRB material specifications are proposed in this study. The gravel material as per modified ARRB specifications is used on the unsealed road network in the Scenic Rim Regional Council in the state of Queensland. Gravel loss monitoring stations were established over the entire region in order to assess the gravel loss and the implication of using a better quality of gravel material. This study discusses the gravel loss monitoring approaches, data analyses, and improved material specification for gravel. It is found that the modified gravel used on unsealed road performs better than conventionally used gravel.
Park, J, Lim, J, Park, Y, Han, DS, Shon, HK, Hoffmann, MR & Park, H 2020, 'In Situ-Generated Reactive Oxygen Species in Precharged Titania and Tungsten Trioxide Composite Catalyst Membrane Filters: Application to As(III) Oxidation in the Absence of Irradiation', Environmental Science & Technology, vol. 54, no. 15, pp. 9601-9608.
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This study demonstrates that in situ-generated reactive oxygen species (ROSs) in prephotocharged TiO2 and WO3 (TW) composite particle-embedded inorganic membrane filters oxidize arsenite (As(III)) into arsenate (As(V)) without any auxiliary chemical oxidants under ambient conditions in the dark. TW membrane filters have been charged with UV or simulated sunlight and subsequently transferred to a once-through flow-type system. The charged TW filters can transfer the stored electrons to dissolved O2, producing ROSs that mediate As(III) oxidation in the dark. Dramatic inhibition of As(V) production with O2 removal or addition of ROS quenchers indicates an ROS-mediated As(III) oxidation mechanism. Electron paramagnetic spectroscopic analysis has confirmed the formation of the HO2•/O2•- pair in the dark. The WO3 fraction in the TW filter significantly influences the performance of the As(III) oxidation, while As(V) production is enhanced with increasing charging time and solution pH. The As(III) oxidation is terminated when the singly charged TW filter is fully discharged; however, recharging of TW recovers the catalytic activity for As(III) oxidation. The proposed oxidation process using charged TW membrane filters is practical and environmentally benign for the continuous treatment of As(III)-contaminated water during periods of unavailability of sunlight.
Parvin, K, Hannan, MA, Al-Shetwi, AQ, Ker, PJ, Roslan, MF & Mahlia, TMI 2020, 'Fuzzy Based Particle Swarm Optimization for Modeling Home Appliances Towards Energy Saving and Cost Reduction Under Demand Response Consideration', IEEE Access, vol. 8, pp. 210784-210799.
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Paryani, S, Neshat, A, Javadi, S & Pradhan, B 2020, 'Comparative performance of new hybrid ANFIS models in landslide susceptibility mapping', Natural Hazards, vol. 103, no. 2, pp. 1961-1988.
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© 2020, Springer Nature B.V. Abstract: Many landslides occur in the Karun watershed in the Zagros Mountains. In the present study, we employed a novel comparative approach for spatial modeling of landslides given the high potential of landslides in the region. The aim of the study was to combine adaptive neuro-fuzzy inference system (ANFIS) with grey wolf optimizer (GWO) and particle swarm optimizer (PSO) algorithms using the outputs of qualitative stepwise weight assessment ratio analysis (SWARA) and quantitative certainty factor (CF) models. To this end, 264 landslide positions and twelve conditioning factors including slope, aspect, altitude, distance to faults, distance to rivers, distance to roads, land use, lithology, rainfall, plan and profile curvature and TWI were then extracted considering regional characteristics, literature review and available data. In the next step, the multi-criteria SWARA decision-making model and CF probability model were used to evaluate a correlation between landslide distribution and conditioning factors. Ultimately, landslide susceptibility maps were generated by ANFIS-GWO and ANFIS-PSO hybrid models and the accuracy of models was assessed by ROC curve. According to the results, the area under the curve (AUC) for the hybrid models ANFIS - GWO SWARA, ANFIS - PSO SWARA, ANFIS - GWO CF and ANFIS - PSO CF was 0.789, 0.838, 0.850 and 0.879, respectively. The hybrid models ANFIS - PSO CF and ANFIS - GWO SWARA showed the highest and lowest prediction rate, respectively. Moreover, CF outperformed the SWARA method in terms of evaluating correlation between conditioning factors and landslides. The map produced in this study can be used by regional authorities to manage landslide risk. Graphic abstract: [Figure not available: see fulltext.].
Paryani, S, Neshat, A, Javadi, S & Pradhan, B 2020, 'GIS-based comparison of the GA-LR ensemble method and statistical models at Sefiedrood Basin, Iran', Arabian Journal of Geosciences, vol. 13, no. 19.
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Pathak, N, Phuntsho, S, Tran, VH, Johir, MAH, Ghaffour, N, Leiknes, T, Fujioka, T & Shon, HK 2020, 'Simultaneous nitrification-denitrification using baffled osmotic membrane bioreactor-microfiltration hybrid system at different oxic-anoxic conditions for wastewater treatment', Journal of Environmental Management, vol. 253, pp. 109685-109685.
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The efficacy of a baffled osmotic membrane bioreactor-microfiltration (OMBR-MF) hybrid system equipped with thin film forward osmosis membrane for wastewater treatment was evaluated at laboratory scale. The novel OMBR-MF hybrid system involved baffles, that separate oxic and anoxic zones in the aerobic reactor for simultaneous nitrification and denitrification (SND), and a bioreactor comprised of thin film composite-forward osmosis (TFC-FO) and polyether sulfone-microfiltration (PES-MF) membranes. The evaluation was conducted under four different oxic-anoxic cycle patterns. Changes in flux, salinity build-up, and microbial activity (e.g., extracellular polymeric substances (EPS) were assessed. Over the course of a 34 d test, the OMBR-MF hybrid system achieved high removal of total organic carbon (TOC) (86-92%), total nitrogen (TN) (63-76%), and PO4-P (57-63%). The oxic-anoxic cycle time of 0.5-1.5 h was identified to be the best operating condition. Incorporation of MF membrane effectively alleviated salinity build-up in the reactor, allowing stable system operation.
Pathak, N, Tran, VH, Merenda, A, Johir, MAH, Phuntsho, S & Shon, H 2020, 'Removal of Organic Micro-Pollutants by Conventional Membrane Bioreactors and High-Retention Membrane Bioreactors', Applied Sciences, vol. 10, no. 8, pp. 2969-2969.
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The ubiquitous presence of organic micropollutants (OMPs) in the environment as a result of continuous discharge from wastewater treatment plants (WWTPs) into water matrices—even at trace concentrations (ng/L)—is of great concern, both in the public and environmental health domains. This fact essentially warrants developing and implementing energy-efficient, economical, sustainable and easy to handle technologies to meet stringent legislative requirements. Membrane-based processes—both stand-alone or integration of membrane processes—are an attractive option for the removal of OMPs because of their high reliability compared with conventional process, least chemical consumption and smaller footprint. This review summarizes recent research (mainly 2015–present) on the application of conventional aerobic and anaerobic membrane bioreactors used for the removal of organic micropollutants (OMP) from wastewater. Integration and hybridization of membrane processes with other physicochemical processes are becoming promising options for OMP removal. Recent studies on high retention membrane bioreactors (HRMBRs) such as osmotic membrane bioreactor (OMBRs) and membrane distillation bioreactors (MDBRs) are discussed. Future prospects of membrane bioreactors (MBRs) and HRMBRs for improving OMP removal from wastewater are also proposed.
Pattison, TG, Spanu, A, Friz, AM, Fu, Q, Miller, RD & Qiao, GG 2020, 'Growing Patterned, Cross-linked Nanoscale Polymer Films from Organic and Inorganic Surfaces Using Ring-Opening Metathesis Polymerization', ACS Applied Materials & Interfaces, vol. 12, no. 3, pp. 4041-4051.
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The ability to modify substrates with thin polymer films allows for the tailoring of surface properties, and through combination of patterning finds use in a large variety of applications such as electronics and lab-on-chip devices. Although many techniques can be used to afford polymer-modified surfaces such as surface-initiated polymerization or layer-by-layer methodologies, their stability in a wide range of environments as well as their ability to target specific chemistry are critical factors to enable their successful application. In this paper, we report a facile technique in creating nanoscale polymer thin films using solid-state continuous assembly of polymers via ring-opening metathesis polymerization (ssCAPROMP) directly from surfaces functionalized through silanization. Using a polymeric precursor that includes norbornene moieties, a highly dense cross-linked network of polymer can be grown in a bottom-up fashion to afford thin films from an olefin-terminated silanized planar surface. Such nanotechnology affords films retaining the desirable qualities of previously reported methods while, at the same time, being covalently bound to the substrate: they are virtually pinhole free and can be reinitiated multiple times. By combining this process with microcontact printing, patterned films can be created by either the patterned deposition of a catalyst or by controlling the surface silanization chemistry and placement of olefin-terminated and nonreactive silanes. Additionally, patterned ssCAPROMP films were grown from SU-8 by selectively functionalizing the surface through masking and lift-off processes after the silanization step, thereby spatially controlling the surface-initiation, and subsequent polymer film formation. These patterned films expand the capabilities of the CAPROMP process and offer advantages over other film formation techniques in processes where patterned substrates and modified but robust surface chemistries are utilized.
Peng, L, Nie, W-B, Ding, J, Ni, B-J, Liu, Y, Han, H-J & Xie, G-J 2020, 'Denitrifying Anaerobic Methane Oxidation and Anammox Process in a Membrane Aerated Membrane Bioreactor: Kinetic Evaluation and Optimization', Environmental Science & Technology, vol. 54, no. 11, pp. 6968-6977.
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Denitrifying anaerobic methane oxidation (DAMO) coupled to anaerobic ammonium oxidation (anammox) is a promising technology for complete nitrogen removal with economic and environmental benefit. In this work, a model framework integrating DAMO and anammox process was constructed based on suspended-growth systems. The proposed model was calibrated and validated using experimental data from a sequencing batch reactor and a membrane aerated membrane bioreactor (MAMBR). The model managed to describe removal rates of ammonium (NH4+), nitrite (NO2-), and total nitrogen, as well as biomass changes of DAMO archaea, DAMO bacteria, and anaerobic ammonium oxidizing bacteria (AnAOB) in both reactors. The estimated parameter values revealed that DAMO archaea possessed properties of faster growth and higher biomass yield in suspended-growth systems compared to those in attached-growth systems (e.g., biofilm). Model simulation demonstrated that solid retention time (SRT) was effective in washing out DAMO bacteria, but retaining DAMO archaea and AnAOB in the MAMBR. The optimal SRT and nitritation efficiency (the ratio of the NO2- to the sum of NH4+ and NO2- in the MAMBR influent) were simulated so that 99% of total nitrogen was removed to meet the discharge standard. MAMBR further suggested to be operated with SRT between 15 and 30 days so that the optimal nitritation efficiency could be minimized to 49% for cost savings.
Pham, TT, Ngo, HH, Tran, VS & Nguyen, MK 2020, 'Removal of As (V) from the aqueous solution by a modified granular ferric hydroxide adsorbent', Science of The Total Environment, vol. 706, pp. 135947-135947.
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A novel adsorbent was prepared in granular form from iron (III) hydroxide and other additives to remove arsenate (As (V)) from aqueous solution. Adsorption of As (V) onto the adsorbent in batch experiments was analyzed to understand the adsorption mechanism, affecting factors, and adsorption isotherms. The optimal working conditions for the developed adsorbent were at pH 3, 30 °C and 50 g/L. The adsorption of arsenate onto the adsorbent occurred rapidly in the first 10 min and reached equilibrium in 2 h. The Langmuir isotherm was found to be best fitted the adsorption. The pre- and post-adsorption adsorbents were characterized by SEM, BET, FTIR, XRD, and Zeta potential techniques. Experimental results clearly demonstrated the potential impact of elemental composition, crystallinity, surface morphology, and other physico-chemical properties of the adsorbent on the adsorption performance variety. The experimental results with the pilot scale treatment system revealed that the adsorbent can be applied successfully and lead to a very efficient drinking water treatment system, at a competitive cost compared to the water market in Hanoi, Vietnam.
Phong Vo, HN, Ngo, HH, Guo, W, Hong Nguyen, TM, Li, J, Liang, H, Deng, L, Chen, Z & Hang Nguyen, TA 2020, 'Poly‐and perfluoroalkyl substances in water and wastewater: A comprehensive review from sources to remediation', Journal of Water Process Engineering, vol. 36, pp. 101393-101393.
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© 2020 Elsevier Ltd Per- and polyfluoroalkyl substances (PFAS) are pollutants have attracted major concern due to their high persistence and bioaccumulation. They are causing increasingly serious epidemiological problems in many communities globally due to consuming PFAS-contaminated water sources. Necessarily, the behavior of PFAS in water and wastewater needs to be understood better. This study attempts to comprehensively review, analyze and discuss PFAS based on the following key aspects: (i) sources, (ii) occurrence in water and wastewater, (iii) transformation, fate and migration, and (iv) remediation technologies. Studies indicated that modern water and wastewater treatment plants cannot deal completely with PFAS and in some cases, the removal efficiency is minus -3500-fold. The main reasons are the high hydrophobicity of PFAS and presence of PFAS precursors. Precursors can account for 33–63% of total PFAS concentration in water and wastewater. Detection and identification of precursors are challenging due to the requirement of advanced analytical instrument and standard chemicals. Several technologies have been developed for PFAS remediation involving two main mechanisms: separation-concentration and destruction. The most widespread in-use technology is adsorption because it is reasonably affordable. Anion exchange resin and synthesized materials are the most effective sorbents having a sorption capacity of 100–2000 mg PFAS/g sorbent, effective within a few hours. The destruction technology such as plasma can also be a promising one for degrading PFAS to below health-based standard in 1 min. However, plasma is costly and not yet ready for full scale application.
Phuntsho, S, Kim, JE, Tran, VH, Tahara, S, Uehara, N, Maruko, N, Matsuno, H, Lim, S & Shon, HK 2020, 'Free-standing, thin-film, symmetric membranes: Next-generation membranes for engineered osmosis', Journal of Membrane Science, vol. 607, pp. 118145-118145.
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© 2020 Elsevier B.V. The support layer of an asymmetric thin-film composite membrane results in structural resistance (internal concentration polarization) that significantly undermines engineered osmosis. Increasing the porosity and reducing the thickness and tortuosity of the membrane support layer reduces structural resistance; however, internal concentration polarization still impacts membrane performance. A novel, ultrathin, free-standing and symmetric membrane has been synthesized using sulfonated polyether ketone and tested for forward osmosis applications. This membrane is composed of a protonic acid group containing an aromatic polyether resin with sulfonated structural units. Polyether ketone provides high mechanical strength essential for ultrathin free-standing membranes, while sulfonation enhances the membrane hydrophilicity. These sulfonated polyether ketone membranes show promising water flux performances with impressive mechanical strength under the hydraulic operating conditions used for a FO process.
Pourzolfaghar, H, Abnisa, F, Wan Daud, WMA, Aroua, MK & Mahlia, TMI 2020, 'Catalyst Characteristics and Performance of Silica-Supported Zinc for Hydrodeoxygenation of Phenol', Energies, vol. 13, no. 11, pp. 2802-2802.
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The present investigation aimed to study the physicochemical characteristics of supported catalysts comprising various percentages of zinc dispersed over SiO2. The physiochemical properties of these catalysts were surveyed by N2 physisorption (BET), thermogravimetry analysis (TGA), H2 temperature-programmed reduction, field-emission scanning electron microscopy (FESEM), inductively coupled plasma-optical emission spectrometry (ICP-OES), and NH3 temperature-programmed desorption (NH3-TPD). In addition, to examine the activity and performance of the catalysts for the hydrodeoxygenation (HDO) of the bio-oil oxygenated compounds, the experimental reaction runs, as well as stability and durability tests, were performed using 3% Zn/SiO2 as the catalyst. Characterization of silica-supported zinc catalysts revealed an even dispersion of the active site over the support in the various dopings of the zinc. The acidity of the calcinated catalysts elevated clearly up to 0.481 mmol/g. Moreover, characteristic outcomes indicate that elevating the doping of zinc metal led to interaction and substitution of proton sites on the SiO2 surface that finally resulted in an increase in the desorption temperature peak. The experiments were performed at temperature 500 °C, pressure 1 atm; weight hourly space velocity (WHSV) 0.32 (h−1); feed flow rate 0.5 (mL/min); and hydrogen flow rate 150 (mL/min). Based on the results, it was revealed that among all the prepared catalysts, that with 3% of zinc had the highest conversion efficiency up to 80%. However, the selectivity of the major products, analyzed by gas chromatography flame-ionization detection (GC-FID), was not influenced by the variation in the active site doping.
Pradhan, B 2020, 'Preface', Advances in Science, Technology and Innovation, pp. v-x.
Pradhan, B, Al-Najjar, HAH, Sameen, MI, Mezaal, MR & Alamri, AM 2020, 'Landslide Detection Using a Saliency Feature Enhancement Technique From LiDAR-Derived DEM and Orthophotos', IEEE Access, vol. 8, pp. 121942-121954.
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Pradhan, B, Al-Najjar, HAH, Sameen, MI, Tsang, I & Alamri, AM 2020, 'Unseen Land Cover Classification from High-Resolution Orthophotos Using Integration of Zero-Shot Learning and Convolutional Neural Networks', Remote Sensing, vol. 12, no. 10, pp. 1676-1676.
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Zero-shot learning (ZSL) is an approach to classify objects unseen during the training phase and shown to be useful for real-world applications, especially when there is a lack of sufficient training data. Only a limited amount of works has been carried out on ZSL, especially in the field of remote sensing. This research investigates the use of a convolutional neural network (CNN) as a feature extraction and classification method for land cover mapping using high-resolution orthophotos. In the feature extraction phase, we used a CNN model with a single convolutional layer to extract discriminative features. In the second phase, we used class attributes learned from the Word2Vec model (pre-trained by Google News) to train a second CNN model that performed class signature prediction by using both the features extracted by the first CNN and class attributes during training and only the features during prediction. We trained and tested our models on datasets collected over two subareas in the Cameron Highlands (training dataset, first test dataset) and Ipoh (second test dataset) in Malaysia. Several experiments have been conducted on the feature extraction and classification models regarding the main parameters, such as the network’s layers and depth, number of filters, and the impact of Gaussian noise. As a result, the best models were selected using various accuracy metrics such as top-k categorical accuracy for k = [1,2,3], Recall, Precision, and F1-score. The best model for feature extraction achieved 0.953 F1-score, 0.941 precision, 0.882 recall for the training dataset and 0.904 F1-score, 0.869 precision, 0.949 recall for the first test dataset, and 0.898 F1-score, 0.870 precision, 0.838 recall for the second test dataset. The best model for classification achieved an average of 0.778 top-one, 0.890 top-two and 0.942 top-three accuracy, 0.798 F1-score, 0.766 recall and 0.838 precision for the first test dataset and 0.737 top-one, 0.906 top-two...
Pramanik, BK, Nghiem, LD & Hai, FI 2020, 'Extraction of strategically important elements from brines: Constraints and opportunities', Water Research, vol. 168, pp. 115149-115149.
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Prathibha, C, Biswas, A, Chunduri, LAA, Reddy, SK, Loganathan, P, Kalaruban, M & Venkatarmaniah, K 2020, 'Zr(IV) functionalized graphene oxide anchored sand as potential and economic adsorbent for fluoride removal from water', Diamond and Related Materials, vol. 109, pp. 108081-108081.
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Premadasa, W & Indraratna, B 2020, 'Discussion of “Numerical Simulation of the Shear Behavior of Rock Joints Filled with Unsaturated Soil” by Libin Gong, Jan Nemcik, and Ting Ren', International Journal of Geomechanics, vol. 20, no. 4, pp. 07020001-07020001.
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Punetha, P & Samanta, M 2020, 'Modelling of Shear Behaviour of Interfaces Involving Smooth Geomembrane and Nonwoven Geotextile Under Static and Dynamic Loading Conditions', Geotechnical and Geological Engineering, vol. 38, no. 6, pp. 6313-6327.
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The constitutive modelling of geosynthetic–geosynthetic interfaces is essential to predict the performance of the engineering structures such as landfills, flood control dykes and geotextile encapsulated-sand systems for the protection of shore. This article presents a mathematical model to simulate the shear stress/force–displacement behaviour of the interfaces involving smooth geomembrane and nonwoven geotextile under static and dynamic loading conditions. The model is the extension of an existing technique developed for predicting the soil-structure interface shear behaviour under static loading conditions. The proposed model can predict the non-linear pre-peak and the post-peak strain softening/hardening behaviour of the interfaces observed during the laboratory testing. The shear stress/force–displacement response of the interfaces has been modelled by dividing it into three parts: pre-peak, peak and post-peak behaviour. Subsequently, the modelling parameters are obtained using the results from the laboratory direct shear tests and fixed–block type shake table tests conducted on these interfaces. Finally, the shear stress/force–displacement response of the interfaces is evaluated and compared with the experimental results. The predicted shear stress/force–displacement response of the interfaces is found to be in good agreement with the experimental data for both static and dynamic loading conditions.
Punetha, P, Nimbalkar, S & Khabbaz, H 2020, 'Analytical Evaluation of Ballasted Track Substructure Response under Repeated Train Loads', International Journal of Geomechanics, vol. 20, no. 7, pp. 04020093-04020093.
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© 2020 American Society of Civil Engineers. The irrecoverable deformations in the substructure layers are detrimental to the track stability and demand frequent maintenance. With an escalation in axle load and traffic volume, the frequency of maintenance operations has remarkably increased. Consequently, there is an inevitable need to predict the long-term behavior of the track substructure layers. This article presents a methodology to evaluate the recoverable and irrecoverable responses of the substructure layers under the train-induced repetitive loads. The present method utilizes an integrated approach combining track loading, resiliency, and settlement models. The track substructure layers are simulated as lumped masses that are connected by springs and dashpots. The method is successfully validated against the field investigation data reported in the literature. A parametric study is conducted to investigate the influence of substructure layer properties on the track response. The results reveal that the response of each track layer is significantly influenced by the neighboring layer properties and the incorporation of multilayered track structure enables more accurate prediction of track behavior. The present analytical approach is simple, computationally efficient and may assist the practicing engineers in the safer design of the ballasted track.
Punetha, P, Nimbalkar, S & Khabbaz, H 2020, 'Evaluation of additional confinement for three-dimensional geoinclusions under general stress state', Canadian Geotechnical Journal, vol. 57, no. 3, pp. 453-461.
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Three-dimensional cellular geoinclusions (e.g., geocells, scrap tires) offer all-around confinement to the granular infill materials, thus improving their strength and stiffness. The accurate evaluation of extra confinement offered by these geoinclusions is essential for predicting their performance in the field. The existing models to evaluate the additional confinement are based on either a plane-strain or axisymmetric stress state. However, these geoinclusions are more likely to be subjected to the three-dimensional stresses in actual practice. This note proposes a semi-empirical model to evaluate the additional confinement provided by cellular geoinclusions under the three-dimensional stress state. The proposed model is successfully validated against the experimental data. A parametric study is conducted to investigate the influence of input parameters on additional confinement. Results reveal that the simplification of the three-dimensional stress state into axisymmetric or plane-strain condition has resulted in inaccurate and unreliable results. The extra confinement offered by the geoinclusion shows substantial variation along the intermediate and minor principal stress directions depending on the intermediate principal stress, infill soil, and geoinclusion properties. The magnitude of additional confinement increases with an increase in the geoinclusion modulus. The findings are crucial for accurate assessment of the in situ performance of three-dimensional cellular geoinclusions.
Putra, N, Sandi, AF, Ariantara, B, Abdullah, N & Indra Mahlia, TM 2020, 'Performance of beeswax phase change material (PCM) and heat pipe as passive battery cooling system for electric vehicles', Case Studies in Thermal Engineering, vol. 21, pp. 100655-100655.
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© 2020 The Authors. Increasing greenhouse gas (GHG) emissions in the atmosphere and the scarcity of fossil fuel sources have encouraged car manufacturers to develop more environmentally friendly electric vehicles (EVs). The technology advancements of EVs - those with battery systems in particular - have increased their travel distances. Therefore, increasing and maintaining the battery capacity is a key concern in the development of sustainable EVs. In this study, passive cooling systems were constructed with a heat pipe and phase change material (PCM), and their performances were investigated with battery simulators. The aim was to determine the effectiveness of the cooling system and to identify the optimal PCM (beeswax or Rubitherm RT 44 HC) for a temperature range of 25-55 °C. The use of a heat pipe could decrease the battery temperature by 26.62 °C under a 60 W heat load compared to the case without passive cooling system. Furthermore, the addition of RT 44 to a heat pipe resulted in a maximal temperature decrease of 33.42 °C. Thus, an RT 44 HC is more effective than beeswax because its melting temperature lies within the recommended range of the battery working temperature, and its latent heat allows the absorption of more heat compared to beeswax.
Qi, C, Chen, H, Shen, L, Li, X, Fu, Q, Zhang, Y, Sun, Y & Liu, Y 2020, 'Superhydrophobic Surface Based on Assembly of Nanoparticles for Application in Anti-Icing under Ultralow Temperature', ACS Applied Nano Materials, vol. 3, no. 2, pp. 2047-2057.
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© 2020 American Chemical Society. A new class of superhydrophobic surface based on assembly of nanoparticles was fabricated for improving mechanical durability and anti-icing performance under ultralow temperature. Furthermore, the anti-icing performance and mechanism of the yielded superhydrophobic surface were investigated by high speed video and thermal infrared imaging equipment. The frozen time of water droplets could be prolonged to 372.0 s when glass slides with superhydrophobic surface were exposed to an ultralow temperature of -40.0 °C. This outstanding anti-icing performance is attributed to the unique structure of the superhydrophobic surface based on assembly of nanoparticles, which possesses good free-energy barrier and low heat transfer rate. This study thus opens up an avenue for the design and fabrication of superhydrophobic surface with good durability and anti-icing performance under ultralow temperature.
Qi, Y & Indraratna, B 2020, 'Energy-Based Approach to Assess the Performance of a Granular Matrix Consisting of Recycled Rubber, Steel-Furnace Slag, and Coal Wash', Journal of Materials in Civil Engineering, vol. 32, no. 7, pp. 04020169-04020169.
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© 2020 American Society of Civil Engineers. Ballasted track progressively deteriorates due to ballast degradation and track deformation under dynamic loading, and this process accelerates when train speeds increase and axle loads become heavier as the railways are seeking to serve the enhanced productivity of the mining and agriculture sectors; on this basis, improving track performance is imperative. One effective solution is to incorporate energy-absorbing materials in the rail track, particularly when these materials are recycled from mining waste and recycled rubber. In this paper the performance of the track specimen with a synthetic energy absorbing layer (SEAL) (i.e., a matrix of recycled rubber crumbs with mining waste) is investigated by a series of large-scale (prototype) cubical triaxial tests. The test results indicate that the inclusion of rubber inside the SEAL matrix has a significant influence on the lateral movement, vertical deformation, ballast degradation, and energy distribution of the track specimen. To facilitate a better understanding of the energy-absorbing mechanism with the addition of rubber, an energy-based analysis has been adopted to identify the critical amount of rubber crumbs needed to efficiently distribute the accumulated energy, hence improve track performance. It is shown that adding 10% of rubber into the SEAL matrix will provide superior performance with less ballast breakage, less vibration (as reflected by the elastic energy), and comparable settlement compared to traditional track.
Qin, H & Stewart, MG 2020, 'Construction defects and wind fragility assessment for metal roof failure: A Bayesian approach', Reliability Engineering & System Safety, vol. 197, pp. 106777-106777.
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Post-damage observations reveal that construction error is one of the major contributors to roof damage for houses subjected to extreme winds. In this study, a Bayesian approach was developed to probabilistically quantify the construction defect rates in roof connections, which enables a systematic integration of expert judgement, human reliability analysis (HRA) techniques and limited construction defect data. The reductions of uplift capacities for defective roof connections were also probabilistically modelled based on experimental evidence and engineering judgement. The developed construction defect model was incorporated in a reliability-based fragility method to assess the wind damage to metal roof cladding and timber roof trusses for contemporary houses in non-cyclonic regions of Australia. It was found that, the effects of construction defects are significant for the predicted roof cladding fragility, whereas for roof truss fragility, such effects are lower.
Qin, H & Stewart, MG 2020, 'Risk-based cost-benefit analysis of climate adaptation measures for Australian contemporary houses under extreme winds', Journal of Infrastructure Preservation and Resilience, vol. 1, no. 1.
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AbstractClimate adaptation measures improve housing resilience to extreme winds, and reduce economic losses associated with wind and rainfall damage under a changing climate. Several adaptation measures are adopted in this study for Australian contemporary houses subjected to non-cyclonic windstorms to either reinforce the building envelope or increase the water resistance of building interior. A risk-based cost-benefit analysis is conducted to evaluate the cost-effectiveness of these adaptation measures that considers the effect of construction defects. It was found that the annual expected losses for houses in Brisbane with construction defects are considerably higher than those without considering construction defects, whereas the influence of construction defects is lower for the Melbourne houses. The cost-benefit analysis reveals that strengthening windows is cost-effective for Brisbane and Melbourne houses. Installing window shutters significantly reduces economic risks associated with extreme winds and is cost-effective for houses in Brisbane. Adaptation measures are generally not cost-effective for Melbourne houses due to lower extreme wind speed and associated rainfall.
Qin, H & Stewart, MG 2020, 'Wind and rain losses for metal-roofed contemporary houses subjected to non-cyclonic windstorms', Structural Safety, vol. 86, pp. 101979-101979.
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Severe windstorms cause millions in losses annually for housing in Southeast Australia that has more than half of Australia's population. The risk assessment for housing in these non-cyclonic regions is the key to assessing the cost-effectiveness of relevant wind mitigation measures to reduce economic losses. This study develops a probabilistic risk assessment framework to evaluate the wind and rain losses for new Australian contemporary houses correctly built and inspected to current standards that are subjected to non-cyclonic windstorms, which integrates the hazard modelling for extreme wind and associated rainfall, reliability-based wind damage assessment, rainwater intrusion evaluation and economic loss modelling. The risk analysis was conducted for metal-roofed contemporary houses in Brisbane and Melbourne, and the efficacy of the proposed risk assessment framework was demonstrated by comparing with inferred insurance loss data. It was found that rainwater damage to building interior and contents is the major contributor to annual expected economic losses associated with windstorms, whereas wind damage to roof cladding and windows comprises a small portion of annual losses. Preliminary model outputs also indicate that houses in Brisbane are generally subject to more losses than houses in Melbourne. However, modelling assumptions that lead to these results have yet been fully validated.
Qu, F, Li, W, Tao, Z, Castel, A & Wang, K 2020, 'High temperature resistance of fly ash/GGBFS-based geopolymer mortar with load-induced damage', Materials and Structures, vol. 53, no. 4.
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© 2020, RILEM. This study investigated the effect of elevated temperatures on the residual mechanical behaviors of geopolymer mortars with initial damage induced by mechanical load. Geopolymer mortar was prepared using different fly ash/ ground granulated blast furnace slag (GGBFS) ratios and was activated by sodium silicate and sodium hydroxide solution. The physical properties and residual mechanical strength were investigated and compared with those of Portland cement mortar (PCM). After elevated temperature exposure, microstructure of GSM was studied by various microcharacterizations. The results show that before the exposure to high temperature, the addition of GGBFS increased the compressive strength of GSM, but made it more sensitive to the preloading damage, leading to the increased strength loss. After exposed to combined preloading damage and high temperature exposure, the GSM exhibited lower residual strength than the ones only suffered from preloading damage or high temperature exposure. Compared to the PCM, GSM with GGBFS performed better at temperature of 300 °C, but became worse at temperatures of 500 and 700 °C due to severe damage caused by combined high load level and large heat exposure. Finally, a low percentage of GGBFS (less than 20%) can be considered as an optimal amount for the GSM to achieve excellent fire resistance capacity.
Qu, F, Li, W, Zeng, X, Luo, Z, Wang, K & Sheng, D 2020, 'Effect of microlimestone on properties of self-consolidating concrete with manufactured sand and mineral admixture', Frontiers of Structural and Civil Engineering, vol. 14, no. 6, pp. 1545-1560.
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© 2020, Higher Education Press. Self-consolidating concrete (SCC) with manufactured sand (MSCC) is crucial to guarantee the quality of concrete construction technology and the associated property. The properties of MSCC with different microlimestone powder (MLS) replacements of retreated manufactured sand (TMsand) are investigated in this study. The result indicates that high-performance SCC, made using TMsand (TMSCC), achieved high workability, good mechanical properties, and durability by optimizing MLS content and adding fly ash and silica fume. In particular, the TMSCC with 12% MLS content exhibits the best workability, and the TMSCC with 4% MLS content has the highest strength in the late age, which is even better than that of SCC made with the river sand (Rsand). Though MLS content slightly affects the hydration reaction of cement and mainly plays a role in the nucleation process in concrete structures compared to silica fume and fly ash, increasing MLS content can evidently have a significant impact on the early age hydration progress. TMsand with MLS content ranging from 8% to 12% may be a suitable alternative for the Rsand used in the SCC as fine aggregate. The obtained results can be used to promote the application of SCC made with manufactured sand and mineral admixtures for concrete-based infrastructure.
Rahman, MS, H. Mondal, MI, Yeasmin, MS, Sayeed, MA, Hossain, MA & Ahmed, MB 2020, 'Conversion of Lignocellulosic Corn Agro-Waste into Cellulose Derivative and Its Potential Application as Pharmaceutical Excipient', Processes, vol. 8, no. 6, pp. 711-711.
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Lignocellulosic biomass is widely grown in many agricultural-based countries. These are typically incinerated or discarded in open spaces, which further may cause severe health and environmental problems. Hence, the proper utilization and conversion of different parts of lignocellulosic biomasses (e.g., corn wastes derived leave, cob, stalk, and husk) into value-added materials could be a promising way of protecting both health and environments. In addition, they have high-potential for myriads applications (e.g., pharmaceuticals, cosmetics, textiles, and so on). In this context, herein, we isolated holocellulose (a mixture of alpha α, beta β, and gamma γ cellulose) from corn waste, and then it was converted into carboxymethyl cellulose (CMC). Subsequently, the prepared CMC was evaluated successfully to be used as a pharmaceutical excipient. Different characterization tools were employed for structural, morphological, and thermal properties of the extracted holocellulose and synthesized CMC. Results showed that the highest yield of CMC was obtained 187.5% along with the highest degree of substitution (DS i.e., 1.83) in a single stage (i.e., size reduction technique) with the lowest particle size of holocellulose (100 µm). This happened due to the use of a single stage instead of multiple stages. Finally, extracted CMC was successfully used as a pharmaceutical excipient with promising results compared to commercially available pharmaceutical-grade CMC.
Rahmati, O, Panahi, M, Ghiasi, SS, Deo, RC, Tiefenbacher, JP, Pradhan, B, Jahani, A, Goshtasb, H, Kornejady, A, Shahabi, H, Shirzadi, A, Khosravi, H, Moghaddam, DD, Mohtashamian, M & Tien Bui, D 2020, 'Hybridized neural fuzzy ensembles for dust source modeling and prediction', Atmospheric Environment, vol. 224, pp. 117320-117320.
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Ramos, A, Gomes Correia, A, Indraratna, B, Ngo, T, Calçada, R & Costa, PA 2020, 'Mechanistic-empirical permanent deformation models: Laboratory testing, modelling and ranking', Transportation Geotechnics, vol. 23, pp. 100326-100326.
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© 2020 Elsevier Ltd Geomaterials exhibit elastoplastic behaviour during dynamic and repeated loading conditions. These loads are induced by the passage of a train or vehicle which then generates recoverable (resilient) deformation and/or permanent (plastic) deformation. Modelling this behaviour is still a challenge for geotechnical engineers as it implies the understanding of the complex deformation mechanism and application of advanced constitutive models. This paper reviews on the major causes of permanent deformation and the factors that influence the long-term performance of materials. It will also present the fundamental concepts of permanent deformation as well as the models and approaches used to characterise this behaviour, including: elastoplastic models, shakedown theory and mechanistic-empirical permanent deformation models. This paper will focus on the mechanistic-empirical approach and highlight the evolution of the models, and the main similarities and differences between them. A comparison between several empirical models as well as the materials used to develop the models is also discussed. These materials are compared by considering the reference conditions on the type of material and its physical state. This approach allows for an understanding of which properties can influence the performance of railway subgrade and pavement structures, as well as the main variables used to characterise this particular behaviour. An innovative ranking of geomaterials that relate to the expected permanent deformation and classification (UIC and ASTM) of soil is also discussed because it can be used as an important tool for the design process.
Rana, HK, Akhtar, MR, Islam, MB, Ahmed, MB, Lió, P, Huq, F, Quinn, JMW & Moni, MA 2020, 'Machine Learning and Bioinformatics Models to Identify Pathways that Mediate Influences of Welding Fumes on Cancer Progression', Scientific Reports, vol. 10, no. 1.
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AbstractWelding generates and releases fumes that are hazardous to human health. Welding fumes (WFs) are a complex mix of metallic oxides, fluorides and silicates that can cause or exacerbate health problems in exposed individuals. In particular, WF inhalation over an extended period carries an increased risk of cancer, but how WFs may influence cancer behaviour or growth is unclear. To address this issue we employed a quantitative analytical framework to identify the gene expression effects of WFs that may affect the subsequent behaviour of the cancers. We examined datasets of transcript analyses made using microarray studies of WF-exposed tissues and of cancers, including datasets from colorectal cancer (CC), prostate cancer (PC), lung cancer (LC) and gastric cancer (GC). We constructed gene-disease association networks, identified signaling and ontological pathways, clustered protein-protein interaction network using multilayer network topology, and analyzed survival function of the significant genes using Cox proportional hazards (Cox PH) model and product-limit (PL) estimator. We observed that WF exposure causes altered expression of many genes (36, 13, 25 and 17 respectively) whose expression are also altered in CC, PC, LC and GC. Gene-disease association networks, signaling and ontological pathways, protein-protein interaction network, and survival functions of the significant genes suggest ways that WFs may influence the progression of CC, PC, LC and GC. This quantitative analytical framework has identified potentially novel mechanisms by which tissue WF exposure may lead to gene expression changes in tissue gene expression that affect cancer behaviour and, thus, cancer progression, growth or establishment.
Rao, RN, Silitonga, AS, Shamsuddin, AH, Milano, J, Riayatsyah, TMI, Sebayang, AH, Nur, TB, Sabri, M, Yulita, MR & Sembiring, RW 2020, 'Effect of Ethanol and Gasoline Blending on the Performance of a Stationary Small Single Cylinder Engine', Arabian Journal for Science and Engineering, vol. 45, no. 7, pp. 5793-5802.
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Rasouli, H & Fatahi, B 2020, 'Geofoam blocks to protect buried pipelines subjected to strike-slip fault rupture', Geotextiles and Geomembranes, vol. 48, no. 3, pp. 257-274.
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© 2019 Elsevier Ltd This paper proposes using geofoam blocks to improve the safety of buried steel pipelines under permanent ground deformation due to strike-slip fault rupture. Since these geofoam blocks are deformable, they can compress during fault rupture and thus reduce the pressure imposed on the pipeline by the surrounding soil. This means that the pipe can sustain a higher level of tectonic deformations. For the pipeline system adopted in this study, the geofoam blocks consist of two 1 m thick blocks at each side and another on the top of the pipeline. The effectiveness of this configuration is then assessed in comparison to the conventional buried pipeline by three dimensional numerical simulations that consider the interaction between soil and structure and the impact of critical parameters such as the pipeline-fault trace crossing angle, geofoam blocks thickness and the internal pressure of the pipeline. The results indicated that the geofoam blocks reduced the axial tensile strain of non-pressurised pipeline from the unacceptable 4.16% to the safe level of 0.75% when the crossing angle was 135°. In addition, geofoam blocks successfully decreased the maximum ovalisation parameter and compressive strain of the non-pressurised pipeline from 0.237 and −25.8% to 0.065 and −0.47%, respectively when the crossing angle was 65°.
Rasouli, H, Fatahi, B & Nimbalkar, S 2020, 'Liquefaction and post-liquefaction assessment of lightly cemented sands', Canadian Geotechnical Journal, vol. 57, no. 2, pp. 173-188.
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Post-liquefaction response of lightly cemented sands during an earthquake may change and become similar to uncemented sands due to bonding breakage. In the current study, the effect of degree of cementation on liquefaction and post-liquefaction behaviour of lightly cemented sands was studied through a series of cyclic and monotonic triaxial tests. Portland cement with high early strength and Sydney sand were used to reconstitute the lightly cemented specimens with unconfined compression strength ranging from 25 to 220 kPa. A series of multi-stage soil element tests including stress-controlled cyclic loading events with different amplitudes and post-cyclic undrained monotonic shearing tests were carried out on both uncemented and cemented specimens. Furthermore, a series of undrained monotonic shearing tests without cyclic loading history on different types of specimens was conducted to investigate the effect of cyclic loading history on the post-cyclic response of the specimens. The results show that residual excess pore-water pressure is correlated to the cyclic degradation of lightly cemented sands during cyclic loading. In addition, optical microstructure images of the cemented specimens after liquefaction showed that a major proportion of cementation bonds remained unbroken, which resulted in a superior post-liquefaction response with respect to initial stiffness and shear modulus in comparison to the uncemented sand.
Ratiko, R, Wisnubroto, DS, Nasruddin, N & Mahlia, TMI 2020, 'Current and future strategies for spent nuclear fuel management in Indonesia', Energy Strategy Reviews, vol. 32, pp. 100575-100575.
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© 2020 The Author(s) Currently, Indonesia has only three nuclear research reactors. However, Indonesia is the world's fourth most populous country. Owing to the enormous size and rapid growth of the population and the limited availability of fossil fuel and renewable energy resources, the construction of new nuclear power plants (NPPs) has been considered. Because of this, the management policies for long-term spent nuclear fuel in Indonesia have become crucial. This paper reviews the current handling and future management strategies for spent nuclear fuel in Indonesia. With a maximum capacity of 1448 spent fuel elements, Indonesia's interim wet storage of spent fuel (ISSF) is designed to store spent nuclear fuel arising from 25 years of reactor operation at maximum power. However, with the existing low-power reactor operation, the ISSF could be utilized for more than 75 years. The potential problem for long-term storage in the ISSF is system, structure, and component (SSC) aging. Continuous planning, operation, monitoring, and maintenance of the SSC in the ISSF have been conducted to ensure safe long-term utilization of the facility. In accordance with the possibility of NPP construction in the future, three possible scenarios may be considered for future nuclear spent fuel management strategies in Indonesia: 1) wet storage - dry storage - disposal; 2) wet storage -repatriation or sending to other countries; and 3) wet storage - moving to wet- or dry storage of NPP candidate - disposal.
Razzaq, L, Imran, S, Anwar, Z, Farooq, M, Abbas, MM, Mehmood Khan, H, Asif, T, Amjad, M, Soudagar, MEM, Shaukat, N, Rizwanul Fattah, IM & Rahman, SMA 2020, 'Maximising Yield and Engine Efficiency Using Optimised Waste Cooking Oil Biodiesel', Energies, vol. 13, no. 22, pp. 5941-5941.
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In this study, waste cooking oil (WCO) was used as a feedstock for biodiesel production, where the pretreatment of WCO was performed using mineral acids to reduce the acid value. The response surface methodology (RSM) was used to create an interaction for different operating parameters that affect biodiesel yield. The optimised biodiesel yield was 93% at a reaction temperature of 57.50 °C, catalyst concentration 0.25 w/w, methanol to oil ratio 8.50:1, reaction stirring speed 600 rpm, and a reaction time of 3 h. Physicochemical properties, including lower heating value, density, viscosity, cloud point, and flash point of biodiesel blends, were determined using American Society for Testing and Materials (ASTM) standards. Biodiesel blends B10, B20, B30, B40, and B50 were tested on a compression ignition engine. Engine performance parameters, including brake torque (BT), brake power (BP), brake thermal efficiency (BTE), and brake specific fuel consumption (BSFC) were determined using biodiesel blends and compared to that of high-speed diesel. The average BT reduction for biodiesel blends compared to HSD at 3000 rpm were found to be 1.45%, 2%, 2.2%, 3.09%, and 3.5% for B10, B20, B30, B40, and B50, respectively. The average increase in BSFC for biodiesel blends compared to HSD at 3500 rpm were found to be 1.61%, 5.73%, 8.8%, 12.76%, and 18% for B10, B20, B30, B40, and B50, respectively.
Ren, L-F, Ngo, HH, Bu, C, Ge, C, Ni, S-Q, Shao, J & He, Y 2020, 'Novel external extractive membrane bioreactor (EMBR) using electrospun polydimethylsiloxane/polymethyl methacrylate membrane for phenol-laden saline wastewater', Chemical Engineering Journal, vol. 383, pp. 123179-123179.
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© 2019 Elsevier B.V. Phenol-laden saline wastewaters can adversely affect water, groundwater, soil, organisms and ecosystems. Given that frequently-used biodegradation process is generally inhibited by salinity, this work aims to solve the problem through a novel configuration of external extractive membrane bioreactor (EMBR) for the objective of simultaneous phenol permeation, salt rejection and biodegradation. Contact angles of 160.9 ± 2.2° (water) and 0.0° (phenol) were observed on the electrospun polydimethylsiloxane/polymethyl methacrylate (PDMS/PMMA) membrane, suggesting this superhydrophobic/superorganophilic membrane was suitable for separating phenol from water-soluble salt. Phenol ranging from 14.1 ± 2.7 to 290.7 ± 10.4 mg/L (stages 1 to 8) was continuously permeated and completely biodegraded in external EMBR under a hydraulic retention time (HRT) of 24 h, which corresponded with detoxification performance improving from 6.3% to 70.5%. After phenol exposure of 8 stages, Proteobacteria and Saccharibacteria became the main phyla for microorganisms. Enumeration of functional genes (phe, amoA, narG, nirS) confirmed that phenol was mainly consumed by denitrifiers and other heterotrophs as the sole carbon and energy source via oxidation and ring cleavage. As bacterial responses, these genes’ proliferation was promoted under low phenol concentrations but inhibited under high phenol concentrations. Meanwhile, results of extracellular polymeric substances revealed that protein was the key substance in toxicity resistance, phenol adsorption and transfer.
Ren, Y, Hao Ngo, H, Guo, W, Wang, D, Peng, L, Ni, B-J, Wei, W & Liu, Y 2020, 'New perspectives on microbial communities and biological nitrogen removal processes in wastewater treatment systems', Bioresource Technology, vol. 297, pp. 122491-122491.
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Biological nitrogen removal (BNR) is a critical process in wastewater treatment. Recently, there have new microbial communities been discovered to be capable of performing BNR with novel metabolic pathways. This review presents the up-to-date status on these microorganisms, including ammonia oxidizing archaea (AOA), complete ammonia oxidation (COMAMMOX) bacteria, anaerobic ammonium oxidation coupled to iron reduction (FEAMMOX) bacteria, anaerobic ammonium oxidation (ANAMMOX) bacteria and denitrifying anaerobic methane oxidation (DAMO) microorganism. Their metabolic pathways and enzymatic reactions in nitrogen cycle are demonstrated. Generally, these novel microbial communities have advantages over canonical nitrifiers or denitrifiers, such as higher substrate affinities, better physicochemical tolerances and/or less greenhouse gas emission. Also, their recent development and/or implementation in BNR is discussed and outlook. Finally, the key implications of coupling these microbial communities for BNR are identified. Overall, this review illustrates novel microbial communities that could provide new possibilities for high-performance and energy-saving nitrogen removal from wastewater.
Rezaei, M, Razavi Bazaz, S, Zhand, S, Sayyadi, N, Jin, D, Stewart, MP & Ebrahimi Warkiani, M 2020, 'Point of Care Diagnostics in the Age of COVID-19', Diagnostics, vol. 11, no. 1, pp. 9-9.
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The recent outbreak of the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) and its associated serious respiratory disease, coronavirus disease 2019 (COVID-19), poses a major threat to global public health. Owing to the lack of vaccine and effective treatments, many countries have been overwhelmed with an exponential spread of the virus and surge in the number of confirmed COVID-19 cases. Current standard diagnostic methods are inadequate for widespread testing as they suffer from prolonged turn-around times (>12 h) and mostly rely on high-biosafety-level laboratories and well-trained technicians. Point-of-care (POC) tests have the potential to vastly improve healthcare in several ways, ranging from enabling earlier detection and easier monitoring of disease to reaching remote populations. In recent years, the field of POC diagnostics has improved markedly with the advent of micro- and nanotechnologies. Due to the COVID-19 pandemic, POC technologies have been rapidly innovated to address key limitations faced in existing standard diagnostic methods. This review summarizes and compares the latest available POC immunoassay, nucleic acid-based and clustered regularly interspaced short palindromic repeats- (CRISPR)-mediated tests for SARS-CoV-2 detection that we anticipate aiding healthcare facilities to control virus infection and prevent subsequent spread.
Rizwanul Fattah, IM, Ong, HC, Mahlia, TMI, Mofijur, M, Silitonga, AS, Rahman, SMA & Ahmad, A 2020, 'State of the Art of Catalysts for Biodiesel Production', Frontiers in Energy Research, vol. 8.
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© Copyright © 2020 Rizwanul Fattah, Ong, Mahlia, Mofijur, Silitonga, Rahman and Ahmad. Biodiesel is one of the potential alternative energy sources that can be derived from renewable and low-grade origin through different processes. One of the processes is alcoholysis or transesterification in the presence of a suitable catalyst. The catalyst can be either homogeneous or heterogeneous. This article reviews various catalysts used for biodiesel production to date, presents the state of the art of types of catalysts, and compares their suitability and associated challenges in the transesterification process. Biodiesel production using homogeneous and heterogeneous catalysis has been studied extensively, and novel heterogeneous catalysts are being continuously investigated. Homogeneous catalysts are generally efficient in converting biodiesel with low free fatty acid (FFA) and water containing single-origin feedstock. Heterogeneous catalysts, on the other hand, provide superior activity, range of selectivity, good FFA, and water adaptability. The quantity and strengths of active acid or basic sites control these properties. Some of the heterogeneous catalysts such as zirconia and zeolite-based catalysts can be used as both basic and acidic catalyst by suitable alteration. Heterogeneous catalysts from waste and biocatalysts play an essential role in attaining a sustainable alternative to traditional homogeneous catalysts for biodiesel production. Recently, high catalytic efficiency at mild operating conditions has drawn attention to nanocatalysts. This review evaluates state of the art and perspectives for catalytic biodiesel production and assesses the critical operational variables that influence biodiesel production along with the technological solutions for sustainable implementation of the process.
Roobavannan, M, Kandasamy, J, Pande, S, Vigneswaran, S & Sivapalan, M 2020, 'Sustainability of agricultural basin development under uncertain future climate and economic conditions: A socio-hydrological analysis', Ecological Economics, vol. 174, pp. 106665-106665.
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© 2020 Elsevier B.V. A socio-hydrological model is used to forecast future conditions in a river basin arising from changes in climate and the economy in order to learn about macroeconomic conditions that would yield pathways for sustainable development and how they may be affected by changes in climate and the economy. The study uses a system dynamics model with endogenous social values and preferences and exogenous climate and economic drivers. Basin scale sustainability is defined as a function of economic growth, provision of environmental services and equality within the basin. The analysis reveals that a diversified basin economy is important to achieve sustainable development. Under current climate conditions, a higher level of diversification in the basin's economy increases sustainability. Higher current capital growth rates, e.g., >2% of the current rate, would also lead to more sustainable development of a kind that is less affected by the availability of water and robust to vagaries of climate change. The results suggest that policy-makers and resource managers should focus on measures to diversify the economy when it is thriving, but also consider the capacity of society to adapt to unpredictable shocks to the system.
Roobavannan, S, Vigneswaran, S & Naidu, G 2020, 'Enhancing the performance of membrane distillation and ion-exchange manganese oxide for recovery of water and lithium from seawater', Chemical Engineering Journal, vol. 396, pp. 125386-125386.
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© 2020 Elsevier B.V. Recovering lithium (Li) from natural sources such as seawater is a sustainable alternative to meet its high demands. Li recovery from seawater must be enhanced to attain economic efficiency. In this work, the potential of enhancing Li recovery from seawater by acid treated manganese oxide ion sieve (HMO) is evaluated by increasing Li concentration in seawater using direct contact membrane distillation (DCMD) and reducing competitive ions. DCMD achieved enhanced water recovery upon pre-treatment with oxalic acid (88–91%) compared to caustic soda ash (65–68%) and without pre-treatment (47–51%). Caustic soda ash required Na addition in alkaline condition for Ca removal, while, oxalic acid removed Ca in acidic condition without any inorganic ion addition. The low ion concentration in acidic condition upon oxalic acid pre-treatment enabled DCMD to concentrate seawater to high levels, increasing Li concentration by 7 times. In Li solution, HMO achieved a maximum adsorptive capacity (Langmuir Qmax) of 17.8 mg/g in alkaline condition. Multiple cycles of desorption and regeneration of HMO showed only 7–11% decline of Li uptake and minimal Mn dissolution, which, established HMO's reuse capacity. Selective Li mechanism is attributed to H/Li exchange as well as high negative surface charge of HMO. In seawater, Li uptake by HMO reduced by 44–46% due to Mg. Seawater with minimal Mg was favourable for enhancing Li uptake by HMO. Seawater treatment in stages – divalent pretreament and concentrating seawater, followed by HMO, provided a favourable scenario for attaining high quality water, selective Li recovery, and other resources – Ca and Mg.
Roslidar, R, Rahman, A, Muharar, R, Syahputra, MR, Arnia, F, Syukri, M, Pradhan, B & Munadi, K 2020, 'A Review on Recent Progress in Thermal Imaging and Deep Learning Approaches for Breast Cancer Detection', IEEE Access, vol. 8, pp. 116176-116194.
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© 2013 IEEE. Developing a breast cancer screening method is very important to facilitate early breast cancer detection and treatment. Building a screening method using medical imaging modality that does not cause body tissue damage (non-invasive) and does not involve physical touch is challenging. Thermography, a non-invasive and non-contact cancer screening method, can detect tumors at an early stage even under precancerous conditions by observing temperature distribution in both breasts. The thermograms obtained on thermography can be interpreted using deep learning models such as convolutional neural networks (CNNs). CNNs can automatically classify breast thermograms into categories such as normal and abnormal. Despite their demostrated utility, CNNs have not been widely used in breast thermogram classification. In this study, we aimed to summarize the current work and progress in breast cancer detection based on thermography and CNNs. We first discuss of breast thermography potential in early breast cancer detection, providing an overview of the availability of breast thermal datasets together with publicly accessible. We also discuss characteristics of breast thermograms and the differences between healthy and cancerous thermographic patterns. Breast thermogram classification using a CNN model is described step by step including a simulation example illustrating feature learning. We cover most research related to the implementation of deep neural networks for breast thermogram classification and propose future research directions for developing representative datasets, feeding the segmented image, assigning a good kernel, and building a lightweight CNN model to improve CNN performance.
Rostami, AA, Karimi, V, Khatibi, R & Pradhan, B 2020, 'An investigation into seasonal variations of groundwater nitrate by spatial modelling strategies at two levels by kriging and co-kriging models', Journal of Environmental Management, vol. 270, pp. 110843-110843.
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Nitrate pollution of groundwater through spatial models is investigated in this paper by using a sample of nitrate values at monitoring wells using the data from four seasons of a year, in which data are sparse. Two spatial modelling strategies are formulated at two levels, in which Strategy 1 comprises: three variations of kriging-based models (ordinary kriging, simple kriging and universal kriging), which are constructed at Level 1 to predict nitrate concentrations; and a Multiple Co-Kriging (MCoK) model is used at Level 2 to enhance the accuracy of the predictions. Strategy 2 is also at two levels but employs Indicator Kriging (IK) at Level 1 as a probabilistic spatial model to predict areas at risk of exceeding two thresholds of 37.5 mg/L and 50 mg/L of nitrate concentration, and Multiple Co-Indicator Kriging (MCoIK) at Level 2 for a better accuracy. The improvements at Level 2 for both strategies are remarkable and hence they are used to gain an insight into inherent problems. The results of a study delineate areas with excessive nitrate concentrations, which are in the vicinity of urban areas and hence reflect poor planning practices since the 1990s. The results further reveal the patterns on sensitivities to seasonal variations driven by aquifer recharge and strong dilution processes in spring times; and on the role of pumpage impacting aquifers giving rise to possible hotspots of nitrate concentrations.
Roy, P, Chandra Pal, S, Arabameri, A, Chakrabortty, R, Pradhan, B, Chowdhuri, I, Lee, S & Tien Bui, D 2020, 'Novel Ensemble of Multivariate Adaptive Regression Spline with Spatial Logistic Regression and Boosted Regression Tree for Gully Erosion Susceptibility', Remote Sensing, vol. 12, no. 20, pp. 3284-3284.
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The extreme form of land degradation through different forms of erosion is one of the major problems in sub-tropical monsoon dominated region. The formation and development of gullies is the dominant form or active process of erosion in this region. So, identification of erosion prone regions is necessary for escaping this type of situation and maintaining the correspondence between different spheres of the environment. The major goal of this study is to evaluate the gully erosion susceptibility in the rugged topography of the Hinglo River Basin of eastern India, which ultimately contributes to sustainable land management practices. Due to the nature of data instability, the weakness of the classifier andthe ability to handle data, the accuracy of a single method is not very high. Thus, in this study, a novel resampling algorithm was considered to increase the robustness of the classifier and its accuracy. Gully erosion susceptibility maps have been prepared using boosted regression trees (BRT), multivariate adaptive regression spline (MARS) and spatial logistic regression (SLR) with proposed resampling techniques. The re-sampling algorithm was able to increase the efficiency of all predicted models by improving the nature of the classifier. Each variable in the gully inventory map was randomly allocated with 5-fold cross validation, 10-fold cross validation, bootstrap and optimism bootstrap, while each consisted of 30% of the database. The ensemble model was tested using 70% and validated with the other 30% using the K-fold cross validation (CV) method to evaluate the influence of the random selection of training and validation database. Here, all resampling methods are associated with higher accuracy, but SLR bootstrap optimism is more optimal than any other methods according to its robust nature. The AUC values of BRT optimism bootstrap, MARS optimism bootstrap and SLR optimism bootstrap are 87.40%, 90.40% and 90.60%, respectively. According ...
Rujikiatkamjorn, C 2020, 'Editorial', Proceedings of the Institution of Civil Engineers - Ground Improvement, vol. 173, no. 4, pp. 187-187.
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Saco, PM, Rodríguez, JF, Moreno-de las Heras, M, Keesstra, S, Azadi, S, Sandi, S, Baartman, J, Rodrigo-Comino, J & Rossi, MJ 2020, 'Using hydrological connectivity to detect transitions and degradation thresholds: Applications to dryland systems', CATENA, vol. 186, pp. 104354-104354.
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Sadeghi, F, Li, J & Zhu, X 2020, 'A Steel-Concrete Composite Beam Element for Structural Damage Identification', International Journal of Structural Stability and Dynamics, vol. 20, no. 10, pp. 2042015-2042015.
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The composite action between the layers of steel and concrete is governed by the shear connection. Because of the complicated interconnection behavior of these composite layers, it is difficult to detect damage in the composite structures, especially, the interfacial integrity of the two layers. In this paper, anovel method has been developed for structural damage identification of composite structures based on a steel-concrete composite beam element with bonding interface. In displacement-based finite element (FE) formulation, three damage indicators have been embedded into stiffness matrix of the composite beam that are defined as a stiffness reduction in the concrete, steel and interface layers. An algorithm-based on recursive quadratic programming has been proposed to identify structural damage in the composite beam from static measurements. The analytical FE model is validated by adapting its static responses in undamaged state with those obtained from an equal experimental model as well as a FE model developed in commercial software ABAQUS. A convergence study is conducted to determine the number of the composite beam FEs. To verify the proposed method, the static responses of the FE model with different damage cases at a given loading are calculated, and the measurements are simulated by adding different levels of white noise. Then, the proposed algorithm is applied to identify damage of the composite beam. The effects of measurement noise, loading location and amplitude, measurement numbers and the sizes of FE mesh on the identified results have been investigated. The numerical results show that this method is efficient and accurate to separately identify small damage in the concrete slab, and the steel girder and bonding interface of the composite beam.
Safira, L, Putra, N, Trisnadewi, T, Kusrini, E & Mahlia, TMI 2020, 'Thermal properties of sonicated graphene in coconut oil as a phase change material for energy storage in building applications1', International Journal of Low-Carbon Technologies, vol. 15, no. 4, pp. 629-636.
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Abstract This study aims to investigate the thermal properties of a phase change material (PCM) based on coconut oil for building energy storage applications. Coconut oil is classified as an organic PCM composed of fatty acids made from renewable feedstock. However, low thermal conductivity is one of the major drawbacks of organic PCMs that must be improved. Graphene could be an effective material to enhance the thermal performance of organic PCMs. In this study, coconut oil with a latent heat capacity of 114.6 J/g and a melting point of 17.38°C was used. PCMs were prepared by sonicating graphene into coconut oil, as a supporting material. The mass fractions of the prepared PCMs were 0, 0.1, 0.2, 0.3, 0.4 and 0.5. Thermal conductivity tests were performed using a KD2 thermal property analyser under different ambient temperatures of 5, 10, 15, 20 and 25°C simulated with a circulating thermostatic bath. The latent heat, melting point and freezing point were determined through differential scanning calorimetry, the thermal stability was determined using thermogravimetric analysis (TGA) and the morphology and chemical structure were examined using transmission electron microscopy and Fourier-transform infrared spectroscopy, respectively. The results of this study showed that graphene addition to coconut oil improved the thermal performance, with the highest improvement seen in a 0.3 wt% sample at 20°C. The latent heat decreased by 11% owing to molecular movements within the PCM. However, TGA revealed that the composite PCMs showed good thermal stability in ambient building temperature ranges.
Saha, S, Saha, A, Hembram, TK, Pradhan, B & Alamri, AM 2020, 'Evaluating the Performance of Individual and Novel Ensemble of Machine Learning and Statistical Models for Landslide Susceptibility Assessment at Rudraprayag District of Garhwal Himalaya', Applied Sciences, vol. 10, no. 11, pp. 3772-3772.
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Landslides are known as the world’s most dangerous threat in mountainous regions and pose a critical obstacle for both economic and infrastructural progress. It is, therefore, quite relevant to discuss the pattern of spatial incidence of this phenomenon. The current research manifests a set of individual and ensemble of machine learning and probabilistic approaches like an artificial neural network (ANN), support vector machine (SVM), random forest (RF), logistic regression (LR), and their ensembles such as ANN-RF, ANN-SVM, SVM-RF, SVM-LR, LR-RF, LR-ANN, ANN-LR-RF, ANN-RF-SVM, ANN-SVM-LR, RF-SVM-LR, and ANN-RF-SVM-LR for mapping landslide susceptibility in Rudraprayag district of Garhwal Himalaya, India. A landslide inventory map along with sixteen landslide conditioning factors (LCFs) was used. Randomly partitioned sets of 70%:30% were used to ascertain the goodness of fit and predictive ability of the models. The contribution of LCFs was analyzed using the RF model. The altitude and drainage density were found to be the responsible factors in causing the landslide in the study area according to the RF model. The robustness of models was assessed through three threshold dependent measures, i.e., receiver operating characteristic (ROC), precision and accuracy, and two threshold independent measures, i.e., mean-absolute-error (MAE) and root-mean-square-error (RMSE). Finally, using the compound factor (CF) method, the models were prioritized based on the results of the validation methods to choose best model. Results show that ANN-RF-LR indicated a realistic finding, concentrating only on 17.74% of the study area as highly susceptible to landslide. The ANN-RF-LR ensemble demonstrated the highest goodness of fit and predictive capacity with respective values of 87.83% (area under the success rate curve) and 93.98% (area under prediction rate curve), and the highest robustness correspondingly. These attempts will play a significant role in ensemble ...
Saharkhiz, MA, Pradhan, B, Rizeei, HM & Jung, HS 2020, 'Land use feature extraction and sprawl development prediction from quickbird satellite imagery using Dempster-Shafer and land transformation model', Korean Journal of Remote Sensing, vol. 36, no. 1, pp. 15-27.
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Accurate knowledge of land use/land cover (LULC) features and their relative changes over upon the time are essential for sustainable urban management. Urban sprawl growth has been always also a worldwide concern that needs to carefully monitor particularly in a developing country where unplanned building constriction has been expanding at a high rate. Recently, remotely sensed imageries with a very high spatial/spectral resolution and state of the art machine learning approaches sent the urban classification and growth monitoring to a higher level. In this research, we classified the Quickbird satellite imagery by object-based image analysis of Dempster-Shafer (OBIA-DS) for the years of 2002 and 2015 at Karbala-Iraq. The real LULC changes including, residential sprawl expansion, amongst these years, were identified via change detection procedure. In accordance with extracted features of LULC and detected trend of urban pattern, the future LULC dynamic was simulated by using land transformation model (LTM) in geospatial information system (GIS) platform. Both classification and prediction stages were successfully validated using ground control points (GCPs) through accuracy assessment metric of Kappa coefficient that indicated 0.87 and 0.91 for 2002 and 2015 classification as well as 0.79 for prediction part. Detail results revealed a substantial growth in building over fifteen years that mostly replaced by agriculture and orchard field. The prediction scenario of LULC sprawl development for 2030 revealed a substantial decline in green and agriculture land as well as an extensive increment in build-up area especially at the countryside of the city without following the residential pattern standard. The proposed method helps urban decision-makers to identify the detail temporal-spatial growth pattern of highly populated cities like Karbala. Additionally, the results of this study can be considered as a probable future map in order to design enough future...
Sahoo, S, Dhar, A, Debsarkar, A, Pradhan, B & Alamri, AM 2020, 'Future Water Use Planning by Water Evaluation and Planning System Model', Water Resources Management, vol. 34, no. 15, pp. 4649-4664.
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© 2020, Springer Nature B.V. Assessment of future water availability is a challenging task under changing climatic conditions and anthropogenic interventions. The current research focuses on future water resources scenario generation for contributing areas of proposed hydraulic structures generated from the Water Evaluation and Planning (WEAP) System model. The proposed methodology was implemented for the Dwarakeswar-Gandherswari river basin (India) which needs a long-term future water use plan. Bias-corrected Representative Concentration Pathways (RCPs) data were used for climate change analysis through a hydrological model. Different simulation model outputs [e.g. Dynamic Conversion of Land-Use and its Effects (Dyna-CLUE), Soil and Water Assessment Tool (SWAT), Modular Finite-Difference Flow Model (MODFLOW)] were utilized in water evaluation model for a generation of future water resources scenarios. Four scenarios (2010–2030–2050-2080) were generated for the sustainability of limited water resources management strategies. SWAT simulated results show an increase in river discharge for 2030 or 2080 and a decrease for 2050. MODFLOW simulated results show a visible groundwater storage change for 2030 but minimal change for 2050 and 2080 scenarios. The results also show a decrease in agricultural land and an increase in population for the contributing areas of three hydraulic structures during 2010–2030–2050-2080. These results provide a piece of valuable information for decision-makers in future water management plan preparation.
Samadi-Boroujeni, H, Abbasi, S, Altaee, A & Fattahi-Nafchi, R 2020, 'Numerical and Physical Modeling of the Effect of Roughness Height on Cavitation Index in Chute Spillways', International Journal of Civil Engineering, vol. 18, no. 5, pp. 539-550.
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© 2019, Iran University of Science and Technology. This study presents the results of physical and numerical modeling of the effect of bed roughness height of chute spillways on the cavitation index. A 1:50-scale physical hydraulic model of the chute spillway of Surk Dam was constructed at the hydraulic laboratory of Shahrekord University, Iran. The experiments were conducted for different flow rates and the parameters of pressure, velocity, and flow depth in 26 positions along the chute. Finally, the ANSYS-FLUENT model was calibrated in the chute spillway using the experimental data by assumptions of two-phase volume of fluid and k–ε (RNG) turbulence models. The cavitation index in different sections of the chute spillway was calculated for different values of bed roughness including the roughness heights of 1, 2, and 2.5 mm. Results showed that the minimum values of the cavitation index were 0.2906, 0.2733, and 0.2471 for the roughness heights of 1, 2, and 2.5 mm, respectively. The statistical significance analysis showed that reducing the roughness height from 2.5 to 1 mm would not change significantly the value of the cavitation index at 95% confidence interval.
Samaei, SM, Gato-Trinidad, S & Altaee, A 2020, 'Performance evaluation of reverse osmosis process in the post-treatment of mining wastewaters: Case study of Costerfield mining operations, Victoria, Australia', Journal of Water Process Engineering, vol. 34, pp. 101116-101116.
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© 2019 Elsevier Ltd Reverse Osmosis (RO) membrane has been used for treatment and purification of industrial wastewaters including those from the mining industry before being discharged to receiving body or reuse for applications that are fit for purpose. This study evaluates the performance of Reverse Osmosis (RO) plant as a post-treatment process in mining operations in Victoria, Australia. The data analysis shows that the RO unit significantly improves the quality of the final permeate before discharged to surface waters. Considering average rejection efficiency for the entire evaluated period, turbidity, total dissolved solids (TDS), Antimony, Arsenic, Nickel, Zinc and Iron concentrations are reduced by 85 %, 96 %, 95 %, 66 %, 82 %, 48 % and 10 %, respectively in the RO permeate compared to the feed water. Although the quality of the RO permeate was in a desirable condition in most days of the evaluated years, TDS concentrations on the October 11 and 20,2016 and November 14, 2017 were higher than the limits specified by Environmental Protection Authority (EPA) Victoria. Anomalies regarding antimony levels in RO permeate occurred in September and November 2016 as well as August 2017 due to inconsistency in the RO feed quality. This resulted in fouling of RO membranes and contributed to discharge non-compliance with EPA licence conditions on TDS and antimony. Discharge to waterways was suspended over the period when TDS and antimony contents were above the EPA guidelines. Changes in the pre-treatment reduced the turbidity of the feed water and improved the performance of the RO system to comply with the discharge guidelines.
Sameen, MI, Pradhan, B & Lee, S 2020, 'Application of convolutional neural networks featuring Bayesian optimization for landslide susceptibility assessment', CATENA, vol. 186, pp. 104249-104249.
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© 2019 Elsevier B.V. This study developed a deep learning based technique for the assessment of landslide susceptibility through a one-dimensional convolutional network (1D-CNN) and Bayesian optimisation in Southern Yangyang Province, South Korea. A total of 219 slide inventories and 17 slide conditioning variables were obtained for modelling. The data showed a complex scenario. Some past slides have spread over steep lands, while others have spread through flat terrain. Random forest (RF) served to keep only important factors for further analysis as a pre-processing measure. To select CNN hyperparameters, Bayesian optimization was used. Three methods contributed to overcoming the overfitting issue owing to small training data in our research. The selection of key factors by RF helped first of all to reduce information dimensionality. Second, the CNN model with 1D convolutions was intended to considerably decrease the number of its parameters. Third, a high rate of drop-out (0.66) helped reduce the CNN parameters. Overall accuracy, area under the receiver operating characteristics curve (AUROC) and 5-fold cross-validation were used to evaluate the models. CNN performance was compared to ANN and SVM. CNN achieved the highest accuracy on testing dataset (83.11%) and AUROC (0.880, 0.893, using testing and 5-fold CV, respectively). Bayesian optimization enhanced CNN accuracy by~3% (compared with default configuration). CNN could outperform ANN and SVM owing to its complicated architecture and handling of spatial correlations through convolution and pooling operations. In complex situations where some variables make a non-linear contribution to the occurrence of landslides, the method suggested could thus help develop landslide susceptibility maps.
Sameen, MI, Pradhan, B, Bui, DT & Alamri, AM 2020, 'Systematic sample subdividing strategy for training landslide susceptibility models', CATENA, vol. 187, pp. 104358-104358.
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© 2019 Elsevier B.V. Current practice in choosing training samples for landslide susceptibility modelling (LSM) is to randomly subdivide inventory information into training and testing samples. Where inventory data differ in distribution, the selection of training samples by a random process may cause inefficient training of machine learning (ML)/statistical models. A systematic technique may, however, produce efficient training samples that well represent the entire inventory data. This is particularly true when inventory information is scarce. This research proposed a systemic strategy to deal with this problem based on the fundamental distribution of probabilities (i.e. Hellinger) and a novel graphical representation of information contained in inventory data (i.e. inventory information curve, IIC). This graphical representation illustrates the relative increase in available information with the growth of the training sample size. Experiments on a selected dataset over the Cameron Highlands, Malaysia were conducted to validate the proposed methods. The dataset contained 104 landslide inventories and 7 landslide-conditioning factors (i.e. altitude, slope, aspect, land use, distance from the stream, distance from the road and distance from lineament) derived from a LiDAR-based digital elevation model and thematic maps acquired from government authorities. In addition, three ML/statistical models, namely, k-nearest neighbour (KNN), support vector machine (SVM) and decision tree (DT), were utilised to assess the proposed sampling strategy for LSM. The impacts of model's hyperparameters, noise and outliers on the performance of the models and the shape of IICs were also investigated and discussed. To evaluate the proposed method further, it was compared with other standard methods such as random sampling (RS), stratified RS (SRS) and cross-validation (CV). The evaluations were based on the area under the receiving characteristic curves. The results show that IICs a...
Sameen, MI, Sarkar, R, Pradhan, B, Drukpa, D, Alamri, AM & Park, H-J 2020, 'Landslide spatial modelling using unsupervised factor optimisation and regularised greedy forests', Computers & Geosciences, vol. 134, pp. 104336-104336.
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Samiee, A, Ahmed, M, Yang, L & Pereloma, E 2020, 'The effect of continuous heating on microstructure development in thermo-mechanically processed Ti-10V-3Fe-3Al alloy produced by powder metallurgy', Materials Characterization, vol. 161, pp. 110172-110172.
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Sandi, SG, Saco, PM, Rodriguez, JF, Saintilan, N, Wen, L, Kuczera, G, Riccardi, G & Willgoose, G 2020, 'Patch organization and resilience of dryland wetlands', Science of The Total Environment, vol. 726, pp. 138581-138581.
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Satya, A, Harimawan, A, Haryani, GS, Johir, MAH, Vigneswaran, S, Ngo, HH & Setiadi, T 2020, 'Batch Study of Cadmium Biosorption by Carbon Dioxide Enriched Aphanothece sp. Dried Biomass', Water, vol. 12, no. 1, pp. 264-264.
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The conventional method for cadmium removal in aqueous solutions (1–100 mg/L) is ineffective and inefficient. Therefore, a batch biosorption reactor using a local freshwater microalga (originating from an urban lake, namely, Situ Rawa Kalong-Depok) as dried biosorbent was tested. Biosorbent made from three kinds of cyanobacterium Aphanothece sp. cultivars (A0, A8, and A15) were used to eliminate cadmium (Cd2+) ions in aqueous solution (1–7 mg/L). The biosorbents were harvested from a photobioreactor system enriched with carbon dioxide gas of 0.04% (atmospheric), 8%, and 15% under continuous light illumination of about 5700–6000 lux for 14 d of cultivation. Produced dried biosorbents had Brunauer–Emmet–Teller (BET) surface area ranges of 0.571–1.846 m2/g. Biosorption of Cd2+ was pH and concentration dependent. Sorption was spontaneous (ΔG = −8.39 to −10.88 kJ/mol), exothermic (ΔH = −41.85 to −49.16 kJ/mol), and decreased randomness (ΔS = −0.102 to −0.126 kJ/mol. K) on the interface between solid and liquid phases when the process was completed. The kinetic sorption data fitted best to the pseudo-second-order model (k2 = 2.79 × 10−2, 3.96 × 10−2, and 4.54 × 10−2 g/mg.min). The dried biosorbents of A0, A8, and A15, after modeling with the Langmuir and Dubinin–Radushkevich isotherm models, indicated that cadmium binding occurred through chemisorption (qmax, D-R = 9.74 × 10−4, 4.79 × 10−3, and 9.12 × 10−3 mol/g and mean free energy of 8.45, 11.18, and 11.18 kJ/mol) on the monolayer and homogenous surface (qmax, Langmuir of 12.24, 36.90, and 60.24 mg/g). In addition, the results of SEM, EDX, and FTIR showed that there were at least nine functional groups that interacted with Cd2+ (led to bond formation) after biosorption through cation exchange mechanisms, and morphologically the surfaces changed after biosorption. Biosorbent A15 indicated the best resilient features over three cycles of sorption–desorption using 1 M HCl as the desorbing eluent. These...
Sekandari, M, Masoumi, I, Beiranvand Pour, A, M Muslim, A, Rahmani, O, Hashim, M, Zoheir, B, Pradhan, B, Misra, A & Aminpour, SM 2020, 'Application of Landsat-8, Sentinel-2, ASTER and WorldView-3 Spectral Imagery for Exploration of Carbonate-Hosted Pb-Zn Deposits in the Central Iranian Terrane (CIT)', Remote Sensing, vol. 12, no. 8, pp. 1239-1239.
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The exploration of carbonate-hosted Pb-Zn mineralization is challenging due to the complex structural-geological settings and costly using geophysical and geochemical techniques. Hydrothermal alteration minerals and structural features are typically associated with this type of mineralization. Application of multi-sensor remote sensing satellite imagery as a fast and inexpensive tool for mapping alteration zones and lithological units associated with carbonate-hosted Pb-Zn deposits is worthwhile. Multiple sources of spectral data derived from different remote sensing sensors can be utilized for detailed mapping a variety of hydrothermal alteration minerals in the visible near infrared (VNIR) and the shortwave infrared (SWIR) regions. In this research, Landsat-8, Sentinel-2, Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and WorldView-3 (WV-3) satellite remote sensing sensors were used for prospecting Zn-Pb mineralization in the central part of the Kashmar–Kerman Tectonic Zone (KKTZ), the Central Iranian Terrane (CIT). The KKTZ has high potential for hosting Pb-Zn mineralization due to its specific geodynamic conditions (folded and thrust belt) and the occurrence of large carbonate platforms. For the processing of the satellite remote sensing datasets, band ratios and principal component analysis (PCA) techniques were adopted and implemented. Fuzzy logic modeling was applied to integrate the thematic layers produced by image processing techniques for generating mineral prospectivity maps of the study area. The spatial distribution of iron oxide/hydroxides, hydroxyl-bearing and carbonate minerals and dolomite were mapped using specialized band ratios and analyzing eigenvector loadings of the PC images. Subsequently, mineral prospectivity maps of the study area were generated by fusing the selected PC thematic layers using fuzzy logic modeling. The most favorable/prospective zones for hydrothermal ore mineralizations and car...
Senanayake, S, Pradhan, B, Huete, A & Brennan, J 2020, 'A Review on Assessing and Mapping Soil Erosion Hazard Using Geo-Informatics Technology for Farming System Management', Remote Sensing, vol. 12, no. 24, pp. 4063-4063.
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Soil erosion is a severe threat to food production systems globally. Food production in farming systems decreases with increasing soil erosion hazards. This review article focuses on geo-informatics applications for identifying, assessing and predicting erosion hazards for sustainable farming system development. Several researchers have used a variety of quantitative and qualitative methods with erosion models, integrating geo-informatics techniques for spatial interpretations to address soil erosion and land degradation issues. The review identified different geo-informatics methods of erosion hazard assessment and highlighted some research gaps that can provide a basis to develop appropriate novel methodologies for future studies. It was found that rainfall variation and land-use changes significantly contribute to soil erosion hazards. There is a need for more research on the spatial and temporal pattern of water erosion with rainfall variation, innovative techniques and strategies for landscape evaluation to improve the environmental conditions in a sustainable manner. Examining water erosion and predicting erosion hazards for future climate scenarios could also be approached with emerging algorithms in geo-informatics and spatiotemporal analysis at higher spatial resolutions. Further, geo-informatics can be applied with real-time data for continuous monitoring and evaluation of erosion hazards to risk reduction and prevent the damages in farming systems.
Senanayake, S, Pradhan, B, Huete, A & Brennan, J 2020, 'Assessing Soil Erosion Hazards Using Land-Use Change and Landslide Frequency Ratio Method: A Case Study of Sabaragamuwa Province, Sri Lanka', Remote Sensing, vol. 12, no. 9, pp. 1483-1483.
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This study aims to identify the vulnerable landscape areas using landslide frequency ratio and land-use change associated soil erosion hazard by employing geo-informatics techniques and the revised universal soil loss equation (RUSLE) model. Required datasets were collected from multiple sources, such as multi-temporal Landsat images, soil data, rainfall data, land-use land-cover (LULC) maps, topographic maps, and details of the past landslide incidents. Landsat satellite images from 2000, 2010, and 2019 were used to assess the land-use change. Geospatial input data on rainfall, soil type, terrain characteristics, and land cover were employed for soil erosion hazard classification and mapping. Landscape vulnerability was examined on the basis of land-use change, erosion hazard class, and landslide frequency ratio. Then the erodible hazard areas were identified and prioritized at the scale of river distribution zones. The image analysis of Sabaragamuwa Province in Sri Lanka from 2000 to 2019 indicates a significant increase in cropping areas (17.96%) and urban areas (3.07%), whereas less dense forest and dense forest coverage are significantly reduced (14.18% and 6.46%, respectively). The average annual soil erosion rate increased from 14.56 to 15.53 t/ha/year from year 2000 to 2019. The highest landslide frequency ratios are found in the less dense forest area and cropping area, and were identified as more prone to future landslides. The river distribution zones Athtanagalu Oya (A-2), Kalani River-south (A-3), and Kalani River- north (A-9), were identified as immediate priority areas for soil conservation.
Shahabuddin, M, Mofijur, M, Kalam, MA & Masjuki, HH 2020, 'Study on the Friction and Wear Characteristics of Bio-lubricant Synthesized from Second Generation Jatropha Methyl Ester', Tribology in Industry, vol. 42, no. 1, pp. 41-49.
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© 2020 Published by Faculty of Engineering. The demands for eco-friendly bio-lubricants are growing due to the environmental concern and the rapid depletion of petroleum oil. This paper outlines the tribological evaluation of jatropha methyl ester (JME) based bio-lubricant by analyzing its anti-wear (AW) and extreme pressure (EP) characteristics. The AW and EP tests were conducted using a four-ball tribotester with standard test methods of ASTM D 4172 and ASTM D 2783, respectively. After each test, the wear scar diameter, flash temperature parameter, viscosity and viscosity index (VI) were measured. The SEM analysis characterized the surface structure of the worn surface. The properties of formulated bio-lubricants were compared with the commercial lubricant SAE 15W-40. Experimental results showed that under boundary lubrication, the bio-lubricants showed excellent tribological properties up to the initial seizure load (ISL). Over the ISL, the friction and wear were increased slightly as compared to the commercial lubricant. The final seizure load (FSL) found for the bio-lubricant (BL 10), and commercial lubricant was 220 kg. The bio-lubricant with 10 % JME (BL 10) was found to be the most favorable, which met standard ISO requirements except for pour point.
Shakor, P, Nejadi, S & Paul, G 2020, 'Investigation into the effect of delays between printed layers on the mechanical strength of inkjet 3DP mortar', Manufacturing Letters, vol. 23, pp. 19-22.
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© 2019 Currently, additive manufacturing have enabled to fabricate the three-dimensional models. 3D-Printing technique is a multipurpose process for producing structural members using a sequential layering approach. The “feature quality” of 3DP specimens can be improved by optimising the build constraints. In this paper, a mortar mix powder-base has been prepared that consists of cementitious materials. Experiments are conducted to investigate the effects of different delays in printing time on the mechanical properties of the scaffolds. It has been shown that the compressive stress and strength of printed specimens with a delay of 200 ms were greater than specimens with other delay values.
Shakor, P, Nejadi, S, Paul, G & Sanjayan, J 2020, 'Dimensional accuracy, flowability, wettability, and porosity in inkjet 3DP for gypsum and cement mortar materials', Automation in Construction, vol. 110, pp. 102964-102964.
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© 2019 Inkjet (powder-based) 3D Printing is a popular and widely used technology, which can be applied to print a wide range of specimens using different powder materials. This paper discusses the use of inkjet 3DP technology for construction applications using custom-made powder instead of commercial gypsum powder (ZP 151). The paper aims to address the differences between ZP 151 and CP (a custom-made construction-specific cement mortar powder) with regard to powder flowability, wettability, powder bed porosity and apparent porosity in 3DP specimens. An inkjet 3D printer is employed and experimental results verify that ZP 151 has a lower angle of repose, a higher contact angle and noticeably less porosity in the powder bed compared with the CP powder. Additionally, specimens printed with ZP 151 have a lower apparent porosity compared with CP specimens. The wettability for each of the powders was tested using contact angle goniometer, while the Optronis Cam-Recorder was used at 1000 fps at 800 × 600 pixel resolution images for the powder flowability tests. The bulk density tester was utilised to find the apparent porosity in the printed specimens. The paper also discusses the details of the printing procedure and dimensional accuracy of printed specimens.
Shakor, P, Nejadi, S, Sutjipto, S, Paul, G & Gowripalan, N 2020, 'Effects of deposition velocity in the presence/absence of E6-glass fibre on extrusion-based 3D printed mortar', Additive Manufacturing, vol. 32, pp. 101069-101069.
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© 2020 Additive Manufacturing (AM) technologies are widely used in various fields of industry and research. Continual research has enabled AM technologies to be considered as a feasible substitute for certain applications in the construction industry, particularly given the advances in the use of glass fibre reinforced mortar. An investigation of the resulting mechanical properties of various mortar mixes extruded using a robotic arm is presented. The nozzle paths were projected via ‘spline’ interpolation to obtain the desired trajectory and deposition velocity in the reference frame of the manipulator. Along each path, various mortar mixes, with and without chopped glass fibre, were deposited at different velocities. Tests were conducted to determine their mechanical performance when incorporated in printed structures with different layers (1, 2, 4 and 6 layers). The results are compared with those of conventional cast-in-place mortar. In this study, the mixes consist of ordinary Portland cement, fine sand, chopped glass fibres (6 mm) and chemical admixtures, which are used to print prismatic- and cubic-shaped specimens. Mechanical strength tests were performed on the printed specimens to evaluate the behaviour of the materials in the presence and absence of glass fibre. Robot end-effector velocity tests were performed to examine the printability and extrudability of the mortar mixes. Finally, horizontal and vertical line printing tests were used to determine the workability, buildability and uniformity of the mortar mix and to monitor the fibre flow directions in the printed specimens. The results show that printed specimens with glass fibre have enhanced compressive strength compared with specimens without glass fibre.
Shanmugam, S, Ngo, H-H & Wu, Y-R 2020, 'Advanced CRISPR/Cas-based genome editing tools for microbial biofuels production: A review', Renewable Energy, vol. 149, pp. 1107-1119.
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© 2019 Elsevier Ltd With rapid progress in the fields of synthetic biology and metabolic engineering, there are possible applications to generate a wide range of advanced biofuels with maximized yield and productivity to achieve a more sustainable bioprocess with reduced carbon footprints. Among the diverse molecular biology tools, clustered regularly interspaced short palindromic repeats-CRISPR-associated proteins (CRISPR-Cas) technology stands out with potential targeted genome editing, exhibiting a more precise and accurate gene knock-out and knock-in system better than its predecessors, for example zinc finger nucleases (ZFN) and transcription activator-like effector nucleases (TALEN). There are reports involved in the advanced microbial genome engineering tools for the biofuels production; however, there is lack of a comprehensive review about the CRISPR-Cas based-techniques in improved biofuel production along with the strategies to reduce the off-target effect that ensures the success and safety of this method. Therefore, in this review we attempt to systematically comment on the mechanism of CRISPR-Cas and its application to microbial biofuels production. This includes bioethanol, biobutanol as well as other hydrocarbons that sequentially follow various suggestions on enhancing the efficiency of targeting genes. The role of inducible on/off genetic circuits in response to environmental stimuli in the regulation of targeted genome editing (TGE) by minimizing metabolic burden and maximizing fermentation efficiency is also discussed. The relevant stringent regulatory demands to ensure minimal off-target cleavage with maximum efficiency coupled with complete biosafety of this technology are considered. It can be concluded that the recent development of CRISPR-Cas technology should open a new avenue in creating microbial biorefineries for potentially enhanced biofuel production.
Sharma, A, Singh, Y, Singh, NK, Singla, A, Ong, HC & Chen, W-H 2020, 'Corrigendum to “Effective utilization of tobacco (Nicotiana Tabaccum) for biodiesel production and its application on diesel engine using response surface methodology approach” [Fuel 273 (2020) 117793]', Fuel, vol. 276, pp. 118133-118133.
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Shen, Q, Lin, Y, Kawabata, Y, Jia, Y, Zhang, P, Akther, N, Guan, K, Yoshioka, T, Shon, H & Matsuyama, H 2020, 'Engineering Heterostructured Thin-Film Nanocomposite Membrane with Functionalized Graphene Oxide Quantum Dots (GOQD) for Highly Efficient Reverse Osmosis', ACS Applied Materials & Interfaces, vol. 12, no. 34, pp. 38662-38673.
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In this study, custom-tailored graphene oxide quantum dots (GOQD) were synthesized as functional nanofillers to be embedded into the polyamide (PA) membrane for reverse osmosis (RO) via interfacial polymerization (IP). The heterostructured interface-functionalization of amine/sulfonic decoration on GOQD (N/S-d-GOQD) takes place via the tuning of the molecular design. The embedded N/S-d-GOQD inside the PA matrix contributes to facilitating water molecules quick transport due to the more accessible capturing sites with higher internal polarity, achieving a nearly 3-fold increase in water permeance when compared to the pristine thin-film composite (TFC) membrane. Covalent bonding between the terminal amine groups and the acyl chloride of trimesoyl chloride (TMC) enables the formation of an amplified selective layer, while the sulfonic part assists in maintaining a robust membrane surface negative charge, thus remarkably improving the membrane selectivity toward NaCl. As a result, the newly developed TFN membrane performed remarkably high water permeance up to 5.89 L m-2 h-1 bar-1 without the compromising of its favorable salt (NaCl) rejection ratio of 97.1%, revealing a comparably high separation property when comparing to the state-of-the-art RO membranes, and surpassing the permeability-selectivity trade-off limits. Furthermore, we systematically investigated the GOQDs with different surface decorations but similar configurations (including 3 different nanofillers of pristine GOQD, amine decorated GOQD (N-d-GOQD), and N/S-d-GOQD) to unveil the underlying mechanisms of the swing effects of internal geometry and polarity of the embedded nanofillers on contributing to the uptake, and/or release of aqueous molecules within TFN membranes, providing a fundamental perspective to investigate the impact of embedded nanofillers on the formation of an IP layer and the overall transporting behavior of the RO process.
Shen, X, Zhang, J, Xie, H, Hu, Z, Liang, S, Ngo, HH, Guo, W, Chen, X, Fan, J & Zhao, C 2020, 'Intensive removal of PAHs in constructed wetland filled with copper biochar', Ecotoxicology and Environmental Safety, vol. 205, pp. 111028-111028.
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Shukla, N, Pradhan, B, Dikshit, A, Chakraborty, S & Alamri, AM 2020, 'A Review of Models Used for Investigating Barriers to Healthcare Access in Australia', International Journal of Environmental Research and Public Health, vol. 17, no. 11, pp. 4087-4087.
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Understanding barriers to healthcare access is a multifaceted challenge, which is often highly diverse depending on location and the prevalent surroundings. The barriers can range from transport accessibility to socio-economic conditions, ethnicity and various patient characteristics. Australia has one of the best healthcare systems in the world; however, there are several concerns surrounding its accessibility, primarily due to the vast geographical area it encompasses. This review study is an attempt to understand the various modeling approaches used by researchers to analyze diverse barriers related to specific disease types and the various areal distributions in the country. In terms of barriers, the most affected people are those living in rural and remote parts, and the situation is even worse for indigenous people. These models have mostly focused on the use of statistical models and spatial modeling. The review reveals that most of the focus has been on cancer-related studies and understanding accessibility among the rural and urban population. Future work should focus on further categorizing the population based on indigeneity, migration status and the use of advanced computational models. This article should not be considered an exhaustive review of every aspect as each section deserves a separate review of its own. However, it highlights all the key points, covered under several facets which can be used by researchers and policymakers to understand the current limitations and the steps that need to be taken to improve health accessibility.
Silitonga, AS, Shamsuddin, AH, Mahlia, TMI, Milano, J, Kusumo, F, Siswantoro, J, Dharma, S, Sebayang, AH, Masjuki, HH & Ong, HC 2020, 'Biodiesel synthesis from Ceiba pentandra oil by microwave irradiation-assisted transesterification: ELM modeling and optimization', Renewable Energy, vol. 146, pp. 1278-1291.
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© 2019 Elsevier Ltd In this study, microwave irradiation-assisted transesterification was used to produce Ceiba pentandra biodiesel, which accelerates the rate of reaction and temperature within a shorter period. The improvement of biodiesel production requires a reliable model that accurately reflects the effects of input variables on output variables. In this study, an extreme learning machine integrated with cuckoo search algorithm was developed to predict and optimize the process parameters. This model will be useful for virtual experimentations in order to enhance biodiesel research and development. The optimum parameters of the microwave irradiation-assisted transesterification process conditions were obtained as follows: (1) methanol/oil ratio: 60%, (2) potassium hydroxide catalyst concentration: 0.84%(w/w), (3) stirring speed: 800 rpm, and (4) reaction time: 388 s. The corresponding Ceiba pentandra biodiesel yield was 96.19%. Three independent experiments were conducted using the optimum process parameters and the average biodiesel yield was found to be 95.42%. In conclusion, microwave irradiation-assisted transesterification is an effective method for biodiesel production because it is more energy-efficient, which will reduce the overall cost of biodiesel production.
Singh, M, Indraratna, B, Rujikiatkamjorn, C & Kelly, R 2020, 'Cyclic response of railway subgrade prone to mud pumping', Australian Geomechanics Journal, vol. 55, no. 1, pp. 43-54.
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Given the fast pace of growth in today's world, the need for a cost-effective and sustainable mode of transportation is indispensable. Railways provide a mode of mass transportation which facilitates travel between two places. Rails are often laid on subgrade soils with difficult conditions such as low bearing capacity, and high groundwater tables, etc., so when trains pass over these challenging ground conditions, the subgrade softens into a slurry and starts pumping the fines into the upper ballast layers. In Australia, this phenomenon is commonly known as mud pumping or mud holes. This paper investigates the cyclic response of subgrade prone to mud pumping. It is observed that the cyclic stress ratio (CSR) has a threshold value beyond which the cyclic axial strains and mean excess pore pressures rapidly accumulate. An empirical model is proposed to capture the generation of mean excess pore pressure in relation to the applied CSR. Further, numerical simulations have been carried out using PLAXIS2D to model vertical drain inclusions in the railway subsoil. The results indicate that vertical drains not only reduce the accumulation of excess pore pressure but also assist in their dissipation under cyclic loading, thereby providing a viable alternative to mitigate the effects of mud pumping.
Singh, R, Altaee, A & Gautam, S 2020, 'Nanomaterials in the advancement of hydrogen energy storage', Heliyon, vol. 6, no. 7, pp. e04487-e04487.
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The hydrogen economy is the key solution to secure a long-term energy future. Hydrogen production, storage, transportation, and its usage completes the unit of an economic system. These areas have been the topics of discussion for the past few decades. However, its storage methods have conflicted for on-board hydrogen applications. In this review, the promising systems based on solid-state hydrogen storage are discussed. It works generally on the principles of chemisorption and physisorption. The usage of hydrogen packing material in the system enhances volumetric and gravimetric densities of the system and helps in improving ambient conditions and system kinetics. Numerous aspects like pore size, surface area ligand functionalization and pore volume of the materials are intensively discussed. This review also examines the newly developed research based on MOF (Metal-Organic Frameworks). These hybrid clusters are employed for nano-confinement of hydrogen at elevated temperatures. A combination of the various methodologies may give another course to a wide scope in the area of energy storage materials later in the future.
Singh, RP, Nimbalkar, S, Singh, S & Choudhury, D 2020, 'Field assessment of railway ballast degradation and mitigation using geotextile', Geotextiles and Geomembranes, vol. 48, no. 3, pp. 275-283.
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© 2019 Elsevier Ltd Rail tracks continue to deform due to degradation of ballast under the application of heavy train traffic. The resulting track deformations often lead to drainage impairment as well as loss of resiliency. For track replenishment, deep screening of ballast is usually adopted by Indian Railway (IR) either after 10 years or passage of 500 MGT traffic, whichever is earlier. To study the effectiveness of geotextile on track stability and assess possible reductions in maintenance costs, a layer of woven geotextile was installed at the ballast-subgrade interface in Bhusawal-Akola central railway section of IR which is the present study area. The results show that the amount of degradation and fouling are different in UP and DN tracks due to inherent variation in traffic characteristics. This study also shows that the placement of geotextile in the track has led to prolonged maintenance cycle with favorable implications on cost and track shutdown periods. The findings of the present case study results will be useful for IR to reduce the ballast procurement and reuse of discarded material during deep screening in future.
Sinha, A, Chand, S, Wijayaratna, KP, Virdi, N & Dixit, V 2020, 'Comprehensive safety assessment in mixed fleets with connected and automated vehicles: A crash severity and rate evaluation of conventional vehicles', Accident Analysis & Prevention, vol. 142, pp. 105567-105567.
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© 2020 Elsevier Ltd Connected and Automated Vehicle (CAV) technology, although in the development stage, is quickly expanding throughout the vehicle market. However, full market penetration will most likely require considerable planning as key stakeholders, manufacturers, consumers and governing agencies work together to determine optimal deployment strategies. Specifically, road safety is a critical challenge to the widespread deployment and adoption of this disruptive technology. During the transition period fleets will be composed of a combination of CAVs and conventional vehicles, and therefore it is imperative to investigate the repercussions of CAVs on traffic safety at different penetration rates. Since crash severity and frequency in conjunction reflect traffic safety, this study attempts to investigate the effect of CAVs on both crash severity and frequency through a microsimulation modelling exercise. VISSM microsimulation platform is used to simulate a case study of the M1 Geelong Ring Road network (Princes Freeway) in Victoria, Australia. Network performance is evaluated using performance metrics (Total System Travel Time, Delay) and kinematic variables (Speed, acceleration, jerk rate). Surrogate safety measures (time to collision, post encroachment time, etc.) are examined to inspect the safety in the network. The results indicate that the introduction of CAVs does not achieve the expected decrease in crash severity and rates involving manual vehicles, despite the improvement in network performance, given the demand and the set of parameters used in our operational CAV algorithm are intact. Additionally, the study identifies that the safety benefits of CAVs are not proportional to CAV penetration, and full-scale benefits of CAVs can only be achieved at 100 % CAV penetration. Further, considering network efficiency as a performance metric and total crash rate involving conventional vehicles as a safety metric, a Pareto frontier is extracted, for varyi...
Sinha, A, Chand, S, Wijayaratna, KP, Virdi, N & Dixit, V 2020, 'Crash Severity and Rate Evaluation of Conventional Vehicles in Mixed Fleets with Connected and Automated Vehicles', Procedia Computer Science, vol. 170, pp. 688-695.
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© 2020 The Authors. Published by Elsevier B.V.All rights reserved. Connected and Automated Vehicle (CAV) technology, although in the development stage, is quickly expanding its market but a full market penetration might not be rapid. The safety concern is the paramount challenge to widespread adoption of this disruptive technology. During the transition period, fleets will be composed of a combination of CAVs and conventional vehicles, therefore it is germane to investigate the repercussions of CAVs on traffic safety at different penetration. Since crash severity and frequency in conjunction reflect the traffic safety, this study attempts to investigate the effect of CAVs on both crash severity and frequency. PTV VISSM microsimulation platform is used to simulate M1 Geelong Ring Road network (Princes Freeway) in Victoria, Australia, which is the testbed for this study. Network performance is evaluated using performance metrics (Total System Travel Time, Delay and instantaneous speed profiles). Surrogate safety measures (time to collision, post encroachment time, etc.) are examined to inspect the safety in the network. The results showed that CAVs would not inevitably decrease the crash severity and crash rate involving manual vehicles, despite the improvement in network performance, given the demand and the set of parameters used in our operational CAV algorithm are intact. Additionally, the study identifies that the safety benefits of CAVs are not proportional to CAV penetration, a full-scale benefits CAVs can only be achieved at 100% CAV penetration. The results presented in this study provide an insight into the repercussion of CAVs on comprehensive traffic safety to the insurance companies and other industry participants, enabling safety-related services and more enterprising business models.
Song, Z, Zhang, X, Sun, F, Ngo, HH, Guo, W, Wen, H, Li, C & Zhang, Z 2020, 'Specific microbial diversity and functional gene (AOB amoA) analysis of a sponge-based aerobic nitrifying moving bed biofilm reactor exposed to typical pharmaceuticals', Science of The Total Environment, vol. 742, pp. 140660-140660.
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© 2018 Elsevier B.V. Four bench-scale sponge-based aerobic nitrifying moving bed biofilm reactors (MBBRs) were used to treat municipal wastewater containing typical pharmaceuticals (1 mg/L, 2 mg/L and 5 mg/L). This preliminary research aims to investigate the effects of sulfadiazine (SDZ), ibuprofen (IBU) and carbamazepine (CBZ) on nitrification performance and explore specific microbial diversity and functional gene (Ammonia-oxidizing bacteria (AOB), amoA) of MBBRs. After 90 days of operation, the MBBR without pharmaceuticals could remove up to 97.4 ± 1.5% of NH4+-N while the removals of NH4+-N by the MBBRs with SDZ, IBU and CBZ were all suppressed to varying degrees. Based on the Shannon and Chao 1 index, the specific microbial diversity and richness in biofilm samples increased at a range of 1 mg/L to 2 mg/L pharmaceuticals (SDZ, IBU or CBZ) and started decreasing after the pharmaceutical concentration was higher than 2 mg/L. The determination of functional gene (AOB amoA) showed that Proteobacteria was the most dominant bacteria within all biofilms with the relative abundance ranging from 24.81% to 55.32%. Furthermore, Nitrosomonas was the most numerous genus in AOB, followed by Campylobacter and Thauera, whose relative abundance shifted under the pressure of different pharmaceuticals.
Sornalingam, K, McDonagh, A, Canning, J, Cook, K, Johir, MAH, Zhou, JL & Ahmed, MB 2020, 'Photocatalysis of 17α-ethynylestradiol and estriol in water using engineered immersible optical fibres and light emitting diodes', Journal of Water Process Engineering, vol. 33, pp. 101075-101075.
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© 2019 Elsevier Ltd This research aims to promote photocatalysis of endocrine disrupting chemicals (EDCs) in water. Two reactor setups with (i) modified air-clad optical fibres and (ii) waterproof LED strips were utilised to transmit light to photocatalysts P25 TiO2 and gold-modified TiO2 (Au-TiO2). The performances to photodegrade 17α-ethynylestradiol (EE2) and estriol (E3) under Cool White and UVA high efficacy LEDs were examined. Au-TiO2 showed superior photocatalytic activity for EE2 removal over P25 TiO2. The pseudo first-order rate constants for EE2 photocatalysis under UVA were 0.55 h−1 and 0.89 h−1 for TiO2 and Au-TiO2, respectively. E3 was effectively degraded by Au-TiO2 in the immersible LED strip reactor (0.13 h−1).
Soudagar, MEM, Kalam, MA, Sajid, MU, Afzal, A, Banapurmath, NR, Akram, N, Mane, SD & Saleel C, A 2020, 'Thermal analyses of minichannels and use of mathematical and numerical models', Numerical Heat Transfer, Part A: Applications, vol. 77, no. 5, pp. 497-537.
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Stewart, MG & Mueller, J 2020, 'Terrorism risks, chasing ghosts and infrastructure resilience', Sustainable and Resilient Infrastructure, vol. 5, no. 1-2, pp. 78-89.
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Risk is the integration of threat, vulnerability and consequences, but threat is often based on worse-case thinking about the capability of terrorists to successfully plan and execute large-scale bombings. The paper looks at the nature of terrorists by exploring their capabilities and motivation, technical skills, and target selection. Key among this is the risk of progressive collapse of multi-storey buildings, and the track record of terrorists attacking targets in the West. In the past decade, most deaths from terrorists in the West have arisen from shooting attacks, vehicle impact, and mass transit bombings. In this case, there is little or no need to protect civilian buildings, bridges and other infrastructure from car or truck bombs unless there is a specific threat. Existing infrastructure has also proven to be highly resilient and robust against car and truck bombings. It is easy to overestimate the impacts of terrorist attacks. An improved understanding of the threat allows decision-makers to more effectively deploy resources to counter it, which includes appropriate design and assessment of civilian and military protective structures. A case study describes existing fatality risks from progressive collapse caused by a large vehicle bomb, and then assesses the costs and benefits of design (protective) measures mandated by the United States to mitigate against progressive collapse for new or leased federal government (civilian and defence) buildings.
Stewart, MG & Netherton, MD 2020, 'Statistical variability and fragility assessment of ballistic perforation of steel plates for 7.62 mm AP ammunition', Defence Technology, vol. 16, no. 3, pp. 503-513.
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The paper describes field test results of 7.62 × 51 mm M61 AP (armour piercing) ammunition fired into mild steel targets at an outdoor range. The targets varied from 10 mm to 32 mm in thickness. The tests recorded penetration depth, probability of perforation (i.e., complete penetration), muzzle and impact velocities, bullet mass, and plate yield strength and hardness. The measured penetration depth exhibited a variability of approximately ±12%. The paper then compared ballistic test results with predictive models of steel penetration depth and thickness to prevent perforation. Statistical parameters were derived for muzzle and impact velocity, bullet mass, plate thickness, plate hardness, and model error. A Monte-Carlo probabilistic analysis was then developed to estimate the probability of plate perforation of 7.62 mm M61 AP ammunition for a range of impact velocities, and for mild steels, and High Hardness Armour (HHA) plates. This perforation fragility analysis considered the random variability of impact velocity, bullet mass, plate thickness, plate hardness, and model error. Such a probabilistic analysis allows for reliability-based design, where, for example, the plate thickness with 95% reliability (i.e. only 1 in 20 shots will penetrate the wall) can be estimated knowing the probabilistic distribution of perforation. Hence, it was found that the plate thickness to ensure a low 5% probability of perforation needs to be 11–15% thicker than required to have a 50/50 chance of perforation for mild steel plates. Plates would need to be 20–30% thicker if probability of perforation is reduced to zero.
Stewart, MG, Netherton, MD & Baldacchino, H 2020, 'Observed airblast variability and model error from repeatable explosive field trials', International Journal of Protective Structures, vol. 11, no. 2, pp. 235-257.
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Explosive field trials have been conducted to measure the peak incident pressure, impulse and time of positive phase duration following the detonation of 15 different masses of the Plastic Explosive No #4. A novel aspect of these field trials was the repeatability of tests. Eight pressure gauges collected data during each blast, and at each scaled distance. In all, 4 blasts were conducted for each scaled distance (i.e. up to 32 measurements recorded for each scaled distance) – 60 blasts were fired in total. Consequently, this repeatability of testing allowed the mean and variance of blast pressure–time histories to be quantified, with a view to better characterise the variability of a blast itself and model error variability. This article describes the explosive field trials, and the statistical analysis of blast load variability and model error for peak incident pressure, impulse and time of positive phase duration. It was found that the mean model error is close to unity with a coefficient of variation of up to 0.15 for pressure and 0.21 for impulse. The lognormal probability distribution best fits the model error data. The probabilistic models derived from these tests can be used for a variety of structural engineering applications, such as calculating reliability-based design load or partial safety factors for explosive blast loading, and estimating the probability of damage and casualties for infrastructure subject to explosive blast loading. This is illustrated for a terrorist explosive scenario involving a spherical free-air burst, where the damage modes of interest are breaching and spalling of a concrete slab. It was found that the variability of charge mass, range and model error have a significant effect on reliability-based design.
Sukor, NR, Shamsuddin, AH, Mahlia, TMI & Mat Isa, MF 2020, 'Techno-Economic Analysis of CO2 Capture Technologies in Offshore Natural Gas Field: Implications to Carbon Capture and Storage in Malaysia', Processes, vol. 8, no. 3, pp. 350-350.
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Growing concern on global warming directly related to CO2 emissions is steering the implementation of carbon capture and storage (CCS). With Malaysia having an estimated 37 Tscfd (Trillion standard cubic feet) of natural gas remains undeveloped in CO2 containing natural gas fields, there is a need to assess the viability of CCS implementation. This study performs a techno-economic analysis for CCS at an offshore natural gas field in Malaysia. The framework includes a gas field model, revenue model, and cost model. A techno-economic spreadsheet consisting of Net Present Value (NPV), Payback Period (PBP), and Internal Rate of Return (IRR) is developed over the gas field’s production life of 15 years for four distinctive CO2 capture technologies, which are membrane, chemical absorption, physical absorption, and cryogenics. Results predict that physical absorption solvent (Selexol) as CO2 capture technology is most feasible with IRR of 15% and PBP of 7.94 years. The output from the techno-economic model and associated risks of the CCS project are quantified by employing sensitivity analysis (SA), which indicated that the project NPV is exceptionally sensitive to gas price. On this basis, the economic performance of the project is reliant on revenues from gas sales, which is dictated by gas market price uncertainties.
Sun, G, Tian, Y, Wang, R, Fang, J & Li, Q 2020, 'Parallelized multiobjective efficient global optimization algorithm and its applications', Structural and Multidisciplinary Optimization, vol. 61, no. 2, pp. 763-786.
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© 2020, Springer-Verlag GmbH Germany, part of Springer Nature. In engineering practice, most optimization problems have multiple objectives, which are usually in a form of expensive black-box functions. The multiobjective efficient global optimization (MOEGO) algorithms have been proposed recently to sequentially sample the design space, aiming to seek for optima with a minimum number of sampling points. With the advance in computing resources, it is wise to make optimization parallelizable to shorten the total design cycle further. In this study, two different parallelized multiobjective efficient global optimization algorithms were proposed on the basis of the Kriging modeling technique. With use of the multiobjective expectation improvement, the proposed algorithm is able to balance local exploitation and global exploration. To implement parallel computing, the “Kriging Believer” and “multiple good local optima” strategies were adopted here to develop new sample infill criteria for multiobjective optimization problems. The proposed algorithms were applied to five mathematical benchmark examples first, which demonstrated faster convergence and better accuracy with more uniform distribution of Pareto points, in comparison with the two other conventional algorithms. The best performed “Kriging Believer” strategy approach was then applied to two more sophisticated real-life engineering case studies on the tailor-rolled blank (TRB) structures for crashworthiness design. After optimization, the TRB hat-shaped tube achieved a 3% increase in energy absorption and a 10.7% reduction in mass, and the TRB B-pillar attained a 10.1% reduction in mass and a 12.8% decrease in intrusion, simultaneously. These benchmark and engineering examples demonstrated that the proposed methods are fairly promising for being an effective tool for a range of design problems.
Sun, L, Zhou, JL & Cai, Q 2020, 'Impacts of soil properties on flow velocity under rainfall events: Evidence from soils across the Loess Plateau', CATENA, vol. 194, pp. 104704-104704.
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© 2020 Elsevier B.V. Flow velocity is one of the most significant hydraulic parameters directly connected to sediment transport-deposition processes. Four soils were collected from north to south of the Loess Plateau, namely Sandy Loess (SL), Loessial Soil (LS), Heilu Soil (HS) and Anthrosol Soil (AS), to examine the impacts of soil property on mean flow velocity in both interrill and rill flows under different simulated rainfall experiments. The mean velocity of interrill flow (MVIF) followed the order of LS > HS ≈ AS > SL at 90 mm h−1 rainfall intensity and LS > HS > AS > SL at 120 mm h−1 rainfall intensity. The mean velocity of rill flow (MVRF) decreased as LS ≈ HS > AS at 90 mm h−1 and LS ≈ HS > AS > SL at 120 mm h−1. The order of MVIF and MVRF on four soil slopes is determined by the relations of runoff discharge, Darcy-Weisbach friction factor in interrill area (fI) and rills (fR), which are closely related to soil properties. Soil properties also changed the effects of rainfall intensity on flow velocities in different erosion stages, resulting in the increasing trend of MVIF on SL, HS and AS slopes and the decreasing trend of MVIF on LS slope with the increase of rainfall intensity. Moreover, soil properties may change the variations of MVIF and MVRF with the increase of slope gradient, by altering the relations of sealing progress and slope effect. The slope effect determined the increasing trend of MVIF with the increase of slope gradients. However, the sealing progress may offset the slope effect and cause the decrease of MVIF on the critical slopes, and the critical slope decreased from the north (20° and 25°) to the south (15°). The equal roles of rill bed roughness and slope effect caused the unchanged of MVRF on LS and HS slopes, while rill bed roughness dominated the fluctuations of MVRF on SL and AS slopes.
Surawski, NC, Macdonald, LM, Baldock, JA, Sullivan, AL, Roxburgh, SH & Polglase, PJ 2020, 'Exploring how fire spread mode shapes the composition of pyrogenic carbon from burning forest litter fuels in a combustion wind tunnel', Science of The Total Environment, vol. 698, pp. 134306-134306.
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© 2019 In this study, solid state 13C nuclear magnetic resonance (NMR) spectroscopy was used to explore the carbon-containing functional groups present in pyrogenic carbon (PyC) produced during different fire spread modes to forest litter fuels from a dry sclerophyll eucalypt forest burnt in a combustion wind tunnel. A replicated experimental study was performed using three different fire spread modes: heading fires (i.e. fires which spread with the wind), flanking fires (i.e. fires which spread perpendicular to the wind) and backing fires (i.e. fires which spread against the wind). In addition to 13C NMR measurements of PyC, detailed fire behaviour measurements were recorded during experiments. Experiments showed that heading fires produced significantly more aryl carbon in ash samples than flanking fires. All other experimental comparisons for burnt fuel samples involving different fire spread modes were statistically insignificant. Principal component analysis (PCA) was used to explore the relationship between 13C NMR functional groups and fire behaviour observations. Results from PCA indicate that maximising the residence time of high temperature combustion and the combustion factor (i.e. the fraction of pre-fire biomass consumed by fire) could be a method for increasing the amount of aryl carbon in PyC. Maximising the amount of aryl carbon could be beneficial for the overall PyC balance from fire, since more recalcitrant carbon (e.g. carbon with a higher aryl carbon content) that is not emitted to the atmosphere has been shown to have longer residence times in environmental media such as soils or sediments.
Suryani, S, Sariani, S, Earnestly, F, Marganof, M, Rahmawati, R, Sevindrajuta, S, Mahlia, TMI & Fudholi, A 2020, 'A Comparative Study of Virgin Coconut Oil, Coconut Oil and Palm Oil in Terms of Their Active Ingredients', Processes, vol. 8, no. 4, pp. 402-402.
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This research aims to study the unique factors of virgin coconut oil (VCO) compared with coconut oil (i.e., coconut oil processed through heating the coconut milk and palm oil sold on the market). Its novelty is that it (VCO) contains lactic acid bacteria and bacteriocin. Lauric acid content was analyzed by the Chromatographic Gas method. Isolation of lactic acid bacteria (LAB) was conducted by the dilution method using MRSA + 0.5% CaCO3 media. Iodium number, peroxide, and %FFA were analyzed using a general method, and isolation bacteriocin by the deposition method using ammonium sulfate. In addition, macromolecular identification was conducted by 16S rRNA. VCO was distinguished by a higher content of lauric acid (C12:0) 41%–54.5% as compared with 0% coconut and 0, 1% palm oil, respectively. The VCO also contains LAB, namely Lactobacillus plantarum and Lactobacillus paracasei, and can inhibit the growth of pathogenic bacteria, such as Pseudomonas aeruginosa, Klebsiella, Staphylococcus aureus, S. epidermidis, Proteus, Escherichia coli, Listeria monocytogenes, Bacillus cereus, Salmonella typhosa and bacteriocin. Comparison with VCO is based on having a high content of lauric acid, 54%, and LAB content. The difference between VCO and coconut oil and palm oil is fatty acids. In VCO there are lauric acid and stearic acid, namely lauric acid VCO (A) 54.06%, VCO (B) 53.9% and VCO (C) 53.7%. The content of stearic acid VCO (A) is 12.03%, VCO (B) 12.01% and VCO (C) 11.9%. Coconut oil contains a little lauric acid, which is 2.81%, stearic acid 2.65% and palmitic acid 2.31%. Palm oil can be said to have very little lauric acid, namely in palm oil 1, 0.45%, and even in palm oil 2, 0%; in turn, palmitic acid palm oil 1 has 2.88% and palm oil 2 palmitic acid has 24.42%.
Suwaileh, W, Pathak, N, Shon, H & Hilal, N 2020, 'Forward osmosis membranes and processes: A comprehensive review of research trends and future outlook', Desalination, vol. 485, pp. 114455-114455.
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Syahir, AZ, Harith, MH, Zulkifli, NWM, Masjuki, HH, Kalam, MA, Yusoff, MNAM, Zulfattah, ZM & Ibrahim, TM 2020, 'Compatibility of Ionic Liquid With Glycerol Monooleate and Molybdenum Dithiocarbamate as Additives in Bio-Based Lubricant', Journal of Tribology, vol. 142, no. 6.
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AbstractThis study reports the tribological characteristics of trimethylolpropane trioleate (TMPTO) additivated with antifriction and antiwear additives, which are ionic liquid (IL), glycerol monooleate (GMO), and molybdenum dithiocarbamate (MoDTC). In addition, to obtain the ideal composition that results in the minimal coefficient of friction (COF), optimization tool was employed using response surface methodology (RSM) technique with the Box–Behnken design. The IL used in this study was a phosphorus-type IL, namely trihexyl(tetradecyl)phosphonium bis(2,4,4-trimethylpentyl) phosphinate, [P14,6,6,6][TMPP]. The resulting COF and worn surface morphology were investigated using high-frequency reciprocating rig (HFRR) tribotester and scanning electron microscope with energy-dispersive X-ray spectroscopy (SEM-EDX), respectively. From the experimental results, a second-order polynomial mathematical model was constructed and able to statistically predict the resulting COF. The optimized values that resulted in the lowest average COF of 0.0458 were as follows: 0.93 wt% IL, 1.49 wt% GMO, and 0.52 wt% MoDTC. The addition of IL into neat base oil managed to reduce the COF, while the combination of IL, GMO, and MoDTC at optimum concentration further reduced the average COF and wear as observed through SEM micrographs when compared with those of additive-free TMPTO, suggesting that GMO and MoDTC were compatible to be used with IL.
Syahir, AZ, Zulkifli, NWM, Masjuki, HH, Kalam, MA, Harith, MH, Yusoff, MNAM, Zulfattah, ZM & Jamshaid, M 2020, 'Tribological Improvement Using Ionic Liquids as Additives in Synthetic and Bio-Based Lubricants for Steel–Steel Contacts', Tribology Transactions, vol. 63, no. 2, pp. 235-250.
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Syifa, M, Kadavi, PR, Lee, C-W & Pradhan, B 2020, 'Landsat images and artificial intelligence techniques used to map volcanic ashfall and pyroclastic material following the eruption of Mount Agung, Indonesia', Arabian Journal of Geosciences, vol. 13, no. 3.
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Tabasi, M, Alesheikh, AA, Sofizadeh, A, Saeidian, B, Pradhan, B & AlAmri, A 2020, 'A spatio-temporal agent-based approach for modeling the spread of zoonotic cutaneous leishmaniasis in northeast Iran', Parasites & Vectors, vol. 13, no. 1, pp. 572-572.
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AbstractBackgroundZoonotic cutaneous leishmaniasis (ZCL) is a neglected tropical disease worldwide, especially the Middle East. Although previous works attempt to model the ZCL spread using various environmental factors, the interactions between vectors (Phlebotomus papatasi), reservoir hosts, humans, and the environment can affect its spread. Considering all of these aspects is not a trivial task.MethodsAn agent-based model (ABM) is a relatively new approach that provides a framework for analyzing the heterogeneity of the interactions, along with biological and environmental factors in such complex systems. The objective of this research is to design and develop an ABM that uses Geospatial Information System (GIS) capabilities, biological behaviors of vectors and reservoir hosts, and an improved Susceptible-Exposed-Infected-Recovered (SEIR) epidemic model to explore the spread of ZCL. Various scenarios were implemented to analyze the future ZCL spreads in different parts of Maraveh Tappeh County, in the northeast region of Golestan Province in northeastern Iran, with alternative socio-ecological conditions.ResultsThe results confirmed that the spread of the disease arises principally in the desert, low altitude areas, and riverside population centers. The outcomes also showed that the restricting movement of humans reduces the severity of the transmission. Moreover, the spread of ZCL has a particular temporal pattern, since the most prevalent cases occurred in the fall. The evaluation test also showed the similarity between the results and the reported spatiotemporal trends.ConclusionsThis study demonstrates the capability and efficiency of ABM to model and predict the spre...
Taddei, C, Zhou, B, Bixby, H, Carrillo-Larco, RM, Danaei, G, Jackson, RT, Farzadfar, F, Sophiea, MK, Di Cesare, M, Iurilli, MLC, Martinez, AR, Asghari, G, Dhana, K, Gulayin, P, Kakarmath, S, Santero, M, Voortman, T, Riley, LM, Cowan, MJ, Savin, S, Bennett, JE, Stevens, GA, Paciorek, CJ, Aekplakorn, W, Cifkova, R, Giampaoli, S, Kengne, AP, Khang, Y-H, Kuulasmaa, K, Laxmaiah, A, Margozzini, P, Mathur, P, Nordestgaard, BG, Zhao, D, Aadahl, M, Abarca-Gómez, L, Rahim, HA, Abu-Rmeileh, NM, Acosta-Cazares, B, Adams, RJ, Agdeppa, IA, Aghazadeh-Attari, J, Aguilar-Salinas, CA, Agyemang, C, Ahluwalia, TS, Ahmad, NA, Ahmadi, A, Ahmadi, N, Ahmed, SH, Ahrens, W, Ajlouni, K, Alarouj, M, AlBuhairan, F, AlDhukair, S, Ali, MM, Alkandari, A, Alkerwi, A, Aly, E, Amarapurkar, DN, Amouyel, P, Andersen, LB, Anderssen, SA, Anjana, RM, Ansari-Moghaddam, A, Aounallah-Skhiri, H, Araújo, J, Ariansen, I, Aris, T, Arku, RE, Arlappa, N, Aryal, KK, Aspelund, T, Assunção, MCF, Auvinen, J, Avdicová, M, Azevedo, A, Azizi, F, Azmin, M, Balakrishna, N, Bamoshmoosh, M, Banach, M, Bandosz, P, Banegas, JR, Barbagallo, CM, Barceló, A, Barkat, A, Bata, I, Batieha, AM, Batyrbek, A, Baur, LA, Beaglehole, R, Belavendra, A, Ben Romdhane, H, Benet, M, Benn, M, Berkinbayev, S, Bernabe-Ortiz, A, Bernotiene, G, Bettiol, H, Bhargava, SK, Bi, Y, Bienek, A, Bikbov, M, Bista, B, Bjerregaard, P, Bjertness, E, Bjertness, MB, Björkelund, C, Bloch, KV, Blokstra, A, Bo, S, Boehm, BO, Boggia, JG, Boissonnet, CP, Bonaccio, M, Bongard, V, Borchini, R, Borghs, H, Bovet, P, Brajkovich, I, Breckenkamp, J, Brenner, H, Brewster, LM, Bruno, G, Bugge, A, Busch, MA, de León, AC, Cacciottolo, J, Can, G, Cândido, APC, Capanzana, MV, Capuano, E, Capuano, V, Cardoso, VC, Carvalho, J, Casanueva, FF, Censi, L, Chadjigeorgiou, CA, Chamukuttan, S, Chaturvedi, N, Chen, C-J, Chen, F, Chen, S, Cheng, C-Y, Cheraghian, B, Chetrit, A, Chiou, S-T, Chirlaque, M-D, Cho, B, Cho, Y, Chudek, J, Claessens, F, Clarke, J, Clays, E, Concin, H, Confortin, SC, Cooper, C, Costanzo, S, Cottel, D, Cowell, C, Crujeiras, AB, Csilla, S, Cui, L, Cureau, FV, D’Arrigo, G, d’Orsi, E, Dallongeville, J, Damasceno, A, Dankner, R, Dantoft, TM, Dauchet, L, Davletov, K, De Backer, G, De Bacquer, D, de Gaetano, G, De Henauw, S, de Oliveira, PD, De Ridder, D, De Smedt, D, Deepa, M, Deev, AD, Dehghan, A, Delisle, H, Dennison, E & et al. 2020, 'Repositioning of the global epicentre of non-optimal cholesterol', Nature, vol. 582, no. 7810, pp. 73-77.
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AbstractHigh blood cholesterol is typically considered a feature of wealthy western countries1,2. However, dietary and behavioural determinants of blood cholesterol are changing rapidly throughout the world3 and countries are using lipid-lowering medications at varying rates. These changes can have distinct effects on the levels of high-density lipoprotein (HDL) cholesterol and non-HDL cholesterol, which have different effects on human health4,5. However, the trends of HDL and non-HDL cholesterol levels over time have not been previously reported in a global analysis. Here we pooled 1,127 population-based studies that measured blood lipids in 102.6 million individuals aged 18 years and older to estimate trends from 1980 to 2018 in mean total, non-HDL and HDL cholesterol levels for 200 countries. Globally, there was little change in total or non-HDL cholesterol from 1980 to 2018. This was a net effect of increases in low- and middle-income countries, especially in east and southeast Asia, and decreases in high-income western countries, especially those in northwestern Europe, and in central and eastern Europe. As a result, countries with the highest level of non-HDL cholesterol—which is a marker of cardiovascular risk—changed from those in western Europe such as Belgium, Finland, Greenland, Iceland, Norway, Sweden, Switzerland and Malta in 1980 to those in Asia and the Pacific, such as Tokelau, Malaysia, The Philippines and Thailand. In 2017, high non-HDL cholesterol was responsible for an estimated 3.9 million (95% credible interval 3.7 million–4.2 million) worldwide deaths, half of which occurred in east, southeast and south Asia. The global repositioning of lipid-related risk, with non-optimal cholesterol shifting from a distinct feature of high-income countries in northwestern Europe, north America and Australasia to one that affects countries in east and ...
Tai, P, Indraratna, B & Rujikiatkamjorn, C 2020, 'Consolidation Analysis of Soft Ground Improved by Stone Columns Incorporating Foundation Stiffness', International Journal of Geomechanics, vol. 20, no. 6, pp. 04020067-04020067.
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Takodjou Wambo, JD, Pour, AB, Ganno, S, Asimow, PD, Zoheir, B, Salles, RDR, Nzenti, JP, Pradhan, B & Muslim, AM 2020, 'Identifying high potential zones of gold mineralization in a sub-tropical region using Landsat-8 and ASTER remote sensing data: A case study of the Ngoura-Colomines goldfield, eastern Cameroon', Ore Geology Reviews, vol. 122, pp. 103530-103530.
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© 2020 Elsevier B.V. Climatic conditions and vegetation constrain the use of optical satellite imagery as an exploration tool for hydrothermal ore mineralization in tropical and subtropical regions. In this investigation, Landsat-8 and ASTER satellite imagery were used to detect hydrothermal alteration zones associated with gold mineralization in the Ngoura-Colomines region, Eastern Cameroon. The study area contains several gold-bearing quartz veins associated with zones of pyritization, muscovite/sericite, iron oxides, and silicification. Principal Component Analysis (PCA), Independent Component Analysis (ICA), and specialized spectral band ratios were used to extract spectral information related to vegetation, iron oxide/hydroxide minerals, Al–OH, Fe-Mg–OH, carbonate group minerals, and silicification using Landsat-8 data at regional scale. Linear Spectral Unmixing (LSU) algorithm was implemented to ASTER VNIR + SWIR bands for detailed discrimination of hematite, jarosite, kaolinite, muscovite, chlorite and epidote at district scale. The Automated Spectral Hourglass (ASH) technique was employed to extract reference spectra directly from the ASTER bands for producing fraction images of end-members using the LSU. A comprehensive field survey was used to verify the remote sensing results. Petrographic study, X-ray diffraction analysis and reflectance spectroscopy indicated the presence of quartz, goethite and sericite, as well as the absorption features of Fe3+/Fe2+, Al–OH, OH/H2O and SiO2 in the alteration zones. Several hydrothermal alteration zones of iron oxide/hydroxide, clay, carbonate minerals and silicification zones were identified, which are spatially associated with known mining areas and gold occurrences in the study area. High potential prospects were also delineated, including the Ngoura-Colomines prospects and the newly discovered Yangamo-Ndatanga and Taparé-Tapondo prospects in the southwestern and southeastern parts of the study area. Co...
Tam, VWY, Butera, A, Le, KN & Li, W 2020, 'Utilising CO2 technologies for recycled aggregate concrete: A critical review', Construction and Building Materials, vol. 250, pp. 118903-118903.
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© 2020 Elsevier Ltd Employment of recycled aggregate within concrete provides great potential for the reduction of landfilling. Unfortunately, recycled aggregate exhibits a high porosity and water absorption and consequently produces a substandard material when compared to the mainstream virgin aggregate concrete. Recently, the injection of CO2 into cementitious materials has been studied, for both improving the overall quality of recycled aggregate concrete as well as permanently chemically converting CO2 into stone. CO2 treatment can permit recycled aggregate concrete to rival virgin aggregate concrete in phycial and mechanical properties. Currently, there are two primary methodologies for the sequestration of CO2 into concrete: (1) carbon-conditioning is the injection of CO2 into recycled aggregate; and (2) carbon-curing involves sequestering CO2 into new concrete's cement paste. Whilst both technologies permit recycled aggregate concrete for achieving great mechanical property and durability, carbon-conditioning provides a practical implementation. Carbon-conditioning permits a prompt and complete carbonation of recycled aggregate which enhances the final concrete's mechanical property and durability. This paper provides an insight into the available CO2 technologies for concrete improvement.
Tan, X, Hu, Z, Li, W, Zhou, S & Li, T 2020, 'Micromechanical Numerical Modelling on Compressive Failure of Recycled Concrete using Discrete Element Method (DEM)', Materials, vol. 13, no. 19, pp. 4329-4329.
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This paper investigates the failure processes of recycled aggregate concrete by a model test and numerical simulations. A micromechanical numerical modeling approach to simulate the progressive cracking behavior of the modeled recycled aggregate concrete, considering its actual meso-structures, is established based on the discrete element method (DEM). The determination procedure of contact microparameters is analyzed, and a series of microscopic contact parameters for different components of modeled recycled aggregate concrete (MRAC) is calibrated using nanoindentation test results. The complete stress–strain curves, cracking process, and failure pattern of the numerical model are verified by the experimental results, proving their accuracy and validation. The initiation, growth, interaction, coalescence of microcracks, and subsequent macroscopic failure of the MRAC specimen are captured through DEM numerical simulations and compared with digital image correlation (DIC) results. The typical cracking modes controlled by meso-structures of MRAC are concluded according to numerical observations. A parameter study indicates the dominant influence of the macroscopic mechanical behaviors from the shear strength of the interfacial transition zones (ITZs).
Tang, RCO, Jang, J-H, Lan, T-H, Wu, J-C, Yan, W-M, Sangeetha, T, Wang, C-T, Ong, HC & Ong, ZC 2020, 'Review on design factors of microbial fuel cells using Buckingham's Pi Theorem', Renewable and Sustainable Energy Reviews, vol. 130, pp. 109878-109878.
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© 2020 Elsevier Ltd Microbial fuel cells (MFCs) have become a promising approach to generate cleaner and more sustainable electrical energy. Involvement of various disciplines had been contributing to enhance the performance of the MFCs. Factors affecting the performance such as chemical components, bacteria species, electrodes materials, flow interaction and electrical parts are being widely reviewed, however most of the research are highly field-specific without considering other important variables from different disciplines. In this study, Buckingham's Pi Theorem has been utilized to be implemented in the design pattern of MFCs. Several dominated variables of interest have also been pointed out including the design limitation. Modelling and application of Buckingham's Pi Theorem has been discussed as well which is useful for performance enhancement of MFCs and their application in wastewater treatment in the future.
Tang, Z, Li, W, Tam, VWY & Luo, Z 2020, 'Investigation on dynamic mechanical properties of fly ash/slag-based geopolymeric recycled aggregate concrete', Composites Part B: Engineering, vol. 185, pp. 107776-107776.
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By harnessing the benefits from both construction and demolition waste recycling and geopolymer binders, geopolymeric recycled aggregate concrete (GRAC) can contribute to the green and eco-friendly construction material products. In this study, the compressive behavior of GRAC based on fly ash and slag was experimentally investigated under both quasi-static and dynamic loadings. Quasi-static compressive tests were performed by using a high-force servo-hydraulic test system, while dynamic compressive tests were carried out by using a Ø80-mm split Hopkinson pressure bar (SHPB) apparatus. The compressive properties of GRAC under dynamic loading, including stress-strain curves, energy absorption capability, and failure modes were obtained and compared with those under quasi-static loading. The results show that the compressive properties of GRAC exhibit a strong strain rate dependency. Although the recycled aggregate replacement decreases the quasi-static compressive strength, it exhibits a slight effect on the compressive strength at high strain rates. The dynamic increase factor (DIF) for compressive strength exhibits an significant increasing trend with the recycled aggregate replacement. On the other hand, the incorporation of slag increases the quasi-static compressive strength, dynamic compressive strength, and DIF. As for the energy absorption capacity, a minor enhancement is achieved with the recycled aggregate replacement, while a significant improvement is identified after the inclusion of slag. Empirical DIF formulae for compressive strength of GRAC are proposed, in which the DIF increases approximately linearly with the strain rate in a logarithmic manner.
Tang, Z, Li, W, Tam, VWY & Xue, C 2020, 'Advanced progress in recycling municipal and construction solid wastes for manufacturing sustainable construction materials', Resources, Conservation & Recycling: X, vol. 6, pp. 100036-100036.
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© 2020 The sharply increasing solid waste generation has raised the environmental concerns worldwide which currently have been escalated to a worrying level. Intending to eliminate the negative environmental impacts of solid waste and meanwhile promote sustainability on the energy- and resource-intensive construction and building sector, considerable efforts have been devoted to recycling solid waste for the possible use in sustainable construction material products. This paper reviews the existing studies on recycling municipal and construction solid waste for the manufacture of geopolymer composites. Special attention is paid to the predominate performance of these geopolymer composite products. The principal findings of this work reveal that municipal and construction solid waste could be successfully incorporated into geopolymer composites in the forms of precursor, aggregate, additive, reinforcement fiber, or filling material. Additionally, the results indicate that although the inclusion of such waste might depress some of the attributes of geopolymer composites, proper proportion design and suitable treatment technique could alleviate these detrimental effects and further smooth the recycling progress. Finally, a brief discussion is provided to identify the important needs in the future research and development for promoting the utilization of solid waste materials in the forthcoming sustainable geopolymer industry. In summary, this work offers guidance for the better ecological choice to municipal and construction solid waste through developing waste materials into highly environmental-friendly construction materials.
Tang, Z, Li, W, Tam, VWY & Yan, L 2020, 'Mechanical behaviors of CFRP-confined sustainable geopolymeric recycled aggregate concrete under both static and cyclic compressions', Composite Structures, vol. 252, pp. 112750-112750.
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© 2020 Elsevier Ltd Geopolymeric recycled aggregate concrete (GRAC) can greatly facilitate sustainability in the construction industry by the simultaneous utilization of solid waste-based recycled aggregate and eco-friendly binder–geopolymer. This study presents an experimental investigation on the mechanical behaviors of GRAC confined by carbon fiber-reinforced polymer (CFRP) jackets under both monotonic and cyclic compressive loading. A total of 24 CFRP-confined GRAC specimens were fabricated and tested, in which four aggregate replacement ratios (i.e., 0%, 25%, 50%, and 100%) and two thicknesses of CFRP jackets (i.e., 1 and 2 layers) were considered. The failure patterns, compressive stress-strain behavior, and axial-lateral strain responses of CFRP-confined GRAC were investigated and compared. The characteristics of stress-strain relationships were also discussed in terms of the peak stress, ultimate strain, residual modulus, plastic strain, reloading modulus, and stress deterioration ratio. Moreover, the related results were analyzed by comparing to the prediction ones of the existing models for FRP-confined concrete, to evaluate their applicability and accuracies for CFRP-confined GRAC. The outcomes will enrich the experimental database of CFRP-confined concrete and provide insights into the practical application of CFRP-confined GRAC.
Tang, Z, Li, W, Tam, VWY & Yan, L 2020, 'Mechanical performance of CFRP-confined sustainable geopolymeric recycled concrete under axial compression', Engineering Structures, vol. 224, pp. 111246-111246.
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© 2020 Elsevier Ltd Sustainable geopolymeric recycled aggregate concrete (RAC) by utilizing environmentally-friendly binder-geopolymer and constructional solid waste-recycled aggregate (RA) will facilitate the sustainability in concrete industry. This study investigated the compressive behavior of sustainable geopolymeric RAC confined by carbon fiber-reinforced polymer (CFRP) jackets. A total of 72 cylindrical fly ash/slag-based geopolymeric concrete specimens, including 48 CFRP-confined specimens and 24 unconfined specimens were fabricated and tested. The testing variables included: coarse aggregate type (i.e., natural aggregate and RA), thickness of CFRP jackets (i.e., 1, 2, and 3 layers) and (iii) slag content (i.e., 0, 10%, 20% and 30% of the total binder by mass). The results indicate that the CFRP confinement remarkably enhances the compressive strength and ultimate strain of geopolymeric concrete, and the enhancement is more pronounced with the increase of CFRP jacket thickness. Moreover, the RA replacement and the inclusion of slag have minor influences on the CFRP confinement performance for the compressive strength, but have obvious effects on the CFRP confinement performance for the ultimate axial strain. Based on the test results, empirical stress and strain models were proposed to predict the ultimate condition of the CFRP-confined geopolymeric concrete.
Tang, Z-E, Lim, S, Pang, Y-L, Shuit, S-H & Ong, H-C 2020, 'Utilisation of biomass wastes based activated carbon supported heterogeneous acid catalyst for biodiesel production', Renewable Energy, vol. 158, pp. 91-102.
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© 2020 Elsevier Ltd This study evaluated the utilisation of biomass wastes as catalyst supports by comparing the catalytic performance of papaya seed, empty fruit bunch (EFB) and corncob biomass waste derived carbon based acid catalysts applied for biodiesel production through esterification reaction of palm fatty acid distillate (PFAD) and methanol. Arylation of 4-benzenediazonium sulfonate synthesis method was able to sulfonate the catalyst support efficiently. The activated carbon (AC) synthesised possessed high porosity with surface area ranged between 639.68 and 972.66 m2/g. The effect of catalyst synthesising condition including carbonisation temperature (600–1000 °C), sulfonation time (0.5–2.5 h) and sulfanilic acid to AC weight ratio (3:1–13:1) towards the FAME yield and free fatty acid (FFA) conversion were evaluated. At the optimum catalyst synthesis conditions, corncob waste derived sulfonated AC catalyst exhibited the highest FAME yield and FFA conversion of 72.09% and 93.49%, respectively. Reusability study showed that corncob waste derived sulfonated AC catalyst was able to achieve relatively high FAME yield at the first two reaction cycles. The esterification reaction followed the irreversible pseudo-homogeneous reaction model. The high catalytic efficiency of the catalyst had shown its high potential to fit into the cost-effective and sustainable framework for biodiesel production.
Tawadros, P, Awadallah, M, Walker, P & Zhang, N 2020, 'Using a low-cost bluetooth torque sensor for vehicle jerk and transient torque measurement', Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering, vol. 234, no. 2-3, pp. 423-437.
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This paper presents the use and development of a specific wireless torque measurement system that is used to obtain the transient torque performance of vehicle transmissions. The torque sensor is strain-based, using surface-mounted strain gauges on a prop shaft. The gauges are connected to a compact printed circuit board, which is clamped to the shaft next to the strain gauges using a three-dimensional printed housing. The printed circuit board contains an amplifier, low-pass filter, analog-to-digital converter, microcontroller and bluetooth transceiver. The printed housing is impact resistant carbon-reinforced nylon and securely retains the printed circuit board and the battery powering the device. The transmitted torque data are received by a transceiver, which is interfaced to a PC through an RS-232 connection. NI LabVIEW is used to process, display and save data. The wireless torque sensor was installed to the Unit Under Test at the output shaft of the five-speed manual transmission. The Unit Under Test was installed on a dynamometer for verification purposes and the transient torque was recorded under various operational conditions. The transient output torque of the manual transmission is measured and compared with results obtained from simulations performed under similar operating conditions. The two sets of transient responses show a good correlation with each other and hence demonstrate that the torque sensor meets the major design specifications. The data obtained will be used to enhance the fidelity of the software model.
Tempa, K, Sarkar, R, Dikshit, A, Pradhan, B, Simonelli, AL, Acharya, S & Alamri, AM 2020, 'Parametric Study of Local Site Response for Bedrock Ground Motion to Earthquake in Phuentsholing, Bhutan', Sustainability, vol. 12, no. 13, pp. 5273-5273.
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Earthquakes, when it comes to natural calamities, are characteristically devastating and pose serious threats to buildings in urban areas. Out of multiple seismic regions in the Himalayas, Bhutan Himalaya is one that reigns prominent. Bhutan has seen several moderate-sized earthquakes in the past century and various recent works show that a major earthquake like the 2015 Nepal earthquake is impending. The southwestern city of Bhutan, Phuentsholing is one of the most populated regions in the country and the present study aims to explore the area using geophysical methods (Multispectral Analysis of Surface Waves (MASW)) for understanding possibilities pertaining to infrastructural development. The work involved a geophysical study on eight different sites in the study region which fall under the local area plan of Phuentsholing City. The geophysical study helps to discern shear wave velocity which indicates the soil profile of a region along with possible seismic hazard during an earthquake event, essential for understanding the withstanding power of the infrastructure foundation. The acquired shear wave velocity by MASW indicates visco-elastic soil profile down to a depth of 22.2 m, and it ranged from 350 to 600 m/s. A site response analysis to understand the correlation of bedrock rigidness to the corresponding depth was conducted using EERA (Equivalent-linear Earthquake Site Response Analysis) software. The amplification factors are presented for each site and maximum amplification factors are highlighted. These results have led to a clear indication of how the bedrock characteristics influence the surface ground motion parameters for the corresponding structure period. The results infer that the future constructional activity in the city should not be limited to two- to five-story buildings as per present practice. Apart from it, a parametric study was initiated to uncover whatever effects rigid bedrock has upon hazard parameters for various d...
Teng, J, Kou, J, Yan, X, Zhang, S & Sheng, D 2020, 'Parameterization of soil freezing characteristic curve for unsaturated soils', Cold Regions Science and Technology, vol. 170, pp. 102928-102928.
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© 2019 The soil freezing characteristic curve (SFCC) describes the relationship between the temperature and unfrozen water content in a soil. The SFCC is indispensable in modelling the hydro-mechanical behaviour of frozen soils, but is less understood for the unsaturated soils. A series of SFCC tests of unsaturated silica sand, silt and red clay are preformed based on a newly developed nuclear magnetic resonance (NMR) apparatus, which can precisely control the sample temperature in the magnetic field. The experimental results show that the measured SFCC varies significantly for different initial water contents, and that a lower initial water content leads to a slower increase in unfrozen water content, proving that the SFCC is closely related to the initial unsaturated state. It is found that the thawing curve is better to represent the SFCC, in contrast the freezing curve is significantly affected by the supercooling phenomenon. A new parameterization of the SFCC is presented for unsaturated soils by combining the Clapeyron equation and the model for Soil Water Characteristic Curve (SWCC). A number of test results from the literature and this study are used to validate the new SFCC model. By inputting the parameters for the SWCC and initial state into the proposed model, the predicted SFCC can agree well with the measured results. The new model has a theoretical basis and simple form and is applicable to both saturated and unsaturated soils.
Teng, J, Liu, J, Zhang, S & Sheng, D 2020, 'Modelling frost heave in unsaturated coarse-grained soils', Acta Geotechnica, vol. 15, no. 11, pp. 3307-3320.
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© 2020, Springer-Verlag GmbH Germany, part of Springer Nature. Coarse-grained soils were considered not susceptible to frost heave. However, substantial frost heave has been observed in unsaturated coarse fills in high-speed railway embankments. Recent experimental results in the literature show that vapour transfer has a considerable influence on the frost heaving of coarse-grained soil. However, vapour transfer has rarely been considered in modelling frost heave. This study presents a new frost heave model that considers vapour transfer and its contribution to ice formation. An updated computer program (PCHeave) is developed to account for the vapour transfer in unsaturated coarse-grained soils, where the rigid ice theory is applied to initiate ice lens formation in the frozen fringe. The results of the proposed model are compared with laboratory test results, which show reasonable agreement. The frost heave data monitored in 2013–2014 along the embankment of the Harbin–Dalian Passenger Dedicated Railway are also used to validate the proposed model. The prediction of the model agrees well with the measured results of frost heave and frost depth. This indicates that the proposed model can reasonably reflect the process of frost heave caused by vapour transfer in unsaturated coarse-grained soils.
Thanh, HT, Li, J & Zhang, YX 2020, 'Numerical simulation of self-consolidating engineered cementitious composite flow with the V-funnel and U-box', Construction and Building Materials, vol. 236, pp. 117467-117467.
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Thomas, P, Chauviré, B, Flower-Donaldson, K, Aldridge, L, Smallwood, A & Liu, B 2020, 'FT-NIR and DSC characterisation of water in opal', Ceramics International, vol. 46, no. 18, pp. 29443-29450.
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© 2020 Elsevier Ltd and Techna Group S.r.l. Opal is a hydrous silica (Si02.nH2O) formed through a dissolution-precipitation process. The formation process incorporates water into the structure as bound silanol and molecular water. As the water is distributed in a range of states, multiple methods of characterisation are required to identify each state. This study reports the results of temperature dependent FT-NIR and DSC investigation on natural opal samples of the opal-A (amorphous) and opal-CT (poorly crystalline cristobalite with tridymitic stacking faults) types. Significant differences in the melting behaviour of crystallisable water as well as differences in the spectral characteristics of the non-crystallisable molecular water are observed. These differences are ascribed to the different microstructures of the opal types.
Thöns, S & Stewart, MG 2020, 'On the cost-efficiency, significance and effectiveness of terrorism risk reduction strategies for buildings', Structural Safety, vol. 85, pp. 101957-101957.
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We analyse the performance of risk reduction strategies for terrorist attacks with Improvised Explosive Devices (IEDs) for large governmental building structures in terms of cost-efficiency, significance and effectiveness accounting for life safety in conjunction with societal preferences and capabilities. The approach builds upon an extended Bayesian pre-posterior decision analysis and the principles of the marginal lifesaving costs based on the Life Quality Index (LQI). The decision scenario is formulated for a decision maker responsible for the safety of governmental or large commercial buildings and consequently the direct risks, the indirect risks due to fatalities and economical importance of the building beside the expected cost for the individual risk reduction strategies are modelled, aggregated and optimised. The considered risk reduction strategies encompass an explicit consideration and distinction of information and actions such as (i) threat surveillance may trigger the temporary evacuation of the building, (ii) the implementation of protection provisions provided by codes and guidelines, (iii) a detailed progressive collapse assessment and specific protection measures and (iv) the combination of protection and surveillance. All considered strategies are found to contribute to risk reduction and can be cost-efficient, especially for higher threat probabilities. The risk reduction strategies comply with societal macroeconomic and demographical characteristics and societal preferences according to the LQI. The progressive collapse assessment with targeted protection measures is found to be the most cost-efficient, significant and effective counter-terrorism strategy. This finding points to the necessity for a comprehensive utilisation of scientific methods and sophisticated engineering for progressive collapse assessment to determine targeted protection measures.
Tian, S, Indraratna, B, Tang, L, Qi, Y & Ling, X 2020, 'A semi-empirical elasto-plastic constitutive model for coarse-grained materials that incorporates the effects of freeze-thaw cycles', Transportation Geotechnics, vol. 24, pp. 100373-100373.
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© 2020 Elsevier Ltd A volume-shear coupling mechanism is imperative for developing high-speed railways in very cold regions. A series of consolidated drained static triaxial experiments were carried out to investigate the effect of freeze-thaw (F-T) cycles on the stress-strain features of coarse-grained materials (CGM) typically used at the bottom layer of subgrade for high-speed rail tracks in China. Mathematical expressions describing the effect of F-T cycles for residual stress state stress ratio, elastic shear modulus, and specific volume have been proposed. Laboratory observations enabled an empirical dilatancy equation to be incorporated in a constitutive model to capture the salient aspects of the monotonic deformation behaviour of CGM including the F-T effects. After comparing with experimental observations and validating through past independent studies, the proposed constitutive model could accurately predict the monotonic shear behaviour of the CGM exposed to F-T cycles.
Tijing, LD, Dizon, JRC, Ibrahim, I, Nisay, ARN, Shon, HK & Advincula, RC 2020, '3D printing for membrane separation, desalination and water treatment', Applied Materials Today, vol. 18, pp. 100486-100486.
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© 2019 Elsevier Ltd Additive manufacturing or commonly known as 3D printing is driving innovation in many industries and academic research including the water resource sector. The capability of 3D printing to fabricate complex objects in a fast and cost-effective manner makes it highly desirable over conventional manufacturing processes. Recent years have seen a rapid increase in research using 3D printing for membrane separation, desalination and water purification applications, potentially revolutionizing this field. This review focuses on recent advancements in 3D-printed materials and methods for water-related applications including developments in module spacers, novel filtration and desalination membranes, adsorbents, water remediation, solar steam generation materials, catalysis, etc. The emergence of new 3D printers with higher printing resolution, better efficiency, faster speed, and wider material applicability has garnered more interest and can potentially reshape research and development in this field. The promising potential, challenges and future prospects of 3D printing, additive manufacturing, and materials for water resource and treatment-related applications are all discussed in this review.
To, VHP, Nguyen, TV, Bustamante, H & Vigneswaran, S 2020, 'Effects of extracellular polymeric substance fractions on polyacrylamide demand and dewatering performance of digested sludges', Separation and Purification Technology, vol. 239, pp. 116557-116557.
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© 2020 Elsevier B.V. High polymer demand in sludge conditioning is an intractable aspect of the water industry. This study investigated the effects of extracellular polymeric substances (EPS) fractions on polyacrylamide demand for conditioning and dewatering performance. Specifically, it examined aerobically and anaerobically digested sludges from seven full-scale wastewater treatment plants (WWTPs). Our study successfully quantified the contributions of soluble EPS to polyacrylamide demand during conditioning and explained the role of tightly bound EPS (TB-EPS) in determining the digested sludges’ dewatering performance. Results show that the concentrations of soluble EPS in the sludges varied between 92 and 1148 mg/L. Experimental results also demonstrated that between 25% and 80% of polyacrylamides used for conditioning were wasted in “parasitic” reactions with soluble EPS. The residual cationic polyacrylamide left in solution, after the parasitic reactions, was substantial and varied between 35 and 254 mg/L. Despite this outcome, the zeta potential values of dewatered sludge cakes remained negative, i.e. between −24 and −35 mV. These indicated that the residual soluble cationic polyacrylamides would not have been absorbed on the negatively charged sludge particles. This explained the relatively poor performance of the dewatering stage in the treatment plants studied. Furthermore the results suggested the TB-EPS attached to the sludge particles would be responsible for the poor dewatering. We postulated that the TB-EPS would gelify and immobilize the water surrounding the sludge particles. Our study suggested that new and more effective polymers for conditioning are needed to both: (i) reduce polymer demand; and (ii) improve the dewatering performance.
Toghroli, A, Mehrabi, P, Shariati, M, Trung, NT, Jahandari, S & Rasekh, H 2020, 'Evaluating the use of recycled concrete aggregate and pozzolanic additives in fiber-reinforced pervious concrete with industrial and recycled fibers', Construction and Building Materials, vol. 252, pp. 118997-118997.
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© 2020 Elsevier Ltd The aim of this study is to investigate the effects of using recycled concrete aggregate (RCA) and pozzolanic materials as a partial replacement of natural coarse aggregate (NCA) and cement, respectively, on the mechanical and permeability properties of fiber-reinforced pervious concrete mixes. For this purpose, mixes were prepared with 25%, 50%, 75%, and 100% (by weight) RCA as coarse aggregate, and cement was partially replaced with 10% silica fume (SF) and 1%, 2%, and 3% nano-clay (NC). In order to enhance the mechanical strength of mixes, steel fiber (STF) and waste plastic fiber (WPF) were incorporated in the mixtures at a volume fraction of 1% and 2%. The experiments were carried out on a total number of 2310 samples casted from 110 mixes. Based on the test results, up to 25% increase in permeability and about 60% reduction in strength properties of mix incorporating 100% RCA were observed. The use of SF and NC led to enhancements in the strength properties because of micro-filling ability and pozzolanic reactivity. In general, the addition of fibers enhanced both compressive and flexural strengths up to 65% and 79%, respectively, over that of the unreinforced counterpart mix by incorporating 2% STF. WPF-reinforced mixes showed inferior performance compared to the STF-reinforced counterparts, due to the low quality and poor dispersion of WPF in mixes. It was found that, incorporating 100% RCA combined with 2% STF and 2% NC yields a pervious concrete suitable for structural applications.
Tong, C-X, Burton, GJ, Zhang, S & Sheng, D 2020, 'Particle breakage of uniformly graded carbonate sands in dry/wet condition subjected to compression/shear tests', Acta Geotechnica, vol. 15, no. 9, pp. 2379-2394.
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Torghabeh, AK, Pradhan, B & Jahandari, A 2020, 'Assessment of geochemical and sedimentological characteristics of atmospheric dust in Shiraz, southwest Iran', Geoscience Frontiers, vol. 11, no. 3, pp. 783-792.
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© 2019 China University of Geosciences (Beijing) and Peking University Geogenic dust is commonly believed to be one of the most important environmental problems in the Middle East. The present study investigated the geochemical characteristics of atmospheric dust particles in Shiraz City (south of Iran). Atmospheric dust samples were collected through a dry collector method by using glass trays at 10 location sites in May 2018. Elemental composition was analysed through inductively coupled plasma optical emission spectrometry. Meteorological data showed that the dustiest days were usually in spring and summer, particularly in April. X-ray diffraction analysis of atmospheric dust samples indicated that the mineralogical composition of atmospheric dust was calcite + dolomite (24%)>palygorskite (18%)>quartz (14%)>muscovite (13%)>albite (11%)>kaolinite (7%)>gypsum (7%)>zircon = anatase (3%). The high occurrence of palygorskite (16%–23%) could serve as a tracer of the source areas of dust storms from the desert of Iraq and Saudi Arabia to the South of Iran. Scanning electron microscopy indicated that the sizes of the collected dust varied from 50 μm to 0.8 μm, but 10 μm was the predominant size. The atmospheric dust collected had prismatic trigonal–rhombohedral crystals and semi-rounded irregular shapes. Moreover, diatoms were detected in several samples, suggesting that emissions from dry-bed lakes, such as Hoor Al-Azim Wetland (located in the southwest of Iran), also contributed to the dust load. Backward trajectory simulations were performed at the date of sampling by using the NOAA HYSPLIT model. Results showed that the sources of atmospheric dust in the studied area were the eastern area of Iraq, eastern desert of Saudi Arabia, Kuwait and Khuzestan Province. The Ca/Al ratio of the collected samples (1.14) was different from the upper continental crust (UCC) value (UCC = 0.37), whereas Mg/Al (0.29), K/Al (0.22) and Ti/Al (0.07) ratios were close to the UC...
Toriello, M, Afsari, M, Shon, H & Tijing, L 2020, 'Progress on the Fabrication and Application of Electrospun Nanofiber Composites', Membranes, vol. 10, no. 9, pp. 204-204.
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Nanofibers are one of the most attractive materials in various applications due to their unique properties and promising characteristics for the next generation of materials in the fields of energy, environment, and health. Among the many fabrication methods, electrospinning is one of the most efficient technologies which has brought about remarkable progress in the fabrication of nanofibers with high surface area, high aspect ratio, and porosity features. However, neat nanofibers generally have low mechanical strength, thermal instability, and limited functionalities. Therefore, composite and modified structures of electrospun nanofibers have been developed to improve the advantages of nanofibers and overcome their drawbacks. The combination of electrospinning technology and high-quality nanomaterials via materials science advances as well as new modification techniques have led to the fabrication of composite and modified nanofibers with desired properties for different applications. In this review, we present the recent progress on the fabrication and applications of electrospun nanofiber composites to sketch a progress line for advancements in various categories. Firstly, the different methods for fabrication of composite and modified nanofibers have been investigated. Then, the current innovations of composite nanofibers in environmental, healthcare, and energy fields have been described, and the improvements in each field are explained in detail. The continued growth of composite and modified nanofiber technology reveals its versatile properties that offer alternatives for many of current industrial and domestic issues and applications.
Tran, VH, Phuntsho, S, Han, DS, Dorji, U, Zhang, X & Shon, HK 2020, 'Submerged module of outer selective hollow fiber membrane for effective fouling mitigation in osmotic membrane bioreactor for desalination', Desalination, vol. 496, pp. 114707-114707.
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© 2020 Elsevier B.V. This paper investigated the membrane fouling mitigation efficacy and performance of a home-made submerged module containing outer selective hollow fiber thin film composite forward osmosis (OSHF TFC FO) membrane in osmosis membrane bioreactor (OMBR) system treating municipal wastewater for desalination. Initial tests, optimization of draw solution flowrate and pumping mode for the submerged module were carried out before it was applied into the OMBR system. Overall, the OMBR system exhibited an initial water flux of approximately 6.3 LMH using 35 g/L NaCl as draw solution, and high removal efficiencies of bulk organic matter and nutrients. Moreover, membrane fouling was effectively mitigated with slow rate of flux decline during 33-day operation of the OMBR system. These results indicated that the submerged membrane module of OSHF TFC FO membrane has stable and reliable performances making it suitable for OMBR supplication without the need of air scouring to prevent membrane fouling.
Trinh, VT, Nguyen, TMP, Van, HT, Hoang, LP, Nguyen, TV, Ha, LT, Vu, XH, Pham, TT, Nguyen, TN, Quang, NV & Nguyen, XC 2020, 'Phosphate Adsorption by Silver Nanoparticles-Loaded Activated Carbon derived from Tea Residue', Scientific Reports, vol. 10, no. 1, p. 3634.
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AbstractThis study presents the removal of phosphate from aqueous solution using a new silver nanoparticles-loaded tea activated carbon (AgNPs-TAC) material. In order to reduce costs, the tea activated carbon was produced from tea residue. Batch adsorption experiments were conducted to evaluate the effects of impregnation ratio of AgNPs and TAC, pH solution, contact time, initial phosphate concentration and dose of AgNPs-AC on removing phosphate from aqueous solution. Results show that the best conditions for phosphate adsorption occurred at the impregnation ratio AgNPs/TAC of 3% w/w, pH 3, and contact time lasting 150 min. The maximum adsorption capacity of phosphate on AgNPs-TAC determined by the Langmuir model was 13.62 mg/g at an initial phosphate concentration of 30 mg/L. The adsorption isotherm of phosphate on AgNPs-TAC fits well with both the Langmuir and Sips models. The adsorption kinetics data were also described well by the pseudo-first-order and pseudo-second-order models with high correlation coefficients of 0.978 and 0.966, respectively. The adsorption process was controlled by chemisorption through complexes and ligand exchange mechanisms. This study suggests that AgNPs-TAC is a promising, low cost adsorbent for phosphate removal from aqueous solution.
Truong, MV, Nguyen, LN, Li, K, Fu, Q, Johir, MAH, Fontana, A & Nghiem, LD 2020, 'Biomethane production from anaerobic co-digestion and steel-making slag: A new waste-to-resource pathway', Science of The Total Environment, vol. 738, pp. 139764-139764.
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Truong, NT, Thi, HPN, Ninh, HD, Phung, XT, Van Tran, C, Nguyen, TT, Pham, TD, Dang, TD, Chang, SW, Rene, ER, Ngo, HH, Nguyen, DD & La, DD 2020, 'Facile fabrication of graphene@Fe-Ti binary oxide nanocomposite from ilmenite ore: An effective photocatalyst for dye degradation under visible light irradiation', Journal of Water Process Engineering, vol. 37, pp. 101474-101474.
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© 2020 Elsevier Ltd Photocatalysis is an effective treatment technique for the removal of toxic pollutants present in water and wastewater. In this study, graphene@Fe-Ti binary oxide composites was prepared using a hydrothermal method and characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Fourier-transform infrared spectroscopy, and Brunauer-Emmett-Teller surface area analysis. The prepared composite exhibited even distribution of the Fe-Ti binary oxide on the surface of graphene, with an average diameter of 16.4 nm and a surface area of 133.7 m2/g. The optical property was evaluated and the band gap was calculated to be 2.867 eV using solid-state UV–vis spectroscopy and the [F(R)hν]1/2 plot. Lab-scale experiments were performed to evaluate the performance of graphene@Fe-Ti binary oxides to remove methyl blue (i.e. a dye) from wastewater. It was observed that the graphene loading had a significant effect on the photocatalytic activity of the composite and a composite with 20 % graphene showed the highest photocatalytic activity, with 100 % removal of the dye, after 20 min of irradiation time and a degradation rate constant of 0.213 min−1. Besides, the possible photocatalytic dye degradation mechanism using graphene@Fe-Ti binary oxide composite has also been proposed.
Ubando, AT, Chen, W, Show, P & Ong, HC 2020, 'Kinetic and thermodynamic analysis of iron oxide reduction by graphite for CO2mitigation in chemical‐looping combustion', International Journal of Energy Research, vol. 44, no. 5, pp. 3865-3882.
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Ukritnukun, S, Koshy, P, Rawal, A, Castel, A & Sorrell, CC 2020, 'Predictive Model of Setting Times and Compressive Strengths for Low-Alkali, Ambient-Cured, Fly Ash/Slag-Based Geopolymers', Minerals, vol. 10, no. 10, pp. 920-920.
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The effects of curing temperature, blast furnace slag content, and Ms on the initial and final setting times, and compressive strengths of geopolymer paste and mortars are examined. The present work demonstrates that ambient-cured geopolymer pastes and mortars can be fabricated without requiring high alkalinity activators or thermal curing, provided that the ratios of Class F fly ash (40–90 wt%), blast furnace slag (10–60 wt%), and low alkalinity sodium silicate (Ms = 1.5, 1.7, 2.0) are appropriately balanced. Eighteen mix designs were assessed against the criteria for setting time and compressive strength according to ASTM C150 and AS 3972. Using these data, flexible and reproducible mix designs in terms of the fly ash/slag ratio and Ms were mapped and categorised. The optimal mix designs are 30–40 wt% slag with silicate modulus (Ms) = 1.5–1.7. These data were used to generate predictive models for initial and final setting times and for ultimate curing times and ultimate compressive strengths. These projected data indicate that compressive strengths >100 MPa can be achieved after ambient curing for >56 days of mixes of ≥40 wt% slag.
Ulhaq, A, Born, J, Khan, A, Gomes, DPS, Chakraborty, S & Paul, M 2020, 'COVID-19 Control by Computer Vision Approaches: A Survey', IEEE Access, vol. 8, pp. 179437-179456.
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The COVID-19 pandemic has triggered an urgent call to contribute to the fight against an immense threat to the human population. Computer Vision, as a subfield of artificial intelligence, has enjoyed recent success in solving various complex problems in health care and has the potential to contribute to the fight of controlling COVID-19. In response to this call, computer vision researchers are putting their knowledge base at test to devise effective ways to counter COVID-19 challenge and serve the global community. New contributions are being shared with every passing day. It motivated us to review the recent work, collect information about available research resources, and an indication of future research directions. We want to make it possible for computer vision researchers to find existing and future research directions. This survey article presents a preliminary review of the literature on research community efforts against COVID-19 pandemic.
Usman, M, Shi, Z, Ren, S, Ngo, HH, Luo, G & Zhang, S 2020, 'Hydrochar promoted anaerobic digestion of hydrothermal liquefaction wastewater: Focusing on the organic degradation and microbial community', Chemical Engineering Journal, vol. 399, pp. 125766-125766.
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Vahabi, S, Stewart, M, Kasim, A, Hancock, H, Norouzi, M, Maddox, J & Austin, D 2020, 'P1383 The effects of doxorubicin on left and right ventricular strain in patients with lymphoma: insights from a retrospective study', European Heart Journal - Cardiovascular Imaging, vol. 21, no. Supplement_1.
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Abstract Funding Acknowledgements South Tees Research and Development Fund (UK) Background Anthracyclines are a cornerstone in the management of lymphoma. However, their use is associated with cardiotoxicity. Speckle tracking echocardiography (STE) has been established as a valid measure of quantifying cardiac function. However, most studies to this date have focused predominantly on left ventricular (LV) global longitudinal strain (GLS) with only a limited number assessing the right ventricle (RV) and other LV strain parameters. Purpose Using 2D STE, we assessed the effects of anthracyclines on LV and RV strain parameters, focusing on LV endocardial (GLS), LV myocardial GLS (myoGLS), LV radial strain (GRS), RV endocardial (RV GLS), myocardial GLS (RV myoGLS), and RV free wall strain (RVFWS). Methods We retrospectively collected data on patients treated for lymphoma between 2015-2018. Two groups (G) were defined: those with a conventional drop in LV ejection fraction (EF), (G1, n = 11) and those without (G2, n = 24). Echocardiograms were performed pre-chemotherapy (T0), mid-treatment (T1), and post-chemotherapy (T2) and were analysed offline using vendor-independent software (TomTec 2D CPA). LV and RV strain analysis was performed in both groups. This study was ethically approved by Health Research Association (REC Reference 18/SS/0139). Results ...
Vahidi, E, Rodríguez, JF, Bayne, E & Saco, PM 2020, 'One Flood Is Not Enough: Pool‐Riffle Self‐Maintenance Under Time‐Varying Flows and Nonequilibrium Multifractional Sediment Transport', Water Resources Research, vol. 56, no. 8.
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AbstractThe interaction of sediment supply and hydrographs can affect, on a mesoscale, geomorphic features like pools and riffles, which are fundamental units of many gravel bed rivers. In the past decades, different hypotheses have been developed to characterize the hydrodynamics of pool‐riffle sequences; however, most of the previous studies considered equilibrium or near‐equilibrium sediment transport conditions. Here we investigate the stability of pools and riffles during a sequence of different hydrographs representative of a natural flow regime, without satisfying the equilibrium sediment transport condition. In the current study, the effects of bed geometry, sediment sorting and hydrograph duration, are explained and quantified. The results show that under nonequilibrium conditions, the reversal episodes are not always competent enough for complete self‐maintenance during a single flood. However, width variations and grain sorting effects prevented the pools to be completely filled up with the upstream sediment supply. Hydrograph duration had a significant role in the riffle bed geometry. Even though a single flood (irrespective of the magnitude) was not competent enough to restore the pool‐riffle feature, a sequence of floods progressively improved conditions for self‐maintenance. These findings can bring more insight into flow management strategies, in terms of the importance of multiple sequential floods for restoring rivers with high sediment supply.
Vakhshouri, B, Nejadi, S & Erkmen, E 2020, 'Advances in numerical analysis of creep effect in time-dependent deflection of light-weight concrete slabs', Mechanics of Advanced Materials and Structures, vol. 27, no. 18, pp. 1563-1570.
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© 2018, © 2018 Taylor & Francis Group, LLC. Using a wide range of creep models, the experimental results of long-term deflection of lightweight concrete slabs subjected to two levels of early-age loading are investigated. Different creep models give considerably different estimation of the experimental deflection of slabs. The included factors in each creep model to simulate the experimental creep behavior of the concrete, and loading level on the slabs are the main causes of different results. Among the investigated models, the BP1 and FIBMC-2010 models including the aggregate type and concrete density is shown to be in good agreement with the experimental data in both loading levels.
Varjani, S, Joshi, R, Srivastava, VK, Ngo, HH & Guo, W 2020, 'Treatment of wastewater from petroleum industry: current practices and perspectives', Environmental Science and Pollution Research, vol. 27, no. 22, pp. 27172-27180.
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© 2019, Springer-Verlag GmbH Germany, part of Springer Nature. Petroleum industry is one of the fastest growing industries, and it significantly contributes to economic growth in developing countries like India. The wastewater from a petroleum industry consist a wide variety of pollutants like petroleum hydrocarbons, mercaptans, oil and grease, phenol, ammonia, sulfide, and other organic compounds. All these compounds are present as very complex form in discharged water of petroleum industry, which are harmful for environment directly or indirectly. Some of the techniques used to treat oily waste/wastewater are membrane technology, photocatalytic degradation, advanced oxidation process, electrochemical catalysis, etc. In this review paper, we aim to discuss past and present scenario of using various treatment technologies for treatment of petroleum industry waste/wastewater. The treatment of petroleum industry wastewater involves physical, chemical, and biological processes. This review also provides scientific literature on knowledge gaps and future research directions to evaluate the effect(s) of various treatment technologies available.
Varjani, S, Pandey, A, Tyagi, RD, Ngo, HH & Larroche, C 2020, 'Preface', pp. xxi-xxii.
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Velasco, SÁ 2020, 'Ilegalizados en Ecuador, el país de la “ciudadanía universal”', Sociologias, vol. 22, no. 55, pp. 138-170.
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Resumen En base a un análisis etnográfico multisituado conducido en Ecuador entre 2015 y 2017, este artículo analiza cómo en el marco del mayor progresismo constitucional en materia migratoria, en el país de la “ciudadanía universal”, varios mecanismos legales y sociales fueron adoptados y terminaron confinando a migrantes y refugiados regionales y extracontinentales a encarnar situaciones de ilegalidad, posible deportación y desechabilidad. Se parte de una revisión teórica sobre el régimen de control fronterizo neoliberal global y sobre cómo la producción legal de la ilegalidad migrante es nodal en su funcionamiento, para después analizar por qué inmigrantes caribeños, africanos y de Medio Oriente escogieron a Ecuador como su destino, cuáles fueron los principales reveses e incongruencias en la política migratoria y cómo éstos impactaron en la cotidianeidad de esos inmigrantes hasta multiplicar sus salidas irregularizadas posteriores. El artículo constata que el giro progresista ecuatoriano no estuvo exento de mecanismos análogos al régimen de control fronterizo neoliberal global, hecho que ayuda a comprender el rol que el país andino cumple en la geopolítica de las migraciones contemporáneas: ser un espacio de producción de migrantes ilegalizados o mano de obra barata en ruta a EE.UU., rol que confirma su funcionalidad como un nodo conector dentro de un sistema mucho más amplio y complejo de control neoliberal de la movilidad.
Vilayphone, V, Outram, JG, Collins, F, Millar, GJ & Altaee, A 2020, 'Process design of coal seam gas associated water treatment plants to facilitate beneficial reuse', Journal of Environmental Chemical Engineering, vol. 8, no. 5, pp. 104255-104255.
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Vo, HNP, Ngo, HH, Guo, W, Chang, SW, Nguyen, DD, Chen, Z, Wang, XC, Chen, R & Zhang, X 2020, 'Microalgae for saline wastewater treatment: a critical review', Critical Reviews in Environmental Science and Technology, vol. 50, no. 12, pp. 1224-1265.
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© 2019, © 2019 Taylor & Francis Group, LLC. Saline wastewater contains numerous pollutants such as nutrients, heavy metals, micropollutants, and organic pollutants. This kind of wastewater needs to be treated prior to discharging. Compared to other technologies for saline wastewater treatment, the microalgae process is considered to be ‘green’ or environmentally friendly as it generates no secondary pollutants and creates profit. To elucidate the issue, this review investigated the following: (1) the nature of saline wastewater; (2) adaptation of microalgae in saline wastewater; (3) pollutants’ remediation by microalgae in saline wastewater; (4) comparisons with other technologies; and (5) future perspectives. Most importantly, during microalgae process, the saline wastewater is transformed from a waste into a source for biofuel and pigment production. This trend implies to heal the environment, cut remediation expenses and raise revenue.
Vo, HNP, Ngo, HH, Guo, W, Liu, Y, Woong Chang, S, Nguyen, DD, Zhang, X, Liang, H & Xue, S 2020, 'Selective carbon sources and salinities enhance enzymes and extracellular polymeric substances extrusion of Chlorella sp. for potential co-metabolism', Bioresource Technology, vol. 303, pp. 122877-122877.
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This study investigated the extracellular polymeric substance (EPS) and enzyme extrusion of Chlorella sp. using seven carbon sources and two salinities for potential pollutant co-metabolism. Results indicated that the levels of biomass, EPS and enzymes of microalgae cultured with glucose and saccharose outcompeted other carbon sources. For pigment production, glycine received the highest chlorophyll and carotene, up to 10 mg/L. The EPS reached 30 mg/L, having doubled the amount of protein than carbohydrate. For superoxide dismutase and peroxidase enzymes, the highest concentrations were beyond 60 U/ml and 6 nmol/d.ml, respectively. This amount could be potentially used for degrading 40% ciprofloxacin of concentration 2000 µg/L. When increasing salinity from 0.1% to 3.5%, the concentrations of pigment, EPS and enzymes rose 3 to 30 times. These results highlighted that certain carbon sources and salinities could induce Chlorella sp. to produce EPS and enzymes for pollutant co-metabolism and also for revenue-raising potential.
Vo, HNP, Ngo, HH, Guo, W, Nguyen, KH, Chang, SW, Nguyen, DD, Liu, Y, Liu, Y, Ding, A & Bui, XT 2020, 'Micropollutants cometabolism of microalgae for wastewater remediation: Effect of carbon sources to cometabolism and degradation products', Water Research, vol. 183, pp. 115974-115974.
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This study investigated the impacts of selective sole carbon source-induced micropollutants (MPs) cometabolism of Chlorella sp. by: (i) extracellular polymeric substances (EPS), superoxide dismutase and peroxidase enzyme production; (ii) MPs removal efficiency and cometabolism rate; (iii) MPs' potential degradation products identification; and (iv) degradation pathways and validation using the Eawag database to differentiate the cometabolism of Chlorella sp. with other microbes. Adding the sole carbon sources in the presence of MPs increased EPS and enzyme concentrations from 2 to 100-fold in comparison with only sole carbon sources. This confirmed that MPs cometabolism had occurred. The removal efficiencies of tetracycline, sulfamethoxazole, and bisphenol A ranged from 16-99%, 32-92%, and 58-99%, respectively. By increasing EPS and enzyme activity, the MPs concentrations accumulated in microalgae cells also fell 400-fold. The cometabolism process resulted in several degradation products of MPs. This study drew an insightful understanding of cometabolism for MPs remediation in wastewater. Based on the results, proper carbon sources for microalgae can be selected for practical applications to remediate MPs in wastewater while simultaneously recovering biomass for several industries and gaining revenue.
Volpin, F, Badeti, U, Wang, C, Jiang, J, Vogel, J, Freguia, S, Fam, D, Cho, J, Phuntsho, S & Shon, HK 2020, 'Urine Treatment on the International Space Station: Current Practice and Novel Approaches', Membranes, vol. 10, no. 11, pp. 327-327.
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A reliable, robust, and resilient water recovery system is of paramount importance on board the International Space Station (ISS). Such a system must be able to treat all sources of water, thereby reducing resupply costs and allowing for longer-term space missions. As such, technologies able to dewater urine in microgravity have been investigated by different space agencies. However, despite over 50 years of research and advancements on water extraction from human urine, the Urine Processing Assembly (UPA) and the Water Processor Assembly (WPA) now operating on the ISS still achieve suboptimal water recovery rates and require periodic consumables resupply. Additionally, urine brine from the treatment is collected for disposal and not yet reused. These factors, combined with the need for a life support system capable of tolerating even dormant periods of up to one year, make the research in this field ever more critical. As such, in the last decade, extensive research was conducted on the adaptation of existing or emerging technologies for the ISS context. In virtue of having a strong chemical resistance, small footprint, tuneable selectivity and versatility, novel membrane-based processes have been in focus for treating human urine. Their hybridisation with thermal and biological processes as well as the combination with new nanomaterials have been particularly investigated. This article critically reviews the UPA and WPA processes currently in operation on the ISS, summarising the research directions and needs, highlighted by major space agencies, necessary for allowing life support for missions outside the Low Earth Orbit (LEO). Additionally, it reviews the technologies recently proposed to improve the performance of the system as well as new concepts to allow for the valorisation of the nutrients in urine or the brine after urine dewatering.
Volpin, F, Jiang, J, El Saliby, I, Preire, M, Lim, S, Hasan Johir, MA, Cho, J, Han, DS, Phuntsho, S & Shon, HK 2020, 'Sanitation and dewatering of human urine via membrane bioreactor and membrane distillation and its reuse for fertigation', Journal of Cleaner Production, vol. 270, pp. 122390-122390.
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© 2020 Elsevier Ltd Source separation and recovery of human urine have often been proposed as an effective way to achieve a more sustainable waste-to-resource cycle. Its high density of available macronutrients (N–P–K) in urine makes it an ideal raw material for the production of fertiliser. However, to improve the safety and public acceptance of urine-based fertilisers, odour and pathogens must be removed. In this work, low-temperature DCMD was investigated a mean to produce a non-odorous high-concentration liquid fertiliser. The effectiveness of urine-fertiliser in hydroponically growing leafy vegetables was benchmarked with a commercial solution. Also, prior to the DCMD, urine was biologically oxidised through an MBR which removed over 95% of the DOC and converted almost 50% of the NH3 into NO3−. The results showed that, despite the high salinity and high LMW organics in human urine, MD was still able to achieve a final product with TDS concentration up to 280 g.L−1. A sharp flux decline was measured after 80% water recovery, but alkaline cleaning effectively removed the thick fouling layer and fully recovered the initial flux. When used to grow lettuce and Pak Choi hydroponically, the produced urine fertiliser achieved promising performances as the biomass from the aerial part of the plants was often similar to the one obtained with commercial fertilisers. Overall, this article investigates the whole urine-to-biomass cycle, from collection to treatment to plant growth tests.
Volpin, F, Woo, YC, Kim, H, Freguia, S, Jeong, N, Choi, J-S, Cho, J, Phuntsho, S & Shon, HK 2020, 'Energy recovery through reverse electrodialysis: Harnessing the salinity gradient from the flushing of human urine', Water Research, vol. 186, pp. 116320-116320.
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Urine dilution is often performed to avoid clogging or scaling of pipes, which occurs due to urine's Ca2+ and Mg2+ precipitating at the alkaline conditions created by ureolysis. The large salinity gradient between urine and flushing water is, theoretically, a source of potential energy which is currently unexploited. As such, this work explored the use of a compact reverse electrodialysis (RED) system to convert the chemical potential energy of urine dilution into electric energy. Urine' composition and ureolysis state as well as solution pumping costs were all taken into account. Despite having almost double its electric conductivity, real hydrolysed urine obtained net energy recoveries ENet of 0.053-0.039 kWh/m3, which is similar to energy recovered from real fresh urine. The reduced performances of hydrolysed urine were linked to its higher organic fouling potential and possible volatilisation of NH3 due to its high pH. However, the higher-than-expected performance achieved by fresh urine is possibly due to the fast diffusion of uncharged urea to the freshwater side. Real urine was also tested as a novel electrolyte solution and its performance compared with a conventional K4Fe(CN)6/K3Fe(CN)6 couple. While K4Fe(CN)6/K3Fe(CN)6 outperformed urine in terms of power densities and energy recoveries, net chemical reactions seemed to have occurred in urine when used as an electrolyte solution, leading to TOC, ammonia and urea removal of up to 13%, 6% and 4.4%, respectively. Finally, due to the migration of K+, NH4+ and PO43-, the low concentration solution could be utilised for fertigation. Overall, this process has the potential of providing off-grid urine treatment or energy production at a household or building level.
Vu, HP, Nguyen, LN, Vu, MT, Johir, MAH, McLaughlan, R & Nghiem, LD 2020, 'A comprehensive review on the framework to valorise lignocellulosic biomass as biorefinery feedstocks', Science of The Total Environment, vol. 743, pp. 140630-140630.
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An effective pretreatment is the first step to enhance the digestibility of lignocellulosic biomass - a source of renewable, eco-friendly and energy-dense materials - for biofuel and biochemical productions. This review aims to provide a comprehensive assessment on the advantages and disadvantages of lignocellulosic pretreatment techniques, which have been studied at the lab-, pilot- and full-scale levels. Biological pretreatment is environmentally friendly but time consuming (i.e. 15-40 days). Chemical pretreatment is effective in breaking down lignocellulose and increasing sugar yield (e.g. 4 to 10-fold improvement) but entails chemical cost and expensive reactors. Whereas the combination of physical and chemical (i.e. physicochemical) pretreatment is energy intensive (e.g. energy production can only compensate 80% of the input energy) despite offering good process efficiency (i.e. > 100% increase in product yield). Demonstrations of pretreatment techniques (e.g. acid, alkaline, and hydrothermal) in pilot-scale have reported 50-80% hemicellulose solubilisation and enhanced sugar yields. The feasibility of these pilot and full-scale plants has been supported by government subsidies to encourage biofuel consumption (e.g. tax credits and mandates). Due to the variability in their mechanisms and characteristics, no superior pretreatment has been identified. The main challenge lies in the capability to achieve a positive energy balance and great economic viability with minimal environmental impacts i.e. the energy or product output significantly surpasses the energy and monetary input. Enhancement of the current pretreatment techno-economic efficiency (e.g. higher product yield, chemical recycling, and by-products conversion to increase environmental sustainability) and the integration of pretreatment methods to effectively treat a range of biomass will be the steppingstone for commercial lignocellulosic biorefineries.
Vu, HP, Nguyen, LN, Zdarta, J, Nga, TTV & Nghiem, LD 2020, 'Blue-Green Algae in Surface Water: Problems and Opportunities', Current Pollution Reports, vol. 6, no. 2, pp. 105-122.
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Vu, MT, Vu, HP, Nguyen, LN, Semblante, GU, Johir, MAH & Nghiem, LD 2020, 'A hybrid anaerobic and microalgal membrane reactor for energy and microalgal biomass production from wastewater', Environmental Technology & Innovation, vol. 19, pp. 100834-100834.
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Wan Mohd Jaafar, WS, Said, NFS, Abdul Maulud, KN, Uning, R, Latif, MT, Muhmad Kamarulzaman, AM, Mohan, M, Pradhan, B, Saad, SNM, Broadbent, EN, Cardil, A, Silva, CA & Takriff, MS 2020, 'Carbon Emissions from Oil Palm Induced Forest and Peatland Conversion in Sabah and Sarawak, Malaysia', Forests, vol. 11, no. 12, pp. 1285-1285.
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The palm oil industry is one of the major producers of vegetable oil in the tropics. Palm oil is used extensively for the manufacture of a wide variety of products and its production is increasing by around 9% every year, prompted largely by the expanding biofuel markets. The rise in annual demand for biofuels and vegetable oil from importer countries has caused a dramatic increase in the conversion of forests and peatlands into oil palm plantations in Malaysia. This study assessed the area of forests and peatlands converted into oil palm plantations from 1990 to 2018 in the states of Sarawak and Sabah, Malaysia, and estimated the resulting carbon dioxide (CO2) emissions. To do so, we analyzed multitemporal 30-m resolution Landsat-5 and Landsat-8 images using a hybrid method that combined automatic image processing and manual analyses. We found that over the 28-year period, forest cover declined by 12.6% and 16.3%, and the peatland area declined by 20.5% and 19.1% in Sarawak and Sabah, respectively. In 2018, we found that these changes resulted in CO2 emissions of 0.01577 and 0.00086 Gt CO2-C yr−1, as compared to an annual forest CO2 uptake of 0.26464 and 0.15007 Gt CO2-C yr−1, in Sarawak and Sabah, respectively. Our assessment highlights that carbon impacts extend beyond lost standing stocks, and result in substantial direct emissions from the oil palm plantations themselves, with 2018 oil palm plantations in our study area emitting up to 4% of CO2 uptake by remaining forests. Limiting future climate change impacts requires enhanced economic incentives for land uses that neither convert standing forests nor result in substantial CO2 emissions.
Wang, A, Wang, W, Chen, J, Mao, R, Pang, Y, Li, Y, Chen, W, Chen, D, Hao, D, Ni, B-J, Saunders, M & Jia, G 2020, 'Dominant Polar Surfaces of Colloidal II–VI Wurtzite Semiconductor Nanocrystals Enabled by Cation Exchange', The Journal of Physical Chemistry Letters, vol. 11, no. 13, pp. 4990-4997.
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Polar surfaces of ionic crystals are of growing technological importance, with implications for the efficiency of photocatalysts, gas sensors, and electronic devices. The creation of ionic nanocrystals with high percentages of polar surfaces is an option for improving their efficiency in the aforementioned applications but is hard to accomplish because they are less thermodynamically stable and prone to vanish during the growth process. Herein, we develop a strategy that is capable of producing polar surface-dominated II-VI semiconductor nanocrystals, including ZnS and CdS, from copper sulfide hexagonal nanoplates through cation exchange reactions. The obtained wurtzite ZnS hexagonal nanoplates have dominant {002} polar surfaces, occupying up to 97.8% of all surfaces. Density functional theory calculations reveal the polar surfaces can be stabilized by a charge transfer of 0.25 eV/formula from the anion-terminated surface to the cation-terminated surface, which also explains the presence of polar surfaces in the initial Cu1.75S hexagonal nanoplates with cation deficiency prior to cation exchange reactions. Experimental results showed that the HER activity could be boosted by the surface polarization of polar surface-dominated ZnS hexagonal nanoplates. We anticipate this strategy is general and could be used with other systems to prepare nanocrystals with dominant polar surfaces. Furthermore, the availability of colloidal semiconductor nanocrystals with dominant polar surfaces produced through this strategy opens a new avenue for improving their efficiency in catalysis, photocatalysis, gas sensing, and other applications.
Wang, B, Ni, B-J, Yuan, Z & Guo, J 2020, 'Unravelling kinetic and microbial responses of enriched nitrifying sludge under long-term exposure of cephalexin and sulfadiazine', Water Research, vol. 173, pp. 115592-115592.
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Wastewater treatment plants (WWTPs) have been identified as one of the reservoirs of antibiotics. Although nitrifying bacteria have been reported to be capable of degrading various antibiotics, there are very few studies investigating long-term effects of antibiotics on kinetic and microbial responses of nitrifying bacteria. In this study, cephalexin (CFX) and sulfadiazine (SDZ) were selected to assess chronic impacts on nitrifying sludge with stepwise increasing concentrations in two independent bioreactors. The results showed that CFX and SDZ at an initial concentration of 100 μg/L could be efficiently removed by enriched nitrifying sludge, as evidenced by removal efficiencies of more than 88% and 85%, respectively. Ammonia-oxidizing bacteria (AOB) made a major contribution to the biodegradation of CFX and SDZ via cometabolism, compared to limited contributions from heterotrophic bacteria and nitrite-oxidizing bacteria. Chronic exposure to CFX (≥30 μg/L) could stimulate ammonium oxidation activity in terms of a significant enhancement of ammonium oxidation rate (p < 0.01). In contrast, the ammonium oxidation activity was inhibited due to exposure to 30 μg/L SDZ (p < 0.01), then it recovered after long-term adaption under exposure to 50 and 100 μg/L SDZ. In addition, 16S rRNA gene amplicon sequencing revealed that the relative abundance of AOB decreased distinctly from 23.8% to 28.8% in the control phase (without CFX or SDZ) to 14.2% and 10.8% under exposure to 100 μg/L CFX and SDZ, respectively. However, the expression level of amoA gene was up-regulated to overcome this adverse impact and maintain a stable and efficient removal of both ammonium and antibiotics. The findings in this study shed a light on chronic effects of antibiotic exposure on kinetic and microbial responses of enriched nitrifying sludge in WWTPs.
Wang, C-T, Chen, Y-M, Tang, RCO, Garg, A, Ong, H-C & Yang, Y-C 2020, 'Dominated flow parameters applied in a recirculation microbial fuel cell', Process Biochemistry, vol. 99, pp. 236-245.
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© 2020 Elsevier Ltd Scaling up of microbial fuel cells is a challenge for practical applications in wastewater treatment. In addition, the flow control is an important aspect for the electrochemical reactions occurring at the electrodes are influenced by fluid motions. By using dimensionless parameter analysis fluid regimes can be investigated in different scales of reactors. In this study, four important dimensionless flow parameters such as Reynolds number, Péclet number, Schmidt number, and Sherwood number were used for systematic analysis of hydrodynamic effects and power performance of recirculation mode microbial fuel cells together with computational fluid dynamics method. Results showed that the higher value of Reynolds number enhanced the convective flow of anolyte due to the dominant inertial forces in the flow field. Therefore, Reynolds number of 1.6 × 101 were obtained high mass transfer coefficient of 4.76 × 10−7 m s-1 and thin diffusion layer thickness of 2.52 × 10-3 m. Maximum power density and limited current density of 2422.8 mW m-2 and 4736.4 mA m-2 were obtained respectively which were higher than Reynolds number of 0 by 1.61 and 1.69 times. These findings shall be useful for effective recirculation flow mode MFCs power production and have a great possibility for large scale applications.
Wang, C-T, Ong Tang, RC, Wu, M-W, Garg, A, Ubando, AT, Culaba, A, Ong, H-C & Chong, W-T 2020, 'Flow shear stress applied in self-buffered microbial fuel cells', Process Biochemistry, vol. 99, pp. 324-330.
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Wang, D, Wu, C, Zhang, Y, Xue, G & Xu, Y 2020, 'Study on seismic performance of a precast buckling-restrained composite shear wall system with three assembly arrangements', Bulletin of Earthquake Engineering, vol. 18, no. 10, pp. 4839-4872.
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© 2020, Springer Nature B.V. Precast buildings have attarcted worldwide attention because of their significant role in the realization of sustainable urbanization. In this study, a precast buckling-restrained composite shear wall (PBRSW) system is developed, which is assemblied by multiple composite shear wall modules on site. The PBRSW system with three assembly arrangements of the composite shear wall modules, vertical, horizontal and cross arrangements, are designed and explored comparatively to mitigate buckling phenomena and obtain beneficial mechanical behaviours with experiment and simulation methods. To bring insight the seismic performance of the developed system, traditional buckling-restrained shear wall (BRSW) system and steel plate shear wall (SPSW) system are further investigated. The results show that the PBRSW system achieves plumper hysteresis behaviors, higher force-bearing and energy-dissipation capacities, and better ductility performance than that of the other two systems. Buckling phenomena of the PBRSW system are restrined effectively, and its maximum out-of-plane displacement is only 1/18 and 1/15 of the SPSW and BRSW systems on average respectively. The PBRSW system with vertical arrangement of the composite shear wall modules shows the best mechanical behavior with the highest bearing capacity and energy dissipation among the three assembly arrangements. Experimental data coincides well with those from finite element model (FEM) analysis and therefore validates FEM.
Wang, G, Li, Y, Sheng, L, Xing, Y, Liu, G, Yao, G, Ngo, HH, Li, Q, Wang, XC, Li, Y-Y & Chen, R 2020, 'A review on facilitating bio-wastes degradation and energy recovery efficiencies in anaerobic digestion systems with biochar amendment', Bioresource Technology, vol. 314, pp. 123777-123777.
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In this review, progress in the potential mechanisms of biochar amendment for AD performance promotion was summarized. As adsorbents, biochar was beneficial for alleviating microbial toxicity, accelerating refractory substances degradation, and upgrading biogas quality. The buffering capacity of biochar balanced pH decreasing caused by volatile fatty acids accumulation. Moreover, biochar regulated microbial metabolism by boosting activities, mediating electron transfer between syntrophic partners, and enriching functional microbes. Recent studies also suggested biochar as potential useful additives for membrane fouling alleviation in anaerobic membrane bioreactors (AnMBR). By analyzing the reported performances based on different operation models or substrate types, debatable issues and associated research gaps of understanding the real role of biochar in AD were critically discussed. Accordingly, Future perspectives of developing biochar-amended AD technology for real-world applications were elucidated. Lastly, with biochar-amended AD as a core process, a novel integrated scheme was proposed towards high-efficient energy-resource recovery from various bio-wastes.
Wang, Q, Li, Q, Wu, D, Yu, Y, Tin-Loi, F, Ma, J & Gao, W 2020, 'Machine learning aided static structural reliability analysis for functionally graded frame structures', Applied Mathematical Modelling, vol. 78, pp. 792-815.
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© 2019 A novel machine learning aided structural reliability analysis for functionally graded frame structures against static loading is proposed. The uncertain system parameters, which include the material properties, dimensions of structural members, applied loads, as well as the degree of gradation of the functionally graded material (FGM), can be incorporated within a unified structural reliability analysis framework. A 3D finite element method (FEM) for static analysis of bar-type engineering structures involving FGM is presented. By extending the traditional support vector regression (SVR) method, a new kernel-based machine learning technique, namely the extended support vector regression (X-SVR), is proposed for modelling the underpinned relationship between the structural behaviours and the uncertain system inputs. The proposed structural reliability analysis inherits the advantages of the traditional sampling method (i.e., Monte-Carlo Simulation) on providing the information regarding the statistical characteristics (i.e., mean, standard deviations, probability density functions and cumulative distribution functions etc.) of any concerned structural outputs, but with significantly reduced computational efforts. Five numerical examples are investigated to illustrate the accuracy, applicability, and computational efficiency of the proposed computational scheme.
Wang, W, Wu, C, Liu, Z, An, K & Zeng, J-J 2020, 'Experimental Investigation of the Hybrid FRP-UHPC-Steel Double-Skin Tubular Columns under Lateral Impact Loading', Journal of Composites for Construction, vol. 24, no. 5, pp. 04020041-04020041.
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© 2020 American Society of Civil Engineers. The lateral impact behavior of hybrid fiber-reinforced polymer (FRP)-ultrahigh-performance concrete (UHPC)-steel double-skin tubular columns (DSTCs) was experimentally investigated in this study. Seven specimens, which had an outer diameter of 168 mm and a length of 2,000 mm, were tested under lateral impact loading. Different parameters, including the axial force level, impact energy, concrete type, void ratio, FRP tube thickness, and the presence/absence of the FRP tube, were investigated. The dynamic responses, including global/local damage modes, lateral deflection-time histories, impact force-time histories, strain-time histories, and acceleration-time histories, were investigated. The test results prove that the hybrid UHPC DSTCs exhibit very ductile behavior under lateral impact loading. The hybrid UHPC DSTCs have a higher lateral impact resistance capacity as compared to the hybrid DSTCs infilled with normal-strength concrete. The lateral impact resistance capacity of hybrid UHPC DSTCs with an applied axial force of 200 kN can be improved to some extent compared with those without any axial force. The impact energy, the void ratio, the FRP tube thickness, and the presence/absence of the FRP tube can significantly affect the lateral impact behavior of hybrid UHPC DSTCs. Furthermore, the lateral impact behaviors of hybrid DSTCs, concrete-filled double-skin steel tubes (CFDSTs), and concrete-filled steel tubes (CFSTs) were compared and discussed based on the experimental results in this study as well as in other literature studies.
Wang, X, Guo, Z, Hu, Z, Ngo, H, Liang, S & Zhang, J 2020, 'Adsorption of phenanthrene from aqueous solutions by biochar derived from an ammoniation-hydrothermal method', Science of The Total Environment, vol. 733, pp. 139267-139267.
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Wang, Y, Liu, X, Liu, Y, Wang, D, Xu, Q, Li, X, Yang, Q, Wang, Q, Ni, B-J & Chen, H 2020, 'Enhancement of short-chain fatty acids production from microalgae by potassium ferrate addition: Feasibility, mechanisms and implications', Bioresource Technology, vol. 318, pp. 124266-124266.
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Anaerobic fermentation of microalgae was always hindered by its rigid cell wall structure. This paper reports a novel technique, i.e., adding potassium ferrate (K2FeO4) into microalgae fermentation systems to enhance short-chain fatty acids (SCFAs) production. The results showed that the maximum SCFAs production and acetic acid proportion were 732.6 mg COD/g VS and 54.6% at a dosage of 112.8 mg Fe(VI)/g VS, which were 168% and 208% of those in the control, respectively. Mechanism studies revealed that K2FeO4 effectively destroyed surface morphology and cell structure, and thus facilitated microalgae solubilization, providing a large number of biodegradable substrates for subsequent SCFA production. Although K2FeO4 inhibited all the microbial activities relevant to hydrolysis, acidification and methanogenesis processes to some degree, its inhibition to methanogens was much severer than that to other microbes. Illumina MiSeq sequencing analyses revealed that K2FeO4 addition increased the relative abundance (from 9.45% to 50.4%) of hydrolytic and SCFAs-forming bacteria.
Wang, Y, Wang, D, Yi, N, Li, Y, Ni, B-J, Wang, Q, Wang, H & Li, X 2020, 'Insights into the toxicity of troclocarban to anaerobic digestion: Sludge characteristics and methane production', Journal of Hazardous Materials, vol. 385, pp. 121615-121615.
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© 2019 Elsevier B.V. Triclocarban (TCC), as the most typical antibacterial agent, is widely discovered in many ecological environment, especially in sludge. However, so far, no studies have reported the effect of TCC exposure on the properties of excess sludge. Therefore, in this study, TCC's toxicities to waste activated sludge (WAS) were analyzed by investigating the variation of physicochemical properties of sludge. It was found that TCC exposure has no effect on sludge pH, while it facilitated organic substances release from sludge, e.g. dissolved organic matter (DOM), protein and polysaccharide, which caused an increase of sludge reduction and changed the structure of functional groups and surface morphology of sludge. Moreover, we explored the effect of TCC on anaerobic digestion of WAS and found methane production was seriously inhibited by TCC. The related mechanism tests had illustrated that TCC exposure did not affect the hydrolysis process, but promoted the acidification and acetogenesis, and importantly inhibited the methanogenesis process. Methanogenic community was further evaluated and observed that the presence of TCC could vary the microbial community of methanogens with the abundance of aceticlastic methanogens increasing and hydrogenotrophic methanogens decreasing. These findings reached in this study would widen the understanding scope for TCC's toxicity to WAS.
Wang, Y, Wei, W, Wu, S-L & Ni, B-J 2020, 'Zerovalent Iron Effectively Enhances Medium-Chain Fatty Acids Production from Waste Activated Sludge through Improving Sludge Biodegradability and Electron Transfer Efficiency', Environmental Science & Technology, vol. 54, no. 17, pp. 10904-10915.
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A novel zerovalent iron (ZVI) technique to simultaneously improve the production of medium-chain fatty acids (MCFAs) from waste activated sludge (WAS) and enhance WAS degradation during anaerobic WAS fermentation was proposed in this study. Experimental results showed that the production and selectivity of MCFAs were effectively promoted when ZVI was added at 1-20 g/L. The maximum MCFAs production of 15.4 g COD (Chemical Oxygen Demand)/L and MCFAs selectivity of 71.7% were both achieved at 20 g/L ZVI, being 5.3 and 4.8 times that without ZVI (2.9 g COD/L and 14.9%). Additionally, ZVI also promoted WAS degradation, which increased from 0.61 to 0.96 g COD/g VS when ZVI increased from 0 to 20 g/L. The microbial community analysis revealed that the ZVI increased the populations of key anaerobes related to hydrolysis, acidification, and chain elongation. Correspondingly, the solubilization, hydrolysis, and acidification processes of WAS were revealed to be improved by ZVI, thereby providing more substrates (short-chain fatty acids (SCFAs)) for producing MCFAs. The mechanism studies showed that ZVI declined the oxidation-reduction potential (ORP), creating a more favorable environment for the anaerobic biological processes. More importantly, ZVI with strong conductivity could act as an electron shuttle, contributing to increasing electron transfer efficiency from electron donor to acceptor. This strategy provides a new paradigm of transforming waste sludge into assets by a low-cost waste to bring significant economic benefits to sludge disposal and wastewater treatment.
Waqas, S, Bilad, MR, Man, Z, Wibisono, Y, Jaafar, J, Indra Mahlia, TM, Khan, AL & Aslam, M 2020, 'Recent progress in integrated fixed-film activated sludge process for wastewater treatment: A review', Journal of Environmental Management, vol. 268, pp. 110718-110718.
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Integrated fixed-film activated sludge (IFAS) process is considered as one of the leading-edge processes that provides a sustainable solution for wastewater treatment. IFAS was introduced as an advancement of the moving bed biofilm reactor by integrating the attached and the suspended growth systems. IFAS offers advantages over the conventional activated sludge process such as reduced footprint, enhanced nutrient removal, complete nitrification, longer solids retention time and better removal of anthropogenic composites. IFAS has been recognized as an attractive option as stated from the results of many pilot and full scales studies. Generally, IFAS achieves >90% removals for combined chemical oxygen demand and ammonia, improves sludge settling properties and enhances operational stability. Recently developed IFAS reactors incorporate frameworks for either methane production, energy generation through algae, or microbial fuel cells. This review details the recent development in IFAS with the focus on the pilot and full-scale applications. The microbial community analyses of IFAS biofilm and floc are underlined along with the special emphasis on organics and nitrogen removals, as well as the future research perspectives.
Wei, J, Li, J & Wu, C 2020, 'Behaviour of hollow-core and steel wire mesh reinforced ultra-high performance concrete columns under lateral impact loading', International Journal of Impact Engineering, vol. 146, pp. 103726-103726.
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© 2020 Elsevier Ltd Adopting UHPC in practical construction is very expensive due to the high steel fibre content (>2.5 vol%) and passive flexure reinforcement. Aiming at balancing the performance and cost, two UHPC column designs (2000 × 168 × 168 mm) are proposed in the present study. Hollow-core components and steel wire mesh reinforced components were cast with UHPC that contained 1.5 vol% steel fibre, and the impact resistance of both structural types was studied. The test specimens included two hollow-core UHPC columns with square and circular hollow shapes, and two steel wire mesh reinforced UHPC columns with 6 and 10 layers wire mesh reinforcement. The impact scenario was modelled with a 411 kg drop hammer falling freely from 1.25 m height to the mid-span of the test specimen. The results demonstrated that all UHPC specimens remained a flexural response with minimal damage. The developed numerical model captured the impact force, structural deformation and damage with reasonable accuracy. With the validated model, the energy evolution, dynamic shear and moment distribution, residual axial capacity and damage level of post-impact columns were evaluated. The effects of hollow section shape and ratio, axial load level, and longitudinal reinforcement ratio for hollow-core UHPC columns and the effects of layers of steel wire mesh for steel wire mesh reinforced UHPC columns were investigated. Compared with other hollow-core UHPC columns under the impact velocities between 4.95 m/s – 6.64 m/s, UHPC columns with a circular hollow section and 15% hollow ratio was the most effective in balancing the cost and impact resistance. For steel wire mesh reinforced UHPC columns, the column with steel wire mesh strengthening in the whole section had better impact resistance than its counterpart that only had wire mesh reinforcement in the tensile zone.
Wei, W, Guo, W, Ngo, HH, Mannina, G, Wang, D, Chen, X, Liu, Y, Peng, L & Ni, B-J 2020, 'Enhanced high-quality biomethane production from anaerobic digestion of primary sludge by corn stover biochar', Bioresource Technology, vol. 306, pp. 123159-123159.
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This study conducted batch and continuous tests to reveal the feasibility of corn stover biochar on improving anaerobic digestion of primary sludge (PS). Dosing biochar (1.82, 2.55 and 3.06 g/g Total Solids (TS)) in digester improved methane content increasing from 67.5% to 81.3-87.3% and enhanced methane production by 8.6-17.8%. Model analysis indicated that biochar accelerated PS hydrolysis and enhanced methane potential of PS. The mechanistic studies showed that biochar enhanced process stability provided by strong buffering capacity and alleviated NH3 inhibition. In continuous test over 116 days, the volatile solids (VS) destruction in the biochar-dosed digester increased by 14.9%, resulting in a 14% reduction in the volume of digestate for disposal. Biochar changed microbial community in an expected direction for anaerobic digestion. This work suggests that biochar technology would apply to co-digestion of WAS and PS to maximize the energy recovery and sludge reduction from the two sludge streams.
Wei, W, Hao, Q, Chen, Z, Bao, T & Ni, B-J 2020, 'Polystyrene nanoplastics reshape the anaerobic granular sludge for recovering methane from wastewater', Water Research, vol. 182, pp. 116041-116041.
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Wastewater has been identified as an important carrier for nanoplastics, which could elicit unintended impacts on critical microbial processes. However, the long-term impacts of nanoplastics on anaerobic granular sludge (AGS) for methane recovery from wastewater and the mechanisms involved remains unclear. In this study, we investigated the long term exposure-response relationship between polystyrene nanoplastics (Nano-PS) and AGS. In continuous test over 120 days with 86 days' Nano-PS exposure, feeding wastewater with 10 μg/L of Nano-PS had no significant impacts on the AGS performance. In comparison, higher levels (i.e., 20 and 50 μg/L) of Nano-PS decreased methane production and chemical oxygen demand (COD) removal by 19.0-28.6% and 19.3-30.0%, respectively, along with volatile fatty acids (VFA) accumulation. More extracellular polymeric substance (EPS) was induced by 10 μg/L of Nano-PS as a response to protect microbes, but higher levels (i.e., 20 and 50 μg/L) of Nano-PS decreased EPS generation, causing a decline in granule size and cell viability. Fluorescence tagging found that a large number of Nano-PS agglomerated/accumulated on the outer layer of AGS and even transferred into deeper layers of AGS over exposure time, producing toxic effects to adherent microorganisms, e.g., Longilinea sp., Paludibacter sp. and Methanosaeta sp.. The oxidative stress induced by Nano-PS was revealed to be a key factor for reshaping the AGS, reflected by the increased reactive oxygen species (ROS) generation and lactate dehydrogenase (LDH) release. The sodium dodecyl sulfate (SDS) leached from Nano-PS was also demonstrated to restrain the activities of antioxidant enzymes, thereby further lessening resistance to oxidative stress induced by Nano-PS. This work improves our ability to predict the risks associated with this ubiquitous contaminant in the environment.
Wei, W, Liu, X, Wu, L, Wang, D, Bao, T & Ni, B-J 2020, 'Sludge Incineration Bottom Ash Enhances Anaerobic Digestion of Primary Sludge toward Highly Efficient Sludge Anaerobic Codigestion', ACS Sustainable Chemistry & Engineering, vol. 8, no. 7, pp. 3005-3012.
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Copyright © 2020 American Chemical Society. In wastewater treatment plants (WWTPs), two main sludge streams, i.e., primary sludge (PS) and waste activated sludge (WAS), are generally mixed for anaerobic codigestion. However, the methane production is usually restricted by the poor and slow biodegradability of PS, and an effective approach for its efficient codigestion with WAS is still lacking due to its highly different sludge properties from those of WAS. Herein, we reported a novel strategy through using the sludge incineration bottom ash to enhance the anaerobic digestion of PS and its codigestion with WAS. Biochemical methane potential (BMP) test results showed that ash additive at 0.6-1.2 g/g-dry matter (DM) significantly enhanced PS anaerobic digestion, identified by an up to 18.2% increase in specific methane production. This was accompanied by a significantly improved dewaterability in the digestate. The transformations of metabolic intermediates revealed that the ash additive accelerated the hydrolysis and acidogenesis processes, which were also supported by the increased hydrolysis rate (k) of PS determined through kinetic modeling. Ash additive was then experimentally demonstrated to be effective in enhancing the anaerobic codigestion of PS and WAS, with the increased volatile solids (VS) destruction being approximately 19.8%, representing a reduction of digestate volume by 12.6%. The novel strategy proposed in this study provides a new paradigm of an integrated sludge-control by sludge to bring significant economic benefits to wastewater treatment and sludge disposal.
Wei, W, Wu, L, Liu, X, Chen, Z, Hao, Q, Wang, D, Liu, Y, Peng, L & Ni, B-J 2020, 'How does synthetic musks affect methane production from the anaerobic digestion of waste activated sludge?', Science of The Total Environment, vol. 713, pp. 136594-136594.
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The increasing use of synthetic musks has led to a large amount of synthetic musks retaining in waste activated sludge (WAS) via wastewater treatment, thereby entering anaerobic digester. However, the potential effects of synthetic musks on WAS anaerobic digestion remain unknown. Herein, this study selected the dominant galaxolide (HHCB) in WAS as the typical synthetic musks and experimentally evaluated the long-term effects on WAS anaerobic digestion using continuous lab-scale anaerobic digesters as well as the mechanisms involved. The results demonstrated that the increased HHCB levels (i.e., 90, 150 and 200 mg/kg-dw) resulted in the decreased methane production, with the methane production at 200 mg/kg-dw being only 80.5 ± 0.1% of the control. Supporting the methane production data, volatile solids (VS) destruction decreased by 18.6 ± 0.9%, which increased 6.8% of volume waste sludge for transfer and disposal. Correspondingly, the microbial community was shifted in the direction against anaerobic digestion. By modeling based on biochemical methane potential tests and investigating the key stages involved in anaerobic digestion, it was found that although the HHCB showed little impacts on the solubilization, WAS hydrolysis-acidification steps was inhibited by HHCB with the decreased hydrolysis rate and methane production potential, thereby causing the deteriorated performance of WAS anaerobic digestion.
Wu, C, Fang, J, Zhang, Z, Entezari, A, Sun, G, Swain, MV & Li, Q 2020, 'Fracture modeling of brittle biomaterials by the phase-field method', Engineering Fracture Mechanics, vol. 224, pp. 106752-106752.
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© 2019 Elsevier Ltd Biomaterials have been extensively used in prosthetic applications for their proven biocompatibility and osseointegration characteristics. Nevertheless, one of the critical issues of some synthetic biomaterials is brittleness prone to experience fracture failure due to low tensile strength and low fracture toughness. This study aims to employ a recently-developed phase-field model to simulate the crack propagation in brittle biomaterials. Unlike discrete fracture modeling methods, the phase-field approach allows simulating crack path in a continuous manner, thereby avoiding remeshing that may not be trivial for complicated fracture surfaces and facilitate iterative procedure commonly required for structural optimization. The phase-field model is formulated to treat the fracture path as a localized region of diffusive damage that can be described in terms of a phase-field function, in which the discreteness in cracked materials is assumed to be smeared. In this study, three representative case studies from the biomedical context, namely a zirconia-based dental bridge (or namely fixed partial denture (FPD)), a ceramic tissue scaffold and an analog saw-bone femur, are employed as illustrative examples. The phase-field modeling results are compared with the in-house experimental tests, demonstrating the effectiveness of the phase-field technique for predicting brittle fracture failure in several typical biomedical case scenarios. The phase-field model provides a useful tool for the computational fracture analysis and design optimization of other brittle biomaterials.
Wu, C, Fang, J, Zhou, S, Zhang, Z, Sun, G, Steven, GP & Li, Q 2020, 'Level‐set topology optimization for maximizing fracture resistance of brittle materials using phase‐field fracture model', International Journal for Numerical Methods in Engineering, vol. 121, no. 13, pp. 2929-2945.
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SummaryFracture is one of the most common failure modes in brittle materials. It can drastically decrease material integrity and structural strength. To address this issue, we propose a level‐set (LS) based topology optimization procedure to optimize the distribution of reinforced inclusions within matrix materials subject to the volume constraint for maximizing structural resistance to fracture. A phase‐field fracture model is formulated herein to simulate crack initiation and propagation, in which a staggered algorithm is developed to solve such time‐dependent crack propagation problems. In line with diffusive damage of the phase‐field approach for fracture; topological derivatives, which provide gradient information for the topology optimization in a LS framework, are derived for fracture mechanics problems. A reaction‐diffusion equation is adopted to update the LS function within a finite element framework. This avoids the reinitialization by overcoming the limitation to time step with the Courant‐Friedrichs‐Lewy condition. In this article, three numerical examples, namely, a L‐shaped section, a rectangular slab with predefined cracks, and an all‐ceramic onlay dental bridge (namely, fixed partial denture), are presented to demonstrate the effectiveness of the proposed LS based topology optimization for enhancing fracture resistance of multimaterial composite structures in a phase‐field fracture context.
Wu, C, Zheng, K, Fang, J, Steven, GP & Li, Q 2020, 'Time-dependent topology optimization of bone plates considering bone remodeling', Computer Methods in Applied Mechanics and Engineering, vol. 359, pp. 112702-112702.
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© 2019 Elsevier B.V. Bone plates have been widely used for the treatment of bone defects and trauma. These fixation plates can stabilize or replace bone tissue to restore appropriate load-bearing functionality. Nevertheless, the use of bone plates may lead to the stress shielding, thereby weakening prosthetic bone substitutes (e.g. bone graft or scaffolds) due to significant change in the biomechanical environment after implantation. To address this issue, we propose a time-dependent topology optimization procedure for the design of bone plates by taking into account bone remodeling. A solid isotropic material penalization (SIMP) model is used to interpolate design variables. The objective is to maximize total bone density within a reconstruction area at the final stage of bone remodeling, subject to a volume constraint of the bone plate and maximum allowable compliance of the prosthetic system. The sensitivity of bone density at the final stage is derived with respect to the topological variables of the plate in a step-wise manner. To facilitate sensitivity analysis, a bone remodeling rule is formulated in two different ways to accommodate a C1continuity. A jaw reconstruction problem is exemplified in this study to demonstrate the effectiveness of the proposed approach. Through this specific case, the non-differentiability issue due to the lazy zone of a remodeling rule is smoothed; and the proposed approach is also compared with that of a time-independent design. The effects of volume fraction and compliance constraints are also investigated to gain further insights into the design of prosthetic substitutes. Together with additive manufacturing technology, the proposed time-dependent topology optimization procedure is expected to form a useful tool for the design of implantable devices ensuring favorable long-term treatment outcomes.
Wu, L, Chen, X, Wei, W, Liu, Y, Wang, D & Ni, B-J 2020, 'A Critical Review on Nitrous Oxide Production by Ammonia-Oxidizing Archaea', Environmental Science & Technology, vol. 54, no. 15, pp. 9175-9190.
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The continuous increase of nitrous oxide (N2O) in the atmosphere has become a global concern because of its property as a potent greenhouse gas. Given the important role of ammonia-oxidizing archaea (AOA) in ammonia oxidation and their involvement in N2O production, a clear understanding of the knowledge on archaeal N2O production is necessary for global N2O mitigation. Compared to bacterial N2O production by ammonia-oxidizing bacteria (AOB), AOA-driven N2O production pathways are less-well elucidated. In this Critical Review, we synthesized the currently proposed AOA-driven N2O production pathways in combination with enzymology distinction, analyzed the role of AOA species involved in N2O production pathways, discussed the relative contribution of AOA to N2O production in both natural and anthropogenic environments, summarized the factors affecting archaeal N2O yield, and compared the distinctions among approaches used to differentiate ammonia oxidizer-associated N2O production. We, then, put forward perspectives for archaeal N2O production and future challenges to further improve our understanding of the production pathways, putative enzymes involved and potential approaches for identification in order to potentially achieve effective N2O mitigations.
Wu, L, Peng, L, Wei, W, Wang, D & Ni, B-J 2020, 'Nitrous oxide production from wastewater treatment: The potential as energy resource rather than potent greenhouse gas', Journal of Hazardous Materials, vol. 387, pp. 121694-121694.
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Nitrous oxide (N2O), produced from wastewater treatment, is a potent greenhouse gas and has become a global concern in recent years. However, N2O has also been commonly used as a powerful oxidant for energy generation. As such, an increasing effort has been devoted to explore the energy potential of N2O from wastewater treatment processes recently. Nevertheless, the holistic knowledge on energy recovery from nitrogen in wastewater is still lacking for facilitating its further development. Striving for sustainable wastewater treatment, this review paper aimed to give the up-to-date status on several essential aspects regarding the N2O recovery as an energy resource rather than emission as a greenhouse gas, including energy production via N2O decomposition, main biotic N2O production sources, the potential bioprocesses used for N2O recovery, and the possible N2O harvesting strategies. We then put forward perspectives for N2O recovery and future challenges to improve our understanding of the energy generation, microbial processes involved and harvesting approaches in order to potentially achieve sustainable wastewater treatment via N2O recovery.
WU, P, WU, C, LIU, Z & XU, S 2020, 'Numerical simulation of SHPB test of ultra-high performance fiber reinforced concrete with meso-scale model', SCIENTIA SINICA Physica, Mechanica & Astronomica, vol. 50, no. 2, pp. 024614-024614.
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Wu, S-L, Sun, J, Chen, X, Wei, W, Song, L, Dai, X & Ni, B-J 2020, 'Unveiling the mechanisms of medium-chain fatty acid production from waste activated sludge alkaline fermentation liquor through physiological, thermodynamic and metagenomic investigations', Water Research, vol. 169, pp. 115218-115218.
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Effective sludge treatment with bioenergy production is attracting increasing interests as large quantities of waste activated sludge (WAS) are produced during the wastewater treatment. In this study, a new biotechnical process for converting the WAS alkaline fermentation liquor (WASAFL) into valuable, easy-separated medium chain fatty acids (MCFAs) through chain elongation (CE) was investigated, which may provide a new insight into sludge treatment. In the process, ethanol was served as the electron donor (EDs) and WASAFL were main electron acceptors (EAs). The MCFAs productions were investigated under three different ED to EA ratios (i.e., 1:2, 1:1 and 2:1). The result showed that MCFAs production was increased from 2.88 ± 0.01 to 5.28 ± 0.18 g COD/L with the increase of ED to EA ratio. However, the highest MCFA selectivity was achieved at 72.9% when the ED to EA ratio was 1:1. The decrease in the selectivity at high ED:EA ratio is mainly due to the production of higher alcohol (i.e., n-butanol and n-hexanol). The thermodynamic analysis confirmed all CE processes for MCFAs production from WASAFL were exothermic reactions, with the spontaneity and energy release of the reactions increased with the ethanol level. The microbial community analysis showed that the relative abundances of Clostridium, Oscillibacter, Leptolinea and Exilispira were positively correlated with the MCFAs production. The metagenomic analysis suggested that both the reverse β-oxidization pathway and fatty acid biosynthesis pathway contributed to the CE process in the studied system. The functional enzymes were mainly associated within Clostridium, with Clostridium Kluyveri, Clostridium botulinum and Clostridium magnum being likely the key species responsible for the CE process.
Wu, S-L, Wei, W, Sun, J, Xu, Q, Dai, X & Ni, B-J 2020, 'Medium-Chain fatty acids and long-chain alcohols production from waste activated sludge via two-stage anaerobic fermentation', Water Research, vol. 186, pp. 116381-116381.
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Traditional bioenergy recovery in the form of short chain fatty acids (SCFAs) from waste activated sludge (WAS) is generally limited by economic unattractiveness and complexity of products separation. Herein, a novel biotechnology process of two-stage anaerobic fermentation for converting the WAS into high energy density, easy-separated medium chain fatty acids (MCFAs) and long-chain alcohols (LCAs) was evaluated. In this process, the WAS was first converted to WAS alkaline fermentation liquid (WASAFL), serving as electron acceptors (EAs) and inoculum, then adding ethanol as electron donor (ED) for chain elongation (CE). The co-production of MCFAs and LCAs during CE were studied under three different ED to EA ratios, i.e., 3:1, 4:1 and 5:1. Experimental results demonstrated that when the ratio of ED to EA increased from 3:1 to 5:1, the production of MCFA and LCAs respectively increased from 5.57 ± 0.17 and 2.58 ± 0.18 to7.67 ± 0.48 and 4.21 ± 0.19 g COD/L. A similar observation was made in the total product electron efficiency, increasing from 59.9% to 72.1%. However, the highest total product selectivity (i.e., 68.0%) and highest products production yield (i.e., 59.77%) were not achieved at the ED to EA ratio of 5:1 due to toxicity caused by higher accumulation of n-caproate. The kinetic analysis further confirmed that high ratio of ED to EA induced improvement in product maximum yield, production rate for both MCFAs and LCAs. Microbial community analysis indicated that Clostridium, Caproiciproducens, Acinetobacter, Exilispira, and Oscillibacter were clearly enriched in the CE reactor and had positive correlation with MCFAs and LCAs production.
Wu, Y, Fang, J, Cheng, Z, He, Y & Li, W 2020, 'Crashworthiness of tailored-property multi-cell tubular structures under axial crushing and lateral bending', Thin-Walled Structures, vol. 149, pp. 106640-106640.
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© 2020 Elsevier Ltd Thin-walled structures have been widely used as energy-absorbing components, which can be probably subjected to multiple loading conditions in real life, such as axial crushing and lateral bending. Most of the existing literature solely focuses on the pure axial crushing or lateral bending. In this paper, a novel tailored-property multi-cell tubular structure is proposed, where the material's ultimate strength at the corner region is increased to accommodate both the axial crushing and lateral bending conditions. Finite element (FE) models were developed and validated through experimental results. The FE models were used to investigate the crashworthiness performances of the tailored-property multi-cell tubes under axial crushing and lateral bending. Under both axial crushing and lateral bending, it was found that the tailored-property multi-cell tubes exhibited noticeable advantages over the corresponding traditional tubes. The tailoring ratio and thickness had a significant influence on the crashworthiness performance of the tailored-property multi-cell tubes. Moreover, the well-designed tailored-property multi-cell tubes could exhibit the progressive deformation mode under axial crushing. Furthermore, a theoretical model for the tailored-property multi-cell tubes under axial crushing was developed based on the Superfolding Element (SFE) Method. The results showed that the theoretical solutions were in good agreement with the finite element analysis results. The findings of this paper have the potential for energy absorption applications under different loading conditions.
Xie, F, Li, L, Sun, X, Hu, T, Song, K, Giesy, JP & Wang, Q 2020, 'A novel Mg(OH)2 binding layer-based DGT technique for measuring phosphorus in water and sediment', Environmental Science: Processes & Impacts, vol. 22, no. 2, pp. 340-349.
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Diffusive gradients in thin films (DGT) have gained wide attention for in situ measurement of reactive phosphorus species (PO4) in natural water, sediments and potentially soils.
Xie, J, Liu, C-H, Mo, Z, Huang, Y & Mok, W-C 2020, 'Near-field dynamics and plume dispersion after an on-road truck: Implication to remote sensing', Science of The Total Environment, vol. 748, pp. 141211-141211.
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Apart from the aerodynamic performance (efficiency and safety), the wake after an on-road vehicle substantially influences the tailpipe pollutant dispersion (environment). Remote sensing is the most practicable measures for large-scale emission control. Its reliability, however, is largely dictated by how well the complicated vehicular flows and instrumentation constraint are tackled. Specifically, the broad range of motion scales and the short sampling duration (less than 1 s) are the most prominent ones. Their impact on remote sensing has not been studied. Large-eddy simulation (LES) is thus employed in this paper to look into the dynamics and the plume dispersion after an on-road heavy-duty truck at speed U∞ so as to elucidate the transport mechanism, examine the sampling uncertainty and develop the remedial measures. A major recirculation of size comparable to the truck height h is induced collectively by the roof-level prevailing flows, side entrainment and underbody wall jet. The tailpipe is enclosed by dividing streamlines so the plume is carried back to the truck right after emission. The recirculation augments the pollutant mixing, resulting in a more homogeneous pollutant distribution together with a rather high fluctuating concentration (over 20% of the time-averaged concentrations). The plume ascends mildly before being purged out of the major recirculation to the far field by turbulence, leading to a huge reduction in pollutant concentration (an order of magnitude) outside the near wake. In the far-field, the plume is higher than the tailpipe and disperses in a conventional Gaussian distribution manner. Under this circumstance, a sampling duration for remote sensing longer than h/U∞ would be prone to underestimating the tailpipe emission.
Xie, S, Li, X, Wang, C, Kulandaivelu, J & Jiang, G 2020, 'Enhanced anaerobic digestion of primary sludge with additives: Performance and mechanisms', Bioresource Technology, vol. 316, pp. 123970-123970.
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Anaerobic digestion of primary sludge with different additives, namely nano magnetite, graphite powder, activated carbon powder and NiCl2/CoCl2, were evaluated by biomethane potential tests, kinetics modelling and microbial community analysis. Specific methane yields increased from 136 mL/g VS for primary sludge to 146 mL/g VS, 151 mL/g VS, and 152 mL/g VS for the addition of nano magnetite, graphite powder, and activated carbon powder at optimal dosages, respectively. The first order hydrolysis constant kh increased from 0.488 d-1 to 0.526 d-1, 0.622 d-1, and 0.724 d-1, respectively. Microbial community analysis revealed that the abundance of key bacterial and archaeal populations was positively correlated with hydrolysis and methane production. The enhanced methane production with activated carbon powder was due to shifting methane formation pathway from acetoclastic to hydrogenotrophic methanogenesis. In contrast, nano magnetite and graphite powder additives enhanced the direct interspecies electron transfer evidenced by increased abundance of Methanosaeta and Methanolinea.
Xie, S, Xia, R, Chen, Z, Tian, J, Yan, L, Ren, M, Li, Z, Zhang, G, Xue, Q, Yip, H-L & Cao, Y 2020, 'Efficient monolithic perovskite/organic tandem solar cells and their efficiency potential', Nano Energy, vol. 78, pp. 105238-105238.
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Xu, B, Ahmed, MB, Zhou, JL & Altaee, A 2020, 'Visible and UV photocatalysis of aqueous perfluorooctanoic acid by TiO2 and peroxymonosulfate: Process kinetics and mechanistic insights', Chemosphere, vol. 243, pp. 125366-125366.
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© 2019 Elsevier Ltd The global occurrence and adverse environmental impacts of perfluorooctanoic acid (PFOA) have attracted wide attention. This study focused on the PFOA photodegradation by using photocatalyst TiO2 with peroxymonosulfate (PMS) activation. Aqueous PFOA (50 mg L−1) at the pH 3 was treated by TiO2/PMS under 300 W visible light (400–770 nm) or 32 W UV light (254 nm and 185 nm). The addition of PMS induced a significant degradation of PFOA under powerful visible light compared with sole TiO2. Under visible light, 0.25 g L−1 TiO2 and 0.75 g L−1 PMS in the solution with the initial pH 3 provided optimum condition which achieved 100% PFOA removal within 8 h. Under UV light irradiation at 254 nm and 185 nm wavelength, TiO2/PMS presented excellent performance of almost 100% removal of PFOA within 1.5 h, attributed to the high UV absorbance by the photocatalyst. The intermediates analysis showed that PFOA was degraded from a long carbon chain PFOA to shorter chain intermediates in a stepwise manner. Furthermore, scavenger experiments indicated that SO4•–radicals from PMS and photogenerated holes from TiO2 played an essential role in degrading PFOA. The presence of organic compounds in real wastewater reduced the degradation efficacy of PFOA by 18–35% in visible/TiO2/PMS system. In general, TiO2/PMS could be an ideal and effective photocatalysis system for the degradation of PFOA from wastewater using either visible or UV light source.
Xu, B, Zhou, JL, Altaee, A, Ahmed, MB, Johir, MAH, Ren, J & Li, X 2020, 'Improved photocatalysis of perfluorooctanoic acid in water and wastewater by Ga2O3/UV system assisted by peroxymonosulfate', Chemosphere, vol. 239, pp. 124722-124722.
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© 2019 Elsevier Ltd Perfluorooctanoic acid (PFOA) has attracted considerable attention worldwide due to its widespread occurrence and environmental impacts. This research focused on the photocatalytic process for the treatment of PFOA in water and wastewater. Gallium oxide (Ga2O3) and peroxymonosulfate (PMS) were mixed directly in PFOA solution, which was irradiated under different light sources. The treatment system showed excellent performance that 100% PFOA was degraded within 90 min and 60 min under 254 nm and 185 nm UV irradiation, respectively. Moreover, the degradation efficacy was unaffected by initial PFOA concentration from 50 ng L−1 to 50 mg L−1. Acidic solution (pH 3) improved the degradation process. The quantum yield in the PMS/Ga2O3 system under UV light (254 nm) was estimated to be 0.009 mol E−1. Scavengers such as tert-butanol (t-BuOH), disodium ethylenediaminetetraacetate (EDTA-Na2) and benzoquinone (BQ) were added into PFOA solution to prove that sulfate radicals (SO4•–), superoxide radical (O2•–) and photogenerated electrons (e–) were the main active species with strong redox ability for PFOA degradation in PMS/Ga2O3/UV system. Combined with the intermediates analysis, PFOA was degraded stepwise from long chain compound to shorter chain intermediates. In addition, PFOA in real wastewater exhibited similar degradation efficiency, together with 75–85% TOC removal by Ga2O3/PMS under 254 nm UV irradiation. Therefore, Ga2O3/PMS system was highly effective for PFOA photodegradation under UV irradiation, which has potential to be applied for the perfluoroalkyl substances (PFAS) treatment in water and wastewater.
Xu, B-H, He, N, Jiang, Y-B, Zhou, Y-Z & Zhan, X-J 2020, 'Experimental study on the clogging effect of dredged fill surrounding the PVD under vacuum preloading', Geotextiles and Geomembranes, vol. 48, no. 5, pp. 614-624.
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Xu, D-S, Xu, X-Y, Li, W & Fatahi, B 2020, 'Field experiments on laterally loaded piles for an offshore wind farm', Marine Structures, vol. 69, pp. 102684-102684.
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© 2019 Elsevier Ltd Pile foundations are widely used to support offshore wind turbines due to their cost effectiveness and rapid constructions. Offshore piles must be designed with enough capacity to withstand overturning moments caused by wind turbines and other environmental factors such as wave excitations and extreme winds. In this study, a full-scale field experimental test is undertaken to determine the pile behaviour under various lateral loading conditions. A distributed fiber optic sensing technology is used to measure strains along two instrumented piles. The bending moments and lateral deflections are calculated from distributed fiber optic sensors, and then analysed with the various p-y methods. Field measurements indicated that for two offshore piles ZK01 and ZK28 with diameter of 2 m and length of 71.5 m and 77.5 m, the maximum lateral movements under a given lateral load of 800 kN were 369.1 mm and 351.7 mm, respectively. The maximum bending moment occurred at 6.5 m and 5.5 m below seabed level with the corresponding depth of 12.15D and 11.95D for pile ZK01 and ZK28, respectively. The position of “zero crossing” of soil resistance for two instrumented piles is almost the same, even though the piles have different lengths. The lateral deflections and bending moments of the two instrumented piles are predicted by the API and hyperbolic method, which indicates that the hyperbolic method yields larger prediction errors than the API method. A modified p-y approach is then proposed for more reliable predictions when compared with field measurements.
Xu, Q, Du, M, Liu, X, Wang, D, Wu, Y, Li, Y, Yang, J, Fu, Q, He, D, Feng, C, Liu, Y, Wang, Q & Ni, B-J 2020, 'Calcium peroxide eliminates grease inhibition and promotes short-chain fatty acids production during anaerobic fermentation of food waste', Bioresource Technology, vol. 316, pp. 123947-123947.
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Deterioration of anaerobic fermentation can occur with the presence of grease in food waste, but little information on eliminating this deterioration is currently available. In this study, it was found that the presence of 10 g/L grease decreased SCFAs production from 16.97 to 13.32 g COD/L and prolonged the optimal fermentation time to 7 days, but could be respectively recovered to 39.10 g COD/L and 4 days with 0.02 mg/g VS (volatile solids) calcium peroxide addition. Mechanism investigations indicated that calcium peroxide facilitated biodegradable organics release and improved grease degradation, thereby providing enough nutrients and better growth environments to microbes for SCFAs-producing, which could be further supported by the elevated enzymes activities responding to hydrolysis and acidification process. Further investigations revealed that among the main derivates of calcium peroxide, OH- and Ca2+ played vital role in SCFAs production promotion, O2- and OH radicals were the main contributors to grease degradation.
Xu, Q, Huang, Q-S, Wei, W, Sun, J, Dai, X & Ni, B-J 2020, 'Improving the treatment of waste activated sludge using calcium peroxide', Water Research, vol. 187, pp. 116440-116440.
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The treatment and disposal of waste activated sludge (WAS) has become one of the major challenges for the wastewater treatment plants (WWTPs) due to large output, high treatment costs and enriched substantial emerging contaminants (ECs). Therefore, reducing sludge volume, recovering energy and resource from WAS, and removing ECs and decreasing environmental risk have gained increasing attentions. Calcium peroxide (CaO2), a versatile and safe peroxide, has been widely applied in terms of WAS treatment including sludge dewatering, anaerobic sludge digestion and anaerobic sludge fermentation due to its specific properties such as generating free radicals and alkali, etc., providing supports for sludge reduction, recycling, and risk mitigation. This review outlines comprehensively the recent progresses and breakthroughs of CaO2 in the fields of sludge treatment. In particular, the relevant mechanisms of CaO2 enhancing WAS dewaterability, methane production from anaerobic digestion, short-chain fatty acids (SCFA) and hydrogen production from anaerobic fermentation, and the removal of ECs in WAS and role of experiment parameters are systematically elucidated and discussed, respectively. Finally, the knowledge gaps and opportunities in CaO2-based sludge treatment technologies that need to be focused in the future are prospected. The review presented can supply a theoretical basis and technical reference for the application of CaO2 for improving the treatment of WAS.
Xu, Q, Liu, X, Yang, G, Wang, D, Wu, Y, Li, Y, Huang, X, Fu, Q, Wang, Q, Liu, Y, Li, X & Yang, Q 2020, 'Norfloxacin-induced effect on enhanced biological phosphorus removal from wastewater after long-term exposure', Journal of Hazardous Materials, vol. 392, pp. 122336-122336.
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In this study, long-term experiments were performed under synthetic wastewater conditions to evaluated the potential impacts of norfloxacin (NOR) (10, 100 and 500 μg/L) on enhanced biological phosphorus removal (EBPR). Experimental result showed that long-term exposure to 10 μg/L NOR induced negligible effects on phosphorus removal. The presence of 100 μg/L NOR slightly decreased phosphorus removal efficiency to 94.41 ± 1.59 %. However, when NOR level further increased to 500 μg/L, phosphorus removal efficiency was significantly decreased from 97.96 ± 0.8 5% (control) to 82.33 ± 3.07 %. The mechanism study revealed that the presence of 500 μg/L NOR inhibited anaerobic phosphorus release and acetate uptake as well as aerobic phosphorus uptake during long-term exposure. It was also found that 500 μg/L NOR exposure suppressed the activity of key enzymes related to phosphorus removal but promoted the transformations of intracellular polyhydroxyalkanoate and glycogen. Microbial analysis revealed that that the presence of 500 μg/L NOR reduced the abundances of polyphosphate accumulating organisms but increased glycogen accumulating organisms, as compared the control.
Xu, S, Wu, P & Wu, C 2020, 'Calibration of KCC concrete model for UHPC against low-velocity impact', International Journal of Impact Engineering, vol. 144, pp. 103648-103648.
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Xu, Y, Peng, L, Liu, Y, Xie, G, Song, S & Ni, B-J 2020, 'Modelling melamine biodegradation in a membrane aerated biofilm reactor', Journal of Water Process Engineering, vol. 38, pp. 101626-101626.
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© 2020 Elsevier Ltd Membrane aerated biofilm reactor (MABR) system is excellent in developing slow growing microorganisms and treating micropollutants prior to entering the aquatic environment. In this work, a mathematical biofilm model was developed to assess melamine biodegradation under different conditions and to predict the profiles of melamine, nitrogen species and microbial biomass in the MABR system. Comtabolism linked to growth of ammonia oxidizing bacteria (AOB) or heterotrophic bacteria (HB) and their respective metabolism were involved in the model to contribute to melamine biodegradation. Results demonstrated the good predictive performance of the developed model in describing dynamic profiles of melamine, COD and nitrogen species in the MABR system. The relative contribution by AOB-induced cometabolism and metabolism by AOB and HB varied depending on the stratification of the biofilm system with AOB prevalent in the inner layer of the biofilm. Metabolism by AOB and HB played more important roles than AOB-induced cometabolism in melamine removal. Controlling optimal biofilm thickness in the suitable range (e.g., more than 750 μm) might realize better simultaneous removal of melamine and nitrogen. This work might provide further insight on efficient removal of melamine from wastewater.
Xue, C, Li, W, Castel, A, Wang, K & Sheng, D 2020, 'Effect of incompatibility between healing agent and cement matrix on self-healing performance of intelligent cementitious composite', Smart Materials and Structures, vol. 29, no. 11, pp. 115020-115020.
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Abstract Encapsulation-based intelligent self-healing cementitious composite with a potential of crack self-healing and closure is promising to recovery concrete from damage and improve the durability and serviceability of infrastructures. The efficiency of self-healing concrete were investigated, but limited studies have been conducted on effect of incompatibility between the self-healing agent and cement matrix on the cracking behaviour and recovery efficiency of crack-healed concrete. In this study, a coupled experimental and numerical investigations were adopted to understand the cracking behaviours of crack-healed cementitious composites using traction–separation law by extended finite element method (XFEM). Firstly, experimental investigation was conducted to characterize the properties and parameters of cement matrix and healing agent-crack interface to calibrate the traction–separation law. Then, various parameters of healing agent, cement matrix, and their interface on the performance of crack-healed cementitious composite was numerically analysed. The results indicate that to achieve excellent self-healing performance, it is vital to consider the incompatibility between healing agent and cement matrix in the design of intelligent self-healing cementitious composites.
Xue, C, Li, W, Qu, F, Sun, Z & Shah, SP 2020, 'Self-healing efficiency and crack closure of smart cementitious composite with crystalline admixture and structural polyurethane', Construction and Building Materials, vol. 260, pp. 119955-119955.
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© 2020 Elsevier Ltd The crack closure and self-healing efficiency of smart self-healing cementitious composite can effectively reveal the mechanism of self-healing performance recovery. This study focused on effects of crack healing on crack closure and mechanical performance recovery of crack-healed cementitious composite, including flexural compressive behaviours. Meanwhile, several parameters were defined to quantify the efficiency of mechanical performance recovery efficiency for self-healing cementitious composite. Furthermore, the interfaces between self-healing products and crack surface were analyzed and compared to provide understanding insight to the self-healing recovery. It is found that the bonding interface dominated the flexural strength recovery, and therefore autonomous self-healing yielded the maximum self-healing efficiency. On the other hand, the stiffness damage recovery index under compression is found to be an effective parameter to evaluate the inner crack healing, which slightly depends on the bonding interface. The related results indicate that the development of smart self-healing cementitious composite should consider the bonding between self-healing product and crack surface to improve the self-healing recovery efficiency for engineering application.
Xue, C, Li, W, Wang, K, Sheng, D & Shah, SP 2020, 'Novel experimental and numerical investigations on bonding behaviour of crack interface in smart self-healing concrete', Smart Materials and Structures, vol. 29, no. 8, pp. 085004-085004.
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© 2020 IOP Publishing Ltd. There are crack interfaces between self-healing agent and cement matrix in smart encapsulation-based self-healing concrete, whose mechanical properties significantly affects the load capacity recovery of crack-healed concrete. In this study, both experimental and numerical investigations were conducted on the crack-healed concrete under uniaxial tension to investigate the interface bonding behaviours and the self-healing agent distribution on the crack surface. The results show that the bonding behaviour of the crack interface depends on the content of healing agent and mechanical properties of the crack surface. However, it is still difficult to accurately understand their effects on the bonding behaviour by experimental investigation due to the high brittleness of the crack interface and the discrepancy of self-healing concrete. Therefore, based on the experimental results, a novel numerical model of the interface between self-healing agent and cement matrix was developed to investigate effects of aggregates, pores and interface properties on the bonding behaviour of crack interface by the cohesive surface technique (CS). Parametric analysis was also performed on the bonding behaviours and a method was proposed for assessing the load capacity of crack-healed concrete. Based on the experimental and numerical investigations on the healing agent-concrete crack interface in the smart encapsulation-based self-healing concrete, this novel numericla methods can be used to assess the recovery efficiency and performance of smart self-healing concrete structure.
Yadav, S, Ibrar, I, Altaee, A, Déon, S & Zhou, J 2020, 'Preparation of novel high permeability and antifouling polysulfone-vanillin membrane', Desalination, vol. 496, pp. 114759-114759.
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A novel high-performance nanofiltration membrane was fabricated by a simple and scalable route involving in situ cross-linking of hydrophilic, cheap, and environmentally friendly vanillin as antifouling agent with polysulfone (PSf) for salt rejection performance. Vanillin acts as a porogen, which induces a negative surface charge on the membrane surface due to the presence of polar functional groups like alcohol and aldehyde. The surface properties, including charge, morphology, and hydrophilicity, were investigated in detail using analytical instruments. The nanofiltration performance of the fabricated PSf-vanillin membranes was dependent on the percentage of vanillin added in the casting solution. The PSf-vanillin membrane antifouling tests were evaluated using 200 mg/L bovine serum albumin (BSA), and results showed 99% rejection with 88.55% flux recovery ratio. Performance studies were compared with commercially available TRISEP® UA60 nanofiltration membrane. PSf-vanillin membrane M2 showed higher MgSO4 (87.49%), NaCl (25.78%) rejection with excellent antifouling properties compared to commercial UA60 membrane. It is believed that charged membranes are the building blocks for the development of future generation desalination membranes possessing high permeability and selectivity index. The developed membranes have potential niche application in the pre-treatment of feed solution.
Yadav, S, Ibrar, I, Altaee, A, Samal, AK, Ghobadi, R & Zhou, J 2020, 'Feasibility of brackish water and landfill leachate treatment by GO/MoS2-PVA composite membranes', Science of The Total Environment, vol. 745, pp. 141088-141088.
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Two-dimensional (2D) based layered materials with tunable chemical functionalities and surface charge properties have emerged for on-demand applications including membrane technology. However, the process control, time and energy-efficient production of non-swelling graphene oxide (GO) with retaining physicochemical properties are still challenging. In this work, we have fabricated highly ordered GO membrane on cellulose acetate supporting membrane filters of 1.2 μm pore size using molybdenum disulphide (MoS2) as a nano-spacer and polyvinyl alcohol (PVA) as an adhesive for the first time with limited swelling. The fabricated membranes were used for NaCl rejection and removal of toxic heavy metal ions, and the radioactive element from landfill leachate water. The introduction of hydrophilic PVA, thickness control using a various amount of nanospacer and graphene oxide played a vital role in the transport mechanism, permeability, and selectivity index. The composition of PVA and MoS2 in the coating solution was optimized to tune the d-spacing of graphene oxide layers. The newly developed composite membranes have 89% rejection rate to NaCl and 3.96 L/m2h water flux at low operating pressures of 5 bar. Also, the prepared membranes have a high rejection of multivalent metal ions in landfill leachate. 86.5% to 99.8% rejection rate of multivalent metal ions in landfill leachate was observed for the M3 (GO (10): MoS2 (10): PVA (0.5)) membrane. The excellent rejection performance is ascribed to the combined impact of size exclusion, ion adsorption, electrostatic interaction and Gibbs-Donnan exclusion mechanism. The excellent stability and high rejection rate even after 216 h of operation make the fabricated membranes promising for use in practical water separation applications.
Yadav, S, Ibrar, I, Bakly, S, Khanafer, D, Altaee, A, Padmanaban, VC, Samal, AK & Hawari, AH 2020, 'Organic Fouling in Forward Osmosis: A Comprehensive Review', Water, vol. 12, no. 5, pp. 1505-1505.
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Organic fouling in the forward osmosis process is complex and influenced by different parameters in the forward osmosis such as type of feed and draw solution, operating conditions, and type of membrane. In this article, we reviewed organic fouling in the forward osmosis by focusing on wastewater treatment applications. Model organic foulants used in the forward osmosis literature were highlighted, which were followed by the characteristics of organic foulants when real wastewater was used as feed solution. The various physical and chemical cleaning protocols for the organic fouled membrane are also discussed. The study also highlighted the effective pre-treatment strategies that are effective in reducing the impact of organic fouling on the forward osmosis (FO) membrane. The efficiency of cleaning methods for the removal of organic fouling in the FO process was investigated, including recommendations on future cleaning technologies such as Ultraviolet and Ultrasound. Generally, a combination of physical and chemical cleaning is the best for restoring the water flux in the FO process.
Yadav, S, Saleem, H, Ibrar, I, Naji, O, Hawari, AA, Alanezi, AA, Zaidi, SJ, Altaee, A & Zhou, J 2020, 'Recent developments in forward osmosis membranes using carbon-based nanomaterials', Desalination, vol. 482, pp. 114375-114375.
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© 2020 Elsevier B.V. Contamination and industrial development are among the reasons for water quality deterioration beyond treatability by conventional processes. Unfortunately, conventional water and wastewater treatment technologies are not always capable of handling industrial wastewaters, and hence more advanced treatment technologies are required. The new trend of osmotically driven membrane technologies has demonstrated an exceptional efficiency for water purification and treatment including seawater desalination. Compared to pressure-driven membrane processes, forward osmosis (FO) technology, as a standalone process, is more energy-efficient, and less prone to membrane fouling than its predecessor reverse osmosis (RO) technology. However, forward osmosis suffers a severe concentration polarization that is acting on both sides of the membrane and results in a sharp decline in water flux. A thinner support layer has been recommended to lessen the concentration polarization impact in the FO process but a very thin support layer compromises the membrane mechanical strength. Recently, researchers have applied different carbon-based nanomaterials to enhance water flux, fouling propensity, and mechanical strength of the FO membrane. This work reviews advancement in the FO membrane fabrication using carbon nanomaterials to improve the membrane characteristics. Despite a large number of laboratory experiments, carbon-based nanomaterials in the FO membrane are still at the early-stage of laboratory investigation and no commercial products are available yet. The study also reviews the main challenges that limit the application of carbon-based nanomaterials for FO membranes.
Yan, B, Ma, J, Wu, D & Wriggers, P 2020, 'The analyses of dynamic response and reliability for failure-dependent stochastic micro-resonator with thermoelastic coupling effects', Applied Mathematical Modelling, vol. 77, pp. 1168-1187.
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© 2019 The Authors A crucial measure for the design of high-performance micro-resonators is to consider the randomness of structural parameters when analyzing the structural system reliability. In this work, the stochastic dynamic response analysis and subsequently, a dynamic reliability assessment of the random micro-resonators are originally presented, where the thermoelastic coupling effects are freshly incorporated in the models proposed. The dynamic characteristics equation of the deterministic micro-resonator is firstly established based on the finite element method. The random dynamic characteristics of the resonator are then solved by implementing the left and right eigenvectors and the block Lanczos algorithm, and the random temperature field and structural random dynamic stress are also tackled. Afterwards, the overall structural reliability is investigated with a comprehensive consideration of the strength failure and frequency resonance failure, in which the Copula function is used for describing the dynamic correlation between two failure modes. Finally, the feasibility and rationality of the method put forward are demonstrated via a practically motivated example.
Yang, G, Zhang, N, Yang, J, Fu, Q, Wang, Y, Wang, D, Tang, L, Xia, J, Liu, X, Li, X, Yang, Q, Liu, Y, Wang, Q & Ni, B-J 2020, 'Interaction between perfluorooctanoic acid and aerobic granular sludge', Water Research, vol. 169, pp. 115249-115249.
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The increasing use of perfluorooctanoic acid (PFOA) raises concerns about its potential toxicity to the environment. However, the interaction between PFOA and aerobic granular sludge has never been documented. This work therefore aims to provide such support through investigating the fate of PFOA at environmentally relevant levels in aerobic granular sludge systems and its impact on aerobic granular sludge. Experimental results showed that 32.0%∼36.4% of wastewater PFOA was removed by aerobic granular sludge in stable operation when PFOA concentration was ranged from 0.1 to 1.0 mg/L. Mass balance analyses and X-ray photoelectron spectroscopy survey scan revealed that the removal of PFOA was dominated by adsorption rather than biodegradation, and sorption kinetic analysis indicated that inhomogeneous multilayer adsorption was responsible for this removal. The adsorbed PFOA deteriorated the settleability of granular sludge and biological nitrogen and phosphorus removal significantly. Experimental results showed that 1.0 mg/L PFOA inhibited anaerobic phosphate release, aerobic phosphate uptake, nitrate reduction, and nitrite reduction processes by 60%, 50%, 13.1%, and 5.8%, respectively. It was observed that PFOA induced large amounts of filamentous villus growing on the surface and increased the extracellular polymeric substances of granular sludge. Fourier-transform infrared spectra and X-ray photoelectron spectroscopy spectrum showed that several function groups in extracellular polymeric substances such as hydroxyl groups, amides and polysaccharides were affected by PFOA. It was also found that PFOA inhibited the cyclic transformations of polyhydroxyalkanoates and glycogen. Microbial community analyses showed that PFOA decreased the abundances of Nitrosomonas, Nitrospira, Accumulibacter, and other function microbes such as Rhodospirillaceae, Thauera, and Azoarcus.
Yang, J, Liu, X, Liu, X, Xu, Q, Wang, W, Wang, D, Yang, G, Fu, Q, Kang, Z, Yang, Q, Liu, Y, Wang, Q & Ni, B-J 2020, 'Enhanced dark fermentative hydrogen production from waste activated sludge by combining potassium ferrate with alkaline pretreatment', Science of The Total Environment, vol. 707, pp. 136105-136105.
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© 2019 Alkaline pretreatment was demonstrated to be effective in the enhancement of hydrogen production. However, the sludge solubilization rate of alkaline pretreatment is still limited. This study reports a new strategy of K2FeO4 + pH 9.5 for sludge mesophilic anaerobic fermentation. Experimental results showed that the combination of K2FeO4/pH 9.5 pretreatment had a greater hydrogen yield than the individual K2FeO4 and pH 9.5. The maximum hydrogen yield was 19.2 mL per gram volatile suspended solids (VSS) under the optimal condition (0.02 g per gram total suspended solids K2FeO4 + pH 9.5). Kinetic analysis showed that the highest hydrogen production potential of 19.9 mL/g VSS was obtained in the combined reactor, which well fitted the first-order kinetic model (R2 = 0.9925). Besides, the fermentation type was mainly acetic and butyric in the combined reactor, which contributed to hydrogen production. Further analyses showed that the combined pretreatment reduced hydrogen sulfide yield, providing an environmentally friendly method to sludge treatment.
Yang, Q, Lyu, M & Zhu, X 2020, 'Nonlinear Connection Stiffness Identification of Heritage Timber Buildings Using a Temperature-Driven Multi-Model Approach', International Journal of Structural Stability and Dynamics, vol. 20, no. 10, pp. 2042001-2042001.
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‘Que-Ti’ is an important component in typical Tibetan heritage timber buildings and it performs similar to corbel brackets connecting beam and column in modern structures. It transfers shear, compression and bending moment by slippage and deformation of components as well as limited joint rotation. A rigorous analytical model of ‘Que-Ti’ is needed for predicting the behavior of a timber structure under extreme loadings. Few researches have been done on this topic, particularly with the parameters describing the performances of this connection subjected to external loads. In this paper, a new temperature-driven multimodel approach is proposed to identify the stiffness parameters of a ‘Que-Ti’ connection in its operating environment. Models with nonlinear compression and rotational springs have been developed to take into account the change of mechanical behavior of the ‘Que-Ti’ affected by the temperature variation in typical heritage Tibetan buildings. The column–beam connection is modeled as two nonlinear rotational springs and one nonlinear compressive spring. Ambient temperature variation is treated as a force function in the input (temperature)–output (local mechanical strains) relationship, and stiffness identification is conducted iteratively via correlating the calculated strain responses with measured data. The nonlinear model of the joint is reproduced with a number of linear local models in different deformation scenarios that are corresponding to different temperature ranges. The stiffness parameters can be identified using a multimodel approach. Numerical results show that the method is effective and reliable to identify the nonlinear connection stiffness of the ‘Que-Ti’ accurately with the temperature change even with 10% noise in measurements. The monitoring data from a long-term monitoring system installed in a typical heritage Tibetan building is used to further verify the method. The experimental results show that the identifie...
Yang, T, Liu, Z, Yang, Y & Wu, C 2020, 'Experimental investigation on behavior of ultra-high performance concrete after high temperature', Tumu yu Huanjing Gongcheng Xuebao/Journal of Civil and Environmental Engineering, vol. 42, no. 3, pp. 115-126.
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The apparent characteristics, mass loss and mechanical properties of ultra-high performance concrete after exposure to high temperature were studied through the high temperature heating test and the cubic compressive strength test. The effects of steel fiber, polypropylene fiber, steel fiber and polypropylene fiber on cracking suppression of ultra-high performance concrete were compared. The effects of temperature, fiber type and content, aggregate (quartz sand and steel slag) on the strength of ultra-high performance concrete were investigated. The test results show that 1% steel fibers and 2% polypropylene fibers can effectively restrain high temperature explosion behavior, and the specimen remains intact after high temperature. Ultra-high performance concrete with steel slag aggregate and hybrid fiber has excellent high temperature mechanical properties, the residual strength of 67% can still be maintained after being exposed to high temperature at 1 000℃. With the increase of temperature, the cubic compressive strength of ultra-high performance concrete increases first and then decreases. High temperature enhances the compressive ductility of ultra-high performance concrete when the target temperature is more than 600℃.
Yang, Y, Zang, Y, Hu, Y, Wang, XC & Ngo, HH 2020, 'Upflow anaerobic dynamic membrane bioreactor (AnDMBR) for wastewater treatment at room temperature and short HRTs: Process characteristics and practical applicability', Chemical Engineering Journal, vol. 383, pp. 123186-123186.
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© 2019 Elsevier B.V. An upflow anaerobic dynamic membrane bioreactor (AnDMBR) was set up for real domestic wastewater treatment at room temperature (20–25 °C) and short hydraulic retention time (HRT = 8 h, 4 h, 2 h, and 1 h). Following continuous operation for 93 days with stepwise decreased HRT, stable average chemical oxygen demand (COD) removal was achieved (between 77.3% and 70.6%) when HRT was reduced from 8 h to 4 h, then 2 h with flux varying from 22.5 to 90 L/m2·h. At these three HRTs, the rate of increase in trans-membrane pressure (TMP) was 0.4, 0.38, and 0.57 kPa/d, and average methane (CH4) production was 0.12, 0.10, and 0.08 L/g CODremoved, respectively. Furthermore, decreasing the HRT to 1 h resulted in less COD being removed (60.4%) and lower CH4 production (0.05 L/g CODremoved) as well as a faster rate of TMP increase (2.11 kPa/d). Various analytical methods were applied to characterize the morphology and composition of the dynamic membrane (DM) layers. Organic components analysis revealed that, with reduced HRT, there were apparent increases in soluble microbial products in the liquid phase and accumulation of tryptophan protein-like substances and aromatic protein-like substances in the DM layer, especially when the HRT was shortened to 1 h. Whilst the upflow AnDMBR proved applicable to wastewater treatment at room temperature with short HRTs, 2 h could be the HRT limit for maintaining stable operation.
Yao, M, Tijing, LD, Naidu, G, Kim, S-H, Matsuyama, H, Fane, AG & Shon, HK 2020, 'A review of membrane wettability for the treatment of saline water deploying membrane distillation', Desalination, vol. 479, pp. 114312-114312.
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© 2020 Elsevier B.V. Membrane distillation (MD) is an alternative membrane technology that offers the capacity to treat highly saline water including industrial wastewater, seawater, brine water from other processes, and oil-gas field produced water. However, conventional hydrophobic membranes suffer fast wetting and severe fouling especially when low surface tension chemicals exist in saline water, which compromises the performance of MD. Recent advances in material science and nanomaterials research have led to the incorporation of special wetting properties on membrane surfaces. Membranes with special wettability can achieve high resistance against membrane fouling and wetting, as well as overcome the trade-off between membrane permeability and selectivity. This review summarizes the progress and recent development of studies on MD membranes with special wettability. Firstly, the fundamental concepts pertaining to membrane surface wettability including insights of their benefits and potential issues are highlighted in this review. Secondly, fabrication methods and applications of membranes utilizing various special wettability are discussed in detail, along with their challenges. Finally, this review concludes the advantages of membranes with special wettability and demonstrates potential solutions to the above-mentioned challenges for future research in high saline wastewater treatment.
Yao, Z & Li, W 2020, 'Microstructure and thermal analysis of APS nano PYSZ coated aluminum alloy piston', Journal of Alloys and Compounds, vol. 812, pp. 152162-152162.
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© 2019 Elsevier B.V. Aluminium alloys in internal combustion (IC) engines may suffer from heat damage. Such heat damage can be mitigated using thermal barrier coatings (TBCs). In this study, the TBC Nano yttria partially stabilized zirconia (PYSZ) is applied as an aggregated powder to an aluminum alloy piston using an atmospheric plasma spray (APS) method. The preparation and application of the Nano PYSZ aggregated powder are critical to its effectiveness as a TBC. IC engine bench experiments were undertaken to provide a baseline against which the effectiveness of the TBC could be judged. The microstructure of the Nano PYSZ aggregated powder and thermal barrier coatings were examined using three instruments: scanning electron microscopy (SEM), field emission scanning electron microscopy (FESEM) and X-ray powder diffraction (XRD). Results from this study show that the Nano PYSZ ceramic TBCs, applied to the aluminum alloy piston using a plasma spraying technique, (a) has a high quality Nano-structure, (b) can effectively resist the thermal shock of high temperature gas in the cylinder and (c) maintains both stable macro characteristics and micro structure during the working cycle of the IC engine. The thermal insulation properties of TBCs were also examined. The thermal analyses describe the distribution of temperature across both the piston and the aluminum alloy substrate. Results desmonstrate the effectiveness of the TBCs in reducing the temperature of the aluminium alloy substrate at the top of piston. One benefit is that the piston can operate effectively at higher temperatures. Specifically, as the thickness of ceramic coating increased from 0.1 mm to 1.4 mm, the maximum temperature of the pistons coated with the TBCs increased from 399 °C to 665 °C. The maximum temperature of the aluminum alloy substrates simultaneously decreased from 336 °C to 241 °C. This study clearly demonstrates the excellent thermal insulation properties of the TBCs and shows...
Yariyan, P, Janizadeh, S, Van Phong, T, Nguyen, HD, Costache, R, Van Le, H, Pham, BT, Pradhan, B & Tiefenbacher, JP 2020, 'Improvement of Best First Decision Trees Using Bagging and Dagging Ensembles for Flood Probability Mapping', Water Resources Management, vol. 34, no. 9, pp. 3037-3053.
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Yau, YH, Wong, CM, Ong, HC & Chin, WM 2020, 'Application of the bin weather data for building energy analysis in the tropics', Energy Efficiency, vol. 13, no. 5, pp. 935-953.
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Ye, X, Wang, S, Li, Q, Zhang, S & Sheng, D 2020, 'Negative Effect of Installation on Performance of a Compaction-Grouted Soil Nail in Poorly Graded Stockton Beach Sand', Journal of Geotechnical and Geoenvironmental Engineering, vol. 146, no. 8, pp. 04020061-04020061.
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© 2020 American Society of Civil Engineers. In this study, a latex membrane with a diameter of 50 mm and thickness of 0.5 mm is used to encase an injection hole. The gap between the membrane and the nail rod is fixed to achieve compaction grouting and to prevent fracturing and permeating; hence, a regular grout bulb is easily formed and locked into the soil matrix to provide a pullout force for a compaction-grouted soil nail. For this type of soil nail, two series of physical model tests for an embedded soil nail and a soil nail with a predrilled hole (the soil sample was moistened and could sustain the hole without collapsing during the placement of the nail rod) were conducted to study the influence of the installation methods on the performance of a compaction-grouted soil nail. The results of the two series of tests were compared, and some conclusions were drawn: First, the aforementioned installation methods for a soil nail had little impact on the mass of injected grout, whereas the shape of the cured grout bulb showed some differences based on the type of soil response. Second, compared with that of an embedded soil nail, the pullout force of a postplaced soil nail remarkably decreased because the hole drilled for installation led to a gap between the soil nail and the surrounding soil. In addition, the loss rate correlated with the grouting pressure (i.e., the diameter of the grout bulb). Third, because of the lower soil densification, dilation, and squeeze effect, a slower growth rate (with increasing grouting pressure) of the pullout force (i.e., resistance) was found for the postplaced soil nail relative to that of the embedded soil nail, during which the efficiency of the increasing pullout force decreased.
Ye, Y, Ngo, HH, Guo, W, Chang, SW, Nguyen, DD, Zhang, X, Zhang, J & Liang, S 2020, 'Nutrient recovery from wastewater: From technology to economy', Bioresource Technology Reports, vol. 11, pp. 100425-100425.
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© 2020 Elsevier Ltd The recovery of fertilizer-used nutrients from wastewater is a sustainable approach for wastewater management and helping social sustainability. This is especially the case given the strict discharge requirements and shortages existing in nutrients supply. Recognizing that wastewater is a very useful resource and the value of recycled nutrients has made researchers consider the recovery of nutrients from wastewater. This review described the current technologies used to recover nutrients in wastewater treatment and their mechanisms, including chemical methods, biological technologies, membrane systems and advanced membrane systems. Also, an economic analysis of these nutrient recovery systems was discussed and compared them in terms of positive and negative aspects. The economic feasibility of recovered nutrients was investigated. Finally, future perspectives expects some possible research directions regarding recovery system which can be more economically accessible for wastewater treatment, in which the osmotic membrane bioreactors (OMBR) and bioelectrochemical systems (BES)-based hybrid systems are highly recommended.
Ye, Y, Ngo, HH, Guo, W, Chang, SW, Nguyen, DD, Zhang, X, Zhang, S, Luo, G & Liu, Y 2020, 'Impacts of hydraulic retention time on a continuous flow mode dual-chamber microbial fuel cell for recovering nutrients from municipal wastewater', Science of The Total Environment, vol. 734, pp. 139220-139220.
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Ying, J, Han, Z, Shen, L & Li, W 2020, 'Influence of Parent Concrete Properties on Compressive Strength and Chloride Diffusion Coefficient of Concrete with Strengthened Recycled Aggregates', Materials, vol. 13, no. 20, pp. 4631-4631.
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Parent concrete coming from a wide range of sources can result in considerable differences in the properties of recycled coarse aggregate (RCA). In this study, the RCAs were obtained by crushing the parent concrete with water-to-cement ratios (W/Cparent) of 0.4, 0.5 and 0.6, respectively, and were strengthened by carbonation and nano-silica slurry wrapping methods. It was found that when W/Cparen was 0.3, 0.4 and 0.5, respectively, compared with the mortar in the untreated RCA, the capillary porosity of the mortar in the carbonated RCA decreased by 19%, 16% and 30%, respectively; the compressive strength of concrete containing the carbonated RCA increased by 13%, 11% and 13%, respectively; the chloride diffusion coefficient of RAC (DRAC) containing the nano-SiO2 slurry-treated RCA decreased by 17%, 16% and 11%; and that of RAC containing the carbonated RCA decreased by 21%, 25% and 26%, respectively. Regardless of being strengthened or not, both DRAC and porosity of old mortar in RCAs increased with increasing W/Cparent. For different types of RCAs, DRAC increased obviously with increasing water absorption of RCA. Finally, a theoretical model of DRAC considering the water absorption of RCA was established and verified by experiments, which can be used to predict the DRAC under the influence of different factors, especially the water absorption of RCA.
Ying, X, Wang, Y, Li, W, Liu, Z & Ding, G 2020, 'Group Layout Pattern and Outdoor Wind Environment of Enclosed Office Buildings in Hangzhou', Energies, vol. 13, no. 2, pp. 406-406.
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This paper presents a study of the effects of wind-induced airflow through the urban built layout pattern using statistical analysis. This study investigates the association between typically enclosed office building layout patterns and the wind environment. First of all, this study establishes an ideal site model of 200 m × 200 m and obtains four typical multi-story enclosed office building group layouts, namely the multi-yard parallel opening, the multi-yard returning shape opening, the overall courtyard parallel opening, and the overall courtyard returning shape opening. Then, the natural ventilation performance of different building morphologies is further evaluated via the computational fluid dynamics (CFD) simulation software Phoenics. This study compares wind speed distribution at an outdoor pedestrian height (1.5 m). Finally, the natural ventilation performance corresponding to the four layout forms is obtained, which showed that the outdoor wind environment of the multi-yard type is more comfortable than the overall courtyard type, and the degree of enclosure of the building group is related to the advantages and disadvantages of the outdoor wind environment. The quantitative relevance between building layout and wind environment is examined, according to which the results of an ameliorated layout proposal are presented and assessed by Phoenics. This research could provide a method to create a livable urban wind environment.
Yu, Y, Gao, W, Castel, A, Liu, A, Chen, X & Liu, M 2020, 'Assessing external sulfate attack on thin-shell artificial reef structures under uncertainty', Ocean Engineering, vol. 207, pp. 107397-107397.
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© 2020 Elsevier Ltd Thin-shell artificial reef (AR) structures with spatial internal volumes have demonstrated superior stock recruitment ability and material efficiency than many gravity-based reef blocks, and cementitious materials, given the easy-to-tailor nature, remains the most popular in reef constructions to date. However, under constant seawater immersion, external sulfate attack (ESA) introduces a major and uncertain reliability concern to this type of AR system, due to the inherent material randomness. This study is concerned with developing a novel stochastic modelling framework for assessing the ESA under material uncertainty. In this paper, the main difficulty associated with the stochastic ESA modelling is identified for the first time, and a novel machine learning aided chemophysical modelling approach is proposed. The performance of the developed framework is carefully examined through the analyses on two types of cementitious materials under ESA.
Yu, Y, Gao, W, Castel, A, Liu, A, Feng, Y, Chen, X & Mukherjee, A 2020, 'Modelling steel corrosion under concrete non-uniformity and structural defects', Cement and Concrete Research, vol. 135, pp. 106109-106109.
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Reinforcement corrosion is one of the most frequent durability problems among ageing concrete structures. Macrocell corrosion is greatly affected by both concrete properties and the steel-concrete interfacial conditions. Inaccurate interpretations of these characteristics lead to unrealistic estimations of early corrosion propagation. Carbonation-induced macrocell corrosion, including the impact of structural defects formed by concrete casting, is addressed in this study. The non-uniform corrosion cell created due to the progressive carbonation of concrete is numerically obtained by combining chemophysical modelling and multiscale homogenisation. The macrocell corrosion under material non-uniformity is then studied by electrochemical modelling based on finite element method. The developed method is first validated against reported experiments to further initiate an in-depth discussion on the significance of material non-uniformity on corrosion modelling either with or without structural defects. The present study is particularly important for advancing the service life monitoring and assessment of ageing concrete structures.
Yu, Y, Royel, S, Li, Y, Li, J, Yousefi, AM, Gu, X, Li, S & Li, H 2020, 'Dynamic modelling and control of shear-mode rotational MR damper for mitigating hazard vibration of building structures', Smart Materials and Structures, vol. 29, no. 11, pp. 114006-114006.
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Abstract Magneto-rheological (MR) materials and their devices are being rapidly developed and have drawn surge of interest for the potential application in vibration control. Among them, a novel shear-mode rotational MR damper (SM-RMRD) with adaptive variable stiffness and damping was developed for adaptive structural control in real-time against different types of earthquakes. To make use of this innovative device perfectly, a robust and reliable model should be developed to simulate the nonlinear and hysteretic behaviours for the application in adaptive control. Accordingly, this research initially presents a new phenomenological model to describe the force response of the SM-RMRD. Then, model parameters are estimated based on experimental data of force, displacement and velocity, which were directly or indirectly obtained from the device under different loading protocols. The field dependence of each model parameter is also investigated so that a general model with current-related parameters is acquired for designing the control strategy. Using the current-dependent model of SM-RMRD, a semi-active controller is developed and implemented to the SM-RMRD to produce the feedback control for the structures in real-time. Finally, the effectiveness of proposed control method is appraised by a numerical study, in which an SM-RMRDs-incorporated three-storey building model with different control strategies are subjected to various scaled benchmark earthquakes. The comparison result verifies the excellent capacity of the proposed controller based on the developed phenomenological model in terms of reducing the storey acceleration and inter-storey drift.
Yu, Y, Subhani, M, Hoshyar, AN, Li, J & Li, H 2020, 'Automated Health Condition Diagnosis of in situ Wood Utility Poles Using an Intelligent Non-Destructive Evaluation (NDE) Framework', International Journal of Structural Stability and Dynamics, vol. 20, no. 10, pp. 2042002-2042002.
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Wood utility poles are widely applied in power transmission and telecommunication systems in Australia. Because of a variety of external influence factors, such as fungi, termite and environmental conditions, failure of poles due to the wood degradation with time is of common occurrence with high degree uncertainty. The pole failure may result in serious consequences including both economic and public safety. Therefore, accurately and timely identifying the health condition of the utility poles is of great significance for economic and safe operation of electricity and communication networks. In this paper, a novel non-destructive evaluation (NDE) framework with advanced signal processing and artificial intelligence (AI) techniques is developed to diagnose the condition of utility pole in field. To begin with, the guided waves (GWs) generated within the pole is measured using multi-sensing technique, avoiding difficult interpretation of various wave modes which cannot be detected by only one sensor. Then, empirical mode decomposition (EMD) and principal component analysis (PCA) are employed to extract and select damage-sensitive features from the captured GW signals. Additionally, the up-to-date machine learning (ML) techniques are adopted to diagnose the health condition of the pole based on selected signal patterns. Eventually, the performance of the developed NDE framework is evaluated using the field testing data from 15 new and 24 decommissioned utility poles at the pole yard in Sydney.
Yu, Y, Wu, D & Gao, W 2020, 'Stochastic chemo-physical-mechanical degradation analysis on hydrated cement under acidic environments', Applied Mathematical Modelling, vol. 78, pp. 75-97.
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© 2019 Elsevier Inc. The accumulation of material degradation under contact with aggressive aqueous environments could lead to reduced structural reliability. In terms of hydrated cementitious materials, such interactions often result in the chemo-physical-mechanical (CPM) degradation, which represents a multiphysics process of high non-linearity and complexity. By further considering the inevitable uncertainties associated with both the materials and the serving conditions, solving such a process requires novel probabilistic approaches. This paper presents a stochastic chemo-physical-mechanical (SCPM) degradation analysis on the hydrated cement under acidic environment. The SCPM analysis consists of modelling the stochastic chemophysical degradation by finite element method, and assessing the mechanical deterioration through analytical micromechanics. The proposed modelling framework couples the conventional Monte Carlo Simulation with a novel support vector regression algorithm. The present method is able to not only address the detailed degradation mechanisms, but also ensure low computational costs for an accurate SCPM degradation assessment.
Zang, Y, Yang, Y, Hu, Y, Ngo, HH, Wang, XC & Li, Y-Y 2020, 'Zero-valent iron enhanced anaerobic digestion of pre-concentrated domestic wastewater for bioenergy recovery: Characteristics and mechanisms', Bioresource Technology, vol. 310, pp. 123441-123441.
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Pre-concentrated domestic wastewater (PDWW) rich in organic matters can be a suitable substrate for anaerobic digestion (AD) towards holistic resource and bioenergy recovery. Micron zero-valent iron (ZVI) was applied in designed batch experiments during anaerobic treatment of PDWW to verify its roles in performance enhancement and associated mechanisms. In the selected range of food to microorganism (F/M) ratio, 0.5 gCOD/gMLVSS was most appropriate as biomethane production potential (BMP) of 0.275 L CH4/gCOD was obtained. The optimal ZVI dosage at fixed F/M of 0.5 was 6 g/L, further enhancing the BMP by 15.2%. Furthermore, ZVI improved the hydrolysis process (producing more soluble organics) and regulated acidification process (affecting volatile fatty acids distribution). No obvious impact on acetoclastic and hydrogenotrophic methanogenesis processes was noted with ZVI addition. ZVI based AD of the PDWW is promising for promoting the practical application of advanced domestic wastewater treatment strategy (pre-concentration plus anaerobic digestion).
Zeweldi, HG, Bendoy, AP, Park, MJ, Shon, HK, Kim, H-S, Johnson, EM, Kim, H, Lee, S-P, Chung, W-J & Nisola, GM 2020, 'Tetrabutylammonium 2,4,6-trimethylbenzenesulfonate as an effective and regenerable thermo-responsive ionic liquid drawing agent in forward osmosis for seawater desalination', Desalination, vol. 495, pp. 114635-114635.
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© 2020 Elsevier B.V. Efficient drawing agents are essential in forward osmosis (FO) for clean water production. Monomeric thermo-responsive ionic liquid (IL) [N4444]2,4,6-MeBnSO3 was thoroughly investigated as a drawing agent in FO. The IL can be safely employed due to its thermal stability and low cytotoxicity. It has a van't Hoff factor i = 1.21, with sufficient ionic strength to generate osmotic pressure ~ 58.92 bars (2 M). FO operations especially under PRO mode demonstrate that 2 M [N4444]2,4,6-MeBnSO3 can induce competitive water flux Jv ~ 12.3 L m−2 h−1 with remarkably low reverse solute flux Js < 0.006 mol m−2 h−1 and specific reverse solute flux Js/Jv ~ 4.5 × 10−4 mol L−1. Using 0.6 M NaCl as feed demonstrates its consistency in desalinating seawater (Jv ~ 3.72 L m−2 h−1, Js ~ 0.004 mol m−2 h−1, and Js/Jv ~ 0.91 × 10−3 mol L−1). After FO, [N4444]2,4,6-MeBnSO3 can be effectively retrieved (~98%) through thermal precipitation at 60 °C, above its cloud point temperature (57 °C). Meanwhile, >99% of the remaining 2% can be recovered through reverse osmosis or membrane distillation to produce water effluents with non-toxic IL concentrations (≪100 mg L−1). Results indicate that thermo-responsive [N4444]2,4,6-MeBnSO3 is a promising alternative reusable drawing agent in FO process.
Zhang, G, Li, Y, Yu, Y, Wang, H & Wang, J 2020, 'Modeling the non-linear rheological behavior of magnetorheological gel using a computationally efficient model', Smart Materials and Structures, vol. 29, no. 10, pp. 105021-105021.
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Abstract Magnetorheological (MR) gel is a novel generation of smart MR material, which has the inherent hysteretic properties and strain stiffening behaviors that are dependent on applied excitation, i.e. magnetic field. The main challenge for the application of the MR gel is the accurate reproduction of the above characteristics by a computationally efficient model that can predict the dynamic stress-strain/rate responses. In this work, parametric modeling on the non-linear rheological behavior of MR gel is conducted. Firstly, a composite MR gel sample was developed by dispersing carbon iron particles into the polyurethane matrix. The dynamic stress-strain/rate responses of the MR gel are obtained using a commercial rheometer with strain-controlled mode under harmonic excitation with frequencies of 0.1 Hz, 5 Hz and 15 Hz and current levels of 1 A and 2 A at a fixed amplitude of 10%. Following a mini-review on the available mathematical models, the experimental data is utilized to fit into the models to find the best candidate utilizing a genetic algorithm. Then, a statistical analysis is conducted to evaluate the model’s performance. The non-symmetrical Bouc–Wen model outperforms all other models in reproducing the non-linear behavior of MR gel. Finally, the parameter sensitivity analysis is employed to simplify the non-symmetrical Bouc–Wen model and then the parameter generalization is conducted and verified for the modified non-symmetrical Bouc–Wen model.
Zhang, H, Liang, X, Gao, Z & Zhu, X 2020, 'Seismic performance analysis of a large-scale single-layer lattice dome with a hybrid three-directional seismic isolation system', Engineering Structures, vol. 214, pp. 110627-110627.
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© 2020 Elsevier Ltd A large number of studies and applications have been carried out on horizontal seismic isolation systems, and their effectiveness has been indicated. For long-span spatial structures, vertical seismic load plays an important role. However, vertical seismic isolation technology has not been extensively investigated. In this paper, a hybrid bearing with three-directional seismic isolation effects is proposed, in which the triple friction pendulum component and the viscous damping component are combined in series. Compared with other seismic isolation systems, the advantages of this hybrid seismic isolation system are that it can not only greatly lengthen the structural periods but also dissipate the seismic energy in all three directions. A hybrid numerical modeling method for this hybrid seismic isolation bearing is also developed. The seismic performance of a welded large-scale single-layer lattice dome with this hybrid seismic isolation system subjected to near-field ground motions is analyzed. The results show that the important dynamic demands in the dome are significantly suppressed compared with the base-fixed dome. The seismic isolation effects are evaluated in all three directions, and the effectiveness of the hybrid isolation system is verified. Finally, a comparative study is performed, and the mechanical parameters of this hybrid bearing are discussed. It is found that the damping energy dissipation in the seismic isolation bearings is not the most important factor in reducing structural dynamic demands. The proposed seismic isolation system and its numerical modeling method provide an attractive and effective alternative for the design of long-span spatial structures with hybrid seismic isolation systems.
Zhang, H, Zhu, X & Yao, S 2020, 'Nonlinear dynamic analysis method for large-scale single-layer lattice domes with uncertain-but-bounded parameters', Engineering Structures, vol. 203, pp. 109780-109780.
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© 2019 Elsevier Ltd Currently, nonlinear dynamic analysis for large-scale single-layer domes is commonly performed using deterministic numerical methods. However, in practical engineering cases, complex large-scale single-layer domes have many uncertain parameters that cannot be considered using deterministic methods. Therefore, there is a growing awareness that classical deterministic methods need to be extended towards the introduction of the uncertain aspects in dynamic analysis, and a non-deterministic analysis method for large-scale spatial structures is required. In this paper, a new method is presented by introducing uncertainties into the nonlinear dynamic analysis for large-scale single-layer lattice domes. The method accounts for uncertainties in material properties, structural imperfections, loads, and damping with bounds. The focus is on the treatment of uncertainty in damping and the adopted geometric shape, which is different from that of conventional approaches. Finite element dynamic analyses for sample structures with multiple sources of uncertainty subjected to dynamic loads are performed. Results show that the variability of the variables with an associated uncertainty imposes significant negative effects on the dynamic properties, dynamic demands, and safety of a dome. Uncertain damping in a structure plays the most important role in determining structural performance. The numerical results reveal the differences between conventional analysis methods with deterministic parameters used in previous practical applications and the uncertain analysis method. Finally, a parametric study is performed, and the impacts of sample size on statistical dynamic demands, single uncertain source on structural failure, and single uncertain source on damping coefficients are discussed.
Zhang, L, Chen, Y, Ma, C, Liu, L, Pan, J, Li, B, Wu, X & Wang, Q 2020, 'Improving heavy metals removal, dewaterability and pathogen removal of waste activated sludge using enhanced chemical leaching', Journal of Cleaner Production, vol. 271, pp. 122512-122512.
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© 2020 In order to enhance heavy metals removal, two enhanced chemical leaching techniques were examined comparatively using NaClO and NaNO2 with the addition of FeCl3. The phosphorus release, dewaterability and pathogen removal of treated sludge were also examined after chemical leaching. The results showed that the heavy metals solubilization, improvement of dewaterability and pathogen removal were simultaneously achieved. Compared with NaClO treatment system, the better solubilization rates of Zn and Ni were observed in the NaNO2 treatment system. The improvement of Cu, Zn and Ni removal can be attributed to the disruption of the organically bound metal fraction based on metal distribution and EEM analysis. The TP loss caused by chemical leaching in this study was in the range of 47 %–54%. The treated sludge of the two systems could both meet Class A biosolids standards (US EPA) for land application. These results provided an alternative chemical leaching method for simultaneous improvement of sludge properties.
Zhang, S, Ly, QV, Nghiem, LD, Wang, J, Li, J & Hu, Y 2020, 'Optimization and organic fouling behavior of zwitterion-modified thin-film composite polyamide membrane for water reclamation: A comprehensive study', Journal of Membrane Science, vol. 596, pp. 117748-117748.
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© 2019 Membrane fouling can hinder the widespread application of thin film composite (TFC) reverse osmosis (RO) for water treatment. This study evaluated a novel zwitterion-grafted TFC RO as a mean to address organic fouling for water reclamation. The membrane exhibited the best permeability at the grafting condition of 45 °C in 1 h. This modified membrane consistently possessed improved antifouling ability irrespective of organic foulants. Among individual foulants, surfactant Dodecyl Trimethyl Ammonium Chloride (DTAC) posed the worst fouling potential due to its low molecular weight and positive charge, whereas fouling induced by other substances were relatively analogous and minor. In the mixture of DTAC and proteins, the former played a key role in governing the membrane fouling. While, their interplay affected membrane fouling, the fouling extent varied upon the membrane materials. The extended Derijaguin, Landau, Verwey and Overbeek (xDLVO) theory was unable to fully describe the interactions between surfactant foulants and the membrane materials. The complementary use of quartz crystal microbalance with dissipation (QCM-D), otherwise, concurred the fouling potential and gave the plausible interpretation for fouling mechanisms by providing insightful information of foulant layer on the polyamide-coated sensor. This study provided critical insights of organic foulants’ behavior on TFC RO membrane and offered the promising industrial implication of the novel membrane.
Zhang, S, Yan, H, Teng, J & Sheng, D 2020, 'A mathematical model of tortuosity in soil considering particle arrangement', Vadose Zone Journal, vol. 19, no. 1.
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AbstractTortuosity is an important parameter for studying the permeability of soil. Existing studies of soil tortuosity are usually of empirical nature and attempt to relate tortuosity to soil porosity alone. By assuming a laminar flow through the pores of two‐dimensional square solid particles, we present a mathematical model for calculating soil tortuosity under different particle arrangements. The effect of the randomness of the particle arrangement on the tortuosity is evaluated, which generates the variation range of the tortuosity. The proposed model provides the upper and lower bounds of the tortuosity, while existing empirical models tend to fall within these bounds. The consistency between the proposed model and the numerical calculation provides a validity for the proposed model.
Zhang, X, Li, W, Tang, Z, Wang, X & Sheng, D 2020, 'Sustainable regenerated binding materials (RBM) utilizing industrial solid wastes for soil and aggregate stabilization', Journal of Cleaner Production, vol. 275, pp. 122991-122991.
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© 2020 Elsevier Ltd This study presents an experimental investigation on a sustainable regenerated binding material (RBM), which is derived from several industrial solid wastes. Initially, the hydration process, mechanical behaviors, and microstructural characteristics of the RBM were investigated. Subsequently, the feasibility of RBM for the stabilization of macadam, expansive soil, and weathered sand was evaluated. The results reveal that in comparison with the ordinary Portland cement (OPC), the RBM exhibits a slightly faster hydration rate at the initial stage and comparable mechanical performance. For the stabilized macadam, the one stabilized by the RBM exhibits better unconfined compressive strength, scouring resistance and freeze-thaw resistance than the counterpart stabilized by OPC. Furthermore, the RBM can significantly improve the performance index of the expansive soil and weathered sand, and this enhancement is more significant as the RBM content increasing. Additionally, the RBM has been successfully applied in practical engineering, manifesting the promising application potential of the RBM. Overall, the excellent performance of RBM as an alternative stabilizer of the subgrade soil and aggregates can promote the application of the RBM low-carbon pavement construction in the future.
Zhang, X, Song, Z, Hao Ngo, H, Guo, W, Zhang, Z, Liu, Y, Zhang, D & Long, Z 2020, 'Impacts of typical pharmaceuticals and personal care products on the performance and microbial community of a sponge-based moving bed biofilm reactor', Bioresource Technology, vol. 295, pp. 122298-122298.
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Four lab-scale moving bed biofilm reactors (MBBRs) were built to treat simulated wastewater containing typical pharmaceuticals and personal care products (PPCPs). The efficiency in removing different PPCPs at different concentrations (1, 2 and 5 mg/L) and their effects on the performance of MBBRs were investigated. Results showed that the average removal efficiencies of sulfadiazine, ibuprofen and carbamazepine were 61.1 ± 8.8%, 74.9 ± 8.8% and 28.3 ± 7.4%, respectively. Compared to the reactor without PPCPs, the total nitrogen (TN) removal efficiency of the reactors containing sulfadiazine, ibuprofen and carbamazepine declined by 21%, 30% and 42%, respectively. Based on the microbial community analysis, increasing the PPCPs concentration within a certain range (<2 mg/L) could stimulate microbial growth and increase microbial diversity yet the diversity reduced when the concentration (5 mg/L) exceeded the tolerance of microorganisms. Furthermore the presence and degradation of different PPCPs resulted in a different kind of microbial community structure in the MBBRs.
Zhang, X, Zhang, Y, Ngo, HH, Guo, W, Wen, H, Zhang, D, Li, C & Qi, L 2020, 'Characterization and sulfonamide antibiotics adsorption capacity of spent coffee grounds based biochar and hydrochar', Science of The Total Environment, vol. 716, pp. 137015-137015.
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A large amount of spent coffee grounds is produced as a processing waste each year during making the coffee beverage. Sulfonamide antibiotics (SAs) are frequently detected in the environment and cause pollution problems. In this study, biochar (BC) and hydrochar (HC) were derived from spent coffee grounds through pyrolysis and hydrothermal carbonization, respectively. Their characteristics and sulfonamide antibiotics adsorption were investigated and compared with reference to adsorption capacity, adsorption isotherm and kinetics. Results showed BC possessed more carbonization and less oxygen-containing functional groups than HC when checked by Elemental Analysis, X-ray diffraction, X-ray photoelectron spectrometry and Fourier transform infrared. These groups affected the adsorption of sulfonamide antibiotics and adsorption mechanism. The maximum adsorption capacities of BC for sulfadiazine (SDZ) and sulfamethoxazole (SMX) were 121.5 μg/g and 130.1 μg/g at 25 °C with the initial antibiotic concentration of 500 μg/L, respectively. Meanwhile the maximum adsorption capacities of HC were 82.2 μg/g and 85.7 μg/g, respectively. Moreover, the adsorption mechanism for SAs adsorbed onto BC may be dominated by π-π electron donor-acceptor interactions, yet the SAs adsorption to HC may be attributed to hydrogen bonds. Further analysis of the adsorption isotherms and kinetics, found that physical and chemical interactions were involved in the SAs adsorption onto BC and HC. Overall, results suggested that: firstly, pyrolysis was an effective thermochemical conversion of spent coffee grounds; and secondly, BC was the more promising adsorbent for removing sulfonamide antibiotics.
Zhang, X, Zhang, Z, Liu, Y, Hao Ngo, H, Guo, W, Wang, H, Zhang, Y & Zhang, D 2020, 'Impacts of sulfadiazine on the performance and membrane fouling of a hybrid moving bed biofilm reactor-membrane bioreactor system at different C/N ratios', Bioresource Technology, vol. 318, pp. 124180-124180.
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The performance and membrane fouling of a hybrid moving bed biofilm reactor-membrane bioreactor (MBBR-MBR) system was evaluated when exposed to 0.5 mg/L of antibiotic sulfadiazine (SDZ). Results indicated that although SDZ reduced the removal efficiency of NH -N and TN (up to 12%) and TOC (up to 6%) at low C/N (2.5 and 4), it had no significant effect at high C/N (6 and 9). It was found that SDZ was removed 75% and 58% at high C/N of 9 and low C/N of 2.5, respectively. SDZ decreased the ratio of volatile biomass/total biomass and sludge particle size and increased the concentrations of extracellular polymeric substance (EPS) and soluble microbial product (SMP) in MBR. Consequently, this accelerated the membrane fouling rates, with an average increase of 6.85 kPa/d at low C/N (2.5) and 0.513–0.701 kPa/d at medium and high C/N (4, 6 and 9). 4 +
Zhang, Y-T, Wei, W, Huang, Q-S, Wang, C, Wang, Y & Ni, B-J 2020, 'Insights into the microbial response of anaerobic granular sludge during long-term exposure to polyethylene terephthalate microplastics', Water Research, vol. 179, pp. 115898-115898.
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The negative effects of ubiquitous microplastics on wastewater treatment have attracted increasing attention. However, the potential impacts of microplastics on anaerobic granular sludge (AGS) remain unknown. To fill this knowledge gap, this paper investigated the response of AGS to the exposure of model microplastics (polyethylene terephthalate (PET-MPs)) and provided insights into the mechanisms involved. The 84 days' long-term exposure experiments demonstrated that PET-MPs, at relatively low level (15 MP L-1) did not affect AGS performance during anaerobic wastewater treatment, while 75-300 MP L-1 of PET-MPs caused the decreases of COD removal efficiency and methane yields by 17.4-30.4% and 17.2-28.4%, accompanied with the 119.4-227.8% increase in short-chain fatty acid (SCFA) accumulation and particle breakage. Extracellular polymeric substances (EPS) analysis showed that dosage-dependent tolerance of AGS to PET-MPs was attributed to the induced EPS producing protection role, but PET-MPs at higher concentrations (75-300 MP L-1) suppressed EPS generation. Correspondingly, microbial community analysis revealed that the populations of key acidogens (e.g., Levilinea sp.) and methanogens (e.g., Methanosaeta sp.) decreased after long-term exposure to PET-MPs. Assessment of the toxicity of PET-MPs revealed that the leached di-n-butyl phthalate (DBP) and the induced reactive oxygen species (ROS) by PET-MPs were causing toxicity towards AGS, confirmed by the increases in cell mortality and lactate dehydrogenase (LDH) release. These results provide novel insights into the ecological risk assessment of microplastics in anaerobic wastewater treatment system.
Zhang, Y-T, Wei, W, Sun, J, Xu, Q & Ni, B-J 2020, 'Long-Term Effects of Polyvinyl Chloride Microplastics on Anaerobic Granular Sludge for Recovering Methane from Wastewater', Environmental Science & Technology, vol. 54, no. 15, pp. 9662-9671.
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Polyvinyl chloride microplastics (PVC-MPs) are emerging contaminants affecting biological wastewater treatment processes. However, most of the previous studies mainly focused on their short-term impacts on floc sludge, with little work being conducted to explore their potential effects on more complex anaerobic granular sludge (AGS), which has been widely used for high-strength organic wastewater treatment. In this paper, the long-term effects of PVC-MPs on AGS were investigated via continuous feeding tests that are representative of real wastewater treatment processes. The results of a continuous 264 days test showed that the prolonged exposure of PVC-MPs at 15-150 MPs·L-1 significantly (p = 7.86 × 10-37, 3.44 × 10-43, and 5.29 × 10-46) inhibited the COD removal efficiency of AGS by 13.2%-35.5%, accompanied by a 11.0%-32.3% decreased production of methane and 40.3%-272.7% increased accumulation of short-chain fatty acids (SCFAs). In addition, the PVC-MPs exposure suppressed the secretion of extracellular polymeric substances (EPS), causing AGS and the inside microorganisms to lose the protection of EPS, thereby resulting in granule breakage and decreased cells viability. Aligning with the deteriorated performance, the long-term exposure of PVC-MPs reduced the total microbial populations and the relative abundances of key methanogens and acidogens. A toxicity mechanism assessment revealed that the negative impacts induced by PVC-MPs are mainly attributed to the toxic leachate and excess oxidative stress.
Zhang, Z, He, N, He, B, Xu, B & Jiang, Y 2020, 'New method to measure structure stress based on distributed optical fiber technology', Yi Qi Yi Biao Xue Bao/Chinese Journal of Scientific Instrument, vol. 41, no. 9, pp. 45-55.
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Stress and deformation monitoring is the significant content for evaluating the structure working characteristics and safety. On the basis of the research results of existing distributed optical fiber sensing technology, this paper optimizes the strain and deformation fitting algorithm is optimized. Aiming at the two cases of concentrated force and multi-point force a distributed structural stress measurement method is troposed based on optical fiber sensing technology. The bending moment and shear force calculation program is written. Through the indoor test of square steel and H-steel beam, the force magnitude and position fitting of the measurement method is studied. The study results show that the fitting values of the measurement method agree well with the theoretical values in terms of bending moment and shear force. The maximum average relative error of shear position fitting in square steel test is only 2.75%, and average relative error of shear force fitting at most stress points is less than 6%, The larger the strain of the stress point is, the higher the fitting accuracy of shear force position and shear force magnitude can be. At the same time, the measurement method can match the accuracy upgrade of the optical fiber measurement equipment. With the improvement of the accuracy specification, more details of the data changes can be captured and the distributed measurement of more stress points can be realized. The measurement method was applied to an example of foundation pit excavation with SMW retaining structures, which can accurately reflect the stress changes of H-steel pile in the excavation process, and has certain engineering practicability.
Zhao, E & Wu, C 2020, 'Unified egg ellipse critical threshold estimation for the deformation behavior of ultrahigh arch dams', Engineering Structures, vol. 214, pp. 110598-110598.
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© 2020 Elsevier Ltd This paper presents an innovative critical threshold estimation approach using unified egg-shaped ellipsoid modelling to study the deformation behavior of ultrahigh arch dams. First, the deformation variation law is regarded as a direct indicator of the overall stability and potential damage of ultrahigh arch dams based on comprehensively comparison with the results of theoretical calculations, experimental tests, numerical simulations and monitoring data. Subsequently, a novel geometric center of an irregular deformation plane constituted by all the deflection curves is proposed according to the measured distribution characteristics of the deformation spatial fields of the Xiaowan and Jinping I arch dams. Furthermore, unified egg-shaped ellipse equations are proposed to systematically identify the deformation critical attributes of Jinping I dam. Eventually, based on the peaks over threshold model, critical indexes are estimated considering the abnormal probabilities. The proposed methods are applied to Xiaowan dam as well. Results demonstrate that unified ellipsoid modelling can uniformly describe the abnormal features of the deformation behaviors of different ultrahigh arch dams, thereby the universal structural evolution characteristics to be understood in a wider range during their long-term operations.
Zhao, E, Wu, C, Wang, S, Hu, J & Wang, W 2020, 'Seepage dissolution effect prediction on aging deformation of concrete dams by coupled chemo-mechanical model', Construction and Building Materials, vol. 237, pp. 117603-117603.
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© 2019 Elsevier Ltd Concrete dams undergo a seepage dissolution process because of huge reservoir water pressure and concrete permeability, and such dissolution weakens the mechanical properties of concrete and produces a certain amount of irreversible aging deformation. This study proposes a coupled chemo-mechanical model to predict the seepage dissolution effect on aging deformation of concrete dams. The interactions between elastic–plastic, chemical damage and mechanical damage are jointly explored combining with on-site inspection of long-term service performance of a concrete gravity dam firstly. Then an aging model of the seepage dissolution damage is digitized, and a novel model on chemo-mechanical coupled effect is put forward by introducing an overall chemo-mechanical damage scalar. The validity of the model is proved by a case study on the gravity dam through finite element simulation on its seepage dissolution and comparison with monitoring data. Finally, these methods are applied into an ultra-high arch dam to quantitatively calculate the irreversible aging deformation with the increase of the seepage dissolution degree. And the annual maximum aging deformation of the arch dam increases 0.65 mm after 100 years. The results indicate that the proposed model can effectively predict the aging deformation caused by the seepage dissolution during long-term operation of concrete dams.
Zhao, S, Dou, P, Song, J, Nghiem, LD, Li, X-M & He, T 2020, 'Direct preparation of dialysate from tap water via osmotic dilution', Journal of Membrane Science, vol. 598, pp. 117659-117659.
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© 2019 Elsevier B.V. Preparation of dialysate for hemodialysis (or dialysis) requires dilution of the dialysis concentrate with purified water. Present practice contains two steps: first to purify water, and then water is transported to clinic to mix with the dialysate concentrate before treatment. As a new forward osmosis dialysis hybrid process, based on osmotic dilution, is evaluated for decentralized health care systems. A commercial cellulose triacetate (CTA) and a tailor-made thin film composite (TFC) polyamide FO membranes were examined. The rejection of salts in tap water by the FO membranes was investigated, and the real rejections of various ions as a function of permeate flux were well described by using a irreversible thermodynamic model. The hollow fiber TFC FO membrane showed higher water flux and lower reverse salt flux than the CTA membrane in diluting process. Both steric hindrance and electrostatic repulsion explained the rejection behavior of the membranes to the ions. Higher rejections of anions were obtained than cations, which was attributed to the anions selection characteristics of the membranes. No obvious foulings or scalings were observed in a relatively long time osmotic dilution process over 5 repeated cycles. The stable, high efficient osmotic dilution process in hemodialysis holds a strong promise in reducing the consumption of purified water or even eliminating the water purification step. This work provides a potentially new platform hemodialysis which can be portable and implementable away from major hospitals and major clinics.
Zheng, J, He, X, Li, Y, Zhao, B, Ye, F, Gao, C, Li, M, Li, X & E, S 2020, 'Viscoelastic and Magnetically Aligned Flaky Fe-Based Magnetorheological Elastomer Film for Wide-Bandwidth Electromagnetic Wave Absorption', Industrial & Engineering Chemistry Research, vol. 59, no. 8, pp. 3425-3437.
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Zhou, X, Gururajan, R, Li, Y, Venkataraman, R, Tao, X, Bargshady, G, Barua, PD & Kondalsamy-Chennakesavan, S 2020, 'A survey on text classification and its applications', Web Intelligence, vol. 18, no. 3, pp. 205-216.
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Text classification (a.k.a text categorisation) is an effective and efficient technology for information organisation and management. With the explosion of information resources on the Web and corporate intranets continues to increase, it has being become more and more important and has attracted wide attention from many different research fields. In the literature, many feature selection methods and classification algorithms have been proposed. It also has important applications in the real world. However, the dramatic increase in the availability of massive text data from various sources is creating a number of issues and challenges for text classification such as scalability issues. The purpose of this report is to give an overview of existing text classification technologies for building more reliable text classification applications, to propose a research direction for addressing the challenging problems in text mining.
Zhou, X, Jin, W, Wang, Q, Guo, S, Tu, R, Han, S-F, Chen, C, Xie, G, Qu, F & Wang, Q 2020, 'Enhancement of productivity of Chlorella pyrenoidosa lipids for biodiesel using co-culture with ammonia-oxidizing bacteria in municipal wastewater', Renewable Energy, vol. 151, pp. 598-603.
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© 2019 Elsevier Ltd As one of the most promising renewable energy, microalgal biodiesel has been widely studied worldwide. However, the low-efficiency of conventional microalgae cultivation procedures restrict the development of microalgae biodiesel production. Microalgal-bacterial symbiosis could both enhance the growth of algal-bacterial culture and promote the removal and conversion of wastewater nutrients. In this study, three strains of high-efficient heterotrophic ammonia-oxidizing bacteria JN1, FN3, and FN5 were screened from municipal wastewater treatment system with over 80% degradation rates of 50 mg/L ammonia-nitrogen (NH3–N) in 24 h. Among them, FN5, belonging to Kluyvera sp., had the optimum effect on enhancing growth of oil-rich microalga Chlorella pyrenoidosa. In stationary phase, the biomass and lipid content of Chlorella pyrenoidosa was14.8% and 13.6% higher than the blank control tests without FN5. In contrast, JN1 and FN3 failed to enhance the growth of Chlorella pyrenoidosa. After the cultivation of Chlorella pyrenoidosa-FN5 consortia in municipal wastewater, the degradation rate of NH3–N was up to 91% while the content of microalgae biomass and lipid attained 0.35 g/L and 39.0%. The Saturated fatty acids (SFAs), Monounsaturated fatty acids (MUFAs), and Polyunsaturated fatty acids (PUFAs) were 43.9, 37.1 and 19.0%, respectively, which had the potential for biodiesel production after pretreatment.
Zhu, D, Indraratna, B, Poulos, H & Rujikiatkamjorn, C 2020, 'Field study of pile – prefabricated vertical drain (PVD) interaction in soft clay', Canadian Geotechnical Journal, vol. 57, no. 3, pp. 377-390.
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Piles and prefabricated vertical drains (PVDs) are two well-established inclusions used by geotechnical practitioners when dealing with soft compressible foundations. Induced movements in highly compressible soil can adversely influence the pile response by inducing additional movements and stresses in the piles. Especially, undesirable soil–pile interaction often leads to the development of excess pore-water pressure during pile installation and negative skin friction caused by the settlement of compressible soil surrounding the piles. Additional drainage by PVDs prior to the installation of a pile could reduce excess pore-water pressure, lateral soil movement, and negative skin friction on the pile. In this paper, full-scale field testing on two trial embankments built on soft soil is reported and the relative behaviour of these two embankments is compared and discussed. Soft soil underneath both embankments was consolidated before one pile was installed at the centre of each embankment. The pore-water pressure, lateral soil movement, surface settlement, and associated strain at the pile shaft were recorded. The pile capacity was tested immediately and 3 h after pile installation. The monitoring and testing results indicated that preconsolidation with PVDs before piling can effectively reduce the excess pore-water pressure, lateral soil movement, and downdrag on the pile.
Zhu, LF, Ke, LL, Xiang, Y & Zhu, XQ 2020, 'Free vibration and damage identification of cracked functionally graded plates', Composite Structures, vol. 250, pp. 112517-112517.
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© 2020 Elsevier Ltd This paper investigates the free vibration and crack identification of functionally graded material (FGM) plates with a through-width edge crack. The material properties of the FGM plates change continuously with the power law distribution along the plate thickness direction. The crack in an FGM plate is simulated as a massless rotational spring and the plate is separated into two sub-plates at the crack location connected by the line spring. The stress intensity factor (SIF) in the FGM strip is calculated to determine the stiffness of the spring. The governing equations of cracked FGM plates are derived from the Mindlin plate theory and solved by the differential quadrature (DQ) method to obtain modal parameters. The vibrational mode of a cracked FGM plate is analyzed by utilizing continuous wavelet transform (CWT). A novel damage index (DI) is developed based on calculated wavelet coefficients to localize the crack in FGM plates. This method can localize the crack accurately and reduce the edge effect even with the measurement noise.
Zhu, L-F, Ke, L-L, Xiang, Y, Zhu, X-Q & Wang, Y-S 2020, 'Vibrational power flow analysis of cracked functionally graded beams', Thin-Walled Structures, vol. 150, pp. 106626-106626.
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© 2020 Elsevier Ltd In this paper, the vibrational power flow of a cracked beam made of functionally graded materials (FGMs) is investigated. The Young's modulus and mass density change exponentially along the thickness direction of the beam. The cracked FGM beam is divided into two sub-beams at the crack section which are connected by a massless rotational spring. Based on the Timoshenko beam theory, the governing equations of the cracked FGM beam are derived by using the neutral plane as the reference plane. The dynamic response of the FGM beam subjected to a harmonic concentrated transverse force is solved by the wave propagation approach. The input power flow and the transmitted power flow are obtained. The effect of the crack location and depth and the Young's modulus ratio on the input power flow and the transmitted power flow is studied in detail. A new damage index (DI) for the crack identification of FGM beams is proposed by applying continuous wavelet transform (CWT) to the transmitted power flow distribution along the beam longitudinal direction. The peak of DI indicates the crack location in FGM beams with small crack depth.
Zhu, Y, Ouyang, L, Zhong, H, Liu, J, Wang, H, Shao, H, Huang, Z & Zhu, M 2020, 'Closing the Loop for Hydrogen Storage: Facile Regeneration of NaBH4 from its Hydrolytic Product', Angewandte Chemie International Edition, vol. 59, no. 22, pp. 8623-8629.
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AbstractSodium borohydride (NaBH4) is among the most studied hydrogen storage materials because it is able to deliver high‐purity H2 at room temperature with controllable kinetics via hydrolysis; however, its regeneration from the hydrolytic product has been challenging. Now, a facile method is reported to regenerate NaBH4 with high yield and low costs. The hydrolytic product NaBO2 in aqueous solution reacts with CO2, forming Na2B4O7⋅10 H2O and Na2CO3, both of which are ball‐milled with Mg under ambient conditions to form NaBH4 in high yield (close to 80 %). Compared with previous studies, this approach avoids expensive reducing agents such as MgH2, bypasses the energy‐intensive dehydration procedure to remove water from Na2B4O7⋅10 H2O, and does not require high‐pressure H2 gas, therefore leading to much reduced costs. This method is expected to effectively close the loop of NaBH4 regeneration and hydrolysis, enabling a wide deployment of NaBH4 for hydrogen storage.
Zhu, Y, Ouyang, L, Zhong, H, Liu, J, Wang, H, Shao, H, Huang, Z & Zhu, M 2020, 'Closing the Loop for Hydrogen Storage: Facile Regeneration of NaBH4 from its Hydrolytic Product', Angewandte Chemie, vol. 132, no. 22, pp. 8701-8707.
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AbstractSodium borohydride (NaBH4) is among the most studied hydrogen storage materials because it is able to deliver high‐purity H2 at room temperature with controllable kinetics via hydrolysis; however, its regeneration from the hydrolytic product has been challenging. Now, a facile method is reported to regenerate NaBH4 with high yield and low costs. The hydrolytic product NaBO2 in aqueous solution reacts with CO2, forming Na2B4O7⋅10 H2O and Na2CO3, both of which are ball‐milled with Mg under ambient conditions to form NaBH4 in high yield (close to 80 %). Compared with previous studies, this approach avoids expensive reducing agents such as MgH2, bypasses the energy‐intensive dehydration procedure to remove water from Na2B4O7⋅10 H2O, and does not require high‐pressure H2 gas, therefore leading to much reduced costs. This method is expected to effectively close the loop of NaBH4 regeneration and hydrolysis, enabling a wide deployment of NaBH4 for hydrogen storage.
Zhu, Y, Ouyang, L, Zhong, H, Liu, J, Wang, H, Shao, H, Huang, Z & Zhu, M 2020, 'Efficient Synthesis of Sodium Borohydride: Balancing Reducing Agents with Intrinsic Hydrogen Source in Hydrated Borax', ACS Sustainable Chemistry & Engineering, vol. 8, no. 35, pp. 13449-13458.
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© 2020 American Chemical Society. Sodium borohydride (NaBH4) has been identified as one of the most promising hydrogen storage materials; however, it is still challenging to produce NaBH4 with low cost and high efficiency, which are largely determined by the sources of boron and hydrogen and reducing agents used. Herein, we report an economical method to produce NaBH4 by ball milling hydrated borax (Na2B4O7·10H2O and/or Na2B4O7·5H2O) with different reducing agents such as MgH2, Mg, and NaH under ambient conditions. The direct use of natural hydrated borax avoids the dehydration process (at 600 °C) and consequently reduces cost and improves overall energy efficiency. A high yield of 93.1% can be achieved for a short ball mill duration (3.5 h) for Na2B4O7·5H2O-NaH-MgH2 system. In this system, H2 is generated in situ which subsequently reacts with Mg forming MgH2. Low cost Mg is therefore employed to replace the majority of MgH2, leading to an attractive yield of 78.6%. To further reduce the cost of raw materials and improve the utilization of hydrogen source in the hydrated borax, Na2B4O7·10H2O is used to partially substitute for Na2B4O7·5H2O, leading to a complete replacement of MgH2. Compared with literature results, the optimized recipe features low cost and high efficiency since it utilizes hydrogen from the hydrated water in natural borax and avoids high temperatures. Our finding is expected to facilitate applications of NaBH4 for hydrogen storage.
Zhuang, L-L, Li, M & Hao Ngo, H 2020, 'Non-suspended microalgae cultivation for wastewater refinery and biomass production', Bioresource Technology, vol. 308, pp. 123320-123320.
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Zhuang, Y, Chi, H, Huang, Y, Teng, Q, He, B, Chen, W & Qian, Y 2020, 'Investigation of water spray evolution process of port water injection and its effect on engine performance', Fuel, vol. 282, pp. 118839-118839.
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© 2020 Elsevier Ltd In this study, a 1.5L turbocharged gasoline direct injection (GDI) engine was modified by installing a port water injection (PWI) system adjacent to the intake valve to simulate the “quasi-direct” water injection. Experiments was performed at 1500 rpm wide throttle open (WOT) condition to investigate the effect of PWI on knock suppression, and 4850 rpm WOT condition to test the removal of fuel enrichment through PWI. Then, numerical simulation was conducted to investigate the water spray evolution process and subsequent influence on mixture formation. The experimental results showed that PWI could effectively suppress knock and decrease combustion temperature. Therefore, at 4850 rpm WOT condition, the engine was able to operate at a stoichiometric air/fuel ratio with moderate advancement of spark timing. The combined effect finally resulted in nearly 6% thermal efficiency improvement. At 1500 rpm WOT, 3.8% efficiency gain was achieved solely due to knock mitigation. Nitrogen oxides (NOx), soot and hydrocarbon (HC) emissions also showed a decreasing trend with the increase of water injection amount. The simulation results indicated that about 80% of total injected water collided on the inner surface of the intake port which became the major source of water vapor. The portion of water vaporized in the air is small. Sufficient time was important for intake port water film evaporation. PWI also resulted in in-cylinder wall wetting. The in-cylinder water wall wetting in 4850 rpm was sober than that at 1500 rpm due to stronger intake air motion and higher cylinder temperature. Although port water injection imposes limited impacts on the whole in-cylinder equivalent ratio, it can induce part fuel-rich zones inside the combustion chamber.
Zhuang, Y, Sun, Y, Huang, Y, Teng, Q, He, B, Chen, W & Qian, Y 2020, 'Investigation of water injection benefits on downsized boosted direct injection spark ignition engine', Fuel, vol. 264, pp. 116765-116765.
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© 2019 Elsevier Ltd Engine downsizing and boosting are key technologies to achieve the increasingly stringent emissions standards for spark ignition (SI) engines. However, knock is a major obstacle inhibiting further downsizing of SI engines. Water injection is a promising technology that has regained attention recently to solve the knock problem. In this paper, a 1.5L turbocharged gasoline direct injection (GDI) engine was modified by installing a water port injection (WPI) system on the intake manifold. The WPI system was modified from a GDI system and deionized water was pressured to 50 bar in a water tank by compressed nitrogen. The effect of WPI on engine combustion and emissions performance were experimentally investigated under different water/gasoline volume percentages and WPI timings. The results show that WPI has great potential in suppressing engine knock. At original engine setting (without adjustment of spark timing), all the combustion indexes related to knock are decreased by WPI, including maximum in-cylinder pressure (Pmax) and maximum pressure rise rate (Rmax). The flame kernel formation process (CA0-5), initiation combustion duration (CA0-10), early combustion duration (CA0-50) and major combustion duration (CA0-90) are deteriorated, resulting in decreased indicated mean effective pressure (IMEP) and thermal efficiency. By properly advancing spark timing, the combustion process can be improved, allowing the engine to achieve higher Pmax and better combustion phases without occurrence of knock. It is also found that the water/gasoline volume percentage should be kept within a proper range (30% in this study) because over WPI can lead to deterioration of combustion and pollutant emissions. WPI can effectively reduce the production of NO and CO emissions, while HC emissions are increased with the rise of water/gasoline volume percentage.